EP0758624B1 - Installation de remplissage stérile de bouteilles suivant un cycle continu - Google Patents
Installation de remplissage stérile de bouteilles suivant un cycle continu Download PDFInfo
- Publication number
- EP0758624B1 EP0758624B1 EP96830270A EP96830270A EP0758624B1 EP 0758624 B1 EP0758624 B1 EP 0758624B1 EP 96830270 A EP96830270 A EP 96830270A EP 96830270 A EP96830270 A EP 96830270A EP 0758624 B1 EP0758624 B1 EP 0758624B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- bottles
- sterile
- group
- operative
- plant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B55/00—Preserving, protecting or purifying packages or package contents in association with packaging
- B65B55/02—Sterilising, e.g. of complete packages
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67C—CLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
- B67C3/00—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus; Filling casks or barrels with liquids or semiliquids
- B67C3/001—Cleaning of filling devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67C—CLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
- B67C7/00—Concurrent cleaning, filling, and closing of bottles; Processes or devices for at least two of these operations
- B67C7/0073—Sterilising, aseptic filling and closing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67C—CLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
- B67C3/00—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus; Filling casks or barrels with liquids or semiliquids
- B67C3/02—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus
- B67C3/22—Details
- B67C3/26—Filling-heads; Means for engaging filling-heads with bottle necks
- B67C2003/2688—Means for filling containers in defined atmospheric conditions
Definitions
- the invention relates to a continuous-cycle sterile bottling plant.
- This kind of plant is already known, and comprises operative groups acting on bottles transiting along a feed line.
- these plants are provided with a number of successive operative groups, including a sterilizing group, a washing group, a filler group and a capping group.
- the whole plant is located in a slightly pressurized atmosphere, in which operators follow and check the operativity of the plant. Obviously the operators wear special garb to prevent contamination of the sterile environment.
- the environment, or chamber, housing the plant has to be sterilized carefully, while the bottling plant itself has to be completely and scrupulously sterilized both internally and externally.
- the external parts are cleaned with sterilizing fluids while the internal parts are subject to a mock functioning cycle during which sterilizing fluid instead of product is circulated.
- the filler group heads are opened by the bottle necks and mouths, in order to complete this mock cycle dummy bottles are used, whose function is to open the filler heads.
- the dummy bottles are loaded by hand by one or more operators; this operation therefore involves considerable preparation time as there is a considerable number of dummy bottles to be loaded.
- GB 2 280 669 discloses a plant as in the preamble of claim 1.
- each operative group comprises a sterile chamber crossed by the bottles.
- Each sterile chamber has walls and is kept slightly pressurized, and represents a sterile zone containing a part of a relative operative group.
- the various sterile chambers are interconnected.
- One of the operative groups is provided upstream for sterilizing bottles.
- Each of the operative groups downstream of the sterilizing group is kept slightly pressurized. This plant can obviate the above-mentioned drawbacks in the prior art, but it exhibites further drawbacks.
- the operators In the first place the operators must don protective garb if they have to access to the motor and the mobile organs of the plant.
- the sterilization fluids injected into the sterile chamber can spread into the adjacent chambers.
- the main aim of the invention is to obviate the above-mentioned drawbacks in the prior art by providing a sterile bottling plant which is rapidly and easily sterilizable and which can be kept sterile in a sure but relatively simple and economical way.
- An advantage of the invention is that it relieves operators of the need to wear protective garb.
- a further aim of the invention is to provide a sterilizing method for the bottle filler group which is both simple and economical, as well as a filler group for using with said method.
- 1 denotes in its entirety a continuous-cycle sterile bottling plant comprising a feed line 2 of bottles 3.
- the bottles 3 are fed one after another to a plurality of operative groups 10, 20, 30, 40, each of which is provided with commandable mobile organs, for acting on the transiting bottles 3.
- each operative group is provided with motorization for moving the bottles 3 as well as means for commanding the movement of the mobile organs.
- the plant 1 comprises a sterilizing group 10, a washing group 20, a filler group 30 and a capping group 40.
- the motors, of known type, for each group are indicated by 5, 6, 7 and 8.
- Two tilting devices 6' are provided for tilting the bottles 3.
- the mobile organs of the various groups are also of known type and are denoted by 11, 21, 29 and 44.
- 11 denotes a vertical pipe for the passage of the sterilizing liquid
- 21 denotes a further vertical pipe for the passage of the washing fluid.
- Each pipe 11 and 21 is vertically slidable with respect to a respective hub 12 and 22 with a sterile barrier.
- Each pipe 11 and 21 superiorly bears a nozzle which can be inserted into a bottle, and through which the relative sterilizing or washing fluid is injected thereinto by spraying.
- Each operative group comprises a respective sterile chamber 10a, 20a, 30a, 40a which is crossed by the bottles 3.
- Each sterile chamber is enclosed by walls 4 and is kept slightly pressurized, and constitutes a sterile zone containing part of the relative operative group.
- At least one wall 4a of the walls 4 of each sterile chamber sealedly separates a relative sterile zone from the motor for the movement of the bottles 3 as well as the means for commanding the movement of the bottles 3 and the means for commanding the mobile organs of the relative operative group.
- the motor and the means for commanding are thus outside the sterile zone.
- the various sterile chambers for each operative group are interconnected.
- the sterile chamber 10a of the sterilizing group 10 is kept at a slightly lower pressure than the sterile chambers of the other operative groups.
- An aperture 13 is provided for placing the sterile chamber 10a for sterilizing in communication with the external atmosphere.
- the filler group 30 is rotary and comprises an entrance 31 and an exit 32 for the bottles 3.
- the filler group 30 is provided with a vertical-axis rotating shaft 25 which rotates a plurality of support organs 33, each of which transports, at each rotation, a bottle 3 from the entrance 31 to the exit 32.
- Each support organ 33 is vertically mobile on command.
- a filler head 34 is associated to each support organ 33, which filler head 34 is connected to means for dispensing the product destined to fill the bottles 3.
- the means for dispensing comprise a plurality of product dispensing pipes 35.
- Each filler head 34 opens, dispensing the product, by means of upwards pressure thereon.
- An annular cam 36 acts on the support organs 33, following a rotation of the latter, to command vertical displacements thereof.
- the cam 36 acts by means of a plurality of vertical-axis shafts 29, one for each support organ 33, which slide vertically in a hub 28 with a sterile barrier.
- Each shaft 29 is superiorly solidly connected to a respective support organ 33 and is coupled inferiorly with the cam 36 by means of a wheel 27.
- Means for positioning 37 are provided for positioning (on command) the cam 36 in a vertical direction. Further, fixed superiorly to each support organ 33 a contact element 39 is arranged such as to exert an upward pressure on the respective filler head 34 when contact is made there-between, which upward pressure is sufficient to cause the filler head 34 to open.
- the contact element 39 is preferably forked, and a bottle neck 5' of a bottle to be filled is inserted into the fork.
- the means for positioning comprise one or more vertical-axis jacks 37 arranged below the cam 36 externally of the sterile zone 30a. Each jack 37 is provided with a vertical-axis rack and a command mechanism, not illustrated. The mechanism can be operated by hand using a gripping organ or crank 38. The upper end of the rack presses on the base of the cam 36 to be lifted.
- the cam 36 acts on the support organs 33 and consequently on the contact element 39 provided for interacting with the respective filler head 34, opening same.
- the capping group 40 comprises a vertical-axis central drive shaft 41 and a disc 42 which latter is fixed coaxially to the drive shaft 41 and is provided at a periphery thereof with means for sealing 43 with an upper wall 4b of the relative sterile chamber 40a.
- the capping group 40 comprises a plurality of rods 44 inferiorly provided with a chuck 45 for capping a respective bottle 3. Each rod 44 is set in rotation by the drive shaft 41 and is mobile on command in a vertical direction passing sealedly through a respective hub 48 with sterile barrier solidly mounted on the disc 42.
- the capping group 40 is further provided with a cap feed line 46 along which the caps 47 undergo a sterilization operation.
- the filler heads 34 are supplied with a sterilization fluid.
- the cam 36 is lifted in order to raise the relative support organs 33 and, consequently, the contact elements 39 which latter exert an upwards pressure against the filler heads 34 which is sufficient to open the filler heads 34.
- the group is operated in this manner for the length of time necessary for sterilizing the dispensing pipes 35 through which during normal functioning the product to be bottled passes.
- the sterilization fluid flows into the chamber 30a and is collected at the bottom thereof. If necessary more than one sterilization and washing liquid can be dispensed.
- the jacks 37 are brought into a lowered position so that the contact elements 39 do not interact with the filler heads 34.
- the operators stay out of the sterile zones and can thus gain easy access to the motor and the mobile organs of the plant without having to don protective garb.
- the sterile chamber 10a of the sterilizing group is kept at a slightly lower temperature with respect to the other sterile chambers, the eventuality of passage of gas into the other chambers can be precluded. This prevents the sterilization fluids injected into the sterile chamber 10a from spreading into the adjacent chambers.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Filling Of Jars Or Cans And Processes For Cleaning And Sealing Jars (AREA)
- Basic Packing Technique (AREA)
- Medicines Containing Plant Substances (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Claims (7)
- Une installation de remplissage stérile de bouteilles suivant un cycle continu, comprenant:une ligne d'alimentation (2) de bouteilles (3);une pluralité de groupes opératifs (10, 20, 30, 40), chacun desquels est pourvu d'organes mobiles sur commande pour agir sur les bouteilles (3) transitant sur ladite ligne d'alimentation (2) et d'un moteur pour commander lesdits organes mobiles;pour chacun des groupes opératifs (10, 20, 30, 40), une chambre stérile (10a, 20a, 30a, 40a) traversée par les bouteilles (3), laquelle chambre stérile (10a, 20a, 30a, 40a) est délimitée par des parois (4) et représente une zone stérile contenant une partie du relatif groupe opératif (10, 20, 30, 40), les différentes chambres stériles pour chaque groupe opératif étant interconnectées;un desdits groupes opératifs (10) étant prévu pour stériliser les bouteilles (3), les autres groupes opératifs étant maintenus légèrement pressurisés;au moins une paroi (4a) de chaque chambre stérile sépare de manière étanche une relative zone stérile dudit moteur et desdits moyens pour commander lesdits organes mobiles du relatif groupe opératif;la chambre stérile (10a) dudit groupe de stérilisation est maintenue légèrement pressurisée à une pression légèrement inférieure à celle de la chambre stérile d'autres groupes opératifs.
- Une installation selon la revendication 1, caractérisée en ce qu'une ouverture (13) est prévue pour placer la chambre stérile (10a) du groupe de stérilisation en communication avec l'atmosphère externe.
- Une installation selon la revendication 1 ou 2, comprenant un groupe opératif pour remplir les bouteilles (3) comprenant:une pluralité d'organes de support (33) pour les bouteilles (3), mobiles sur commande dans une direction verticale, à chacun desquels est associée une tête de remplissage (34), laquelle est reliée à un conduit d'alimentation (35) d'un produit destiné à remplir lesdites bouteilles (3), laquelle tête de remplissage (34) s'ouvre pour délivrer ledit produit au moyen d'une pression vers le haut;une came (36) agissant sur lesdits organes de support (33) pour commander des déplacements verticaux;un élément de contact (39), solidaire de chacun desdits organes de support (33), conformé et disposé de manière à exercer sur une respective tête de remplissage (34), lorsqu'il entre en contact avec celle-ci, une pression vers le haut suffisante pour causer son ouverture;des moyens (37) pour positionner sur commande ladite came (36) dans une direction verticale.
- Une installation selon la revendication 3, caractérisée en ce que lesdits moyens de positionnement comprennent au moins un vérin (37) à axe vertical opérativement associé à ladite came (36).
- Une installation selon la revendication 3 ou 4, caractérisée en ce que ledit élément de contact (39) est en forme de fourche, et en ce que ce dernier accueille un col (5') d'une bouteille (3) devant être remplie.
- Une installation selon n'importe laquelle des revendications précédentes, caractérisée en ce que:elle comprend un groupe opératif pour boucher, comprenant un arbre moteur (41) central à axe vertical et un disque (42) fixé coaxialement audit arbre moteur (41) et étant pourvu sur sa périphérie de moyens d'étanchéité (43) avec une paroi supérieure (4b) d'une relative chambre stérile (40a);une pluralité de tiges (44), munies inférieurement d'un mandrin (45) pour boucher une bouteille (3) et entrainées en rotation par ledit arbre moteur (41), sont mobiles sur commande dans une direction verticale et chacune desquelles passant de manière étanche au travers d'un moyeu (48) pourvu d'une barrière stérile, monté solidairement dudit disque (42).
- Une installation selon n'importe laquelle des revendications précédentes, caractérisée en ce que l'un desdits groupes opératifs est un groupe de remplissage des bouteilles, comprenant:une entrée (31) et une sortie (32) pour lesdites bouteilles (3);une pluralité d'organes de support (33), chacun desquels se déplace cycliquement sur commande pour transporter une bouteille (3) de ladite entrée (31) à ladite sortie (32), chacun desdits organes de support (32) étant mobile sur commande dans une direction verticale;une pluralité de têtes de remplissage (34), chacune desquelles étant associée à l'un des organes de support (33), étant reliée à un conduit d'alimentation (35) d'un produit destiné à remplir les bouteilles (3), et s'ouvrant pour délivrer ledit produit au moyen d'une pression vers le haut;une came (36) qui agit sur lesdits organes de support (33) pour causer leur déplacement en direction verticale;un élément de contact (39), solidaire de chacun desdits organes de support (33), conformé et disposé de manière à exercer sur une respective tête de remplissage (34), lorsqu'il est en contact avec celle-ci, une pression vers le haut suffisante pour causer son ouverture;des moyens (37) pour positionner sur commande ladite came (36) dans une direction verticale.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT95MO000120A IT1279846B1 (it) | 1995-08-11 | 1995-08-11 | Impianto di imbottigliamento asettico in continuo |
ITMO950120 | 1995-08-11 | ||
AU71878/96A AU727925B2 (en) | 1995-08-11 | 1996-11-20 | A continuous-cycle sterile bottling plant |
JP8317923A JPH10157797A (ja) | 1995-08-11 | 1996-11-28 | 連続サイクル無菌瓶詰め工場および瓶充填グループならびに瓶充填グループ滅菌方法 |
US08/767,628 US5848515A (en) | 1995-08-11 | 1996-12-17 | Continuous-cycle sterile bottling plant |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0758624A1 EP0758624A1 (fr) | 1997-02-19 |
EP0758624B1 true EP0758624B1 (fr) | 2002-08-07 |
Family
ID=27423772
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96830270A Expired - Lifetime EP0758624B1 (fr) | 1995-08-11 | 1996-05-09 | Installation de remplissage stérile de bouteilles suivant un cycle continu |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0758624B1 (fr) |
JP (1) | JPH10157797A (fr) |
AT (1) | ATE221855T1 (fr) |
AU (1) | AU727925B2 (fr) |
DE (1) | DE69622800T2 (fr) |
ES (1) | ES2180724T3 (fr) |
IT (1) | IT1279846B1 (fr) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19731796A1 (de) * | 1997-07-24 | 1999-01-28 | Kronseder Maschf Krones | Verfahren und Vorrichtung zum hochreinen Abfüllen von Getränken in Flaschen |
DE19921274A1 (de) * | 1999-05-07 | 2000-11-09 | Ruediger Haaga Gmbh | Maschinenanlage zum Befüllen von Behältern mit Füllgut |
CN1177753C (zh) * | 1999-09-07 | 2004-12-01 | 阿尔科阿德意志大地有限公司 | 一种灌装容器的灌装设备及其使用方法 |
DE19947786A1 (de) * | 1999-10-05 | 2001-04-19 | Bosch Gmbh Robert | Verpackungsmaschine, insbesondere zum Abfüllen und Verschliessen von flüssigen Pharmazeutika enthaltenden Behältnissen |
DE19956186A1 (de) * | 1999-11-22 | 2001-05-23 | Krones Ag | Verfahren und Vorrichtung zum Sterilisieren von Verpackungsbehältern |
JP4547828B2 (ja) | 2001-04-19 | 2010-09-22 | 大日本印刷株式会社 | 容器搬送システム |
DE10145803C2 (de) * | 2001-09-17 | 2003-10-02 | Alfill Engineering Gmbh & Co K | Behälterbehandlungsmaschine mit abgeschlossenem Raum |
EP1357081B1 (fr) * | 2002-04-22 | 2005-02-16 | Krones Ag | Machine de remplissage aseptique |
DE10352016B3 (de) | 2003-11-07 | 2005-08-11 | Khs Maschinen- Und Anlagenbau Ag | Verschließmaschine zum Verschließen von Gefäßen |
DE102004005342B4 (de) | 2004-02-04 | 2006-01-26 | Khs Maschinen- Und Anlagenbau Ag | Anlage zum aseptischen Abfüllen eines flüssigen Füllgutes |
CN100428962C (zh) * | 2004-03-31 | 2008-10-29 | I.M.A.工业机械自动装置股份公司 | 用于塑料材料容器灭菌和灌装液体物质的方法和设备 |
FR2882341B1 (fr) | 2005-02-23 | 2009-11-20 | Serac Group | Installation de conditionnement aseptique a zones tampon aseptiques |
ITBO20060682A1 (it) * | 2006-10-03 | 2008-04-04 | Sympak Corazza S P A | Apparecchiatura per il confezionamento di un prodotto. |
KR100792680B1 (ko) | 2007-06-13 | 2008-01-09 | 박인만 | 충진 장치 |
DE102007047733A1 (de) * | 2007-10-05 | 2009-04-09 | Krones Ag | Flaschenbehandlungsanlage mit Sicherheitseinrichtung |
DE202007017932U1 (de) | 2007-12-22 | 2008-10-02 | Krones Ag | Anordnung zum Bearbeiten von Getränkeeinheiten |
ITBO20080255A1 (it) * | 2008-04-23 | 2009-10-24 | Azionaria Costruzioni Macchine Spa | Struttura di copertura per macchine e/o blocchi di macchine per il confezionamento di contenitori, in particolare per macchine tappatrici. |
DE102008056241A1 (de) * | 2008-11-06 | 2010-05-12 | Krones Ag | Verschlussvorrichtung für Behältnisse |
DE102009008138A1 (de) * | 2009-02-09 | 2010-08-19 | Khs Ag | Transportsystem für Flaschen oder dergleichen Behälter |
ATE539871T1 (de) † | 2009-04-28 | 2012-01-15 | Gea Procomac Spa | Vorrichtung zur herstellung von behältern aus vorformlingen |
DE102010000501B4 (de) * | 2010-02-22 | 2021-05-27 | Krones Aktiengesellschaft | Behälterformungs- und Behälterbehandlungsanlage |
DE102010027077A1 (de) | 2010-07-13 | 2012-01-19 | Krones Aktiengesellschaft | Aseptische Abfüllanlage |
DE102010031873A1 (de) * | 2010-07-21 | 2012-01-26 | Krones Aktiengesellschaft | Vorrichtung und Verfahren zum Befüllen von Behältnissen mit Reinigungseinrichtung |
CN112249447A (zh) * | 2020-08-31 | 2021-01-22 | 福建省三明市恒伟饮品有限公司 | 一种瓶装饮用水瓶的洗涤消毒设备及消毒方法 |
DE102021107727A1 (de) | 2021-03-26 | 2022-09-29 | Krones Aktiengesellschaft | Abfüllanlage und Verfahren zur aseptischen Abfüllung flüssiger Produkte in Flaschen |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0309926A2 (fr) * | 1987-09-29 | 1989-04-05 | Siemens Aktiengesellschaft | Méthode pour fabriquer des circuits, dont les paramètres peuvent être entièrement spécifiés, dans la technologie de circuits intégrés |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1488428A (en) * | 1974-11-30 | 1977-10-12 | Shibuya Kogyo Co Ltd | Rotary filling machine comprising a washing device |
EP0518828B1 (fr) * | 1991-06-10 | 1995-08-02 | Manzini Comaco S.p.A. | Méthode et installation pour la mise en boîte de produits alimentaires |
IT1253386B (it) * | 1991-09-10 | 1995-08-08 | Manzini Comaco Spa | Macchina riempitrice provvista di sterilizzazione e lavaggio degli ugelli in automatico ed operante in asettico |
GB2280669B (en) * | 1993-07-27 | 1996-11-13 | Raymond William Sheppard | Aseptic new filling system |
DE4343425A1 (de) * | 1993-12-18 | 1995-06-22 | Khs Masch & Anlagenbau Ag | Hubvorrichtung für eine Füllmaschine sowie Füllmaschine mit einer solchen Hubvorrichtung |
-
1995
- 1995-08-11 IT IT95MO000120A patent/IT1279846B1/it active IP Right Grant
-
1996
- 1996-05-09 DE DE69622800T patent/DE69622800T2/de not_active Expired - Fee Related
- 1996-05-09 AT AT96830270T patent/ATE221855T1/de not_active IP Right Cessation
- 1996-05-09 EP EP96830270A patent/EP0758624B1/fr not_active Expired - Lifetime
- 1996-05-09 ES ES96830270T patent/ES2180724T3/es not_active Expired - Lifetime
- 1996-11-20 AU AU71878/96A patent/AU727925B2/en not_active Ceased
- 1996-11-28 JP JP8317923A patent/JPH10157797A/ja active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0309926A2 (fr) * | 1987-09-29 | 1989-04-05 | Siemens Aktiengesellschaft | Méthode pour fabriquer des circuits, dont les paramètres peuvent être entièrement spécifiés, dans la technologie de circuits intégrés |
Also Published As
Publication number | Publication date |
---|---|
JPH10157797A (ja) | 1998-06-16 |
AU7187896A (en) | 1998-05-28 |
ATE221855T1 (de) | 2002-08-15 |
DE69622800T2 (de) | 2002-12-05 |
ITMO950120A1 (it) | 1997-02-11 |
ITMO950120A0 (it) | 1995-08-11 |
EP0758624A1 (fr) | 1997-02-19 |
DE69622800D1 (de) | 2002-09-12 |
ES2180724T3 (es) | 2003-02-16 |
IT1279846B1 (it) | 1997-12-18 |
AU727925B2 (en) | 2001-01-04 |
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