EP0494683A1 - Textilausrüstungsmittel - Google Patents
Textilausrüstungsmittel Download PDFInfo
- Publication number
- EP0494683A1 EP0494683A1 EP19920100344 EP92100344A EP0494683A1 EP 0494683 A1 EP0494683 A1 EP 0494683A1 EP 19920100344 EP19920100344 EP 19920100344 EP 92100344 A EP92100344 A EP 92100344A EP 0494683 A1 EP0494683 A1 EP 0494683A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- agent
- liquor
- polysiloxane
- textile
- means according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000009988 textile finishing Methods 0.000 title claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 18
- -1 polysiloxane Polymers 0.000 claims abstract description 14
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 13
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 9
- 229920000570 polyether Polymers 0.000 claims abstract description 9
- 239000004599 antimicrobial Substances 0.000 claims abstract description 8
- 239000003054 catalyst Substances 0.000 claims abstract description 8
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 8
- 239000004753 textile Substances 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 6
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000004593 Epoxy Substances 0.000 claims description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims 2
- 230000001804 emulsifying effect Effects 0.000 claims 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 15
- 239000004744 fabric Substances 0.000 description 7
- 230000000845 anti-microbial effect Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 241000193830 Bacillus <bacterium> Species 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 241000588724 Escherichia coli Species 0.000 description 2
- 241000589517 Pseudomonas aeruginosa Species 0.000 description 2
- 241000191967 Staphylococcus aureus Species 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 244000052769 pathogen Species 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- 241000193738 Bacillus anthracis Species 0.000 description 1
- 244000063299 Bacillus subtilis Species 0.000 description 1
- 235000014469 Bacillus subtilis Nutrition 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000222122 Candida albicans Species 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 206010061217 Infestation Diseases 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- 241000588769 Proteus <enterobacteria> Species 0.000 description 1
- 241001354013 Salmonella enterica subsp. enterica serovar Enteritidis Species 0.000 description 1
- 241000607764 Shigella dysenteriae Species 0.000 description 1
- 241000191963 Staphylococcus epidermidis Species 0.000 description 1
- 229940065181 bacillus anthracis Drugs 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/11—Compounds containing epoxy groups or precursors thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/65—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing epoxy groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/907—Resistant against plant or animal attack
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2402—Coating or impregnation specified as a size
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2525—Coating or impregnation functions biologically [e.g., insect repellent, antiseptic, insecticide, bactericide, etc.]
Definitions
- the invention relates to a textile finishing agent and method for finishing textile goods.
- Natural, untreated textiles generally do not meet the high demands placed on the properties of a textile. They are therefore chemically treated to give them the desired properties. The means used for this are called equipment.
- finishing agents are almost never universally usable for all common basic textile materials. Finishing agents for textiles made from cellulose are therefore needed differently than those made from keratin fibers (e.g. wool) or synthetic fibers such as polyesters.
- finishing agents based on N-hydroxymethyl or N-methoxymethyl compounds which emit formaldehyde under the conditions of use and more or less strongly crosslink the cellulose-containing material, had prevailed for cellulose-containing textiles.
- the invention is therefore based on the object of providing finishing agents for textiles which can be used universally for all customary textile base materials and are free from formaldehyde or formaldehyde-releasing compounds.
- the invention has for its object in particular to provide a finishing agent of the type mentioned above, which gives the textile antimicrobial properties, crease resistance, soft feel and good air permeability and is largely washable.
- Polysiloxanes of the above formula I are advantageous in which the polyether residue R 'contains about 50 to 200 units of the formulas given, the epoxy polyether residue R' 'has 1 to 10 epoxy groups and the polyethoxy residue R' '' has about 50 to 200 ethoxy units.
- R ', R''andR''' can therefore also be characterized by the following formulas: where "n" each represents an integer from about 50 to 200 and the epoxy group in the rest R ′′ can occur several times, for example 2 to 10 times.
- the polysiloxane of the formula I preferably has a molecular weight between 100,000 and 300,000, in particular a molecular weight of 200,000 to 250,000.
- This polysiloxane is readily water-soluble, at least it should be easily dispersible or emulsifiable in water.
- the methylsiloxane units with the radicals R ', R''andR''' can also be repeated several times in the molecule. In this case, the side chains R ', R''andR''' can be made correspondingly shorter or the number "m" of the dimethylsiloxane units can be reduced accordingly.
- the polysiloxanes of the general formula I are prepared in a manner known per se, e.g. by cohydrolysis and subsequent condensation of various organohalosilanes, cf. e.g. Ullmann's Encyclopedia of Technical Chemistry, 4th Edition, Vol. 21, pp. 500 ff.
- the textile finishing agent according to the invention preferably also contains an antimicrobial agent, a crosslinking agent and at least one catalyst.
- the preferred antimicrobial agent is dodecyldimethylbenzylammonium chloride of the formula II: used.
- Alpha, omega-bisepoxypropyl-hexamethylene diamine of the formula III is preferably used as the crosslinking agent: used.
- Acetic acid and magnesium chloride are advantageously used as catalysts.
- a ready-to-use aqueous solution preferably contains:
- the above-mentioned contents are the application contents in aqueous solution, ie in an aqueous liquor.
- the agent can of course also be handled in the form of a concentrated stock solution, from which the application liquor is prepared by dilution with water. It is advantageous to store the middle undiluted in the form of a 2 or 3-component packaging.
- the antimicrobial agent and the catalysts can be combined and stored together and the polysiloxane and the crosslinking agent added separately packed. The components are advantageously combined in the aqueous solution immediately before use.
- the process according to the invention for finishing textiles is carried out in such a way that the components described above, if appropriate in the presence of customary additives, in the proportions given above in Water dissolves and then the textile material is treated with the solution.
- the textile material is preferably completely impregnated with the solution and then a certain liquor content is set by pressing, for example in a padder. Then it is dried in the heat and finally briefly heated to a higher temperature. Drying is advantageously carried out at 70 to 100 ° C, the drying time is then about 5 to 15 minutes, advantageously 6 to 10 minutes. Finally, the mixture is heated, for example, to 110 to 120 ° for 20 to 90 seconds, advantageously to 115 ° C., and the whole is aged for about 24 hours.
- the agent according to the invention absorbs very well on textiles made of all natural materials, such as cotton, wool and silk, but also on synthetic materials. It is self-crosslinking, the bond to the textile material is therefore very strong, which is expressed in an unusually high wash resistance.
- the agent gives tissue a pleasant, soft feel, does not impair the coloration of the tissue, is physiologically very compatible and can be applied in the usual way using conventional devices.
- a very advantageous embodiment of the agent according to the invention is the combination with the crosslinking agent and the catalysts mentioned above.
- an antimicrobial agent in particular the above-mentioned dodecyldimethylbenzylammonium chloride, is particularly advantageous.
- the overall combination of organopolysiloxane, crosslinking agent, catalysts and antimicrobial agent described here results in a textile finish of the highest quality.
- This equipment protects against moth and mold infestation and inhibits or kills most common pathogens, such as: Staphylococcus aureus, (with and without drug resistance) Staphylococcus albus, Candida albicans, Bacillus subtilis, Bacillus coli, Bacillus pyocyaneus, Bacillus dysenteriae, Bacillus enteritidis, Bacillus typhosus, Bacillus proteus, Bacillus anthracis.
- Staphylococcus aureus (with and without drug resistance) Staphylococcus albus
- Candida albicans Bacillus subtilis
- Bacillus coli Bacillus pyocyaneus
- Bacillus dysenteriae Bacillus enteritidis
- Bacillus typhosus Bacillus proteus
- Bacillus anthracis most common pathogens
- This antimicrobial finish is very effective, extremely wash-resistant and body-friendly. It can therefore be used very well in both technical and hygienic areas.
- Textiles finished in this way prevent the transmission of pathogenic microbes and odor formation due to microbial degradation. Textiles of this kind work therefore also deodorising, for example in refrigerators, storage rooms, toilets and bathrooms.
- 100 g of a bleached cotton fabric such as is used for the manufacture of doctor's coats, are immersed in the aforementioned liquor, agitated a few times in the liquor to remove air bubbles and to completely impregnate the fabric, after about 30 to 60
- the tissue is removed for seconds. It is allowed to drain for a few seconds and then the excess liquor is removed between squeeze rollers, a moisture content of about 70% being set.
- the mixture is then dried at 70 to 100 ° C. for 6 to 10 minutes, then heated to 115 ° C. for 40 to 60 seconds, and finally the tissue treated in this way is allowed to age for 24 hours.
- the equipment thus obtained is extremely wash-resistant and antimicrobial.
- the test results described above were achieved with a fabric of this type.
- Example 1 In a liter of a liquor obtained according to Example 1, 150 g of a dyed silk fabric of a normal lining quality are immersed and agitated therein for a few seconds in order to achieve complete wetting and impregnation. The fabric is then removed, it is allowed to drip off and the excess liquor is removed between squeeze rollers, a moisture content of 60% being set. Then it is dried at 70 to 100 ° C for 6 to 8 minutes and heated to 115 ° C for 30 to 40 seconds. Then let it age for 24 hours.
- the equipment obtained in this way is just as washable as the above and its antimicrobial effect remains unchanged even after approx. 60 washing cycles.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4100703 | 1991-01-11 | ||
| DE19914100703 DE4100703A1 (de) | 1991-01-11 | 1991-01-11 | Textilausruestungsmittel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0494683A1 true EP0494683A1 (de) | 1992-07-15 |
Family
ID=6422874
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19920100344 Withdrawn EP0494683A1 (de) | 1991-01-11 | 1992-01-10 | Textilausrüstungsmittel |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US5254134A (enrdf_load_stackoverflow) |
| EP (1) | EP0494683A1 (enrdf_load_stackoverflow) |
| JP (1) | JPH0610272A (enrdf_load_stackoverflow) |
| DE (1) | DE4100703A1 (enrdf_load_stackoverflow) |
| TW (1) | TW235321B (enrdf_load_stackoverflow) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5563231A (en) * | 1995-06-06 | 1996-10-08 | Bayer Corporation | Capped silanes and their application to textile substrates |
| US5981066A (en) * | 1996-08-09 | 1999-11-09 | Mtc Ltd. | Applications of metallized textile |
| US5871816A (en) * | 1996-08-09 | 1999-02-16 | Mtc Ltd. | Metallized textile |
| TW448255B (en) * | 1996-08-27 | 2001-08-01 | Takemoto Oil & Amp Fat Co Ltd | Agents for lubricating synthetic yarns for false twisting process and methods of lubricating synthetic yarns for false twisting process |
| KR100438148B1 (ko) * | 1996-08-28 | 2004-08-12 | 다케모토 유시 가부시키 가이샤 | 쇼트히터식가연가공에제공하는합성섬유필라멘트사조의윤활성부여방법 |
| DE10012913A1 (de) | 2000-03-16 | 2001-09-20 | Ciba Sc Pfersee Gmbh | Polyorganosiloxane mit alkoxilierten Seitenketten |
| IL135487A (en) * | 2000-04-05 | 2005-07-25 | Cupron Corp | Antimicrobial and antiviral polymeric materials and a process for preparing the same |
| US20050150514A1 (en) * | 2000-04-05 | 2005-07-14 | The Cupron Corporation | Device for cleaning tooth and gum surfaces |
| US20040247653A1 (en) * | 2000-04-05 | 2004-12-09 | The Cupron Corporation | Antimicrobial and antiviral polymeric materials and a process for preparing the same |
| IL149206A (en) * | 2002-04-18 | 2007-07-24 | Cupron Corp | Method and device for inactivation of hiv |
| US20050123589A1 (en) * | 2002-04-18 | 2005-06-09 | The Cupron Corporation | Method and device for inactivating viruses |
| US7296690B2 (en) * | 2002-04-18 | 2007-11-20 | The Cupron Corporation | Method and device for inactivating viruses |
| US20040167483A1 (en) * | 2003-02-21 | 2004-08-26 | The Cupron Corporation C/O Law Offices Of Mr. Sylavin Jakabovics | Disposable diaper for combating diaper rash |
| US7364756B2 (en) * | 2003-08-28 | 2008-04-29 | The Cuprin Corporation | Anti-virus hydrophilic polymeric material |
| IL157625A0 (en) * | 2003-08-28 | 2004-03-28 | Cupron Corp | Anti-virus hydrophilic polymeric material |
| US7480393B2 (en) * | 2003-11-19 | 2009-01-20 | Digimarc Corporation | Optimized digital watermarking functions for streaming data |
| AU2005303369B2 (en) | 2004-11-09 | 2011-08-04 | Cupron Inc. | Methods and materials for skin care |
| US8292971B2 (en) * | 2008-10-27 | 2012-10-23 | Man Soo Choi | Method of treating fabric conditioner for washable silk products |
| CN117364480A (zh) * | 2023-11-07 | 2024-01-09 | 青岛大学 | 染色抗皱抗紫外棉及棉混纺纤维素纤维织物及其染整工艺 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4184004A (en) * | 1978-04-21 | 1980-01-15 | Union Carbide Corporation | Treatment of textile fabrics with epoxy-polyoxyalkylene modified organosilicones |
| US4408996A (en) * | 1981-10-09 | 1983-10-11 | Burlington Industries, Inc. | Process for dyeing absorbent microbiocidal fabric and product so produced |
| EP0292963A2 (en) * | 1987-05-26 | 1988-11-30 | Toray Silicone Company, Limited | Fiber-treatment composition |
| EP0313867A2 (de) * | 1987-10-16 | 1989-05-03 | Th. Goldschmidt AG | Organopolysiloxane mit Buntesalzgruppen |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE33049C (de) * | F. WlCKARDT in Einbeck, Geiststr. 1 | Garnwinde | ||
| DE313867C (enrdf_load_stackoverflow) * | ||||
| DE3060191D1 (en) * | 1979-03-23 | 1982-03-25 | Goldschmidt Ag Th | Preparation for making wool shrink-proof |
| DE3034380A1 (de) * | 1980-09-12 | 1982-03-25 | Th. Goldschmidt Ag, 4300 Essen | Zubereitung zum schrumpffestmachen von wolle |
| US4414268A (en) * | 1981-10-09 | 1983-11-08 | Burlington Industries, Inc. | Absorbent microbiocidal fabric and process for making same |
| DE3323881C2 (de) * | 1983-07-02 | 1985-06-13 | Th. Goldschmidt Ag, 4300 Essen | Organopolysiloxane mit Buntesalzgruppen, deren Herstellung und Verwendung zur Oberflächenbehandlung von anorganischen oder organischen Materialien |
| GB8319300D0 (en) * | 1983-07-16 | 1983-08-17 | Ciba Geigy Ag | Treating textiles |
| JPS6094680A (ja) * | 1983-10-28 | 1985-05-27 | 東レ・ダウコーニング・シリコーン株式会社 | 繊維処理剤 |
| DE3802622A1 (de) * | 1988-01-29 | 1989-08-10 | Goldschmidt Ag Th | Mittel zum ausruesten von textilfasern oder aus textilfasern bestehenden produkten |
| US4842932A (en) * | 1988-03-08 | 1989-06-27 | Basf Corporation | Fiber-containing yarn possessing antimicrobial activity |
| US5126138A (en) * | 1988-07-19 | 1992-06-30 | Dow Corning Corporation | Antimicrobial flourochemically treated plastic (nylon) surfaces |
-
1991
- 1991-01-11 DE DE19914100703 patent/DE4100703A1/de not_active Withdrawn
-
1992
- 1992-01-10 EP EP19920100344 patent/EP0494683A1/de not_active Withdrawn
- 1992-01-10 JP JP2179692A patent/JPH0610272A/ja active Pending
- 1992-01-11 TW TW81100160A patent/TW235321B/zh active
- 1992-01-13 US US07/820,073 patent/US5254134A/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4184004A (en) * | 1978-04-21 | 1980-01-15 | Union Carbide Corporation | Treatment of textile fabrics with epoxy-polyoxyalkylene modified organosilicones |
| US4408996A (en) * | 1981-10-09 | 1983-10-11 | Burlington Industries, Inc. | Process for dyeing absorbent microbiocidal fabric and product so produced |
| EP0292963A2 (en) * | 1987-05-26 | 1988-11-30 | Toray Silicone Company, Limited | Fiber-treatment composition |
| EP0313867A2 (de) * | 1987-10-16 | 1989-05-03 | Th. Goldschmidt AG | Organopolysiloxane mit Buntesalzgruppen |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0610272A (ja) | 1994-01-18 |
| TW235321B (enrdf_load_stackoverflow) | 1994-12-01 |
| US5254134A (en) | 1993-10-19 |
| DE4100703A1 (de) | 1992-07-16 |
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