EP0694622B1 - Korrosionbeständige Legierung und Verfahren zur Herstellung korrosionsbeständiger Schneidwaren - Google Patents
Korrosionbeständige Legierung und Verfahren zur Herstellung korrosionsbeständiger Schneidwaren Download PDFInfo
- Publication number
- EP0694622B1 EP0694622B1 EP95890122A EP95890122A EP0694622B1 EP 0694622 B1 EP0694622 B1 EP 0694622B1 EP 95890122 A EP95890122 A EP 95890122A EP 95890122 A EP95890122 A EP 95890122A EP 0694622 B1 EP0694622 B1 EP 0694622B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alloy
- temperature
- concentrations
- corrosion resistant
- carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 23
- 239000000956 alloy Substances 0.000 title claims abstract description 23
- 238000005260 corrosion Methods 0.000 title claims abstract description 20
- 230000007797 corrosion Effects 0.000 title claims abstract description 20
- 238000005520 cutting process Methods 0.000 title claims abstract description 6
- 238000000034 method Methods 0.000 title claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 238000005496 tempering Methods 0.000 claims description 2
- 239000012535 impurity Substances 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 239000011651 chromium Substances 0.000 description 9
- 229910052804 chromium Inorganic materials 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 229910000734 martensite Inorganic materials 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 206010020751 Hypersensitivity Diseases 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- -1 chlorine ions Chemical class 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 206010012434 Dermatitis allergic Diseases 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229910001566 austenite Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000029142 excretion Effects 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/002—Heat treatment of ferrous alloys containing Cr
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/18—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for knives, scythes, scissors, or like hand cutting tools
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/24—Ferrous alloys, e.g. steel alloys containing chromium with vanadium
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/78—Combined heat-treatments not provided for above
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/04—Hardening by cooling below 0 degrees Celsius
Definitions
- the invention relates to a corrosion-resistant alloy. Furthermore, the invention relates to a method for Production of cutlery with high hardness and great flexural strength.
- Stainless steels i.e. iron-based alloys with a Cr content of around 13%, e.g. DIN material no. 1.4110, are used successfully for cutlery used.
- alloys with approx. 18% Cr content e.g. Material No. 1.4112 for Use which increased due to a higher Cr concentration Resistant to chemical attack.
- Alloys with approx. 18% Cr and However, above 0.85% C have the disadvantage that, in particular, through coarse Carbide deposits, although with increased wear resistance and hardness of the Material, the bending toughness and the polishability can be reduced. An attempt has already been made to use a steel with approx.
- DE-C-3 901 470 relates to a corrosion-resistant, high-strength martensitic cold work steel.
- JP-A-2-166 228 relates to a high-carbon stainless steel with excellent quenching hardness, wear resistance and corrosion resistance.
- the object of the invention is now to provide a particularly corrosion-resistant alloy which is compatible with skin contact and which has high hardness, good polishability and, in particular, high flexural strength with high fracture resistance, which can also be used in media containing chlorine ions.
- the invention further aims to provide a method for producing corrosion-resistant cutlery for the food industry and for medical instruments, with which the disadvantages of the known cut parts are eliminated.
- the advantages achieved by the invention are in particular that the Composition of the alloy with a low total carbide content low Carbide grain sizes as well as a high matrix hardness and therefore a good grinding and This ensures polishability and, in particular, good bending toughness important that in the concentration limits the sum of the contents of carbon and nitrogen are in a certain range. It was surprising found that the steel with a chromium content of about 17.5% Chromium concentration in the matrix increased by alloying with nitrogen and thus the corrosion resistance can be improved, without The carbon concentration can be reduced.
- the Advantages achieved by the invention can be seen essentially in the fact that alloys can be produced economically and by heat treatment
- the knives and instruments made from it have the best usage properties Parts can be reached. It is important that the alloy engineering Requirements are given and that by solution annealing a homogeneous structure is achieved. It is also of particular importance a soft annealing of the material around the A3 point of the alloy in front of you Austenitize to the excretion and transformation kinetics in subsequent cooling with increased intensity.
- a subsequent tempering treatment is carried out at a comparatively low temperature carried out and serves in particular to relax the material.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Heat Treatment Of Articles (AREA)
- Nonmetal Cutting Devices (AREA)
- Powder Metallurgy (AREA)
- Dry Shavers And Clippers (AREA)
- ing And Chemical Polishing (AREA)
- Pressure Welding/Diffusion-Bonding (AREA)
- Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Knives (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT0128394A AT401387B (de) | 1994-06-29 | 1994-06-29 | Korrosionsbeständige legierung und verfahren zur herstellung korrosionsbeständiger schneidwaren |
AT1283/94 | 1994-06-29 | ||
AT128394 | 1994-06-29 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0694622A1 EP0694622A1 (de) | 1996-01-31 |
EP0694622B1 true EP0694622B1 (de) | 2001-10-04 |
Family
ID=3510544
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP95890122A Expired - Lifetime EP0694622B1 (de) | 1994-06-29 | 1995-06-28 | Korrosionbeständige Legierung und Verfahren zur Herstellung korrosionsbeständiger Schneidwaren |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0694622B1 (no) |
AT (2) | AT401387B (no) |
DE (1) | DE59509656D1 (no) |
DK (1) | DK0694622T3 (no) |
ES (1) | ES2164142T3 (no) |
FI (1) | FI111273B (no) |
NO (1) | NO309045B1 (no) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6770243B2 (en) | 2000-01-17 | 2004-08-03 | Stahlwerk Ergste Westig Gmbh | Chrome steel alloy |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT402224B (de) * | 1994-11-04 | 1997-03-25 | Boehler Edelstahl | Verwendung einer eisenbasislegierung sowie plungerkolben und kolbenring |
ES2130065B1 (es) * | 1997-03-17 | 2000-01-16 | Gsb Grupo Siderurgico Vasco S | Procedimiento de fabricacion de aceros microaleados con estructuras de ferrita acicular enfriadas de forma convencional. |
DE102009038382A1 (de) * | 2009-08-24 | 2011-03-03 | Stahlwerk Ergste Gmbh | Rostfreier martensitischer Chromstahl |
DE102011102293A1 (de) * | 2011-02-24 | 2012-08-30 | Stahlwerk Ergste Westig Gmbh | Verwendung eines Chromstahls mit martensitischem Gefüge und karbidischen Einschlüssen |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT139392B (de) * | 1934-02-02 | 1934-11-10 | Oskar Teuchmann | Elektromagnetische Schalldose. |
DE739958C (de) * | 1937-04-30 | 1943-10-08 | Sandvikens Jernverks Ab | Stahllegierung fuer durch Walzen oder aehnliche Verarbeitungsverfahren hergestellte korrosionsbestaendige, gehaertete Schneidwerkzeuge |
GB643367A (en) * | 1947-10-31 | 1950-09-20 | Anders Goeran Molinder | Improvements in or relating to the thermal treatment of steel and products thereof |
US4150978A (en) * | 1978-04-24 | 1979-04-24 | Latrobe Steel Company | High performance bearing steels |
AT392485B (de) * | 1985-05-21 | 1991-04-10 | Boehler Gmbh | Werkstoff zur herstellung von stanz- und gegenplatten |
JPH02166228A (ja) * | 1988-12-20 | 1990-06-26 | Nippon Steel Corp | 均一微細な炭化物組織を有する高炭素含有ステンレス鋼の製造方法 |
DE3901470C1 (en) * | 1989-01-19 | 1990-08-09 | Vereinigte Schmiedewerke Gmbh, 4630 Bochum, De | Cold-working steel and its use |
AT397968B (de) * | 1992-07-07 | 1994-08-25 | Boehler Ybbstalwerke | Korrosionsbeständige legierung zur verwendung als werkstoff für in berührungskontakt mit lebewesen stehende teile |
DE9215141U1 (de) * | 1992-11-06 | 1993-01-07 | Borchmann, Michael, Dr.med.dent., 4518 Bad Laer | Material zum Gebrauch in der Schmuckwarenindustrie für Schmuckwaren aller Art |
FR2708939B1 (fr) * | 1993-08-11 | 1995-11-03 | Sima Sa | Acier martensitique à l'azote à faible teneur en carbone et son procédé de fabrication. |
-
1994
- 1994-06-29 AT AT0128394A patent/AT401387B/de not_active IP Right Cessation
-
1995
- 1995-06-26 NO NO952557A patent/NO309045B1/no not_active IP Right Cessation
- 1995-06-28 DE DE59509656T patent/DE59509656D1/de not_active Expired - Lifetime
- 1995-06-28 DK DK95890122T patent/DK0694622T3/da active
- 1995-06-28 ES ES95890122T patent/ES2164142T3/es not_active Expired - Lifetime
- 1995-06-28 EP EP95890122A patent/EP0694622B1/de not_active Expired - Lifetime
- 1995-06-28 AT AT95890122T patent/ATE206477T1/de active
- 1995-06-29 FI FI953218A patent/FI111273B/fi not_active IP Right Cessation
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6770243B2 (en) | 2000-01-17 | 2004-08-03 | Stahlwerk Ergste Westig Gmbh | Chrome steel alloy |
Also Published As
Publication number | Publication date |
---|---|
DE59509656D1 (de) | 2001-11-08 |
DK0694622T3 (da) | 2002-01-21 |
FI111273B (fi) | 2003-06-30 |
AT401387B (de) | 1996-08-26 |
ES2164142T3 (es) | 2002-02-16 |
EP0694622A1 (de) | 1996-01-31 |
FI953218A0 (fi) | 1995-06-29 |
NO952557D0 (no) | 1995-06-26 |
FI953218A (fi) | 1995-12-30 |
ATA128394A (de) | 1996-01-15 |
NO952557L (no) | 1996-01-02 |
NO309045B1 (no) | 2000-12-04 |
ATE206477T1 (de) | 2001-10-15 |
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