EP0616028A1 - Cleaning compositions with short chain nonionic surfactants - Google Patents

Cleaning compositions with short chain nonionic surfactants Download PDF

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Publication number
EP0616028A1
EP0616028A1 EP93870050A EP93870050A EP0616028A1 EP 0616028 A1 EP0616028 A1 EP 0616028A1 EP 93870050 A EP93870050 A EP 93870050A EP 93870050 A EP93870050 A EP 93870050A EP 0616028 A1 EP0616028 A1 EP 0616028A1
Authority
EP
European Patent Office
Prior art keywords
hydrocarbon
short chain
mixtures
formula
surfactants
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP93870050A
Other languages
German (de)
English (en)
French (fr)
Inventor
Michel Jean Carrié
William Ajalon Cilley
Peter Rosalia Joannes Geboes
Massimo Morini
Louise Gail Scott
Eddy Vos
Ricky Ah-Man Woo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to EP93870050A priority Critical patent/EP0616028A1/en
Priority to EP93870125A priority patent/EP0616026A1/en
Priority to DK93870181T priority patent/DK0600847T3/da
Priority to EP93870181A priority patent/EP0600847B2/en
Priority to DE69321562T priority patent/DE69321562T3/de
Priority to ES93870181T priority patent/ES2124778T5/es
Priority to AT93870181T priority patent/ATE172234T1/de
Priority to TR01058/93A priority patent/TR28413A/xx
Priority to EP93870215A priority patent/EP0616027A1/en
Priority to AU56149/94A priority patent/AU681365B2/en
Priority to CA002149227A priority patent/CA2149227C/en
Priority to PCT/US1993/011293 priority patent/WO1994012599A1/en
Priority to KR1019950702134A priority patent/KR950704462A/ko
Priority to NZ258466A priority patent/NZ258466A/en
Priority to US08/432,154 priority patent/US5559091A/en
Priority to BR9307515-4A priority patent/BR9307515A/pt
Priority to JP6513290A priority patent/JPH08505413A/ja
Priority to EG73993A priority patent/EG20373A/xx
Priority to MA23345A priority patent/MA23039A1/fr
Priority to NZ263393A priority patent/NZ263393A/en
Priority to BR9406012A priority patent/BR9406012A/pt
Priority to NZ263930A priority patent/NZ263930A/en
Priority to AU65194/94A priority patent/AU6519494A/en
Priority to JP6521159A priority patent/JPH08507825A/ja
Priority to CN 94192052 priority patent/CN1122611A/zh
Priority to JP6521160A priority patent/JPH08508765A/ja
Priority to PCT/US1994/002746 priority patent/WO1994021770A1/en
Priority to KR1019950703979A priority patent/KR960701185A/ko
Priority to BR9406015A priority patent/BR9406015A/pt
Priority to CN94192051A priority patent/CN1122612A/zh
Priority to CA002158541A priority patent/CA2158541C/en
Priority to CN94192049A priority patent/CN1044717C/zh
Priority to JP6521161A priority patent/JPH08508766A/ja
Priority to CA 2158542 priority patent/CA2158542A1/en
Priority to AU64073/94A priority patent/AU6407394A/en
Priority to PCT/US1994/002747 priority patent/WO1994021767A1/en
Priority to BR9406013A priority patent/BR9406013A/pt
Priority to AU64074/94A priority patent/AU695680B2/en
Priority to CA002158543A priority patent/CA2158543C/en
Priority to US08/522,354 priority patent/US5707948A/en
Priority to PCT/US1994/002748 priority patent/WO1994021768A1/en
Priority to US08/522,391 priority patent/US5981455A/en
Priority to NZ26339494A priority patent/NZ263394A/en
Priority to MA23443A priority patent/MA23136A1/fr
Priority to MA23446A priority patent/MA23138A1/fr
Priority to MA23445A priority patent/MA23137A1/fr
Publication of EP0616028A1 publication Critical patent/EP0616028A1/en
Priority to FI952540A priority patent/FI952540A/fi
Priority to NO952058A priority patent/NO952058L/no
Priority to NO953503A priority patent/NO953503D0/no
Priority to NO953502A priority patent/NO953502D0/no
Priority to NO953644A priority patent/NO953644L/no
Priority to FI954395A priority patent/FI954395A0/fi
Priority to FI954397A priority patent/FI954397A0/fi
Priority to FI954396A priority patent/FI954396A0/fi
Priority to AU74176/98A priority patent/AU7417698A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0026—Low foaming or foam regulating compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C11D1/8255—Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups

Definitions

  • the present invention relates to cleaning compositions. Although the present invention applies primarily to hard surface cleaning compositions, it may also be of interest for other cleaning compositions including dishwashing and laundry detergent compositions.
  • short chain alkoxylated alcohols namely alkoxylated alcohols with a short alkyl chain in the alcohol, hereinafter short chain alkoxylated alcohols.
  • said short chain alkoxylated alcohols are particularly efficient in cleaning.
  • Such short chain alkoxylated alcohols further meet the other objects of providing surfactants which are low foaming and which are mild to the skin.
  • Another advantage is that such short chain alkoxylated alcohols are particularly suitable for formulating concentrated cleaning compositions.
  • EP 125 854 discloses a composition comprising 2.7% of C8EO4.8 together with 14.2% of ammonium C11.8 linear alkyl benzene sulphonate, 10.4 of ammonium C12-13 alkyl ethoxylated sulphate, 8.6% magnesium C12-13 alkyl sulphate, 4.0% coconut monoethanolamide and 9.1% ethanol and water. EP 125 854 however fails to draw the difference between long and short chain nonionic surfactants.
  • EP 496 188 discloses an aqueous solution comprising 3% of C8EO6 and 8% maleic acid. EP 486 188 does not draw the difference between long and short chain nonionic surfactants.
  • the present invention encompasses aqueous cleaning compositions comprising a short chain alkoxylated alcohol surfactant according to the formula RO(A)nH, wherein R is a C6 to C10 hydrocarbon chain, A is ethylene oxide or propylene oxide or mixtures thereof and n is of from 1 to 10, or mixtures thereof, and other conventional cleaning ingredients selected from anionic, cationic, zwitterionic and nonionic co-surfactants, including short chain co-surfactants, builders, solvents, bleaches and minors including dyes, perfumes, or mixtures thereof.
  • a short chain alkoxylated alcohol surfactant according to the formula RO(A)nH, wherein R is a C6 to C10 hydrocarbon chain, A is ethylene oxide or propylene oxide or mixtures thereof and n is of from 1 to 10, or mixtures thereof
  • other conventional cleaning ingredients selected from anionic, cationic, zwitterionic and nonionic co-surfactants, including short chain co-surfactants, builders, solvents
  • the present invention also encompasses such compositions in a concentrated form, the use of said surfactants for neat grease cleaning, for dilute grease cleaning and for soap scum cleaning.
  • the present invention further encompasses the use of said surfactants as skin mild surfactants and as low foaming surfactants.
  • the present invention encompasses aqueous compositions which comprise conventional cleaning ingredients and a short chain alkoxylated alcohol surfactant.
  • the short chain nonionic surfactants for use herein are alkoxylated alcohols according to the formula RO(A)nH, wherein R is a C6 to C10 hydrocarbon chain and n, representing the average alkoxylation degree, is from 1 to 10, or mixtures thereof. R is indifferently straight or branched. A is ethylene oxide or propylene oxide or mixtures thereof. Similar nonionic surfactants which have longer R groups than those of the present invention are known in the art and are commonly used in cleaning compositions. The present invention is based on the finding that alkoxylated alcohols with shorter R groups provide better cleaning, as well as the multiple benefits described herein.
  • Suitable surfactants for use herein can be readily made by condensing alcohols having the desired chain length with propylene or ethylene oxide, or mixtures thereof, as disclosed in the art for alkoxylated alcohols with longer chains.
  • Suitable short chain alkoxylated alcohols for use herein are also commercially available from several suppliers, for instance Dehydol 04 R from Henkel (C8EO4), Mergital C4 R from Sidobre (C8EO4), and Imbentin AG/810/050 and AG/810/080 R from Kolb (respectively C8-10EO5 and C8-10EO8).
  • compositions according to the present invention comprise from 0.1% to 50% by weight of the total composition of said short chain alkoxylated alcohols, preferably from 1% to 30%, most preferably from 1.5% to 20%.
  • the short chain alkoxylated alcohols herein are particularly suitable for the formulation of so-called concentrated cleaning compositions. Indeed, the short chain alkoxylated alcohols have a very high solubility in water, but they are also able to solubilize other conventional organic ingredients for cleaning compositions, such as perfumes.
  • cleaning compositions are provided in a concentrated form, which only comprise from 1% to 80% by weight of the total composition of water, preferably from 30% to 70%.
  • Such compositions typically comprise from 0.1% to 50% by weight of the total composition of said short chain alkoxylated alcohols, preferably from 5% to 30%.
  • the present invention encompasses the use of said surfactants for neat grease cleaning.
  • neat grease cleaning means the cleaning of greasy soils, using an aqueous solution comprising at least one of the surfactants according to the present invention, within the ranges above.
  • Greasy soils are typically found in kitchens or bathrooms.
  • Preferred short chain alkoxylated alcohols for use in neat grease cleaning are those according to the formula hereinabove where R is a hydrocarbon chain from C6 to C8 and n is from 1 to 10.
  • Preferred short chain alcohol ethoxylates for neat grease cleaning are the surfactants according to the formula above where R is a C6 hydrocarbon chain and n is 4 or 6 (C6EO4 and C6EO6); or R is a C8 hydrocarbon chain and n is 4 or 6 (C8EO4 and C8EO6); or R is a C8 hydrocarbon chain and n is 10 (C8EO10).
  • dilute grease cleaning means the cleaning of greasy soils using an aqueous solution comprising a surfactant according to the present invention, in the ranges described above, but which is diluted typically in 10 to 150 times its weight in water before it is used to clean the greasy soils.
  • Dilute cleaning compositions and conditions have been described for instance in EP 503 219.
  • Suitable short chain alkoxylated alcohols for use in dilute grease cleaning are those according to the formula hereinabove where R a hydrocarbon chain from C8 to C10, and n is from 1 to 10.
  • R a hydrocarbon chain from C8 to C10
  • n is from 1 to 10.
  • Preferred short chain alkoxylated alcohols herein for dilute grease cleaning are those according to the formula herein above where R is a C8 hydrocarbon chain and n is of from 4 to 10, preferably 4, 6 or 10 (C8EO4, C8EO6, C8EO10), R is a C10 hydrocarbon and n ranges from 3 to 6 or n is 10 (C10EO3, C10EO4, C10EO5, C10EO6, C10EO10), as well as a mixture of surfactants where R is a C10 hydrocarbon and a C8 hydrocarbon and n is 5 (C8-10EO5), or n is 8 (C8-C10EO8).
  • the present invention encompasses the use of said surfactants for cleaning soap scum. Soap scum, which is mainly found in bathroom is quite peculiar in its composition and traditionally leads detergent manufacturers to formulate specialty cleaning products for bathroom environment. The present invention is thus particularly applicable to the formulation of such specialty products.
  • Suitable short chain alkoxylated alcohols for use in cleaning soap scum are those wherein, in the formula hereinabove, R a hydrocarbon chain from C8 to C10, and n is from 1 to 10. When R is in the higher range, i.e. towards 10, it is preferred to use lower ethoxylation degrees, typically 1 to 6.
  • Preferred alkoxylated alcohols for cleaning soap scum are those where, in the formula hereinabove, R is a C8 hydrocarbon chain and n is of from 4 to 10, preferably 4, 6 or 10 (C8EO4, C8EO6, C8EO10), R is a C10 hydrocarbon and n ranges from 3 to 6 (C10EO3, C10EO4, C10EO5, C10EO6), as well as a mixture of surfactants where R is a C10 hydrocarbon and a C8 hydrocarbon and n is 5 (C8-10EO5), or n is 8 (C8-C10EO8).
  • the present invention encompasses the use of said surfactants as low foaming surfactants.
  • Low foaming surfactants are usually of interest for heavy duty laundry detergents, but also for hard surface cleaners which are designed to be used as no-rinse products in dilute form.
  • the surfactants within the present invention which have been found to produce low foaming are those according to the formula herein above where R is a C6 to C10 hydrocarbon chain and n is of from 1 to 10.
  • Preferred low foaming surfactants herein are those where R is a C6 hydrocarbon chain and n is 4 or 6 (C6EO4, C6EO6); or R is a C8 hydrocarbon chain and n is 4, 6 or 10 (C8EO4, C8EO6, C8EO10), R is a C10 hydrocarbon and n ranges from 3 to 6 (C10EO3, C10EO4, C10EO5, C10EO6), as well as a mixture of surfactants where R is a C10 hydrocarbon and a C8 hydrocarbon and n is 5 (C8-10EO5), or n is 8 (C8-C10EO8); or mixtures thereof.
  • the present invention encompasses the use of said surfactants as skin mild surfactants. Mildness to the skin is quite an advantage when formulating products which are bound to be in contact with the user's skin. Such is the case for dishwashing compositions, or hard surface cleaning compositions. Skin mildness benefits are usually advertised when they exist in a given product.
  • the surfactants within the present invention which have been found to be particularly mild to the skin are those according to the formula herein above where R is a C6 to C8 hydrocarbon chain and n is of from 1 to 10.
  • Preferred surfactants are those where R is a C6 hydrocarbon chain and n is 4 or 6 (C6EO4, C6EO6), or R is a C8 hydrocarbon chain and n is 4, 6 or 10, or mixtures thereof (C8EO4, C8EO6, C8EO10).
  • compositions according to the invention further comprise conventional ingredients selected from other nonionic, anionic, cationic and zwitterionic co-surfactants (from 0% to 30% by weight of the total composition, preferably from 1% to 20%), builders (from 0% to 20% by weight of the total composition, preferably from 1% to 10%), solvents (from 0% to 20% by weight of the total composition, preferably from 0% to 5%), non-hypochlorite bleaches (from 0% to 10% by weight of the total composition, preferably from 1% to 5%) and minors including dyes, perfumes, all of which are well known and extensively described in the art.
  • nonionic, anionic, cationic and zwitterionic co-surfactants from 0% to 30% by weight of the total composition, preferably from 1% to 20%
  • builders from 0% to 20% by weight of the total composition, preferably from 1% to 10%
  • solvents from 0% to 20% by weight of the total composition, preferably from 0% to 5%
  • compositions according to the present invention depend on the end-use envisioned. Mixtures of the short chain surfactants according to the present invention can also be used in order to combine several benefits. Compositions according to the present invention can be formulated indifferently as alkaline and acidic hard surface cleaners, dishwashing products or laundry detergents.
  • compositions are made by mixing the listed ingredients in the listed proportions.
  • Triethanolamine 1.9 1.9 - 1.0 - MEA up to pH - - - - 7 Ammonia up to pH 3.5 3.5 2.0 - - NaOH up to pH - - - 10.5 - Water and minors -----------up to 100% -------------------- Lutensol AO30 is C13-15(EO)30 Lutensol AO7 is C13-15(EO)7 MEA stands for monoethanolamine.
  • compositions 1 and 2 hereinabove are particularly efficient in removing soapscum and are therefore particularly suitable as a bathroom cleaner.
  • Composition 3 is particularly effective in providing low suds.
  • Composition 4 is particularly effective on dilute and neat grease cleaning.
  • Composition 5 is a concentrated composition.

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  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Medicinal Preparation (AREA)
EP93870050A 1992-11-26 1993-03-19 Cleaning compositions with short chain nonionic surfactants Withdrawn EP0616028A1 (en)

Priority Applications (55)

Application Number Priority Date Filing Date Title
EP93870050A EP0616028A1 (en) 1993-03-19 1993-03-19 Cleaning compositions with short chain nonionic surfactants
EP93870125A EP0616026A1 (en) 1993-03-19 1993-07-07 Concentrated cleaning compositions
DK93870181T DK0600847T3 (da) 1992-11-26 1993-08-31 Rensesammensætning med kombineret stærkt hydrofile og stærkt hydrofobe, nonioniske, overfladeaktive midler
EP93870181A EP0600847B2 (en) 1992-11-26 1993-08-31 Cleaning compositions with combined highly hydrophilic and highly hydrophobic nonionic surfactants
DE69321562T DE69321562T3 (de) 1992-11-26 1993-08-31 Reinigungsmittelzusammensetzungen mit einer Kombination aus stark hydrophilen und stark hydrophoben nichtionischen Tensiden
ES93870181T ES2124778T5 (es) 1992-11-26 1993-08-31 Composiciones de limpieza con tensioactivos no ionicos combinados muy hidrofilos y muy hidrofobos.
AT93870181T ATE172234T1 (de) 1992-11-26 1993-08-31 Reinigungsmittelzusammensetzungen mit einer kombination aus stark hydrophilen und stark hydrophoben nichtionischen tensiden
TR01058/93A TR28413A (tr) 1992-11-26 1993-11-16 Birlikte yüksek ölcüde hidrofilik ve yüksek ölcüde hidrofobik noniyonik sürfaktanlara sahip olan temizleme bilesimleri.
EP93870215A EP0616027A1 (en) 1993-03-19 1993-11-16 Concentrated cleaning compositions
AU56149/94A AU681365B2 (en) 1992-11-26 1993-11-19 Cleaning compositions with combined highly hydrophilic and highly hydrophobic nonionic surfactants
CA002149227A CA2149227C (en) 1992-11-26 1993-11-19 Cleaning compositions with combined highly hydrophilic and highly hydrophobic nonionic surfactants
PCT/US1993/011293 WO1994012599A1 (en) 1992-11-26 1993-11-19 Cleaning compositions with combined highly hydrophilic and highly hydrophobic nonionic surfactants
KR1019950702134A KR950704462A (ko) 1992-11-26 1993-11-19 고 친수성 및 고 소수성 비이온계 계면활성제의 혼합물을 함유하는 세정 조성물(cleaning compositions with combined highly hydrophilic and highly hydrophobic nonionic surfactants)
NZ258466A NZ258466A (en) 1992-11-26 1993-11-19 Cleaning compositions comprising a non-ionic surfactant system containing a mixture of highly hydrophilic and highly hydrophobic non-ionic surfactants and at least one alkanolamine
US08/432,154 US5559091A (en) 1992-11-26 1993-11-19 Alkaline cleaning compositions with combined highly hydrophilic and highly hydrophobic nonionic surfactants
BR9307515-4A BR9307515A (pt) 1992-11-26 1993-11-19 Composições de limpeza com tensoativos não iÈnicos altamente hidrofìlicos e altamente hidrofóbicos combinados
JP6513290A JPH08505413A (ja) 1992-11-26 1993-11-19 高親水性および高疎水性のノニオン性界面活性剤を組み合わせたクリーニング組成物
EG73993A EG20373A (en) 1992-11-26 1993-11-24 Cleaning compositions with combined highly hydrophilic and highly hydrophobic monionic surfactants
MA23345A MA23039A1 (fr) 1992-11-26 1993-11-25 Composition de nettoyage avec des tensio-actifs non ioniques hautement hydrophiles et hautement hydrophobes combines.
NZ263393A NZ263393A (en) 1993-03-19 1994-03-14 Cleaning composition; stable, clear, concentrated composition comprising at least one long chain surfactant and stabilised by the additional presence of short chain surfactants
BR9406012A BR9406012A (pt) 1993-03-19 1994-03-14 Composições de limpeza com tensoativos nao-iônicos de cadeia, curta
NZ263930A NZ263930A (en) 1993-03-19 1994-03-14 Aqueous cleaning composition comprising short chain alkoxylated alcohols as nonionic surfactants
AU65194/94A AU6519494A (en) 1993-03-19 1994-03-14 Cleaning compositions with short chain nonionic surfactants
JP6521159A JPH08507825A (ja) 1993-03-19 1994-03-14 短鎖のノニオン性界面活性剤を含むクリーニング組成物
CN 94192052 CN1122611A (zh) 1993-03-19 1994-03-14 浓缩洗涤剂组合物
JP6521160A JPH08508765A (ja) 1993-03-19 1994-03-14 濃縮クリーニング組成物
PCT/US1994/002746 WO1994021770A1 (en) 1993-03-19 1994-03-14 Cleaning compositions with short chain nonionic surfactants
KR1019950703979A KR960701185A (ko) 1993-03-19 1994-03-14 단쇄 비이온성 계면활성제가 함유된 세정 조성물(Cleaning compositions with short chain nonionic surfactants)
BR9406015A BR9406015A (pt) 1993-03-19 1994-03-14 Composiçoes de limpeza concentradas
CN94192051A CN1122612A (zh) 1993-03-19 1994-03-14 含短链非离子型表面活性剂的洗涤剂组合物
CA002158541A CA2158541C (en) 1993-03-19 1994-03-14 Cleaning compositions with short chain nonionic surfactants
CN94192049A CN1044717C (zh) 1993-03-19 1994-03-14 浓缩的清洗组合物
JP6521161A JPH08508766A (ja) 1993-03-19 1994-03-14 濃縮クリーニング組成物
CA 2158542 CA2158542A1 (en) 1993-03-19 1994-03-14 Concentrated cleaning compositions
AU64073/94A AU6407394A (en) 1993-03-19 1994-03-14 Concentrated cleaning compositions
PCT/US1994/002747 WO1994021767A1 (en) 1993-03-19 1994-03-14 Concentrated cleaning compositions
BR9406013A BR9406013A (pt) 1993-03-19 1994-03-14 Composições de limpeza concentrades
AU64074/94A AU695680B2 (en) 1993-03-19 1994-03-14 Concentrated cleaning compositions
CA002158543A CA2158543C (en) 1993-03-19 1994-03-14 Concentrated cleaning compositions
US08/522,354 US5707948A (en) 1993-03-19 1994-03-14 Stable and clear concentrated cleaning compositions comprising at least one short chain surfactant
PCT/US1994/002748 WO1994021768A1 (en) 1993-03-19 1994-03-14 Concentrated cleaning compositions
US08/522,391 US5981455A (en) 1993-03-19 1994-03-14 Cleaning compositions with short chain nonionic surfactants
NZ26339494A NZ263394A (en) 1993-03-19 1994-03-14 Cleaning composition; stable, concentrated and clear composition comprising at least one short chain surfactant, the composition not being in the form of a microemulsion
MA23443A MA23136A1 (fr) 1993-03-19 1994-03-16 Composition de nettoyage comprenant des tensio- actifs a courte chaine .
MA23446A MA23138A1 (fr) 1993-03-19 1994-03-17 Compositions de nettoyages concentrees comprenat au moins un agent tensio-actif achaine courte
MA23445A MA23137A1 (fr) 1993-03-19 1994-03-17 Composition de netoyage concentrees
FI952540A FI952540A (fi) 1992-11-26 1995-05-24 Puhdistuskoostumukset, joissa on hyvin hydrofiilisiä ja hyvin hydrofobisia ei-ionisia pinta-aktiivisia aineita
NO952058A NO952058L (no) 1992-11-26 1995-05-24 Renseblandinger med kombinerte höyhydrofile og höyhydrofobe ikke-ioniske overflateaktive midler
NO953503A NO953503D0 (no) 1993-03-19 1995-09-06 Konsentrerte rengjöringsblandinger
NO953502A NO953502D0 (no) 1993-03-19 1995-09-06 Renseblandinger med kortkjedede ikke-ioniske overflateaktive midler
NO953644A NO953644L (no) 1993-03-19 1995-09-15 Konsentrerte rengjöringsblandinger
FI954395A FI954395A0 (fi) 1993-03-19 1995-09-18 Lyhytketjuisia ionittomia pinta-aktiivisia aineita sisältäviä puhdistuskoostumuksia
FI954397A FI954397A0 (fi) 1993-03-19 1995-09-18 Konsentroituja puhdistuskoostumuksia
FI954396A FI954396A0 (fi) 1993-03-19 1995-09-18 Konsentroituja puhdistuskoostumuksia
AU74176/98A AU7417698A (en) 1993-03-19 1998-07-06 Cleaning compositions with short chain nonionic surfactants

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP93870050A EP0616028A1 (en) 1993-03-19 1993-03-19 Cleaning compositions with short chain nonionic surfactants

Publications (1)

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EP0616028A1 true EP0616028A1 (en) 1994-09-21

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EP93870050A Withdrawn EP0616028A1 (en) 1992-11-26 1993-03-19 Cleaning compositions with short chain nonionic surfactants

Country Status (12)

Country Link
EP (1) EP0616028A1 (zh)
JP (1) JPH08507825A (zh)
KR (1) KR960701185A (zh)
CN (1) CN1122612A (zh)
AU (2) AU6519494A (zh)
BR (1) BR9406012A (zh)
CA (1) CA2158541C (zh)
FI (1) FI954395A0 (zh)
MA (1) MA23136A1 (zh)
NO (1) NO953502D0 (zh)
NZ (1) NZ263930A (zh)
WO (1) WO1994021770A1 (zh)

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US5767055A (en) * 1996-02-23 1998-06-16 The Clorox Company Apparatus for surface cleaning
WO2000029528A2 (en) * 1998-11-12 2000-05-25 Colgate-Palmolive Company Microemulsion liquid cleaning composition containing a short chain amphiphile
WO2006008094A1 (de) 2004-07-16 2006-01-26 Basf Aktiengesellschaft Methode zur beschleunigung der netzung in lacken
US7371716B2 (en) 2002-04-26 2008-05-13 Basf Aktiengesellschaft C10-alkanolalkoxylate mixtures and the use thereof
US7419552B2 (en) 2002-04-26 2008-09-02 Basf Aktiengesellschaft C10-alkanol alkoxylates and the use thereof
WO2008132133A1 (de) * 2007-04-25 2008-11-06 Basf Se Phosphatfreies maschinengeschirrspülmittel mit ausgezeichneter klarspülleistung
WO2008137381A1 (en) * 2007-05-03 2008-11-13 Innovation Services, Inc. Water soluble barrier film conformal coating composition and method of cleaning contaminated surfaces
WO2009156254A1 (de) * 2008-06-26 2009-12-30 Henkel Ag & Co. Kgaa Schmutzabweisendes reinigungsmittel
US20100069509A1 (en) * 2006-12-14 2010-03-18 Basf Se Nonionic emulsifiers for emulsion concentrates for spontaneous emulsification
WO2010070088A1 (de) 2008-12-18 2010-06-24 Basf Se Tensidgemisch enthaltend verzweigte kurzkettige sowie verzweigte langkettige komponenten
WO2011003904A1 (de) 2009-07-10 2011-01-13 Basf Se Tensidgemisch mit kurz- und langkettigen komponenten
US8152931B2 (en) 2007-04-25 2012-04-10 Basf Se Dishwasher detergent with excellent rinsing power
EP3418358A1 (en) * 2017-06-22 2018-12-26 The Procter & Gamble Company Cleaning product
US11180715B2 (en) 2017-06-22 2021-11-23 The Procter & Gamble Company Sprayable cleaning composition

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EP0616027A1 (en) * 1993-03-19 1994-09-21 The Procter & Gamble Company Concentrated cleaning compositions
JP3464593B2 (ja) * 1997-07-08 2003-11-10 ライオン株式会社 液体洗浄剤組成物
CA2300456C (en) 1999-03-12 2004-05-11 Pfizer Products Inc. Compositions comprising a potassium salt active ingredient, including oral compositions for reducing dental nerve and dentin sensitivity comprising a non-menthol flavoring
DE102010055742A1 (de) * 2010-12-22 2012-06-28 Clariant International Ltd. Zusammensetzungen enthaltend sekundäres Paraffinsulfonat und Alkoholalkoxylat
DE102010055743A1 (de) * 2010-12-22 2012-06-28 Clariant International Ltd. Zusammensetzungen enthaltend sekundäres Paraffinsulfonat und Alkoholalkoxylat
RU2016128716A (ru) * 2013-12-23 2018-01-30 Акцо Нобель Кемикалз Интернэшнл Б.В. Способ промывки шерсти
CN106701351A (zh) * 2015-11-12 2017-05-24 艺康美国股份有限公司 低起泡器皿清洗清洁剂，含增强含油污垢除去的混合的阳离子/非离子表面活性剂体系
CN107446719A (zh) * 2017-08-25 2017-12-08 中山市优贝科技股份有限公司 汽车表面清洗剂及其制备方法

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EP0496188A1 (en) * 1991-01-22 1992-07-29 The Procter & Gamble Company Limescale removing composition

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GB1462134A (en) * 1974-03-21 1977-01-19 Procter & Gamble Detergent compositions
FR2339672A1 (fr) * 1976-02-02 1977-08-26 Procter & Gamble Compositions detergentes contenant un agent tensioactif non ionique et un ether cellulosique
EP0125854A2 (en) * 1983-05-14 1984-11-21 The Procter & Gamble Company Liquid detergent compositions
EP0213554A2 (de) * 1985-08-28 1987-03-11 Henkel Kommanditgesellschaft auf Aktien Demulgierendes Reinigungsmittel mit Flächenfeuchthalteeffekt
EP0244006A1 (en) * 1986-04-22 1987-11-04 Unilever N.V. General-purpose cleaning composition
US4772415A (en) * 1986-12-22 1988-09-20 Adone Donald J Heavy duty degreaser composition and method of use
EP0340704A2 (de) * 1988-05-05 1989-11-08 BASF Aktiengesellschaft Wässrige saure Reinigerformulierungen
EP0496188A1 (en) * 1991-01-22 1992-07-29 The Procter & Gamble Company Limescale removing composition

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5767055A (en) * 1996-02-23 1998-06-16 The Clorox Company Apparatus for surface cleaning
WO2000029528A2 (en) * 1998-11-12 2000-05-25 Colgate-Palmolive Company Microemulsion liquid cleaning composition containing a short chain amphiphile
WO2000029528A3 (en) * 1998-11-12 2000-10-05 Colgate Palmolive Co Microemulsion liquid cleaning composition containing a short chain amphiphile
US7419552B2 (en) 2002-04-26 2008-09-02 Basf Aktiengesellschaft C10-alkanol alkoxylates and the use thereof
US7371716B2 (en) 2002-04-26 2008-05-13 Basf Aktiengesellschaft C10-alkanolalkoxylate mixtures and the use thereof
US7608653B2 (en) 2004-07-16 2009-10-27 Basf Aktiengesellschaft Method for accelerating the cross-linking process in paints
WO2006008094A1 (de) 2004-07-16 2006-01-26 Basf Aktiengesellschaft Methode zur beschleunigung der netzung in lacken
US8163101B2 (en) 2006-07-26 2012-04-24 Stryker Corporation Method of cleaning contaminated surfaces
US7540926B2 (en) 2006-07-26 2009-06-02 Innovation Services, Inc. Method of cleaning contaminated surfaces
US7541321B2 (en) 2006-07-26 2009-06-02 Innovation Services, Inc. Water soluble barrier film conformal coating composition
US7893015B2 (en) 2006-07-26 2011-02-22 Stryker Corporation Water soluble barrier film conformal coating composition and method of cleaning contaminated surfaces
US20100069509A1 (en) * 2006-12-14 2010-03-18 Basf Se Nonionic emulsifiers for emulsion concentrates for spontaneous emulsification
US8152931B2 (en) 2007-04-25 2012-04-10 Basf Se Dishwasher detergent with excellent rinsing power
US8123867B2 (en) 2007-04-25 2012-02-28 Basf Se Phosphate-free dishwasher detergent with excellent rinsing power
WO2008132133A1 (de) * 2007-04-25 2008-11-06 Basf Se Phosphatfreies maschinengeschirrspülmittel mit ausgezeichneter klarspülleistung
WO2008137381A1 (en) * 2007-05-03 2008-11-13 Innovation Services, Inc. Water soluble barrier film conformal coating composition and method of cleaning contaminated surfaces
WO2009156254A1 (de) * 2008-06-26 2009-12-30 Henkel Ag & Co. Kgaa Schmutzabweisendes reinigungsmittel
WO2010070088A1 (de) 2008-12-18 2010-06-24 Basf Se Tensidgemisch enthaltend verzweigte kurzkettige sowie verzweigte langkettige komponenten
WO2011003904A1 (de) 2009-07-10 2011-01-13 Basf Se Tensidgemisch mit kurz- und langkettigen komponenten
EP3418358A1 (en) * 2017-06-22 2018-12-26 The Procter & Gamble Company Cleaning product
WO2018236713A1 (en) * 2017-06-22 2018-12-27 The Procter & Gamble Company CLEANING PRODUCT
US11124739B2 (en) 2017-06-22 2021-09-21 The Procter & Gamble Company Cleaning product
US11180715B2 (en) 2017-06-22 2021-11-23 The Procter & Gamble Company Sprayable cleaning composition

Also Published As

Publication number Publication date
NZ263930A (en) 1998-03-25
JPH08507825A (ja) 1996-08-20
AU7417698A (en) 1998-10-01
AU6519494A (en) 1994-10-11
CN1122612A (zh) 1996-05-15
CA2158541C (en) 1999-05-18
CA2158541A1 (en) 1994-09-29
WO1994021770A1 (en) 1994-09-29
MA23136A1 (fr) 1994-10-01
BR9406012A (pt) 1996-01-02
NO953502L (no) 1995-09-06
FI954395A (fi) 1995-09-18
NO953502D0 (no) 1995-09-06
FI954395A0 (fi) 1995-09-18
KR960701185A (ko) 1996-02-24

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