EP0533652B1 - Verfahren und vorrichtung zum betrieb einer gasturbine mit zuführung von zusatzstoffen - Google Patents

Verfahren und vorrichtung zum betrieb einer gasturbine mit zuführung von zusatzstoffen Download PDF

Info

Publication number
EP0533652B1
EP0533652B1 EP89901457A EP89901457A EP0533652B1 EP 0533652 B1 EP0533652 B1 EP 0533652B1 EP 89901457 A EP89901457 A EP 89901457A EP 89901457 A EP89901457 A EP 89901457A EP 0533652 B1 EP0533652 B1 EP 0533652B1
Authority
EP
European Patent Office
Prior art keywords
water
burner
fuel
magnesium compound
magnesium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP89901457A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0533652A1 (de
Inventor
Norbert Czech
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens AG
Original Assignee
Siemens AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens AG filed Critical Siemens AG
Publication of EP0533652A1 publication Critical patent/EP0533652A1/de
Application granted granted Critical
Publication of EP0533652B1 publication Critical patent/EP0533652B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J7/00—Arrangement of devices for supplying chemicals to fire
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L7/00—Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
    • F23L7/002—Supplying water
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L7/00—Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
    • F23L7/002—Supplying water
    • F23L7/005—Evaporated water; Steam

Definitions

  • the present invention relates to a method for operating a gas turbine according to the preamble of claim 1 and a corresponding device according to the preamble of claim 7.
  • a method for operating a gas turbine fired with vanadium-containing fuel which has at least one burner in a combustion chamber and means for feeding a magnesium compound dissolved in water as an additive into the combustion chamber, the burner acting on the fuel becomes.
  • a so-called hybrid burner which also provides options for injecting water or steam into the combustion zone.
  • magnesium orthovanadate Mg3V2O8
  • Mg3V2O8 magnesium orthovanadate
  • the resulting magnesium-containing deposits are easy to remove from the blades. So far, the magnesium has been added to the fuel either in the form of oil-soluble compounds, colloidal suspensions or in the form of water-soluble salts that have to be emulsified.
  • the concentration of the water-soluble magnesium compound in the water can be adjusted so that about one tenth of the volume of water with dissolved magnesium compound must be injected per volume of fuel. From a technical point of view, this is not a problem because the injection of much larger portions of water is already solved in another context.
  • MgSO4 dissolve in water.
  • the amount of additional sulfur introduced by the sulfate is insignificant compared to the amount of sulfur usually contained in the fuel. Otherwise there are no disadvantages for the combustion process and the resulting emissions compared to the addition of an oil-soluble magnesium compound.
  • a burner was selected as an example, as is described in detail in EP-A-0 193 838. There is no explanation of the structural details of the burner itself. It is only important that the burner 1 has devices for injecting water 2 and / or steam 3. It is not decisive whether it is a premix burner, a diffusion burner or a so-called hybrid burner. According to the invention, such a burner is assigned at least one storage container 4, which is connected via a metering device 5 to the injection devices 2, 3 for water and / or steam.
  • the present invention is particularly suitable for gas turbine plants in which vanadium-containing fuel is to be burned always or temporarily.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
EP89901457A 1988-03-10 1989-01-19 Verfahren und vorrichtung zum betrieb einer gasturbine mit zuführung von zusatzstoffen Expired - Lifetime EP0533652B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE3808016 1988-03-10
DE3808016 1988-03-10
PCT/DE1989/000026 WO1989008803A1 (en) 1988-03-10 1989-01-19 Process and device for operating a gas turbine with introduction of additives

Publications (2)

Publication Number Publication Date
EP0533652A1 EP0533652A1 (de) 1993-03-31
EP0533652B1 true EP0533652B1 (de) 1995-03-29

Family

ID=6349401

Family Applications (1)

Application Number Title Priority Date Filing Date
EP89901457A Expired - Lifetime EP0533652B1 (de) 1988-03-10 1989-01-19 Verfahren und vorrichtung zum betrieb einer gasturbine mit zuführung von zusatzstoffen

Country Status (5)

Country Link
EP (1) EP0533652B1 (nl)
JP (1) JP2977569B2 (nl)
DE (1) DE58909147D1 (nl)
IN (1) IN171209B (nl)
WO (1) WO1989008803A1 (nl)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009014026A1 (de) * 2008-12-03 2010-06-10 Ernest Stangl Verfahren zur Erzeugung thermischer Energie

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE59204270D1 (de) * 1991-04-25 1995-12-14 Siemens Ag Brenneranordnung, insbesondere für gasturbinen, zur schadstoffarmen verbrennung von kohlegas und anderen brennstoffen.
ES2144057T3 (es) * 1993-09-08 2000-06-01 Siemens Ag Procedimiento para el funcionamiento de una turbina de gas con alimentacion de un aditivo.
EP0735002A1 (en) * 1995-03-31 1996-10-02 Siemens Aktiengesellschaft Method and apparatus for dissolving a magnesium compound in water
JP2002372233A (ja) * 2001-06-14 2002-12-26 Seiji Inoue ボイラ付帯設備
EP1329614A1 (de) * 2002-01-21 2003-07-23 Siemens Aktiengesellschaft Verfahren zum Betrieb eines Brenners sowie Brenner, insbesondere für eine Gasturbine
EP2318494B1 (en) 2008-07-08 2013-11-27 The Lubrizol Corporation Marine diesel cylinder lubricant
US8123821B2 (en) * 2009-02-10 2012-02-28 General Electric Company Regulating vanadium inhibitor in a gas turbine
EP2230458A1 (de) 2009-03-17 2010-09-22 Siemens Aktiengesellschaft Brenneranordnung für fluidische Brennstoffe und Verfahren zum Herstellen der Brenneranordnung
EP2264370B1 (de) * 2009-06-16 2012-10-10 Siemens Aktiengesellschaft Brenneranordnung für eine Verfeuerungsanlage zum Verfeuern fluidischer Brennstoffe und Verfahren zum Betrieb einer solchen Brenneranordnung

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB731242A (en) * 1950-06-28 1955-06-08 Power Jets Res & Dev Ltd Improvements in or relating to fuel oils and the combustion of fuel oils
ES454017A1 (es) * 1976-12-07 1977-11-16 Alentorn Ricos S L R Perfeccionamientos en instalaciones para el ratamiento de la combustion mediante oxidos metalicos.
AU496757B2 (en) * 1977-02-03 1977-04-21 The Percom Company, Inc Compositions and methods for inhibiting corrosion and ash deposition in fossil fuel burning equipment
DE2932676C2 (de) * 1979-08-11 1983-01-27 L. & C. Steinmüller GmbH, 5270 Gummersbach Verfahren zur Bindung von Schwefel-, Chlor- und Fluorverbindungen bei der Verbrennung
US4375359A (en) * 1979-11-02 1983-03-01 Dearborn Chemical Company Limited Water based fireside additive
GB2095283B (en) * 1981-02-09 1984-08-01 Polarchem Ltd Method for the prevention of deposits on or the removal ofdeposits from heating and ancillary surfaces
DE3318374A1 (de) * 1983-05-20 1984-11-22 Günter 3000 Hannover Hackerodt Verfahren zum abtrennen von schwefeloxiden aus verbrennungsgasen sowie vorrichtung zur durchfuehrung des verfahrens
DE3444469C1 (de) * 1984-12-06 1986-06-19 L. & C. Steinmüller GmbH, 5270 Gummersbach Verfahren und Rundbrenner zur Einduesung von waessrigen Additivsuspensionen im Zentrum eines Rundbrenners

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009014026A1 (de) * 2008-12-03 2010-06-10 Ernest Stangl Verfahren zur Erzeugung thermischer Energie

Also Published As

Publication number Publication date
EP0533652A1 (de) 1993-03-31
DE58909147D1 (de) 1995-05-04
JPH03503303A (ja) 1991-07-25
JP2977569B2 (ja) 1999-11-15
WO1989008803A1 (en) 1989-09-21
IN171209B (nl) 1992-08-15

Similar Documents

Publication Publication Date Title
DE3852747T2 (de) Verfahren zur stickstoffoxydminderung und zur minimierung der herstellung sonstiger schadstoffe.
EP0533652B1 (de) Verfahren und vorrichtung zum betrieb einer gasturbine mit zuführung von zusatzstoffen
DE3720216C2 (nl)
DE3830380C2 (nl)
DE60108395T2 (de) Ein brennstoffzusatz
DE3830045A1 (de) Verfahren zur reduktion von in abgasen enthaltenen stickoxiden mittels eines zeolithhaltigen katalysators
DE2653026A1 (de) Als kraftstoff fuer verbrennungsmotoren verwendbares fluessigkeitsgemisch
DE10205380A1 (de) Verfahren sowie Vorrichtung zur Behandlung von Dieselabgas
EP0426978B1 (de) Verfahren zur selektiven nicht-katalytischen Reduktion der Emission von Schadstoffen aus ölbefeuerten Kesselanlagen
EP0492101B1 (de) Verwendung von metallorganischen Additiven zur Verbesserung der Russverbrennung in Dieselkraftstoffen
DE19704874B4 (de) Verfahren zum Herstellen und Verwenden eines viskosen Kohlenwasserstoffes
DE3872105T2 (de) Verfahren zur reduktion von stickstoffoxiden in abgasen mittels zucker.
DE3840212C2 (nl)
EP0742363A1 (de) Verfahren und Vorrichtung zum Mischen und Fördern einer Emulsion für eine Dieselbrennkraftmaschine
EP0140278A2 (de) Verfahren, Vorrichtung und Mittel zur kontinuierlichen Versorgung von Verbrennungsmotoren und/oder Hilfseinrichtungen davon mit Additiven
EP0717813B1 (de) Verfahren zum betrieb einer gasturbine mit zuführung eines zusatzstoffes
DE10043144C1 (de) Verwendung von 2,2-Bisferrocenylalkanen als Kraftstoffadditive
DE3804834A1 (de) Verfahren zum herstellen bzw. verbrennen eines brennstoffes sowie kohlenwasserstoff-brennstoff dafuer
DE3590348T1 (de) Wärmeübertragende Flüssigkeit
DE2757419A1 (de) Verfahren und vorrichtung zum aufbereiten von rueckstandsoel fuer die verwendung in einer gasturbine
EP0961871B1 (de) Verfahren und einrichtung zur steuerung einer verbrennungsanlage und zur katalytischen abgasreinigung sowie verbrennungsanlage
DE19731546C2 (de) Verfahren und Mittel zur selektiven Reduktion von Stickoxiden in Rauchgasen von Kesselanlagen
EP0897462B1 (de) Verfahren zur verringerung des russgehalts im abgas eines dieselmotors und einrichtung zur durchführung dieses verfahrens
DE102023101081B3 (de) Brennkraftmaschine und Verfahren zum Betreiben derselben
DE2520971C3 (de) Wasser-Kraftstoffemulsion, die als Emulgator einen Alkylarylpolyglykoläther enthält

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19900726

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): CH DE FR GB IT LI SE

17Q First examination report despatched

Effective date: 19930928

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): CH DE FR GB IT LI SE

REF Corresponds to:

Ref document number: 58909147

Country of ref document: DE

Date of ref document: 19950504

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 19950426

ITF It: translation for a ep patent filed

Owner name: STUDIO JAUMANN

ET Fr: translation filed
PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
REG Reference to a national code

Ref country code: GB

Ref legal event code: IF02

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED.

Effective date: 20050119

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 20060105

Year of fee payment: 18

Ref country code: GB

Payment date: 20060105

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20060123

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20060322

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 20060411

Year of fee payment: 18

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070120

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070131

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070131

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070801

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

EUG Se: european patent has lapsed
GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20070119

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20070930

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070119

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070131

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20060131

Year of fee payment: 18

PGRI Patent reinstated in contracting state [announced from national office to epo]

Ref country code: IT

Effective date: 20080301

PGRI Patent reinstated in contracting state [announced from national office to epo]

Ref country code: IT

Effective date: 20080301