EP0697090A1 - Rippenrohr-wärmeaustauscher - Google Patents
Rippenrohr-wärmeaustauscherInfo
- Publication number
- EP0697090A1 EP0697090A1 EP95911195A EP95911195A EP0697090A1 EP 0697090 A1 EP0697090 A1 EP 0697090A1 EP 95911195 A EP95911195 A EP 95911195A EP 95911195 A EP95911195 A EP 95911195A EP 0697090 A1 EP0697090 A1 EP 0697090A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- heat exchanger
- finned tube
- tube heat
- exchanger according
- sections
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000001816 cooling Methods 0.000 claims abstract description 17
- 230000007704 transition Effects 0.000 claims abstract description 13
- 238000004049 embossing Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F3/00—Plate-like or laminated elements; Assemblies of plate-like or laminated elements
- F28F3/02—Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations
- F28F3/04—Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations the means being integral with the element
- F28F3/042—Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations the means being integral with the element in the form of local deformations of the element
- F28F3/046—Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations the means being integral with the element in the form of local deformations of the element the deformations being linear, e.g. corrugations
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/10—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses
- F28F1/12—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element
- F28F1/24—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending transversely
- F28F1/32—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending transversely the means having portions engaging further tubular elements
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/10—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses
- F28F1/12—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element
- F28F1/24—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending transversely
- F28F1/32—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending transversely the means having portions engaging further tubular elements
- F28F1/325—Fins with openings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S165/00—Heat exchange
- Y10S165/454—Heat exchange having side-by-side conduits structure or conduit section
- Y10S165/50—Side-by-side conduits with fins
- Y10S165/505—Corrugated strips disposed between adjacent conduits
Definitions
- the invention relates to a finned tube heat exchanger according to the features in the preamble of claim 1.
- the finned tube heat exchanger according to DE-PS 34 19 734 is able to condense large amounts of steam. It also has the northern part that a pressure equalization between all areas of the tube cross-section occurs at every point of the heat exchanger tubes. As a result, the condensation of the exhaust steam in the front pipe sections facing the flow direction of the cooling air ends at exactly the same point as in the pipe sections rear in the flow direction of the cooling air. Dead zones can thus hardly be established. In addition, relatively large pipe cross sections are formed, so that the flow pressure losses due to the larger hydraulic cross section are considerably reduced. The fins protruding perpendicularly from the surfaces of the heat exchanger tubes are smooth and non-protruding.
- the finned tube heat exchanger of DE-OS 19 58 909 has leading edges integrated into the fins between the heat exchanger tubes.
- the leading edges are formed by pressing out surface sections from the planes of the ribs.
- the cooling air finds obstacles.
- the heat transfer is improved by this measure, but the disadvantage is paid that the pressure loss increases several times due to the leading edges.
- the invention is based on the object of perfecting such a finned tube heat exchanger in such a way that the external heat transfer between the cooling air and the surfaces of the heat exchanger tubes can be increased significantly without a substantial increase in the pressure loss.
- the ribs are then provided on at least one side surface with a zigzag-shaped configuration having air guide grooves.
- the air guide grooves generally have a longitudinal extension in the direction of flow of the cooling air. They are open at the fin ends and thus allow the cooling air to flow in the air guide grooves, with the zigzag-shaped configuration significantly improving the external heat transfer between the cooling air and the surface of the heat exchanger tubes is reached without significantly increasing the pressure losses.
- the air guide grooves can extend over the entire side surface of a rib. They are usually provided by appropriate embossing on both sides of a rib. In this case, the air guide grooves of adjacent ribs face each other frontally.
- the fins configured according to the invention can be provided individually on each heat exchanger tube. However, it is particularly advantageous if two heat exchanger tubes running side by side are connected in a web-like manner by ribs with air guide grooves running in a zigzag shape. These can be individual ribs or ribbed ribbons embossed in a U-shaped or trapezoidal shape.
- the air guide grooves are curved in a wave shape
- a preferred embodiment according to claim 2 is seen in that the mutually angled groove sections of the air guide grooves run in a straight line.
- the groove sections are preferably of the same length.
- each transition section is advantageously curved in a circular arc.
- the radii of the transition sections are expediently designed identically.
- a particularly advantageous embodiment of the rib design is seen in the features of claim 4. These are either individual ribs which are fixed to the heat exchanger tubes via the fastening strips, or the ribs form part of corrugated, U-shaped or trapezoidal ribbed strips which are connected to the heat exchanger tubes via the fastening strips.
- 15 areas from the fields to the fastening strip can preferably be carried out on a suitable embossing machine.
- the transition sections In order to ensure that the cooling air in the air-guiding grooves is deflected as swirl-free as possible, the transition sections have a radius of 1.5 mm to 3 mm.
- the distance between a transverse plane intersecting a center of curvature and the intersection of the adjacent center lines is Groove sections with the line of symmetry about 3 mm to 10 mm, preferably about 7.5 mm.
- the air guide grooves have a semicircular cross section with a radius and a depth of approximately 1 mm to 2 mm, preferably approximately 1.5 mm.
- the uniform course of the air guide grooves - preferably on both side surfaces of the ribs - is optimized in accordance with claim 10 in that the distance between the center lines of two adjacent air guide grooves is approximately 4.5 mm to 6 mm, preferably approximately 5.0 mm. This results in a ratio of the distance of two transverse planes intersecting in the longitudinal direction of an air guiding groove to the center of curvature intersecting to the distance of the center lines of two adjacent air guiding grooves of approximately 3.5-4.5: 1, preferably 4: 1. Finally, a further improvement in the heat transfer conditions can be achieved in that the distance between two adjacent ribs is approximately 2 mm to 4 mm, preferably approximately 3 mm.
- FIG. 1 shows a vertical cross section through a section of a finned tube heat exchanger in the diagram
- Figure 2 is a partial view of the finned tube heat exchanger according to arrow II of Figure 1;
- Figure 3 shows an enlarged view of section III of Figure 1;
- FIG. 5 shows an enlarged cross section through the illustration of FIG. 3 along the line V-V;
- FIG. 6 shows a section of a U-shaped ribbed belt in perspective
- FIG. 7 shows a side view of the rib band of FIGS. 6 and 6
- FIG. 8 shows a top view of the ribbed band of FIG. 6.
- FIGS. 1 to 3 in FIGS. 1 to 3 represent a partial area of a finned tube heat exchanger for condensing the exhaust vapors of large turbine systems by means of cooling air.
- the finned tube heat exchanger 1 has a plurality of heat exchanger tubes 2, which are arranged in parallel at a distance A and have an elongated cross section.
- the heat exchanger tubes 2 are connected to one another by fins 3, which extend parallel to the direction of flow SR of the cooling air and are fastened perpendicularly to the lateral surfaces 4 of the heat exchanger tubes 2 by means of suitable fixing strips.
- FIG. 1 shows that the length L of the cross section of the heat exchanger tubes 2 is several times larger than the width B.
- the ribs 3 (FIGS. 2 and 5) arranged at a distance of AI of 3 mm from one another have on both side surfaces 5 in a zigzag configuration parallel to one another and continuous in the flow direction SR of the cooling air, open at the fin ends 6, air guide grooves 7, which are formed by a corresponding embossing of the ribs 3 with a thickness D of approximately 0.1 mm for aluminum or copper or approximately to 0.5 mm for steel (FIGS. 1 to 5).
- Each air guide groove 7 is made up of straight groove sections 8 and two successive groove sections 8 continuously connecting the arcuate transition sections 9 (FIGS. 1, 3 and 4).
- FIG. 4 shows the geometrical relationships of an air guide groove 7 in an enlarged representation on the basis of the emphasized center lines 10 of two successive groove sections 8. It can then be seen that the arcuate transition sections 9 are semicircularly curved.
- the center of curvature 11 of the transition sections 9 are at a distance from the symmetry line SL of the air guide groove 7.
- the transition sections 9 have a radius Rl of 1.5 mm to 3 mm.
- the distance A2 from two successive centers of curvature 11 intersecting transverse planes (E) is 10 mm.
- the intersection 12 of the center lines 10 of two successive groove sections 8 is arranged at a distance A3 of 3.5 mm from the symmetry line SL.
- the air guide grooves 7 have a semicircular cross section with a radius R and a depth T of 1.5 mm.
- the distance A4 of the center lines 10 of two adjacent air guide grooves is 5.0 mm (FIGS. 1 and 5).
- the U-shaped ribbed belt 13 of FIGS. 6 to 8 consists of a plurality of ribs 3a and fastening strips 14, 14a connecting the ribs 3a, which at the same time also serve to fix the ribbed belt 13 to the heat exchanger tubes 2.
- the ribs 3a are divided in the longitudinal direction into a plurality of successively zigzag fields 15, each with parallel groove sections 8a.
- the groove sections 8a form constituents of air guide grooves 7a which extend over the length of the ribs 3a.
- the longitudinal edges 16, 17 of the fields 15 run both at an angle l to the fastening strips 14, 14a extending in the parallel planes El-E1, E2-E2 and at an angle ⁇ 1 to the longitudinal edges 18, 19 of each rib 3a intersecting plane E3-E3.
- the angles ⁇ , ⁇ l, ß, ßl are 14 °.
- the design of the ribs 3a and the air guide grooves 7a formed on the ribs 3a corresponds to the design of the ribs 3 and the air guide grooves 7 of the embodiment of FIGS. 1 to 5, so that a further explanation can be dispensed with.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Geometry (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Accessories For Mixers (AREA)
Abstract
Description
Claims
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4406966 | 1994-03-03 | ||
DE4406966 | 1994-03-03 | ||
DE19503766 | 1995-02-04 | ||
DE19503766A DE19503766C2 (de) | 1994-03-03 | 1995-02-04 | Rippenrohr-Wärmeaustauscher |
PCT/DE1995/000239 WO1995023949A1 (de) | 1994-03-03 | 1995-02-23 | Rippenrohr-wärmeaustauscher |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0697090A1 true EP0697090A1 (de) | 1996-02-21 |
EP0697090B1 EP0697090B1 (de) | 1998-06-10 |
Family
ID=25934323
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP95911195A Expired - Lifetime EP0697090B1 (de) | 1994-03-03 | 1995-02-23 | Rippenrohr-wärmeaustauscher |
Country Status (9)
Country | Link |
---|---|
US (1) | US5623989A (de) |
EP (1) | EP0697090B1 (de) |
JP (1) | JPH08510047A (de) |
CN (1) | CN1124057A (de) |
AU (1) | AU1888595A (de) |
BR (1) | BR9505782A (de) |
CA (1) | CA2162051A1 (de) |
CZ (1) | CZ287995A3 (de) |
WO (1) | WO1995023949A1 (de) |
Families Citing this family (43)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2821283B1 (fr) * | 2001-02-28 | 2003-04-18 | Inst Francais Du Petrole | Procede et reacteur multi-etages catalytique a faible epaisseur avec echangeur thermique interne, et son utilisation |
FR2834783B1 (fr) * | 2002-01-17 | 2004-06-11 | Air Liquide | Ailette d'echange thermique, son procede de fabrication et echangeur de chaleur correspondant |
KR20040017920A (ko) * | 2002-08-22 | 2004-03-02 | 엘지전자 주식회사 | 열교환기의 응축수 배출장치 |
KR20040017768A (ko) * | 2002-08-23 | 2004-02-27 | 엘지전자 주식회사 | 열교환기의 응축수 배출장치 |
JP3864916B2 (ja) * | 2002-08-29 | 2007-01-10 | 株式会社デンソー | 熱交換器 |
EP1538415A1 (de) * | 2003-12-01 | 2005-06-08 | Balcke-Dürr GmbH | Strömungskanal |
DE202005009948U1 (de) * | 2005-06-23 | 2006-11-16 | Autokühler GmbH & Co. KG | Wärmeaustauschelement und damit hergestellter Wärmeaustauscher |
CN101233380B (zh) * | 2005-07-29 | 2012-11-07 | 国立大学法人东京大学 | 热交换器、使用该热交换器的空调装置及空气性质转化器 |
JP4756585B2 (ja) * | 2005-09-09 | 2011-08-24 | 臼井国際産業株式会社 | 熱交換器用伝熱管 |
KR100745231B1 (ko) * | 2006-06-13 | 2007-08-01 | 모딘코리아 유한회사 | 열교환기용 방열핀 |
JP2008096048A (ja) * | 2006-10-13 | 2008-04-24 | Tokyo Radiator Mfg Co Ltd | 排気ガス用熱交換器のインナーフィン |
US20090250201A1 (en) | 2008-04-02 | 2009-10-08 | Grippe Frank M | Heat exchanger having a contoured insert and method of assembling the same |
WO2008091918A1 (en) * | 2007-01-23 | 2008-07-31 | Modine Manufacturing Company | Heat exchanger and method |
US8424592B2 (en) * | 2007-01-23 | 2013-04-23 | Modine Manufacturing Company | Heat exchanger having convoluted fin end and method of assembling the same |
EP2108911B1 (de) | 2007-01-25 | 2019-08-21 | The University of Tokyo | Wärmetauscher |
JP5082120B2 (ja) * | 2007-03-23 | 2012-11-28 | 国立大学法人 東京大学 | 熱交換器 |
DE102008010187A1 (de) * | 2008-02-20 | 2009-08-27 | Modine Manufacturing Co., Racine | Flachrohr und Herstellungsverfahren |
JP5536312B2 (ja) * | 2008-04-23 | 2014-07-02 | シャープ株式会社 | 熱交換システム |
JP5156773B2 (ja) * | 2010-02-25 | 2013-03-06 | 株式会社小松製作所 | コルゲートフィンおよびそれを備える熱交換器 |
JP5545260B2 (ja) | 2010-05-21 | 2014-07-09 | 株式会社デンソー | 熱交換器 |
KR101299072B1 (ko) * | 2011-11-29 | 2013-08-27 | 주식회사 코렌스 | 웨이브 핀 |
JP2012198023A (ja) * | 2012-07-26 | 2012-10-18 | Komatsu Ltd | コルゲートフィンおよびそれを備える熱交換器 |
JP5694282B2 (ja) * | 2012-12-10 | 2015-04-01 | 株式会社小松製作所 | コルゲートフィンおよびそれを備える熱交換器 |
JP2014142180A (ja) * | 2014-04-24 | 2014-08-07 | Komatsu Ltd | コルゲートフィンおよびそれを備える熱交換器 |
CN104142085B (zh) * | 2014-08-01 | 2016-04-06 | 兰州交通大学 | 圆管管翅式换热器流线型变波幅抛物形波纹翅片 |
CN104089519B (zh) * | 2014-08-01 | 2016-02-17 | 兰州交通大学 | 圆管管翅式换热器流线型等波幅圆弧形波纹翅片 |
CN104101243B (zh) * | 2014-08-01 | 2016-02-17 | 兰州交通大学 | 圆管管翅式换热器流线型变波幅折线形波纹翅片 |
CN104110986B (zh) * | 2014-08-01 | 2016-01-06 | 兰州交通大学 | 圆管管翅式换热器流线型变波幅圆弧形波纹翅片 |
CN104132573B (zh) * | 2014-08-01 | 2016-05-18 | 兰州交通大学 | 椭圆管管翅式换热器流线型等波幅折线形波纹翅片 |
CN104154804B (zh) * | 2014-08-01 | 2016-01-06 | 兰州交通大学 | 椭圆管管翅式换热器流线型变波幅正/余弦形波纹翅片 |
CN104089515B (zh) * | 2014-08-01 | 2016-05-18 | 兰州交通大学 | 圆管管翅式换热器流线型等波幅折线形波纹翅片 |
CN104132574B (zh) * | 2014-08-01 | 2016-04-06 | 兰州交通大学 | 椭圆管管翅式换热器流线型变波幅抛物形波纹翅片 |
CN104142083B (zh) * | 2014-08-01 | 2016-05-18 | 兰州交通大学 | 椭圆管管翅式换热器流线型变波幅折线形波纹翅片 |
CN104110987B (zh) * | 2014-08-01 | 2016-01-06 | 兰州交通大学 | 圆管管翅式换热器流线型等波幅抛物形波纹翅片 |
CN104154797B (zh) * | 2014-08-01 | 2016-08-17 | 兰州交通大学 | 圆管管翅式换热器流线型等波幅正/余弦形波纹翅片 |
CN104142086B (zh) * | 2014-08-01 | 2016-05-18 | 兰州交通大学 | 椭圆管管翅式换热器流线型等波幅波纹翅片 |
EP3196580B1 (de) | 2014-09-19 | 2018-08-29 | T.RAD Co., Ltd. | Wellrippen für wärmetauscher |
JP6567536B2 (ja) * | 2014-09-19 | 2019-08-28 | 株式会社ティラド | 熱交換器用コルゲートフィン |
JP2015180852A (ja) * | 2015-07-24 | 2015-10-15 | 株式会社小松製作所 | コルゲートフィンおよびそれを備える熱交換器 |
GB201513415D0 (en) * | 2015-07-30 | 2015-09-16 | Senior Uk Ltd | Finned coaxial cooler |
CN108700384A (zh) * | 2015-12-28 | 2018-10-23 | 国立大学法人东京大学 | 换热器 |
NL2017947B1 (nl) * | 2016-12-07 | 2018-06-19 | Recair Holding B V | Recuperator |
JP6663899B2 (ja) * | 2017-11-29 | 2020-03-13 | 本田技研工業株式会社 | 冷却装置 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
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FR409013A (de) * | ||||
FR328959A (fr) * | 1902-07-17 | 1903-07-23 | George Augustus Mower | Perfectionnements dans les appareils à chauffer ou réfrigérer l'air ou d'autres gaz |
GB362073A (en) * | 1930-10-04 | 1931-12-03 | Serck Radiators Ltd | Improvements relating to heat interchanging apparatus |
GB392065A (en) * | 1931-11-24 | 1933-05-11 | Luis Baxeras Font | Improvements in or relating to the construction of radiators for automobiles and thelike |
CH169148A (de) * | 1932-11-04 | 1934-05-15 | Keller Walter | Distanzblech für luftgekühlte, wasserführende Lamellenkühler und Verfahren zur Herstellung desselben. |
US2252211A (en) * | 1939-10-18 | 1941-08-12 | Mccord Radiator & Mfg Co | Heat exchange core |
FR1494167A (fr) * | 1966-07-15 | 1967-09-08 | Chausson Usines Sa | Echangeur thermique, notamment pour véhicules automobiles et applications analogues |
US3515207A (en) * | 1968-07-17 | 1970-06-02 | Perfex Corp | Fin configuration for fin and tube heat exchanger |
DE2108688A1 (de) * | 1971-02-24 | 1972-09-07 | Hornkohl & Wolf | Luftleitkorper fur einen Wärmetauscher |
DE4039293C3 (de) * | 1990-12-08 | 1995-03-23 | Gea Luftkuehler Happel Gmbh | Wärmeaustauscher |
-
1995
- 1995-02-23 AU AU18885/95A patent/AU1888595A/en not_active Abandoned
- 1995-02-23 CZ CZ952879A patent/CZ287995A3/cs unknown
- 1995-02-23 JP JP7522624A patent/JPH08510047A/ja active Pending
- 1995-02-23 EP EP95911195A patent/EP0697090B1/de not_active Expired - Lifetime
- 1995-02-23 CA CA002162051A patent/CA2162051A1/en not_active Abandoned
- 1995-02-23 CN CN95190131A patent/CN1124057A/zh active Pending
- 1995-02-23 US US08/535,191 patent/US5623989A/en not_active Expired - Lifetime
- 1995-02-23 WO PCT/DE1995/000239 patent/WO1995023949A1/de not_active Application Discontinuation
- 1995-02-23 BR BR9505782A patent/BR9505782A/pt not_active Application Discontinuation
Non-Patent Citations (1)
Title |
---|
See references of WO9523949A1 * |
Also Published As
Publication number | Publication date |
---|---|
JPH08510047A (ja) | 1996-10-22 |
CZ287995A3 (en) | 1996-02-14 |
US5623989A (en) | 1997-04-29 |
WO1995023949A1 (de) | 1995-09-08 |
BR9505782A (pt) | 1996-03-05 |
AU1888595A (en) | 1995-09-18 |
EP0697090B1 (de) | 1998-06-10 |
CN1124057A (zh) | 1996-06-05 |
CA2162051A1 (en) | 1995-09-08 |
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