EP0549577A1 - Verfahren und vorrichtung zum trocknen von feststoffmaterialien in einem indirekt beheizten wirbelschichtbett. - Google Patents
Verfahren und vorrichtung zum trocknen von feststoffmaterialien in einem indirekt beheizten wirbelschichtbett.Info
- Publication number
- EP0549577A1 EP0549577A1 EP90916213A EP90916213A EP0549577A1 EP 0549577 A1 EP0549577 A1 EP 0549577A1 EP 90916213 A EP90916213 A EP 90916213A EP 90916213 A EP90916213 A EP 90916213A EP 0549577 A1 EP0549577 A1 EP 0549577A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fluidized bed
- solid material
- steam
- solid
- discharged
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B3/00—Drying solid materials or objects by processes involving the application of heat
- F26B3/02—Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air
- F26B3/06—Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air the gas or vapour flowing through the materials or objects to be dried
- F26B3/08—Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air the gas or vapour flowing through the materials or objects to be dried so as to loosen them, e.g. to form a fluidised bed
- F26B3/084—Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air the gas or vapour flowing through the materials or objects to be dried so as to loosen them, e.g. to form a fluidised bed with heat exchange taking place in the fluidised bed, e.g. combined direct and indirect heat exchange
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B3/00—Drying solid materials or objects by processes involving the application of heat
- F26B3/02—Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air
- F26B3/06—Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air the gas or vapour flowing through the materials or objects to be dried
- F26B3/08—Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air the gas or vapour flowing through the materials or objects to be dried so as to loosen them, e.g. to form a fluidised bed
Definitions
- the invention relates to a method and a device for drying solid materials, such as lignite, peat, sand, filter cakes from mechanical separation processes and sludges which contain less than 98% by mass of a vaporizable material, for example water, in which an indirectly heated fluidized bed is formed, which contains the solid material whirled up by a fluidizing medium, the fluidizing medium being the vaporizable material in vapor form and in which the dried material discharged from the fluidized bed dryer, optionally after cooling, further processing, Use or landfill, but the vaporized material can be supplied for cleaning, cooling, material use and / or heat energy recovery " and is suitable for use in industry, construction, agriculture and municipal disposal.
- a vaporizable material for example water
- Drying processes in particular those which separate water as a vaporizable fraction from solid materials, were of great economic and social importance for industrial production, construction, energy conversion and the disposal of municipalities and businesses. Drying is sometimes as natural or integrated into the process as it is when burning water-containing fuels, e.g. Lignite and sludge,
- plate and tube dryers i.e. contact dryers
- contact dryers which are indirectly heated with steam, as described by Krug and Nauendorf in the book “Lignite Briquetting” Volume 1, Drying Section, VEB German Publishing House for the Raw Material Industry, Leipzig, 1984, 1. Edition, have been described in detail.
- turbine extraction or counterpressure steam as a heat energy carrier for drying, which indirectly transfers its latent heat energy to the coal through condensation after it has been converted to saturated steam, for example, by injecting condensate, the known principle of "power Heat coupling "and a lowering of the fuel requirement attributable to drying.
- power Heat coupling the known principle of "power Heat coupling” and a lowering of the fuel requirement attributable to drying.
- the comparable sum of the flue gas emissions occurring during the individual refining and utilization sections could therefore fall to approximately 1.3 times the minimum required by natural law.
- drag air since "drag air" is used in most cases, these advantages are not effective.
- DD-PS 67 770 discloses a method and a device for predrying water-containing solid fuels, in particular soft lignite, in which the lignite is dried in a steam boiler in a fluidized bed dryer heated directly with steam before it is burned.
- turbine extraction steam or counterpressure steam should be used and the principle of cogeneration should therefore be used.
- DD-PS 67770 it is assumed that any suitable fluidizing medium, including steam, can be used to stir up the lignite above the fluidized bed in the fluidized bed dryer.
- REPLACEMENT LEAF US Pat. No. 3,800,427 describes an indirectly heated fluidized bed drying process in which the lignite is whirled up with water vapor, so that the drying takes place in a water vapor atmosphere.
- the invention is based on the fact that the lignite is heated in the steam atmosphere to such an extent that sulfur compounds split off, which accumulate on additives which may be present in the fluidized bed at the same time.
- DE-PS 29 01 723 extends the use of a fluidized bed, which is indirectly heated with steam and fluidized with steam, to dry solid materials which contain less than 95% by mass of a vaporizable material.
- the vaporizable material can also be other materials, such as solvents, which, in their vapor form as a fluidizing medium and in their saturated vapor form using different partial pressures, are also heat energy sources for the indirect heating of the fluidized bed.
- DE-PS 29 01 723 restricts the permissible temperature of the fluidized bed in comparison to US-PS 38 00 427 and specifies that this is substantially below the decomposition temperature of the solid matter, so that the steam discharged from the fluidized bed dryer in the should consist essentially of the vaporizable material without contamination by other gaseous substances.
- the table completely contains the vapor of the evaporable material emerging from the fluidized bed dryer.
- the aim of the invention is to recover the predominant portion of the thermal energy used for drying and to reduce the emissions resulting from drying by evaporation, evaporation, pyrolysis, degassing and gasification, in particular those which cannot be condensed at ambient temperature.
- the invention is based on the object, taking into account the technically realizable and reworkable principles of drying technology, a process and the device required for realizing the process for drying solid materials in a fluidized bed, the bed whose indirectly heated fluidized bed is preferably dried Solid material itself is formed, which is whirled up by the vaporizable material in vapor form, to achieve the goal of the invention in practical operation.
- the decisive factor for the solution of the task is the knowledge gained that the conversion of the vaporizable portion of a solid material or sludge into its vapor form in a gas phase, which is formed by the vaporizable portion of the solid material, is dependent on an isobaric process sequence on a substance-specific boiling curve that characterizes the solid material of the material to be evaporated, which fixes the necessary temperature of the solid material depending on the proportion of the evaporable material in the solid material.
- the temperature of the fluidized bed is therefore set as a function of the desired mass fraction of evaporable material in the solid material discharged from the fluidized bed by supplying solid material with a higher mass fraction of evaporable material for the removal and removal of dried solid material from the fluidized bed so that it corresponds to the substance-specific boiling temperature of the vaporizable material in the solid material discharged from the fluidized bed, so that the vapor discharged from the fluidized bed dryer also includes the gaseous substances of the vaporizable material and other gaseous impurities which are fed to the fluidized bed dryer, for example with the solid material contains only the volatile constituents of the solid fractions of the solid material or the sludge below this boiling temperature.
- the steam discharged from the fluidized bed dryer is cooled indirectly, so that it condenses while releasing its latent heat energy and the gaseous substances contained in the steam of the vaporizable material, other gaseous impurities and decomposition products of the solids content, which at Ambient temperature is not condensable and is not soluble in the condensate of the vaporizable material, separated from the steam and then released into the environment or a landfill and / or other gas purification.
- the method according to the invention normally requires the provision of the solid material to be dried in particulate form, preferably with a grain size of 0 to 10 mm, that is to say as a swirlable bulk material.
- Solid material in particular sludge products, which are not directly suitable for producing a swirlable bulk material, can be converted into a consistency by admixing already dried solid material, which permits the production of an entry material corresponding to the requirements of the process.
- Another way of converting solid material to be dried into a form corresponding to the method is to convert it into a pumpable and sprayable sludge form with condensate of the evaporable material. If it is necessary to maintain the bulk of the solid material to be dried, the process can be successfully implemented if the fluidized bed is not from the solid material itself, but from a smaller-sized solid material, which is different from the material to be dried 1. 2 to 5.0 times the density is marked, formed v.rd.
- bed material is discharged from the fluidized bed with the dried solid material. This requires the bed material to be separated from the dried, coarse solid material and the bed material to be returned to the fluidized bed.
- Decisive for the performance of the process is the temperature difference between the required temperature of the fluidized bed and the condensation temperature of the heating steam used for indirect heat transfer, which according to the invention should be between 10 and 150 K.
- REPLACEMENT LEAF Pressure in the fluidized bed dryer which corresponds approximately to the ambient pressure of the atmosphere, requires the heating steam pressure of 0.2 to 4.0 MPa, which when using steam as heating medium, with slightly overheated heating steam, steam temperatures from 125 to 225 * C results. While high heating steam pressures enable the construction of small dryers, low heating steam pressures and thus low temperature differences between the condensing steam and the fluidized bed ensure good use of the advantages of combined heat and power.
- the recovery of the predominant portion of the thermal energy used for drying and the separation of the gaseous, non-condensable and insoluble in the condensate contaminants, according to the invention, requires the condensation of the evaporated portion of the solid material. If the fluidized bed dryer operates under steam pressures which correspond to the pressure of the surrounding atmosphere, the substance-dependent condensation temperature determines the temperature level of the heat energy which can be recovered in the process. If the material to be evaporated is water, then the thermal energy recovered under the conditions according to the invention can reach a temperature of over 90'C, suitable for the fulfillment of heating heating and preheating tasks in industrial processes. If there is no need for thermal energy at this temperature level, the steam can be expanded with the release of technical work after appropriate cleaning of dust to such an extent that condensation at ambient temperature is still possible.
- REPLACEMENT LEAF A further possibility is to increase the steam from the fluidized bed dryer, also after appropriate cleaning of dust, before its condensation by compression so far that the heat of condensation arises at a temperature level which is sufficient to fulfill the intended heat transfer, for example for heating the fluidized bed of the process according to the invention is sufficient.
- a feed for the solid material to be dried to the fluidized bed dryer with a device for introducing the solid material into the fluidized bed dryer, is provided which is controlled by the fluidized bed temperature in terms of its output and which is based on the mass of the Solid material has at least 1.5 times the performance and, in the case of the introduction of particulate, vortex-capable or slurried solid material, at least 25% and, if lumpy, difficult or non-vortexable solid material is introduced, at least 75% of the surface of the fluidized bed is approximately uniform the entered solid aterial.
- the fluidized bed covers radiators arranged in the fluidized bed dryer by at least 250 to 1000 mm.
- Further components of the device are a discharge device for the dried solid material which is controlled in terms of its performance by the predetermined height of the fluidized bed and a mechanical dust separation for lowering the proportion of the grain size less than 0.5 mm with the vapor of the vaporizable material via the discharge discharged dust of the solid material below 10% by mass.
- the device according to the invention includes a steam return with a compressor which increases the pressure of the steam to such an extent that the device reduces at least twice the amount of steam which is required for the transfer of the solid on the fluidized bed from the fixed bed to the fluidized bed, and a condenser which separates the gaseous impurities from the vapor by condensation of the material evaporated in the fluidized bed and, if appropriate, with the aid of suction of the environment or deodorization and / or other gas cleaning and the condensate via a pump to the condenser and for further processing and use.
- the device according to the invention can be completed with a single and multi-stage compressor which raises the pressure of the vapor to such an extent that the condensation of the vapor during the temperature level required to fulfill the heat supply task can be carried out, for example for indirect heating of the fluidized bed.
- the vapor of the evaporable material from the fluidized bed dryer can be fed to a steam turbine system after leaving the dedusting system, in which it is reduced to the extent that technical work is done in the pressure, that condensation at ambient temperature, e.g. 30 "C, is still possible.
- the task of the example is to produce a dry lignite with a water content of 10 mass% from a raw lignite broken down in a conventional impact hammer mill to a grain size of 0 to 6 mm with a water content of 55% by mass.
- the raw lignite mass flow is 100 t / h, that of dry lignite correspondingly 50 t / h.
- a total of 50 t of coal water / h must be evaporated.
- the calculation of the post-evaporation shows that the water content after discharge from the fluidized bed dryer 2 is reduced by 1.5% by mass, so that the dried coal with a water content of 11.5% by mass is removed from the fluidized bed dryer 2 and in Fluid bed dryer 249.152 kg water / h are to be evaporated.
- the 2,848 kg of water evaporating per hour outside the fluidized bed dryer are suctioned off and fed as vapors with an air fraction of 2 kg / kg of water vapor to a separate dedusting system 9.
- coal which corresponds to a volume of 142.9 irr at a cut weight of 0.7 kp / liter, 200 irr air / h are introduced into the fluidized bed dryer 2 in accordance with the stipulations made for the entry element.
- the coal water in the example the vaporizable material, should contain 20 m 3 of dissolved gaseous impurities, in particular carbon dioxide, so that it is dried by drying in a
- a heating surface density of 100 irr fluidized bed 5 is to be achieved, ie the fluidized bed dryer 2 has a fluidized bed 5 of approximately 32 m 2 , which with a width of the fluidized bed 5 of 4 m gives a length of 8 m for the fluidized bed 5. If the solid material on the fluidized bed 5 reaches its loosening point at an empty pipe speed of 0.35 m / s, then 80670 irr water vapor, which corresponds to 53.8 t / h, must be recirculated according to the invention.
- the thermal energy requirement of the fluidized bed drying system according to the invention is 39.3 MW / h th , of which around 30.8 MW / h ⁇ , which is 78% of the thermal energy expended, is recovered in the condenser 18 at a temperature level of up to 95 * C can, with which this objective of the invention is achieved. If the non-condensable gaseous impurities are released into the environment with a saturation temperature of 60'C, around 275 irr / h are emitted.
- the substance-specific boiling curve of the coal to be dried in the example requires a fluidized bed temperature of 118 ° C.
- a heating steam with a minimum pressure of 0.59 MPa is required to achieve the temperature difference of 40 K between the fluidized bed 6 and the heating element 7.
- the fluidized bed height must be regulated by the controlled discharge of dried coal due to the predetermined heating element 7 with a height of 2.0 m and a space between the heating element 7 and the fluidized bed 5 with a height of 250 mm to at least 2500 mm, but a maximum of 3250 mm , are regulated.
Landscapes
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Microbiology (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Drying Of Solid Materials (AREA)
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4029525 | 1990-09-18 | ||
DE4029525A DE4029525A1 (de) | 1990-09-18 | 1990-09-18 | Verfahren und vorrichtung zum trocknen von feststoffmaterialien in einem indirekt beheizten wirbelschichtbett |
PCT/EP1990/001744 WO1992005393A1 (de) | 1990-09-18 | 1990-10-15 | Verfahren und vorrichtung zum trocknen von feststoffmaterialien in einem indirekt beheizten wirbelschichtbett |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0549577A1 true EP0549577A1 (de) | 1993-07-07 |
EP0549577B1 EP0549577B1 (de) | 1994-06-22 |
Family
ID=6414459
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90916213A Expired - Lifetime EP0549577B1 (de) | 1990-09-18 | 1990-10-15 | Verfahren und vorrichtung zum trocknen von feststoffmaterialien in einem indirekt beheizten wirbelschichtbett |
Country Status (8)
Country | Link |
---|---|
US (1) | US5373648A (de) |
EP (1) | EP0549577B1 (de) |
AU (1) | AU6618690A (de) |
DE (1) | DE4029525A1 (de) |
DK (1) | DK0549577T3 (de) |
ES (1) | ES2057598T3 (de) |
RU (1) | RU2075708C1 (de) |
WO (1) | WO1992005393A1 (de) |
Families Citing this family (41)
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DE4220953A1 (de) * | 1992-06-26 | 1994-01-05 | Metallgesellschaft Ag | Verfahren zum Trocknen wasserhaltiger Feststoffe im Wirbelbett |
DE4344593C1 (de) * | 1993-12-24 | 1995-02-16 | Somos Gmbh | Vorrichtung zum Trocknen von Schüttgut |
DE4401623A1 (de) * | 1994-01-20 | 1995-07-27 | Waldner Gmbh & Co Hermann | Verfahren und Vorrichtung zum Trocknen von Klärschlamm |
DE4404813C1 (de) * | 1994-02-16 | 1995-02-23 | Kraftanlagen Ag | Verfahren zur Wirbelschichttrocknung von Schlamm und Wirbelschichttrockner zur Durchführung des Verfahrens |
DE19602290A1 (de) * | 1996-01-23 | 1997-07-24 | Loedige Maschbau Gmbh Geb | Verfahren zur Trocknung von Klärschlamm oder Schlämmen ähnlicher Konsistenz |
CA2300978C (en) * | 1998-06-11 | 2007-08-21 | Universal Dynamics, Inc. | Method and apparatus for drying granular solids with venturi powered gas circulation |
JP3825587B2 (ja) * | 1999-08-18 | 2006-09-27 | 新日本製鐵株式会社 | 石炭の乾燥方法及び乾燥装置 |
AU2003253682A1 (en) * | 2002-06-24 | 2004-01-06 | The Procter And Gamble Company | Food package |
US7540384B2 (en) | 2004-10-12 | 2009-06-02 | Great River Energy | Apparatus and method of separating and concentrating organic and/or non-organic material |
US7987613B2 (en) | 2004-10-12 | 2011-08-02 | Great River Energy | Control system for particulate material drying apparatus and process |
US7730633B2 (en) * | 2004-10-12 | 2010-06-08 | Pesco Inc. | Agricultural-product production with heat and moisture recovery and control |
US8579999B2 (en) | 2004-10-12 | 2013-11-12 | Great River Energy | Method of enhancing the quality of high-moisture materials using system heat sources |
US7275644B2 (en) | 2004-10-12 | 2007-10-02 | Great River Energy | Apparatus and method of separating and concentrating organic and/or non-organic material |
US8523963B2 (en) | 2004-10-12 | 2013-09-03 | Great River Energy | Apparatus for heat treatment of particulate materials |
US8062410B2 (en) | 2004-10-12 | 2011-11-22 | Great River Energy | Apparatus and method of enhancing the quality of high-moisture materials and separating and concentrating organic and/or non-organic material contained therein |
CN102177406B (zh) * | 2008-08-12 | 2013-11-06 | 施维英生物泥公司 | 闭环干燥系统和方法 |
US20100038288A1 (en) * | 2008-08-12 | 2010-02-18 | MR&E, Ltd. | Refining coal-derived liquid from coal gasification, coking, and other coal processing operations |
EP2196756A1 (de) | 2008-12-15 | 2010-06-16 | Siemens Aktiengesellschaft | Vorrichtung zum Trocknen von Brennstoff |
CA2800166C (en) | 2009-05-22 | 2018-08-21 | The University Of Wyoming Research Corporation | Efficient low rank coal gasification, combustion, and processing systems and methods |
TR201112915T1 (tr) * | 2009-06-04 | 2012-09-21 | Shan Dong Tian Li Drying Equipment Co. Ltd. | Kızgın buhar kullanarak çok etkili kahverengi kömür ön kurutma sistemi ve bunlarla ilgili proses. |
US8366882B2 (en) * | 2009-07-14 | 2013-02-05 | C20 Technologies, Llc | Process for treating agglomerating coal by removing volatile components |
WO2011008832A2 (en) * | 2009-07-14 | 2011-01-20 | C20 Technologies, Llc | Process for treating agglomerating or bituminous coal by removing volatile components |
US8470134B2 (en) * | 2009-07-14 | 2013-06-25 | C2O Technologies, Llc | Process for treating coal by removing volatile components |
FR2953005B1 (fr) * | 2009-11-23 | 2011-12-09 | Degremont | Procede et installation de sechage de matieres pateuses, en particulier de boues de stations d'epuration |
CN101922859B (zh) * | 2010-09-13 | 2011-09-28 | 山东天力干燥股份有限公司 | 一种用于褐煤提质的分级粉碎干燥器 |
RU2013111466A (ru) | 2010-09-16 | 2014-10-27 | Франклин Г. РИНКЕР | Переработка угля с добавлением биомассы и контролем летучих веществ |
CN102183122A (zh) * | 2011-03-01 | 2011-09-14 | 中国中轻国际工程有限公司 | 含水固形物干燥脱水蒸汽再利用工艺及设备 |
US8968520B2 (en) | 2011-06-03 | 2015-03-03 | National Institute Of Clean And Low-Carbon Energy (Nice) | Coal processing to upgrade low rank coal having low oil content |
US9005322B2 (en) | 2011-07-12 | 2015-04-14 | National Institute Of Clean And Low-Carbon Energy (Nice) | Upgrading coal and other carbonaceous fuels using a lean fuel gas stream from a pyrolysis step |
US9074138B2 (en) | 2011-09-13 | 2015-07-07 | C2O Technologies, Llc | Process for treating coal using multiple dual zone steps |
KR101216827B1 (ko) * | 2011-12-15 | 2012-12-28 | 한국서부발전 주식회사 | 과열증기를 이용한 석탄 건조 시스템 |
JP5851883B2 (ja) * | 2012-02-28 | 2016-02-03 | 三菱日立パワーシステムズ株式会社 | 非凝縮性ガスの排気装置およびガス化複合発電設備 |
AU2014205416A1 (en) | 2013-01-09 | 2015-07-09 | C2O Technologies Llc | Process for treating coal to improve recovery of condensable coal derived liquids |
DE102013220501A1 (de) | 2013-10-11 | 2015-04-16 | Technische Universität Bergakademie Freiberg | Verfahren und Vorrichtung zur Kohle-Pyrolyse |
DE102013221075A1 (de) | 2013-10-17 | 2015-04-23 | Technische Universität Bergakademie Freiberg | Verfahren zur Kohletrocknung und Pyrolyse |
CN105021020A (zh) * | 2014-08-26 | 2015-11-04 | 呼伦贝尔东能化工有限公司 | 褐煤干燥系统除尘收集方法 |
US9327320B1 (en) | 2015-01-29 | 2016-05-03 | Green Search, LLC | Apparatus and method for coal dedusting |
US11215360B2 (en) * | 2015-08-18 | 2022-01-04 | Glock Ökoenergie Gmbh | Method and device for drying wood chips |
AT517644B1 (de) * | 2015-08-18 | 2018-08-15 | Gaston Ing Glock | Verfahren und Vorrichtung zum Trocknen von Holzschnitzeln |
CN105222528B (zh) * | 2015-10-23 | 2017-06-06 | 天华化工机械及自动化研究设计院有限公司 | 一种流化床煤干燥与水回收方法 |
CN106862077B (zh) * | 2017-01-21 | 2018-10-19 | 中国矿业大学 | 一种潮湿细粒煤分选与干燥的耦合系统及方法 |
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AT390018B (de) * | 1988-05-05 | 1990-03-12 | Waagner Biro Ag | Verfahren und regenerationseinrichtung zur thermischen behandlung wie z.b. trocknung, verschwelung, vergasung pastoeser oder schlammartiger substanzen |
DD282509A5 (de) * | 1989-04-18 | 1990-09-12 | Orgreb Inst Kraftwerke | Verfahren und vorrichtung zum trocknen von feststoffmaterialien in einem indirekt beheizten wirbelschichtbett |
-
1990
- 1990-09-18 DE DE4029525A patent/DE4029525A1/de not_active Withdrawn
- 1990-10-15 US US08/030,040 patent/US5373648A/en not_active Expired - Lifetime
- 1990-10-15 WO PCT/EP1990/001744 patent/WO1992005393A1/de active IP Right Grant
- 1990-10-15 DK DK90916213.3T patent/DK0549577T3/da active
- 1990-10-15 ES ES90916213T patent/ES2057598T3/es not_active Expired - Lifetime
- 1990-10-15 AU AU66186/90A patent/AU6618690A/en not_active Abandoned
- 1990-10-15 EP EP90916213A patent/EP0549577B1/de not_active Expired - Lifetime
- 1990-10-15 RU RU9093005012A patent/RU2075708C1/ru active
Non-Patent Citations (1)
Title |
---|
See references of WO9205393A1 * |
Also Published As
Publication number | Publication date |
---|---|
ES2057598T3 (es) | 1994-10-16 |
AU6618690A (en) | 1992-04-15 |
RU2075708C1 (ru) | 1997-03-20 |
EP0549577B1 (de) | 1994-06-22 |
WO1992005393A1 (de) | 1992-04-02 |
DK0549577T3 (da) | 1994-11-14 |
DE4029525A1 (de) | 1992-03-19 |
US5373648A (en) | 1994-12-20 |
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