EP0637056B1 - Lampe à décharge haute pression - Google Patents
Lampe à décharge haute pression Download PDFInfo
- Publication number
- EP0637056B1 EP0637056B1 EP94111177A EP94111177A EP0637056B1 EP 0637056 B1 EP0637056 B1 EP 0637056B1 EP 94111177 A EP94111177 A EP 94111177A EP 94111177 A EP94111177 A EP 94111177A EP 0637056 B1 EP0637056 B1 EP 0637056B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- getter
- discharge vessel
- boron
- radiation
- light
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910001507 metal halide Inorganic materials 0.000 claims description 35
- 150000005309 metal halides Chemical group 0.000 claims description 34
- 239000000126 substance Substances 0.000 claims description 23
- 229910052736 halogen Inorganic materials 0.000 claims description 22
- 150000002367 halogens Chemical class 0.000 claims description 22
- 229910052760 oxygen Inorganic materials 0.000 claims description 21
- 239000001301 oxygen Substances 0.000 claims description 21
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 20
- 150000004820 halides Chemical class 0.000 claims description 17
- -1 phosphorus compound Chemical class 0.000 claims description 14
- 229910052698 phosphorus Inorganic materials 0.000 claims description 13
- 239000011574 phosphorus Substances 0.000 claims description 13
- 230000005855 radiation Effects 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- 150000002739 metals Chemical class 0.000 claims description 9
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 9
- 150000002910 rare earth metals Chemical class 0.000 claims description 9
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 229910052796 boron Inorganic materials 0.000 claims description 8
- 229910052706 scandium Inorganic materials 0.000 claims description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 7
- 229910052753 mercury Inorganic materials 0.000 claims description 7
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 6
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 5
- YMEKEHSRPZAOGO-UHFFFAOYSA-N boron triiodide Chemical compound IB(I)I YMEKEHSRPZAOGO-UHFFFAOYSA-N 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- CECABOMBVQNBEC-UHFFFAOYSA-K aluminium iodide Chemical compound I[Al](I)I CECABOMBVQNBEC-UHFFFAOYSA-K 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- PQLAYKMGZDUDLQ-UHFFFAOYSA-K aluminium bromide Chemical compound Br[Al](Br)Br PQLAYKMGZDUDLQ-UHFFFAOYSA-K 0.000 claims 4
- 239000004411 aluminium Substances 0.000 claims 3
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims 2
- ILAHWRKJUDSMFH-UHFFFAOYSA-N boron tribromide Chemical compound BrB(Br)Br ILAHWRKJUDSMFH-UHFFFAOYSA-N 0.000 claims 2
- FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 claims 2
- 150000003657 tungsten Chemical class 0.000 claims 2
- 241000501667 Etroplus Species 0.000 claims 1
- 230000007797 corrosion Effects 0.000 description 13
- 238000005260 corrosion Methods 0.000 description 13
- 229910052721 tungsten Inorganic materials 0.000 description 11
- 239000010937 tungsten Substances 0.000 description 11
- 239000000654 additive Substances 0.000 description 10
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 10
- 239000007772 electrode material Substances 0.000 description 6
- 239000000945 filler Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- JEEHQNXCPARQJS-UHFFFAOYSA-N boranylidynetungsten Chemical class [W]#B JEEHQNXCPARQJS-UHFFFAOYSA-N 0.000 description 3
- 150000003842 bromide salts Chemical class 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 150000001805 chlorine compounds Chemical class 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000000295 emission spectrum Methods 0.000 description 3
- 150000004694 iodide salts Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052756 noble gas Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- WZSUOQDIYKMPMT-UHFFFAOYSA-N argon krypton Chemical compound [Ar].[Kr] WZSUOQDIYKMPMT-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- BSPSZRDIBCCYNN-UHFFFAOYSA-N phosphanylidynetin Chemical class [Sn]#P BSPSZRDIBCCYNN-UHFFFAOYSA-N 0.000 description 2
- PZHNNJXWQYFUTD-UHFFFAOYSA-N phosphorus triiodide Chemical compound IP(I)I PZHNNJXWQYFUTD-UHFFFAOYSA-N 0.000 description 2
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 2
- CMJCEVKJYRZMIA-UHFFFAOYSA-M thallium(i) iodide Chemical compound [Tl]I CMJCEVKJYRZMIA-UHFFFAOYSA-M 0.000 description 2
- JTDNNCYXCFHBGG-UHFFFAOYSA-L tin(ii) iodide Chemical compound I[Sn]I JTDNNCYXCFHBGG-UHFFFAOYSA-L 0.000 description 2
- RMUKCGUDVKEQPL-UHFFFAOYSA-K triiodoindigane Chemical compound I[In](I)I RMUKCGUDVKEQPL-UHFFFAOYSA-K 0.000 description 2
- DZKDPOPGYFUOGI-UHFFFAOYSA-N tungsten(iv) oxide Chemical compound O=[W]=O DZKDPOPGYFUOGI-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- VIZQREHVDDPWOK-UHFFFAOYSA-N IP(I)(I)=O Chemical compound IP(I)(I)=O VIZQREHVDDPWOK-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229910052729 chemical element Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- ZSUXOVNWDZTCFN-UHFFFAOYSA-L tin(ii) bromide Chemical compound Br[Sn]Br ZSUXOVNWDZTCFN-UHFFFAOYSA-L 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J7/00—Details not provided for in the preceding groups and common to two or more basic types of discharge tubes or lamps
- H01J7/14—Means for obtaining or maintaining the desired pressure within the vessel
- H01J7/18—Means for absorbing or adsorbing gas, e.g. by gettering
- H01J7/183—Composition or manufacture of getters
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/24—Means for obtaining or maintaining the desired pressure within the vessel
- H01J61/26—Means for absorbing or adsorbing gas, e.g. by gettering; Means for preventing blackening of the envelope
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/82—Lamps with high-pressure unconstricted discharge having a cold pressure > 400 Torr
- H01J61/827—Metal halide arc lamps
Definitions
- the invention relates to a high-pressure discharge lamp according to the preamble of patent claim 1.
- Electrode corrosion significantly shortens the lifespan of halogen-containing lamps. It occurs when there is free halogen on the electrodes in the operating state at an electrode temperature at which the halogen of the wholly or partially dissociated metal halide filling component can react with the electrode material.
- Residual oxygen which, for example, comes into the discharge vessel in the form of water as an impurity in the filling gases and the discharge vessel material or in the form of OH groups in the quartz glass, is crucially responsible for this harmful cycle. Higher oxygen concentrations accelerate electrode corrosion considerably.
- the electrode material which is usually tungsten or thoriated tungsten
- the electrode material which is usually tungsten or thoriated tungsten
- the vaporous tungsten halide or tungsten oxyhalide is dissociated again in the discharge, the tungsten being released being deposited at the hot points of the electrode, at the tip of the electrode.
- This process can take up lead to the electrodes breaking off at the point thinned by corrosion and thus to failure of the lamp.
- This reaction scheme taking place in the case of electrode corrosion can be explained on the basis of the schematic illustration in FIG. 2.
- the residual oxygen (O 2 ) first forms tungsten dioxide (WO 2 ), which reacts with the halogen (X 2 ) to form tungsten oxyhalide (WO 2 X 2 ).
- the tungsten oxyhalide compound dissociates in the discharge, with the tungsten being deposited on the hot areas of the electrodes, while the oxygen (O 2 ) and the halogen (X 2 ) on the cooler electrode parts, where the tungsten removal takes place, for further cycles with the electrode material (W) are available.
- Metal halide high-pressure discharge lamps are particularly affected by electrode corrosion, the metal halide filler additive predominantly containing sodium and tin halide, and UV lamps, the metal halide filler additive primarily containing mercury halides, iron and / or nickel halides.
- the patent specification FR 2 342 553 describes a gas discharge lamp with a fill containing metal halide. Elemental phosphorus or a phosphorus compound is contained in the discharge space of this lamp. The phosphorus or the phosphorus compound act within the discharge vessel as a getter for the undesired water vapor.
- Japanese Patent Application Laid-Open No. 55-133732 discloses a manufacturing method for a high pressure metal halide discharge lamp. While the discharge vessel is being evacuated and provided with the filling additives, the discharge space is connected to an auxiliary chamber in which a metallic getter is arranged. When the discharge space is heated, this getter binds oxygen and hydrogen impurities that were caused by the introduction of the metal halide. After heating, the secondary chamber is separated from the discharge vessel.
- the getter according to the invention binds the residual oxygen introduced into the discharge vessel by impurities in the filling substances. As a result, the oxygen is no longer available for the harmful cycle shown in FIG. 2, i.e. the accelerated, catalytic effect of the oxygen on the chemical reaction of the halogens with the electrode material is eliminated. In this way, the halogen attack on the electrodes and thus the electrode corrosion are suppressed.
- the getter substances are advantageously the chemical elements boron, aluminum, scandium or the rare earth metals and their halides, preferably iodides bromides or chlorides, and the tungsten-boron compounds WB and W 2 B and the tin-phosphorus compounds SnP, SnP 3 , Sn 4 P 3 and the phosphorus halides used. These getter substances bind the residual oxygen in the discharge vessel and, given the low dosage given below, do not influence the color locus of the lamp or damage the quartz glass wall of the discharge vessel.
- the dosage of the getter substances in the high-pressure discharge lamps according to the invention is selected such that the proportion by weight of the active getter element (e.g. boron and aluminum) contained in the getter compounds mentioned above, based on the total weight of the metal halide fill additives used in the discharge lamp for light or radiation generation, is approx 0.05 to 1 weight percent, and preferably 0.05 to 0.5 weight percent.
- the dose of getter substances in the discharge vessel is about 0.05 to about 1 percent by weight for the elements boron and aluminum and about 0.1 to 6 percent by weight for their halides.
- the dosage is chosen such that the boron or phosphorus fraction is approximately 0.05 to 1 percent by weight.
- the dosage is approximately 0.05 to 0.5 percent by weight and for their halides approximately 0.1 to 6 percent by weight.
- All percentages by weight relate to the metal halide fill additives of the discharge lamp used to generate light or radiation.
- getter With smaller amounts of getter, the usually free residual oxygen can no longer be completely bound, while a larger amount of getter than specified here can lead to blackening of the discharge vessel wall or to an influence on the emission spectrum of the lamp. If the getter content is too high, the halogen circuit which keeps the discharge vessel wall clean is also impaired.
- the amount of getter introduced is so small that the getter substances have no influence on the emission spectrum and the color locus of the invention Use metal halide lamp.
- This aspect is particularly important when halides of rare earth metals, which are well known as light or radiation emitting fill components, are used as getter substances for binding the free oxygen.
- the getter can advantageously be added together with the metal halide filler additives serving to emit light or radiation in the form of a solid dosage.
- FIG. 1 shows the structure of a metal halide lamp that is pinched on both sides according to the invention.
- the lamp 1 has a gas-tight discharge vessel 2 made of quartz glass, which is surrounded by a glass outer bulb 3.
- the discharge vessel 2 there are two tungsten electrodes 4, 5, between which a gas discharge is formed in the operating state.
- the electrodes 4, 5 are sealed in a gas-tight manner in the squeezing ends of the discharge vessel 2 and are each electrically conductively connected via a molybdenum foil 6, 7 to a respective power supply 8, 9.
- the power supply lines 8, 9 in turn produce an electrically conductive connection to the electrical connections 12, 13 of the lamp 1 via a respective molybdenum foil melt 10, 11 of the outer bulb 3.
- Inside the outer bulb 3 there is a getter 14 which is attached to a squeezing end of the discharge vessel 2.
- the discharge vessel ends both have a heat-reflecting coating 15, 16.
- the first five exemplary embodiments of the invention are each a 70W metal halide high-pressure discharge lamp which generates a warm white light color.
- the ionizable, light-emitting filling of this lamp consists of 125 mbar argon-krypton noble gas mixture, 14.2 mg mercury and 1.4 mg metal halide filler additives.
- the metal halide fill contains 33.51 weight percent sodium iodide (NaI), 34.96 weight percent tin bromide (SnBr 2 ), 23.3 weight percent tin iodide (SnI 2 ), 7.8 weight percent thallium iodide (TlI) and 0.43 weight percent indium iodide (InI).
- the getter substance is introduced into the discharge vessel together with the metal halide fill additives in the form of a solid dosage.
- the exemplary embodiments one to five differ only in the type or the amount of the getter introduced.
- the first exemplary embodiment has approximately 0.4 percent by weight phosphorus iodide (PI 3 ) as an oxygen-binding getter substance, while approximately 2.0 percent by weight phosphorus iodide (PI 3 ) are added to the second exemplary embodiment.
- the getter amount refers to the amount of metal halide fill additives used to emit light.
- boron iodide (BI 3 ) and in the fourth exemplary embodiment approximately 5.0 percent by weight of boron iodide (BI 3 ) are filled into the discharge vessel as oxygen getters.
- the fifth exemplary embodiment contains approximately 0.4 percent by weight of aluminum iodide (AlI 3 ) as the getter substance.
- the exemplary embodiments six to eight are each a double-sided squeezed 150W metal halide high-pressure discharge lamp which emits light of a warm white color.
- the structure of such a lamp is shown schematically in FIG. 1.
- the filling of these lamps consists of 2.8 mg metal halide, which is preferably filled into the discharge vessel as a solid dosage.
- the metal halide fill contains 41.93 weight percent tin iodide (SnI 2 ), 25.32 weight percent sodium iodide (NaI), 17.41 weight percent sodium bromide (NaBr), 12.66 weight percent thallium iodide (TlI), 1.34 weight percent indium iodide (InI) and 1 , 34 percent by weight (LiBr).
- the exemplary embodiments six to nine differ only in the admixed getter substances.
- phosphoric iodide PI 3
- PI 3 phosphoric iodide
- the metal halide filling of the seventh exemplary embodiment is admixed with about 1.8 percent by weight of boron iodide (BI 3 ) as a getter.
- BI 3 boron iodide
- the eighth embodiment contains approximately 0.4 weight percent aluminum iodide (AlI 3 ).
- the tin-phosphorus compound SnP is used as the getter.
- the dosage here is 2.16 percent by weight of SnP the total weight of the metal halide filling components. This corresponds to a phosphorus content of approximately 0.5 percent by weight.
- the invention is not limited to the exemplary embodiments explained in more detail above. So instead of the iodides of aluminum, boron and phosphorus, their bromides or chlorides can also be used. Scandium halide or halides, in particular iodides, bromides and chlorides, of the rare earth metals are also suitable as getter substances. It is also possible to use the substances aluminum, phosphorus, boron, scandium and the rare earth metals in elemental form instead of the getter compounds mentioned above. The rare earth metals or rare earth metal halides and scandium or scandium halide serving as getters are used in such small doses that the getter substances have no significant influence on the emission spectrum, in particular the color temperature, of the lamp. Successful experiments were also carried out with the tungsten-boron compounds WB and W 2 B as oxygen getters.
- the getter substances mentioned above can advantageously also be used in metal halide lamps which emit primarily in the UV range.
- the ionizable filling of these UV lamps contains metal halide additives, which mainly consist of halides (iodides and bromides) of the metals mercury, iron or nickel.
Claims (8)
- Lampe à décharge à haute pression comportant une enceinte de décharge qui renferme une atmosphère ionisable halogénée, qui sert à produire de la lumière ou un rayonnement, et ayant des électrodes en saillie dans le volume de l'enceinte de décharge, caractérisée en ce que l'enceinte de décharge contient un getter fixant l'oxygène, le getter contenant une ou plusieurs substances du groupe suivant: bore, aluminium, iodure de bore, bromure de bore, chlorure de bore, iodure d'aluminium, bromure d'aluminium, chlorure d'aluminium, les composés à base de tungstène et de bore WB et W2B.
- Lampe à décharge à haute pression comportant une enceinte de décharge qui renferme une atmosphère ionisable halogénée, qui sert à produire de la lumière ou un rayonnement, et ayant des électrodes en saillie dans le volume de l'enceinte de décharge, caractérisée en ce que l'enceinte de décharge contient un getter fixant l'oxygène, le getter étant introduit sous forme de scandium ou d'un métal des terres rares ou sous forme d'halogénures du scandium ou d'un métal des terres rares.
- Lampe à décharge à haute pression suivant les revendications 1 ou 2, caractérisée en ce que l'atmosphère ionisable halogénée, qui sert à produire de la lumière ou un rayonnement, contient des halogénures des métaux sodium et étain, ainsi que, éventuellement, des halogénures d'autres métaux.
- Lampe à décharge à haute pression suivant les revendications 1 ou 2, caractérisée en ce que l'atmosphère ionisable halogénée, qui sert à produire de la lumière ou un rayonnement, contient un ou plusieurs halogénures des métaux mercure, fer et/ou nickel, ainsi que, éventuellement, des halogénures d'autres métaux.
- Lampe à décharge à haute pression suivant la revendication 1, caractérisée en ce que le getter contient une ou plusieurs des substances du groupe bore, aluminium, les composés à base de tungstène et de bore WB et W2B, la proportion en poids des substances servant de getter introduites dans l'enceinte de décharge étant, rapportée aux constituants de l'atmosphère aux halogénures métalliques servant à l'émission de lumière ou d'un rayonnement, comprise entre 0,05 et 1 pour-cent en poids.
- Lampe à décharge à haute pression suivant la revendication 1, caractérisée en ce que le getter contient une ou plusieurs des substances du groupe iodure de bore, bromure de bore, chlorure de bore, iodure d'aluminium, bromure d'aluminium, chlorure d'aluminium, la proportion en poids des substances servant de getter introduites dans l'enceinte de décharge étant, rapportée aux constituants de l'atmosphère aux halogénures métalliques servant à l'émission de lumière ou d'un rayonnement, comprise entre 0,1 et 6 pour-cent en poids.
- Lampe à décharge à haute pression suivant la revendication 2, caractérisée en ce que la proportion en poids des substances servant de getter introduites dans l'enceinte de décharge est, rapportée aux constituants de l'atmosphère aux halogénures métalliques servant à l'émission de lumière ou d'un rayonnement, comprise entre 0,05 et 0,5 pour-cent en poids.
- Lampe à décharge à haute pression, comportant une enceinte de décharge qui renferme une atmosphère ionisable halogénée, qui sert à produire de la lumière ou un rayonnement, et ayant des électrodes en saillie dans le volume de l'enceinte de décharge, l'atmosphère ionisable contenant des halogénures des métaux sodium et étain, ainsi que, éventuellement, des halogénures d'autres métaux, et un getter à teneur en phosphore étant introduit dans l'enceinte de décharge, caractérisée en ce que le getter à teneur en phosphore est un getter qui fixe l'oxygène et qui est introduit dans l'enceinte de décharge sous forme d'un composé à base d'étain et de phosphore du groupe SnP, SnP3, Sn4P3 ou d'un halogénure du phosphore.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4325679 | 1993-07-30 | ||
DE4325679A DE4325679A1 (de) | 1993-07-30 | 1993-07-30 | Elektrische Lampe mit Halogenfüllung |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0637056A1 EP0637056A1 (fr) | 1995-02-01 |
EP0637056B1 true EP0637056B1 (fr) | 1997-05-02 |
Family
ID=6494127
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP94111177A Expired - Lifetime EP0637056B1 (fr) | 1993-07-30 | 1994-07-18 | Lampe à décharge haute pression |
Country Status (4)
Country | Link |
---|---|
US (1) | US5461281A (fr) |
EP (1) | EP0637056B1 (fr) |
JP (1) | JP3654929B2 (fr) |
DE (2) | DE4325679A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20210210606A1 (en) * | 2019-11-15 | 2021-07-08 | Alliance For Sustainable Energy, Llc | Oxygen getters for activation of group v dopants in ii-vi semiconductor materials |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2504817B2 (ja) * | 1988-11-16 | 1996-06-05 | キヤノン株式会社 | 光学素子の成形方法 |
JPH07114902A (ja) * | 1993-10-19 | 1995-05-02 | Hamamatsu Photonics Kk | メタルハライドランプ |
US5846109A (en) * | 1996-09-30 | 1998-12-08 | General Electric Company | Oxygen control agents for fluorescent lamps |
US5754002A (en) * | 1996-11-05 | 1998-05-19 | General Electric Company | Antioxidant control of leachable mercury in fluorescent lamps |
US5898272A (en) * | 1997-08-21 | 1999-04-27 | Everbrite, Inc. | Cathode for gas discharge lamp |
TW403819B (en) * | 1998-04-08 | 2000-09-01 | Koninkl Philips Electronics Nv | High-pressure metal-halide lamp |
JP3655126B2 (ja) * | 1999-06-14 | 2005-06-02 | 株式会社小糸製作所 | メタルハライドランプ |
DE60029088T2 (de) * | 1999-11-11 | 2007-02-01 | Koninklijke Philips Electronics N.V. | Hochdruck-gasentladungslampe |
JP3219084B2 (ja) | 2000-03-10 | 2001-10-15 | 日本電気株式会社 | 高圧放電灯およびその製造方法 |
JP2003045373A (ja) | 2001-08-03 | 2003-02-14 | Nec Lighting Ltd | 高圧放電灯 |
EP1766650A4 (fr) * | 2004-07-13 | 2008-06-25 | Advanced Lighting Tech Inc | Lampes a halogenure metallise de krypton |
US7714512B2 (en) * | 2005-10-19 | 2010-05-11 | Matsushita Electric Industrial Co., Ltd. | High red color rendition metal halide lamp |
US7868553B2 (en) * | 2007-12-06 | 2011-01-11 | General Electric Company | Metal halide lamp including a source of available oxygen |
US7777418B2 (en) * | 2008-04-08 | 2010-08-17 | General Electric Company | Ceramic metal halide lamp incorporating a metallic halide getter |
JP2010182581A (ja) * | 2009-02-06 | 2010-08-19 | Seiko Epson Corp | 放電ランプ、光源装置、およびプロジェクタ |
US8497633B2 (en) | 2011-07-20 | 2013-07-30 | General Electric Company | Ceramic metal halide discharge lamp with oxygen content and metallic component |
CN112979465B (zh) * | 2019-12-02 | 2022-06-28 | 浙江省化工研究院有限公司 | 一种制备二氟溴乙酸乙酯的方法 |
CN112978693A (zh) * | 2021-03-09 | 2021-06-18 | 昆明理工大学 | 一种气相法制备三磷化锡的方法 |
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DD110138A1 (fr) * | 1974-02-25 | 1974-12-05 | ||
DE2456757C2 (de) * | 1974-11-30 | 1983-06-01 | Philips Patentverwaltung Gmbh, 2000 Hamburg | Metallhalogenid-Hochdruckgasentladungslampe |
GB1577734A (en) * | 1976-02-25 | 1980-10-29 | Thorn Electrical Ind Ltd | Electric lamps and their production |
JPS55133732A (en) * | 1979-04-06 | 1980-10-17 | Toshiba Corp | Manufacture of metal halide lamp |
US4360756A (en) * | 1979-11-13 | 1982-11-23 | General Electric Company | Metal halide lamp containing ThI4 with added elemental cadmium or zinc |
US4633136A (en) * | 1982-04-20 | 1986-12-30 | Patent-Treuhand-Gesellschaft Fur Elektrische Gluhlampen Mbh | High-pressure discharge lamp with low power input |
CA1222274A (fr) * | 1983-03-10 | 1987-05-26 | Philip J. White | Support de degazeur de lampe a vapeur de sodium haute pression non saturee |
US4859905A (en) * | 1983-03-10 | 1989-08-22 | Gte Products Corporation | Unsaturated vapor high pressure sodium lamp getter mounting |
US5034656A (en) * | 1989-09-26 | 1991-07-23 | General Electric Company | Tungsten halogen lamp including phosphorous and bromine |
DE4013039A1 (de) * | 1990-04-24 | 1991-10-31 | Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh | Hochdruckentladungslampe |
DE4132530A1 (de) * | 1991-09-30 | 1993-04-01 | Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh | Hochdruckentladungslampe kleiner leistung |
-
1993
- 1993-07-30 DE DE4325679A patent/DE4325679A1/de not_active Withdrawn
-
1994
- 1994-07-06 JP JP17762394A patent/JP3654929B2/ja not_active Expired - Fee Related
- 1994-07-07 US US08/271,192 patent/US5461281A/en not_active Expired - Lifetime
- 1994-07-18 EP EP94111177A patent/EP0637056B1/fr not_active Expired - Lifetime
- 1994-07-18 DE DE59402590T patent/DE59402590D1/de not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20210210606A1 (en) * | 2019-11-15 | 2021-07-08 | Alliance For Sustainable Energy, Llc | Oxygen getters for activation of group v dopants in ii-vi semiconductor materials |
Also Published As
Publication number | Publication date |
---|---|
JPH0757697A (ja) | 1995-03-03 |
EP0637056A1 (fr) | 1995-02-01 |
US5461281A (en) | 1995-10-24 |
DE4325679A1 (de) | 1995-02-02 |
JP3654929B2 (ja) | 2005-06-02 |
DE59402590D1 (de) | 1997-06-05 |
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