EP0547572B1 - Verfahren und Vorrichtung für die wiedereinschreibbare und löschbare Aufzeichnung - Google Patents

Verfahren und Vorrichtung für die wiedereinschreibbare und löschbare Aufzeichnung Download PDF

Info

Publication number
EP0547572B1
EP0547572B1 EP19920121382 EP92121382A EP0547572B1 EP 0547572 B1 EP0547572 B1 EP 0547572B1 EP 19920121382 EP19920121382 EP 19920121382 EP 92121382 A EP92121382 A EP 92121382A EP 0547572 B1 EP0547572 B1 EP 0547572B1
Authority
EP
European Patent Office
Prior art keywords
erasing
recording
medium
heating means
energy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP19920121382
Other languages
English (en)
French (fr)
Other versions
EP0547572A1 (de
Inventor
Keiki C/O Mitsubishi Denki K.K. Yamada
Masaru c/o Mitsubishi Denki K.K. Ohnishi
Niro C/O Toppan Printing Co. Ltd. Watanabe
Yuji c/o Toppan Printing Co. Ltd. Nakatsu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Electric Corp
Original Assignee
Mitsubishi Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Electric Corp filed Critical Mitsubishi Electric Corp
Publication of EP0547572A1 publication Critical patent/EP0547572A1/de
Application granted granted Critical
Publication of EP0547572B1 publication Critical patent/EP0547572B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/36—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using a polymeric layer, which may be particulate and which is deformed or structurally changed with modification of its' properties, e.g. of its' optical hydrophobic-hydrophilic, solubility or permeability properties
    • B41M5/363—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using a polymeric layer, which may be particulate and which is deformed or structurally changed with modification of its' properties, e.g. of its' optical hydrophobic-hydrophilic, solubility or permeability properties using materials comprising a polymeric matrix containing a low molecular weight organic compound such as a fatty acid, e.g. for reversible recording

Definitions

  • the present invention relates to a method for erasing and /or recording using reversible thermal recording medium (rewritable recording medium), on which recording and erasing image are derived from the heat sensitive nature of the medium layer.
  • reversible thermal recording medium rewritable recording medium
  • thermal recording mediums on which recording and erasing image can be done iteratively using heating, have developed very widely.
  • conventional types of such mediums for example, so called an organic low-molecular type and leuco dye type are known.
  • thermal recording and erasing are carried out using physical phase transition of its nature which has cloudy and transparent phase, and the phase transition happens iteratively by the given temperature, and either of the phase is kept stably below a specified temperature (see Japanese Patent Laid-Open No. Sho 55-154198).
  • thermal recording and erasing are carried out by using chemical reaction including some compounds in the medium, which includes leuco dyes, developers and reducers, and these developers and reducers usually have hydroxyl group and carboxyl group in a compound molecule to release hydrogen ion.
  • the color of the dye appears when a temperature is given to the medium, and it disappears when the lower temperature than before is given (see Japanese Patent Laid-Open No. Hei 2-188294).
  • the organic low-molecular type medium is comprised of the matrix substance made of thermoplastic resins and organic low-molecular substances dispersed in the matrix.
  • the medium When the medium is kept over the specified temperature T0, its phase is changed according to the temperature given to the medium. Namely, the medium has two phase transition temperatures T1 and T2 (T1 ⁇ T2) which are higher than T0. After heating the medium T2 or higher and maintained at the temperature, and then it is cooled to T0 or lower, the medium becomes cloudy to provide the maximum light intercept phase. After heating the cloudy layer between T1 or more and T2 or less, and then it is cooled to T0 or lower, the layer becomes transparent.
  • T1 ⁇ T2 phase transition temperatures
  • the phase transition of the leuco dye type medium can be controlled simply by the given heat energy. That is, the lactone ring including the leuco dye in the media is opened when the higher transition temperature is given by the energy, and the ring closed when the lower transition temperature is given to return the leuco compound colorless.
  • Such phenomena derives from the structures of the developer and reducer, and the reversible nature of the leuco dye which enables to open and close the ring repeatedly.
  • a salt formed by gallic acid and aliphatic amine or the like are known.
  • the former low-molecular type employed a transparent protection layer formed on the recording layer, and this has been described in Japanese Patent Laid-Open Nos. Sho 57-82086, Hei 2-117891, Hei 2-131984, Hei 2-81672, Hei 2-566 and so on.
  • the latter leuco dye type employed also a protection layer made of thermoplastic resin or the like.
  • a heating means absorbs tails, either of the resin or organic low-molecular substance are oxidized and loose their properties, or the surface the medium is abraded to make random reflection at the iterative number about 100 or more.
  • the iterative number is further increased, for example, to more than 500, the large friction between the record medium and the heating means makes recording itself on the medium impossible.
  • the medium has less the maximum iterative number than former type, and recording itself becomes impossible about 50 iterations.
  • the former can be accomplished by employing the method for forming a recording layer using capsules, as described in Japanese Patent Filing No. Hei 3-118310 (Japanese Patent Laid-Open No. Hei 4-345886) assigned to the applicant.
  • Such a method can provide only the maximum iterative number ranged between about 100 and about 1,000. Consequently, the present invention was done by establishing the optimum conditions of the latter method.
  • the recording conditions in the present invention are selected such that any recorded trace brought from heat and pressure will not be left and also the surface of the recording layer is kept smooth without being roughened.
  • the erasing conditions are selected such that the erasing can be reliably performed and also the surface of the recording layer does not receive any configuration change on it.
  • An apparatus for use in the present method does not use both erasing-heating means and control means having particular accuracies, and generally used devices in the thermal recording or thermography are available for the present invention.
  • An erasing-heating means used in the apparatus can erase the recorded image certainly whilst increasing the maximum iterative number of the medium.
  • the present invention provides a method for repeated recording and erasing for a thermoreversible recording medium having an optical density comprising the steps of:
  • the method of claim 1 is characterized in that the heating time for erasing the image on the medium is at least twice that required for recording.
  • the method of claim 1 is characterized in that the speed of erasing the image on the mediumis greater than or equal to Tmm/s, and the width of an erasing/heating means is T ⁇ m or more, and that a pressure appied to the erasing/heating means is set to be ranged between 8 x 10 3 Pa and 5 x 10 4 Pa.
  • the method of claim 1 is further charaterized in that the erasing voltage is controlled to be ranged between 0,68 times and 0,86 times the recording voltage if the heating time on erasing is equal to that on recording.
  • the method of claim 1 is further characterized in that the erasing voltage is controlled to be ranged between 0,4 times and 0,7 times the recording voltage when the heating time is twice that on recording.
  • the method of claim 1 is further characterized in that the erasing voltage is ranged between 0,5 times and 0,75 times the recording voltage.
  • the method of claim 1 is further characterized in that the recording energy is ranged between 1.05 times and 1,2 times the energy at the start of saturation.
  • the desired record of the image was provided through optimizing the energy applied for recording without any deformation on the surface of the recording layer
  • the certain erasing was provided through optimizing the voltage applied or heating time for erasing with keeping the surface of the recording layer smooth, and also it makes the maximum iterative number increased.
  • Tmm/s of the erasing speed, T ⁇ m or more of the width of the erasing-heating means, and from 8 x 10 3 Pa to 5 x 10 4 Pa of the pressure are employed in the apparatus, they make further improved apparatus which enables to erase recorded image without any trace and also incresases the maximum iterative number. Therefore, the problems of the prior art including degradation of image quality and so on can be avoided with a remarkable improvement in the maximum iterative number.
  • Figs. 1(a) and (b) are schematic views of two different structures for rewritably displaying a record.
  • Figs. 2(a) and (b) are schematic views of two different structures for rewritably displaying a record.
  • Fig. 3(a) shows the recording characteristics curve - energy.
  • Fig. 3(b) shows the optical density - maximum iterative number.
  • Fig. 4(a) shows the contrast ratio-energy.
  • Fig. 4(b) shows the maximum iterative number - energy.
  • Fig. 5(a) shows the dispersion of optical density - energy.
  • Fig. 5(b) shows the relationship between the energy and the number of disfigurements.
  • Fig. 6 shows the erasing characteristics.
  • Fig. 7 shows the relationship between the heating time and ⁇ OD.
  • Fig. 8(a) shows the erasing characteristics.
  • Fig. 8(b) shows ⁇ OD - the maximum iterative number.
  • Figs. 9(a) and (b) show the relationship between the erasing speed and the width of the heating means.
  • Fig. 10(a) shows the relationship between the pressure and ⁇ OD.
  • Fig. 10(b) shows the relationship between the pressure and the maximum iterative number.
  • Fig. 1(a) illustrates the schematic structure of the apparatus used in the embodiment.
  • a rewritable recording medium 10 which is a reversible thermal recording medium comprising a protection layer, recording layer and support member and further including a colored layer, magnetic recording layer and so on, if required, although they are not illustrated.
  • recording-heating means 12 is such as a thermal head having a resolution of 8 dots/mm.
  • Reference numeral 14 designates a platen roller; 16 recording control means (RCM) for electrically controlling the recording-heating means (RM) 12; 18 erasing-heating means (EM) such as a thermal head; 20 a platen roller; 22 erasing control means (ECM) for electrically controlling the erasing-heating means 18.
  • the medium 10 may comprise a transparent or opaque support member (not shown) formed of paper, polyethylene terephthalate film, metallic sheet (light reflecting layer) or the like, and a recording layer containing an organic low-molecular substance as a main component and having its property reversibly variable depending on temperature.
  • the organic low-molecular substance may be a mixture of behenic acid with dodecanodioic acid in a ratio of 7:3. Such a material was used to form a recording layer having 10 ⁇ m thickness.
  • the principal of the phase transition of the medium which is shown in the present invention causes from the transition of the crystalline structure deformation of the low-molecular organic substances; the medium is the cloudy phase when it is cooled at room temperature after given the high temperature, and it is returned to the transparent phase when it is cooled to room temperature after given the lower temperature.
  • the organic low-molecular substance is poly-crystallized with its crystalline orientation being disturbed when it is cooled after first being molten at the raised temperature. Such a disturbed crystalline orientation scatters the incident light to induce the cloudy phase in the medium.
  • the organic low-molecular substance is partially molten when it is given the lower temperature. The organic low-molecular substance then forms the single crystals with maintaining orientation. Therefore the organic low-molecular substance is in the transparent phase wherein the incident light can pass through the crystalline layer or be reflected by the support member, without scattering.
  • the platen roller 20 is driven by any suitable drive means like motors.
  • the medium 10 is moved in a direction of arrow A under the friction between the rotating platen roller 20 and the erasing-heating means 18.
  • a current is applied to a heating member (not shown) at a given timing so that the organic low-molecular substance 10 is heated by the heating member to erase an image thereon.
  • a heating member not shown
  • the image on the medium is erased line by line iteratively with such operation.
  • the image on the medium 10 can be erased two-dimensionally.
  • the recording control means 16 receives a recording signal corresponding to the image from a signal terminal (not shown), as in the erasing cycle. The recording signal is then fed to the recording-heating means 12 to record a desired image.
  • Fig. 3(a) shows the basic profile of optical density obtained when the recording-heating means 12 in the aforementioned arrangement was used to heat the medium 10.
  • a vertical axis represents optical density while a horizontal axis represents in energy to be applied to the recording-heating means 12.
  • the medium 10 is gradually clouded as the energy applied is increased. It is noted that when the applied energy exceeds 0.6 mj/dot, the optical density is saturated at about 0.3.
  • the optical density is measured using a densitometer (e.g. RD914 manufactured by Macbeth Co. Ltd.) after the medium 10 is given various voltage applied or heating time with the recording-heating means 12 and then cooled at room temperature (25°C).
  • the optical density of the medium 10 itself is represented by a descendent curve since its phase turns gradually from transparent into cloudy.
  • Fig. 3(b) shows the optical density profile after recording and erasing were repeated.
  • a vertical axis represents the optical density while a horizontal axis represents the maximum iterative number.
  • a straight line B shows ideal profile of the optical density
  • a curve C shows the actual optical density after repeating erasing.
  • a curve D shows the actual optical density after repeating recording and a straight line E shows the ideal optical density.
  • the optical density for recording is substantially along with the straight line E and the optical density for erasing is substantially along with the straight line B.
  • the optical density curve went over the line E,when the given energy is 0.6 mj/dot or lower.
  • the energy applied was 0.9 mj/dot or higher, the deviation from each of the straight lines B and E became large following the iterative number was increased, shown as the curves C and D. Such a tendency became remarkable as the applied energy increased.
  • Fig. 4(a) is a graph in which a vertical axis represents the contrast ratio between the transparent and cloudy parts after the recording and erasing cycle have been repeated 10,000 times while a horizontal axis represents the applied energy.
  • the contrast ratio is a value obtained when the optical density after 10,000 erasing is divided by the optical density after 10,000 recordings. From Fig.
  • the contrast is deteriorated with the applied energy equal to or lower than 0.5 mj/dot since the heated part is less cloudy after recording and also that the contrast is similarly deteriorated with the applied energy equal to or higher than 0.9 mj/dot since the optical density after recording increases with increase of the maximum iterative number (failure on recording) and the optical density after erasing decreases to increase the non-erased area.
  • Fig. 4(b) is a graph in which a vertical axis represents the maximum iterative number and a horizontal axis represents the applied energy.
  • Fig. 4(b) shows how many recording and erasing cycles can be repeated with clear contrast of the optical density before the recording and after the erasing.
  • Fig. 4(b) represents the maximum iterative number for an optical density which is invariable against the respective energies on recording. It is understood from Fig. 4(b) that if the applied energy is lower than 0.9 mj/dot, the maximum iterative number can be about 10,000.
  • the optimum recording condition is ranged between 0.8 times and 1.5 times the energy on the start of saturation. This is because as the applied energy becomes higher than 0.9 mj/dot, the medium is overheated to roughen the surface thereof or to oxidize the recording layer so that the recording and erasing cycle cannot be repeated.
  • the heating member may be so heated that it becomes damaged. This may also lead to damage in the both protection and recording layers in the medium. More particularly, the protection layer may be fused to the thermal head to degrade the image formed on the medium or increase the friction between the thermal head and the medium so that the recording cycle cannot be performed. Further, the cycle becomes impossible due to oxidization of the recording layer or separation of the organic low-molecular substance out of the recording layer. Similar problems may be deteriorated without any affection against the surface smoothness in the medium and other factors.
  • the contrast in the image formed on the medium as well as the iterative number of cycles that the medium can be used are maintained better if the energy applied to the medium is ranged between 0.8 times and 1.5 times the energy at the start of saturation in the optical density.
  • the recording energy applied to the medium is ranged between 1.05 times and 1.2 times the energy at the start of saturation
  • the contrast is further improved and the medium can be repeatedly subjected to 10,000 cycles with reduction of all the damage of the medium, the abrasion of the surface and the random reflection. This is because the range of the applied energy between 0.8 times and 1.05 times the energy at the start of saturation causes the optical density to be unstable.
  • FIG. 5(a) shows results when a dispersion in the optical density was determined with respect to a standard deviation which had been obtained from 10 times the energy of 0.6 mj/dot in Fig. 3(a). From Fig. 5(a), it is understood that the dispersion in the optical density is unstably increased at a level of energy equal to or lower than 1.05 times the energy at the start of saturation (about 0.63 mj/dot) even if the energy applied to the medium is invariable. On the other hand, the surface of the medium is slightly damaged after the recording and erasing cycle has been repeated within the range of energy between 1.2 times and 1.5 times the energy at the start of saturation (but the maximum iterative number will not be affected). This will be described with reference to Fig.
  • a vertical axis represents the number of cracks on the medium 10 per 10 cm 2 and a horizontal axis represents the energy applied to the medium.
  • the number of iterations is 5,000. It is understood from Fig. 10 that it is preferred that the energy applied to the medium is equal to or lower than 1.2 times the energy at the start of saturation.
  • the energy applied to the medium is preferably ranged between 0.8 times and 1.05 time the energy at the start of saturation.
  • a range of energy is suitable for test printing in the word processing or the other application in which any visual judgment is permissible.
  • the energy applied to the medium is ranged between 1.2 times and 1.5 times the energy at the start of saturation, it is suitable for case when one makes greater account of the contrast in the image formed on the medium than the optical density thereof, such as a commutation ticket, an image display and the others.
  • the energy applied to the medium is ranged between 1.05 times and 1.2 times, it is applicable to all the above cases.
  • the rewritable record displaying apparatus is characterized by an erasing means in the field of heat recording which is similar to the heat-sensitive recording process such as FAX and the like and to the heat transfer process such as color printer and the like. It is a primary object of the present invention to set recording conditions in which the complete erasing cycle is reliably performed to permit the iteration of the recording and erasing cycle such that the recording cycle will be performed without affection to the erasing cycle or with improvement of the recording characteristics.
  • the recording conditions selected in accordance with the present invention is basically different from those of the prior art heat recording device. With the heat-sensitive recording device, for example, the medium can be recorded by an energy two times that at the start of saturation in the optical density without any disadvantage.
  • the present invention provides the optimum recording conditions that an image formed on a record medium can be completely erased with the maximum iterative number of the record medium being improved and that the contrast in the image formed on the medium can be improved.
  • the aforementioned results were obtained by using the organic low-molecular type medium in which the recording layer was formed of a mixture of behenic acid with dodecanodioic acid at the ratio of 7:3 and into a thickness equal to 10 ⁇ m.
  • the energy at the start of saturation in the optical density is variable depending on the thickness of the recording layer, the material forming the recording layer and so on.
  • the energy at the start of saturation is variable and if the recording energy applied to the medium is substantially ranged between 0.8 times and 1.5 times the energy at the start of saturation, the image formed on the medium can be erased completely and repeatedly with an improved contrast in the image formed on the medium.
  • the use of dye other than the organic low-molecular substance showed the characteristics similar to those of the organic low-molecular dye.
  • the erasing conditions were selected by the following procedure.
  • Fig. 6 is a graph showing the erasing characteristics obtained from experiments by the use of the device shown in Fig. 1(a), in which a horizontal axis represents voltages applied to the erasing-heating means 18 and a vertical axis represents the optical densities after erasing. Experiments were carried out under such a condition that an image was recorded on the reversible heat-sensitive record medium 10 by the recording-heating means 12 with the optical density being equal to 0.3. Thereafter, the voltage applied to the erasing-heating means 18 was varied to erase the image. The voltage applied to the recording-heating means 12 was 14 volts with the heating time being 2 ms. A curve F in Fig.
  • FIG. 6 shows results from the heating time of the erasing-heating means 18 which is set to be 2 ms. From these results, it is understood that when the voltage applied to the erasing-heating means 18 is varied from about 9.5 V to about 12 V, the image formed on the medium can be substantially completely erased. In other words, it is preferred that the erasing voltage is controlled to be ranged between 0.68 times and 0.86 times the recording voltage if the heating time on erasing is equal to that on recording. On the other hand, a curve G was obtained when the heating time in the erasing-heating means 18 is set to be equal to one-half the aforementioned heating time (i.e. one ms).
  • the erasing voltage at a level equal to about 0.9 times the recording voltage (i.e. 12.6 V). It is however to be noted that the optical density after erasing becomes slightly lower than that in the heating time equal to 2 ms. It is believed that this results from the fact that the heating time required in the erasing cycle does not reach a predetermined time. On the other hand, if the erasing voltage was higher than 0.9 times the recording voltage, no erasing could be made even when the heating time is reduced. It is believed that this results from the fact that the heating time became too short while at the same time the temperature at the erasing-heating means exceeded the range of erasing temperature.
  • the characteristics are represented by a curve H.
  • the erasing cycle can be carried out when the erasing voltage is ranged between 0.4 times and 0.7 times the recording voltage.
  • the heating time is increased, the voltage applied to the erasing-heating means 18 tends to decrease.
  • the erasing voltage is smaller than 0.3 times the recording voltage, it was impossible to erase the image formed on the medium on the basis of the characteristics in the heating means such as thermal head. This means that since the medium is insufficiently heated, the temperature at the medium itself cannot reach the range of erasing temperature.
  • the image formed on the medium could be erased by the erasing voltage ranged between 0.3 times and 0.9 times and more preferably between 0.5 times and 0.75 times the recording voltage.
  • the above values are effective when the recording-heating means is also used as the erasing-heating means or when the erasing-heating means has the same structure as that of the recording-heating means.
  • the former is superior in cost performance since only a single heating means is required.
  • the first example enables both the recording and erasing to be carried out even if the voltage applied to the heating means is only varied. In this case, the recording and erasing cycles can be carried out at the same speed.
  • the aforementioned results were obtained by using the organic low-molecular type medium in which the recording layer was formed on the support member from a mixture of behenic acid with dodecanodioic acid at the ratio of 7:3 and into a thickness equal to 10 ⁇ m.
  • the recording layer's thickness, the material forming the recording layer and so on are varied and when the erasing voltage applied to the medium is ranged between 0.3 times and 0.9 times the recording voltage, the image formed on the medium can be completely erased improving the maximum iterative number.
  • the use of dye other than the organic low-molecular substance showed the characteristics similar to those of the organic low-molecular dye.
  • the energy to be applied to the recording-heating means was set at a level ranged between 0.8 times and 1.5 times the energy at the start of recording saturation in the recording layer formed of the organic low-molecular type heat-sensitive material which contains a mixture of behenic acid with dodecanodionic acid with a ratio of 7:3.
  • the erasing-heating means having the same structure as that of the recording-heating means was used with the erasing voltage ranged between 0.3 times and 0.9 times the recording voltage.
  • the recording and erasing cycles were repeatedly carried out by iterating the heating step and the cooling-at-room-temperature step for both the recording and erasing cycles.
  • the reversible heat-sensitive record medium may have no support member if the recording layer is formed to have its thickness and mechanical stability sufficient to maintain the configuration of the medium.
  • the experiment was carried out using the same apparatus under the same recording conditions in the first experiment, and erasing conditions were different from those in the first experiment.
  • the erasing conditions were selected from the following experiments.
  • Fig. 7 shows the relationship between ⁇ OD and heating time.
  • a vertical axis represents ⁇ OD and a horizontal axis represents heating time.
  • the term " ⁇ OD" used herein represents the transparency after erasing the image, and it is shown as a value that DD-0.3.
  • DD is the optical density when the image on the medium 10, which was recorded at 0.3 of the optical density using the recording/heating means 12, was erased using said erasing/heating mean 5. Namely, as the value of ⁇ OD is large, the recorded image is well erased, and if the value is zero, it means that the erasing is impossible.
  • Fig. 7 shows data obtained from optical density at the various heating time when an image was recorded on the medium using the recording-heating means 12 under the conditions of 14V for 2 ms, and thereafter erased by the erasing-heating means 18 on which 7V is applied. If the heating time on erasing is substantially two times longer than that on recording, the erasing was completely carried out. If the voltage applied to the erasing-heating means 18 is lower than 7V, the heating time will be prolonged, however, the erasing was completely done when the heating time is two times longer than that on recording as in Fig. 7.
  • the heating time will be shortened, however, the erasing was more reliable when the heating time is two times longer than that on recording. If the erasing voltage applied was 10V or higher, the erasing was not completely done because 10V is over the range of the erasing temperature when the heating time on erasing was two times or longer that on recording.
  • the voltage should be reduced and the heating time is two times or longer than that of recording with lower temperature than the recording one.
  • the heating time for the erasing was two time or longer than that on recording. It is believed that if the organic low-molecular type is used, it takes much longer time when the polycrystalline phase (cloudy) transit to single crystalline phase (transparent) than reverse transition of the phase. In the cloudy phase, molecule in the recording layer of the medium 10 is partially molten, and if the heating time is enough longer the polycrystalline changes into the single crystalline (transparent) phase. Similar results was obtained from the other the erasing-heating means laser beam, flash light or the like. Even if a leuco dye type medium was used, the heating time for erasing was required two times or longer than that for recording.
  • the experiment conducted here employed the same apparatus and recording conditions as the first example, and also by setting the heating time for erasing is two times or longer than that for recording.
  • the initial characteristics and the maximum iterative number of the medium were similar to those of the first example.
  • the temperature range of the medium for erasing in the apparatus shown in Fig.1 was set to 15 C or higher by selecting the materials which comprising the medium.
  • Fig. 8(a) shows the erasing characteristics of the medium.
  • a hot stamp was used as the erasing/heating means, and the temperatures and optical density for recording (or erasing) with 100 kPa (one kg/cm 2 ) pressure for two second were shown in Fig.8.
  • the characteristics using the hot stamp shows that if the heating temperature is between 75°C and 100°C, the image recorded on the medium 10 can be erased.
  • the range of erasing temperature of the medium is 25°C.
  • the range of erasing temperature depends on the composition of the material forming the recording layer in the medium 10, and can be varied into about 5°C - about 50°C.
  • Fig. 8(b) is a graph in which a vertical axis represents the value of ⁇ and a horizontal axis represents the maximum iterative number. Parameters used were selected that they make the erasing temperature range of the medium 10 at 5°C, 10°C, 12.5°C, 15°C, 20°C, 25°C, 30°C and 40°C possible. For example, if the erasing temperature ranges is 5°C, it means that when the medium is heated between 77.5°C and 82.5°C, the image recorded thereon can be erased. The erasing temperature range is 10°C means that the image can be erased by heating the medium between 75°C and 85°C. Experiments were carried out using such a device as shown in Fig.
  • the reason that the erasing temperature range below 15 °C gives less iterative number of the medium is considered as follows. Firstly, given temperature is not well controlled in 7.5°C of desired temperature using the erasing-heating means 18, because the shape of the resister in the means, the variability of the heating resistor itself, or the uneven pressure from the means.
  • the thermal head, heat roller and their control means which are shown in Fig. 1(a) and used in the experiments, have accuracies similar to those normally used in the field of therm recording, therm transfer recording and so on. If the given temperature is well controlled below 7.5°C, these means must be manufactured with different specifications from usual ones. Naturally, this leads to increase of the manufacturing cost. Secondly, when the erasing speed is fast, the medium has no time to cool down from the precedent to the next step, and then heat is accumulated in the medium and it over the erasing temperature range.
  • the erasing means may be a thermal head, heat roller, planar heating member or light irradiating means.
  • the difference of the material does not affect to control the erasing temperature range, if the medium has the range higher 15°C.
  • both of heating means and heating control means which are used widely for thermal printing and thermography as the heating means and heating control means with usual regulation mode to control temperature, are avairable for the apparatus.
  • the apparatus of the present invention does not need any heating means and heating control means with high accuracy.
  • the fourth example relates to the erasing-heating means in the apparatus.
  • Fig. 9(a) shows the relationship between the width of the erasing-heating means 18, that is, the length of the same means 18 which moves to the direction and the erasing speed of the image on the medium.
  • Fig. 9(b) illustrates the width of the erasing-heating means 18 and the direction that the medium is moved to.
  • a symbol " ⁇ " shows a completely erasable area; a symbol " ⁇ ” shows an erasable area; and a symbol “x” shows an unerasable area.
  • the recording conditions were 14V of applied voltage, 2 ms of applied time, and 0.3 of optical density.
  • the erasing speed and the width of the erasing-heating means 18 are variable.
  • the width of the erasing-heating means 18 is 150 ⁇ m or more, when the erasing speed is 150 mm/s. This relationship comes from that lines or dots erased need assure time to heat them.
  • the relationship between the width of the erasing-heating means and erasing speed should be satisfy that when the erasing-heating means is T mm/s and the erasing speed is T ⁇ m or more. To be equal to or larger than T ⁇ m.
  • the apparatus of the present invention enables to erase the image on the medium with the same speed as recording them.
  • Fig. 10(a) shows the relationship between the pressure applied to the erasing-heating means 18 and the above ⁇ OD. This result is obtained from 500 iterations of recording and erasing the image. Higher the pressure, better the erasing characteristics, and 8 x 10 3 Pa of the pressure is enough to erase.
  • Fig. 10(b) shows the relationship between the pressure and the maximum iterative number. From Fig. 10(b), higher the pressure, less the iterative number. When unnecessary pressure is applied to the heating means, the heating means receives damage with deforming or distraction in the worst case, the medium has roughened surface with physical trace of the heating means, and these are causes which make the iterative number less than lower pressure is applied.
  • Fig. 1(a) When the erasing-heating means in the apparatus shown in Fig. 1(a) was used to record and erase the image 10,000 times while determining the width of the erasing-heating means dependent on the erasing speed and optimizing the pressure applied to the erasing-heating means between 8 x 10 3 Pa and 5 x 10 4 Pa, the image is erased completely.
  • the erasing-heating means 18 may be any one of thermal head, heat roller, planer heating member and the like.
  • the apparatus abovementioned comprises thermal heads as recording-heating means 12 and erasing-heating means 18 shown in Fig. 1(a)
  • the erasing-heating means 18 may comprise a planar heating member such as ceramic heater and a support member 24 formed of a plastic material coated with rubber or Teflon instead of a platen roller shown in Fig. 1(b).
  • the erasing-heating means 18 may be a heat roller 26 shown in Fig. 2(a).
  • the width of the erasing-heating means is defined as that portion of the heat roller 26 contacting the medium 10.
  • the heat roller 26 may be located on each side of the medium 10 or under the medium 10.
  • a single heating means 28 which is used for both recording and erasing shown in Fig. 2(b).
  • Such a single heating means 28 may be electrically controlled by a recording and erasing control means 30.
  • Such kinds of modifications of the apparatus are including in the scope of the invention.
  • the examples described above are employed the organic low-molecular type dye to form the medium 10, the present invention is not limited to such a material, and known reversible mediums are avairable.
  • the leuco or other dyes may be useful in the present invention. The same effect was obtained from when an organic low-molecular type dye which has cloudy phase at high temperature and transparent phase at lower temperature, and vice versa.
  • the present invention can optimize the recording and erasing conditions in the rewritable record display.
  • the present invention can provide a display contrast and maximum iterative number which are substantially similar to the limits in the recording and erasing reactions due to the physical or chemical change in the heat-sensitive material forming the recording layer.
  • the range of erasing temperature for the reversible heat-sensitive record medium in the rewritable record displaying apparatus is set to be equal to or higher than 15 C
  • the medium used in the present invention can be subjected to the reliable erasing reaction by the use of a simplified structure comprising the erasing-heating means and the control means.
  • the rewritable record displaying apparatus can be superior in the maximum iterative number and perform the reliable and complete erasing function.

Landscapes

  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)
  • Heat Sensitive Colour Forming Recording (AREA)

Claims (7)

  1. Verfahren zur wiederholten Aufzeichnung und Löschung für ein thermoreversibles Aufzeichnungsmedium mit einer optischen Dichte,
    gekennzeichnet durch
    die Schritte:
    a) Aufzeichnung eines Bildes auf dem Medium durch Anwendung von Energie auf das Medium mit einem Heizelement mit einem Energieniveau zwischen dem 0,8- und 1,5-fachen des Energieniveaus, bei dem die Sättigung der optischen Dichte des Mediums erreicht ist, wobei das Energieniveau, bei dem die Sättigung erreicht ist, als Niveau definiert ist, bei dem die optische Dichte mit weniger als 10 % variiert, wenn eine weitere Energie auf das Medium wirkt; und
    (b) die Löschung des Bildes auf dem Medium durch Anlegen einer Spannung am Heizelement in einem Bereich zwischen dem 0,3- und 0,9-fachen der Spannung, die im Schritt für die Aufzeichnung an das Heizelement angelegt ist, erfolgt.
  2. Verfahren nach Anspruch 1,
    dadurch gekennzeichnet, daß die Erwärmungszeit für die Löschung des Bildes auf dem Medium mehr als doppelt so lang wie die Erwärmungszeit für die Aufzeichnung des Bildes auf dem Medium ist.
  3. Verfahren nach Anspruch 1,
    dadurch gekennzeichnet, daß die Löschungsgeschwindigkeit für das Bild auf dem Medium größer als oder gleich T mm/s, und die Größe eines Löschungs-/Erwärmungselementes Tµm oder mehr ist, und daß ein Druck auf das Löschungs-/Erwärmungselement, der einem Wert zwischen 8 x 103 Pa und 5 x 104 Pa entspricht, wirkt.
  4. Verfahren nach Anspruch 1,
    dadurch gekennzeichnet, daß die Löschungsspannung in einem Bereich zwischen dem 0,68-fachen und dem 0,86-fachen der Aufzeichnungsspannung gesteuert wird, wenn die Erwärmungszeit zur Löschung gleich zu der zur Aufzeichnung ist.
  5. Verfahren nach Anspruch 1,
    dadurch gekennzeichnet, daß die Löschungsspannung in einem Bereich zwischen dem 0,4-fachen und dem 0,7-fachen der Aufzeichnungsspannung gehalten wird, wenn die Erwärmungszeit doppelt so groß wie die Erwärmungszeit bei der Aufzeichnung ist.
  6. Verfahren nach Anspruch 1,
    dadurch gekennzeichnet, daß die Löschungsspannung in einem Bereich zwischen dem 0,5-fachen und dem 0,75-fachen der Aufzeichnungsspannung gehalten wird.
  7. Verfahren nach Anspruch 1,
    dadurch gekennzeichnet, daß die Aufzeichnungsenergie in einem Bereich zwischen dem 1,05-fachen und dem 1,2-fachen der Sättigungsbeginn-Energie gehalten wird.
EP19920121382 1991-12-19 1992-12-16 Verfahren und Vorrichtung für die wiedereinschreibbare und löschbare Aufzeichnung Expired - Lifetime EP0547572B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP33663391A JPH05169841A (ja) 1991-12-19 1991-12-19 リライタブル記録消去方法及びリライタブル記録表示装置
JP336633/91 1991-12-19

Publications (2)

Publication Number Publication Date
EP0547572A1 EP0547572A1 (de) 1993-06-23
EP0547572B1 true EP0547572B1 (de) 1996-07-24

Family

ID=18301182

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19920121382 Expired - Lifetime EP0547572B1 (de) 1991-12-19 1992-12-16 Verfahren und Vorrichtung für die wiedereinschreibbare und löschbare Aufzeichnung

Country Status (4)

Country Link
EP (1) EP0547572B1 (de)
JP (1) JPH05169841A (de)
CA (1) CA2084955A1 (de)
DE (1) DE69212445T2 (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4832035B2 (ja) * 2004-09-14 2011-12-07 株式会社リコー 画像処理方法
JP5127441B2 (ja) * 2007-12-28 2013-01-23 株式会社リコー 物流管理システム及び情報記録消去装置
JP5785524B2 (ja) * 2011-06-28 2015-09-30 株式会社東芝 消色装置

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2557357B2 (ja) * 1986-11-21 1996-11-27 株式会社リコー 可逆性感熱記録材料
JPH07115545B2 (ja) * 1986-08-05 1995-12-13 株式会社リコー 可逆性感熱記録材料
JP2594263B2 (ja) * 1986-11-25 1997-03-26 株式会社リコー 表示装置
JPS6423245A (en) * 1987-07-18 1989-01-25 Ricoh Kk Overhead projector
JPS6472894A (en) * 1987-09-14 1989-03-17 Ricoh Kk Information storing method
JP2726297B2 (ja) * 1988-01-27 1998-03-11 株式会社リコー 可逆性感熱記録材料
JPH0736718Y2 (ja) * 1989-02-09 1995-08-23 パイロットインキ株式会社 色彩記憶玩具用品セット
EP0429010B1 (de) * 1989-11-17 1994-06-08 Oki Electric Industry Co., Ltd. Thermoreversibles Aufzeichnungsmaterial, eine Vorrichtung, die das Material gebraucht und Verfahren zu deren Herstellung
JP3121358B2 (ja) * 1989-12-20 2000-12-25 株式会社リコー 画像表示方法
JP2932442B2 (ja) * 1990-05-17 1999-08-09 凸版印刷株式会社 カード
JPH0596852A (ja) * 1991-10-04 1993-04-20 Ricoh Co Ltd 可逆的感熱記録媒体

Also Published As

Publication number Publication date
JPH05169841A (ja) 1993-07-09
CA2084955A1 (en) 1993-06-20
DE69212445T2 (de) 1996-11-28
EP0547572A1 (de) 1993-06-23
DE69212445D1 (de) 1996-08-29

Similar Documents

Publication Publication Date Title
US5471044A (en) Information recording card, and information recording and recognition methods using the card
US6121987A (en) Thermal transfer recording apparatus
KR101352735B1 (ko) 비접촉형 개서 가능한 기록매체의 기록방법
US6154243A (en) Reversible thermal recording method and apparatus therefor
US4692774A (en) Multi-color recording apparatus
US6064414A (en) Thermal transfer recording method and thermal transfer printer
EP0547572B1 (de) Verfahren und Vorrichtung für die wiedereinschreibbare und löschbare Aufzeichnung
US5896159A (en) Temperature controlling method and apparatus for a thermal printhead
CA1275008A (en) Thermal transfer printing
JP3176986B2 (ja) 記録装置
US20010038424A1 (en) Recording method and recording apparatus for thermoreversible recording medium
JPH06171226A (ja) 可逆的感熱記録媒体の記録の消色方法
US6731318B2 (en) Method for controlling the heating elements of a thermal print head
JP2828823B2 (ja) リライタブル記録表示装置
JPH11192737A (ja) 印字・消去方法及び装置
JP3215148B2 (ja) 記録装置および記録方法
JP3559079B2 (ja) 可逆性感熱記録材料および可逆性感熱記録方法
JP2707920B2 (ja) 書替え可能な感熱記録媒体
JP3828250B2 (ja) 画像記録方法および画像記録装置
AU722424B2 (en) Thermal transfer recording method and thermal transfer printer
JPH06270543A (ja) 可逆的感熱記録媒体
JPS59225969A (ja) 熱転写形プリンタの記録方式
JP2003094699A (ja) 可逆性感熱記録媒体用記録消去装置及び可逆性感熱記録媒体用画像記録装置
JP2001030633A (ja) 可逆性感熱記録媒体
JP2005343175A (ja) 可逆性感熱記録媒体および可逆性感熱記録装置

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): DE FR GB

17P Request for examination filed

Effective date: 19931216

17Q First examination report despatched

Effective date: 19941004

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): DE FR GB

REF Corresponds to:

Ref document number: 69212445

Country of ref document: DE

Date of ref document: 19960829

ET Fr: translation filed
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 19961209

Year of fee payment: 5

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 19961219

Year of fee payment: 5

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 19970219

Year of fee payment: 5

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19971216

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: THE PATENT HAS BEEN ANNULLED BY A DECISION OF A NATIONAL AUTHORITY

Effective date: 19971231

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 19971216

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980901

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST