EP0493100A1 - Papier pour impression par jet d'encre et étiquettes ainsi fabriquées - Google Patents

Papier pour impression par jet d'encre et étiquettes ainsi fabriquées Download PDF

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Publication number
EP0493100A1
EP0493100A1 EP91311999A EP91311999A EP0493100A1 EP 0493100 A1 EP0493100 A1 EP 0493100A1 EP 91311999 A EP91311999 A EP 91311999A EP 91311999 A EP91311999 A EP 91311999A EP 0493100 A1 EP0493100 A1 EP 0493100A1
Authority
EP
European Patent Office
Prior art keywords
ink jet
jet recording
recording paper
weight
paper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP91311999A
Other languages
German (de)
English (en)
Inventor
Yoshihiro Research Dev. Lab. Products Kuroyama
Yoshio Research Dev. Lab. Products Yoshida
Satomi Research Dev. Lab. Products Suzuki
Yoshifumi Research Dev. Lab. Products Iimori
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanyo Kokusaku Pulp Co Ltd
Original Assignee
Sanyo Kokusaku Pulp Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sanyo Kokusaku Pulp Co Ltd filed Critical Sanyo Kokusaku Pulp Co Ltd
Publication of EP0493100A1 publication Critical patent/EP0493100A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings
    • B41M5/5218Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings
    • B41M5/5227Macromolecular coatings characterised by organic non-macromolecular additives, e.g. UV-absorbers, plasticisers, surfactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings
    • B41M5/5254Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers

Definitions

  • This invention relates to an ink jet recording paper having a high scratch strength recording layer and ink jet recording labels made therefrom.
  • ink jet recording There are various mechanisms by which ink jet recording may be accomplished. In all of these mechanisms, however, recording is effected by ejecting fine ink droplets, and making these droplets adhere to recording paper so as to form dots. Compared to dot impact recording techniques, ink jet recording offers the advantages of noiselessness, easy adaptation to full colour recording, and the possibility of high speed printing.
  • an ink jet recording paper wherein the recording layer has high scratch strength is required from the viewpoint of durability.
  • high resolution printing can be performed so that characters can be recorded, and in particular so that small characters are sufficiently clear and distinct.
  • Conventional coat-type ink jet recording paper however suffers from the disadvantages that its frictional resistance and scratch resistance are inadequate, and that in some cases small characters cannot be distinguished. For these reasons, it is unable to satisfy the aforesaid requirements.
  • the amount of binder in the layer is merely increased, printed dots spread out and fine lines become thicker, so that the desired recording properties are not obtained.
  • the inventors of the present invention carried out various studies on ink jet recording paper. As a result of these studies, it has been found that satisfactory results can be achieved by treating the paper with both borax or boric acid and polyvinyl alcohol.
  • an ink jet recording paper comprising a substrate which is coated with at least 0.1 g/m2 of borax or boric acid on at least one side, and an ink jet recording layer which is coated at a coverage of 5-20 g/m2 on one coated surface of the substrate, with the ink jet recording layer comprising 100 parts by weight of a pigment having a synthetic silica as its main ingredient and 10 - 35 parts by weight of a binder having polyvinyl alcohol as its main ingredient; and by an ink jet recording label made from the aforesaid paper.
  • the layer of borax or boric acid forming an undercoat to the ink jet recording layer causes gelation of the polyvinyl alcohol in the ink jet recording layer during the coating process, thereby increasing the surface retention of binder and improving the scratch strength of the ink jet recording layer without an increase in the amount of binder. Further, the borax or boric acid and polyvinyl alcohol undergo a crosslinking reaction, so that even when the amount of binder is decreased to a level at which there does not occur such blotting of dots or thickening of fine lines as to impair recording properties, and at which high resolution recording can therefore be performed, sufficient scratch strength of the ink jet recording layer is still maintained.
  • the recording layer has high scratch strength and, what is more, has recording resolution high enough to make small characters clear and distinct, or to render them distinguishable.
  • reference numeral 1 indicates an ink jet recording layer, 2 a borax or boric acid treated layer, and 3 a support.
  • the support used in this invention may be suitably chosen from any of the materials known in the art, but chemical pulp paper, mechanical woodpulp paper and recycled paper are particularly to be preferred.
  • a borax or boric acid treatment is first applied to at least one side of the substrate 3 by coating at least one side of the substrate 3 with an aqueous solution of borax or boric acid.
  • the coating method may be suitably chosen from any of the methods known to those skilled in the art such as the use of an air knife, roller, bar, gravure or size press.
  • the coverage of the solution on the or each face of the substrate should be at least 0.1 g/m2 on a solids basis, but more preferably from 0.2 g/m2 to 5 g/m2 for borax and more preferably from 0.4 g/m2 to 5 g/m2 for boric acid.
  • the ink jet recording layer 1 which is formed on this borax or boric acid layer 2 comprises a pigment having a synthetic silica as its main ingredient and a binder having polyvinyl alcohol as its main ingredient, but it may also contain various auxiliary agents in common use such as dispersants, antifoamers, dyes, fluidity modifiers and the like.
  • a borax or boric acid treated layer 2 as described herinbefore causes gelation of the polyvinyl alcohol in the ink jet recording layer 1 during the coating process so that it cannot easily penetrate the paper and increases the surface retention of binder.
  • the scratch strength of the ink jet recording layer 1 can therefore be increased without increasing the amount of binder.
  • the borax or boric acid and polyvinyl alcohol undergo a crosslinking reaction so that scratch strength is maintained even when the amount of binder is reduced.
  • the synthetic silica which is the main ingredient of the pigment that is which constitutes from 60 wt% to 100 wt% of the total amount of pigment, may be suitably chosen from any kind of synthetic silica known in the art, but silica with a large specific surface is particularly to be preferred.
  • Typical examples of such silica are fine silica obtained by the wet process, white carbon, silica gel, and ultrafine silica obtained by the dry process.
  • the pigment which can be used as an auxiliary ingredient together with the synthetic silica which is the main ingredient may be suitably chosen from among those known in the art such as kaolin, calcium carbonate, aluminium hydroxide, satin white and aluminium silicate.
  • the binder of which the main ingredient is polyvinyl alcohol is used in a proportion of 10 - 35 parts by weight with respect to 100 parts by weight of pigment.
  • a high molecular compound suitably chosen from resins known in the art such as casein, starch, carboxymethyl cellulose, styrene/butadiene latex, acrylic emulsions and vinyl acetate emulsions may be added either as an auxiliary ingredient of the binder or in addition to the aforesaid binder.
  • the amount of such added auxiliary agent is preferably no greater than 15 parts by weight, and more preferably no greater than 5 parts by weight, of binder.
  • cationic polyelectrolytes may be added to the ink jet recording layer 1 in order to improve the water resistance of the printed part of the paper.
  • aqueous ink is used in ink jet recording, so the recording tended to blot or run after printing due to adhesion of water.
  • Cationic polyelectrolytes react with groups such as -SO3Na, -SO3H and -NH2 in water-soluble direct dye or water-soluble acidic dye molecules in the ink so as to form salts which are insoluble in water, and their addition therefore improves the water resistance of the printed part of the paper.
  • cationic polyelectrolytes examples include polyvinylbenzyltrimethylammonium halides, polydiacryldimethylammonium halides, polydimethyl-aminoethylmethacrylate hydrochloride, polyethyleneimine, dicyanodiamide-formaldehyde condensates, epichlorohydrin-modified polyalkylamines, polyvinylpyridinium halides, and other quaternary ammonium salts and polyamines.
  • cationic polyelectrolytes are added in a proportion of 2 parts - 30 parts by weight, and more preferably 4 parts - 20 parts by weight, to 100 parts by weight of pigment, but this proportion may be suitably adjusted depending on the amount of coating material, and the type and quantity of ink to be used.
  • any suitable coating means may be used which is known in the art for general manufacture of pigment-coated paper such as a blade coater, air knife coater, roller coater, curtain coater, bar coater, gravure coater or comma coater.
  • the amount of coated material should normally be 5 - 20 g/m2, and more preferably 7 - 15 g/m2, in terms of solids equivalent for each surface of the paper, but this amount may be adjusted as desired provided that the surface is covered and sufficient ink absorption is obtained.
  • Fig. 2 is a sectional view of an ink jet recording label comprising a layer of pressure sensitive adhesive 4 covered by a release paper 5 and formed on a support 3 of the recording paper of Fig. 1.
  • the pressure sensitive adhesive used in the pressure sensitive layer 4 may be either solvent-based or water-based.
  • the pressure sensitive layer 4 and release layer 5 may be fixed on the support by, for example, so-called "transfer coating” wherein a pressure sensitive adhesive is coated onto a release paper or film which has been peel-off treated with a silicone resin or the like, dried, and then laminated with a substrate.
  • the ink jet recording label of the invention is used by recording on the ink jet recording layer 1, removing the release paper 5, and affixing the label to an object 6 as shown in Fig. 3.
  • a 1 wt% aqueous solution of borax was coated by a size press onto both sides of ordinary woodfree paper with a basis weight of 64 g/m2 so as to have a total coverage of 0.4 g/m2 (0.2 g/m2 on each side) on a solids basis.
  • 100 parts by weight of a synthetic silica (commercial name Finesil X-37: Tokuyama Soda K.K.) was dispersed in 350 parts by weight of water, and mixed with a solution prepared by dissolving 30 parts by weight of polyvinyl alcohol (PVA 117: Kuraray K.K.) in 270 parts by weight of water to give an ink jet recording layer coating colour.
  • PVA 117 Kuraray K.K.
  • This colour was applied with a bar coater to the aforesaid borax-treated paper at a coverage of 15 g/m2 on a solids basis, and dried to give an ink jet recording paper.
  • a 5 wt% aqueous solution of boric acid was coated by a size press onto both sides of ordinary woodfree paper with a basis weight of 75 g/m2 so as to have a total coverage of 1.0 g/m2 (0.5 g/m2 on each side) on a solids basis.
  • the ink jet recording layer coating color used in Example 1 was applied by a bar coater at a coverage of 10 g/m2 on a solids basis, and dried to give an ink jet recording paper.
  • This ink jet recording paper was evaluated in the same way as in Example 1, and the results are shown in Table 1.
  • a synthetic silica (Finesil X-37) was dispersed in 350 parts by weight of water, and mixed with a solution prepared by dissolving 20 parts by weight of polyvinyl alcohol (PVA 117) in 180 parts by weight of water followed by 5 parts by weight of a polyvinylbenzyltrimethylammonium halide to give an ink jet recording layer coating color.
  • PVA 117 polyvinyl alcohol
  • This color was applied by a bar coater to the borax-treated paper used in Example 1 at a coverage of 14 g/m2 on a solids basis, and dried to give an ink jet recording paper.
  • the recording paper obtained was evaluated in a similar way to Example 1, and the results are shown in Table 1. Further, when the recording paper was immersed in water after printing and the paper observed after 5 minutes, there was found to be little running of ink.
  • An acrylic emulsion pressure sensitive adhesive (Toughtac 601: Sanyo Kokusaku Pulp K.K.) was coated at a coverage of 20 g/m2 on a release paper (EK 120D2: Lintec K. K.).
  • This coated release paper was laminated with the ink jet recording paper obtained in Example 3 to fabricate a label.
  • the ink jet recording label thus obtained was evaluated in a similar way to Example 1, and the results are shown in Table 1. Further, after printing, this label was affixed to a video cassette, and exhibited satisfactory affixing properties without peeling off.
  • a 1 wt% aqueous solution of borax was coated by a bar coater onto both sides of ordinary woodfree paper with a basis weight of 64 g/m2 so as to have a total coverage of 0.6 g/m2 (0.3 g/m2 on each side) on a solid basis. Further, 100 parts by weight of a synthetic silica (commercial name Syloid 620: Fuji Davison Chemical Ltd.) was dispersed in 350 parts by weight of water, and mixed with a solution prepared by dissolving 10 parts by weight of polyvinyl alcohol (PVA 117: Kuraray K.K.) in 90 parts by weight of water to give an ink jet recording layer coating color.
  • PVA 117 Kuraray K.K.
  • This color was applied with an air-knife coater to the aforesaid borax-treated paper at a coverage of 20 g/m2 on a solids basis, and dried to give an ink jet recording paper.
  • This ink jet recording paper was evaluated in the same way as in Example 1, and the results are shown in Table 1.
  • a 1 wt% aqueous solution of boric acid was coated by a bar coater onto both sides of ordinary woodfree paper with a basis weight of 64 g/m2 so as to have a total coverage of 0.4 g/m2 (0.2 g/m2 on each side) on a solids basis.
  • the ink jet recording layer coating color used in Example 5 was applied by an air-knife coater at a coverage of 5 g/m2 on a solids basis, and dried to give an ink jet recording paper.
  • This ink jet recording paper was evaluated in the same way as in Example 1, and the results are shown in Table 1.
  • a 5 wt% aqueous solution of boric acid was coated by a size press onto both sides of ordinary woodfree paper with a basis weight of 64 g/m2 so as to have a total coverage of 1.2 g/m2 (0.6 g/m2 on each side) on a solids basis.
  • the ink jet recording layer coating color used in Example 5 was applied by a bar coater at a coverage of 18 g/m2 on a solids basis, and dried to give an ink jet recording paper.
  • This ink jet recording paper was evaluated in the same way as in Example 1, and the results are shown in Table 1.
  • a 5 wt% aqueous solution of boric acid was coated by a size press onto both sides of ordinary woodfree paper with a basis weight of 64 g/m2 so as to have a total coverage of 1.2 g/m2 (0.6 g/m2 on each side) on a solids basis.
  • the ink jet recording layer coating color used in Example 5 was applied by a bar coater at a coverage of 5 g/m2 on a solids basis, and dried to give an ink jet recording paper.
  • This ink jet recording paper was evaluated in the same way as in Example 1, and the results are shown in Table 1.
  • Example 1 The ink jet recording layer coating color used in Example 1 was applied to ordinary woodfree paper with a basis weight of 64 g/m2 so as to have a coverage of 10 g/m2 on a solids basis, and dried to give an ink jet recording paper.
  • the recording paper obtained was evaluated in a similar way to Example 1, and the results are shown in Table 1. Further, when the recording paper was immersed in water after printing and the paper observed after 5 minutes, there was found to be some running of the print.
  • Example 1 100 parts by weight of a synthetic silica (Finesil X-37) was dispersed in 350 parts by weight of water, and mixed with a solution prepared by dissolving 5 parts by weight of polyvinyl alcohol (PVA 117) in 45 parts by weight of water to give an ink jet recording layer coating color.
  • PVA 117 polyvinyl alcohol
  • This color was applied by a bar coater to the borax-treated paper used in Example 1 so as to have a coverage of 14 g/m2 on a solids basis, and dried to give an ink jet recording paper.
  • the recording paper obtained was evaluated in a similar way to Example 1, and the results are shown in Table 1.
  • Example 1 100 parts by weight of a synthetic silica (Finesil X-37) was dispersed in 350 parts by weight of water, and mixed with a solution prepared by dissolving 50 parts by weight of polyvinyl alcohol (PVA 117) in 450 parts by weight of water to give an ink jet recording layer coating color.
  • PVA 117 polyvinyl alcohol
  • This color was applied by a bar coater to the borax-treated paper used in Example 1 so as to have a coverage of 14 g/m2 on a solids basis, and dried to give an ink jet recording paper.
  • the recording paper obtained was evaluated in a similar way to Example 1, and the results are shown in Table 1.
  • Example 1 The ink jet recording layer coating color used in Example 1 was applied by a bar coater to the borax- treated paper used in Example 2 so as to have a coverage of 2 g/m2 on a solids basis, and dried to give an ink jet recording paper.
  • the recording paper obtained was evaluated in a similar way to Example 1, and the results are shown in Table 1.
  • Example 1 The ink jet recording layer coating color used in Example 1 was applied by a bar coater to the borax- treated paper used in Example 2 so as to have a coverage of 25 g/m2 on a solids basis, and dried to give an ink jet recording paper.
  • the recording paper obtained was evaluated in a similar way to Example 1, and the results are shown in Table 1.

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Paper (AREA)
EP91311999A 1990-12-26 1991-12-23 Papier pour impression par jet d'encre et étiquettes ainsi fabriquées Withdrawn EP0493100A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP413949/90 1990-12-26
JP2413949A JPH0737175B2 (ja) 1990-12-26 1990-12-26 インクジェット記録紙及びそれを用いたラベル

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EP0493100A1 true EP0493100A1 (fr) 1992-07-01

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JP (1) JPH0737175B2 (fr)
AU (1) AU8806091A (fr)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0605840A2 (fr) * 1992-12-25 1994-07-13 Mitsubishi Paper Mills, Ltd. Feuille d'enregistrement à jet d'encre
EP0634286A1 (fr) * 1993-07-14 1995-01-18 Asahi Glass Company Ltd. Fluide de revêtement à base de sol d'alumine et support d'impression
EP0734882A2 (fr) * 1995-03-31 1996-10-02 Nippon Paper Industries Co., Ltd. Papier d'enregistrement
DE19602793C1 (de) * 1996-01-26 1997-09-25 Schoeller Felix Jun Foto Aufzeichnungsmaterial für das Tintenstrahl-Druckverfahren
EP0888904A1 (fr) * 1997-07-01 1999-01-07 Konica Corporation Méthode pour l'enregistrement par jet d'encre
EP1111452A2 (fr) * 1999-12-17 2001-06-27 Eastman Kodak Company Méthode d'obtention d'une couche ayant une viscosité élevée sur un support en mouvement et articles obtenus par cette méthode
EP1378369A1 (fr) * 2002-07-01 2004-01-07 ILFORD Imaging Switzerland GmbH Procédé pour le revêtement d'un support en mouvement et articles préparés par ce procédé
US6746713B2 (en) 2001-04-19 2004-06-08 Stora Enso North America Corporation Method of making ink jet recording media
EP1318026A3 (fr) * 2001-12-04 2004-10-20 Eastman Kodak Company Elément pour l'enregistrement au jet d'encre et procédé d'impression
EP1386751A3 (fr) * 2002-07-31 2004-10-20 Eastman Kodak Company Elément pour impression par jet d'encre et procédé d'impression
US6908191B2 (en) * 2002-07-31 2005-06-21 Eastman Kodak Company Ink jet printing method
EP1671805A2 (fr) 2004-12-16 2006-06-21 Agfa-Gevaert Procédé d'impression avec encre durcissable par rayonnement utilisant un liquide pour contrôler la taille des points
US7575314B2 (en) 2004-12-16 2009-08-18 Agfa Graphics, N.V. Dotsize control fluid for radiation curable ink-jet printing process
EP2420619A1 (fr) * 2010-08-20 2012-02-22 Polymer Ventures, Inc. Revêtements améliorés de polyol, articles et procédés
US8247045B2 (en) 2007-11-08 2012-08-21 Eastman Kodak Company Inkjet recording element
US8247044B2 (en) 2007-11-08 2012-08-21 Eastman Kodak Company Inkjet recording element
US8287974B2 (en) 2009-06-01 2012-10-16 Polymer Ventures, Inc. Polyol-based release paper, articles, and methods

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2686670B2 (ja) * 1990-04-02 1997-12-08 キヤノン株式会社 インクジェット用被記録材
JPH07290818A (ja) * 1994-03-04 1995-11-07 Mitsubishi Paper Mills Ltd インクジェット記録用タックシート
JP4592105B2 (ja) * 2003-08-04 2010-12-01 キヤノン株式会社 インク用被記録媒体及びその製造方法
WO2006132286A1 (fr) * 2005-06-09 2006-12-14 Oji Paper Co., Ltd. Procede de fabrication d'une feuille d'impression jet d'encre

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0246987A1 (fr) * 1986-05-20 1987-11-25 Aussedat-Rey Feuille pour enregistrement par jet d'encre et procédé pour sa préparation

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0246987A1 (fr) * 1986-05-20 1987-11-25 Aussedat-Rey Feuille pour enregistrement par jet d'encre et procédé pour sa préparation

Cited By (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0605840A2 (fr) * 1992-12-25 1994-07-13 Mitsubishi Paper Mills, Ltd. Feuille d'enregistrement à jet d'encre
EP0605840A3 (fr) * 1992-12-25 1994-12-14 Mitsubishi Paper Mills Ltd Feuille d'enregistrement à jet d'encre.
US5472757A (en) * 1992-12-25 1995-12-05 Mitsubishi Paper Mills Limited Ink jet recording sheet
EP0634286A1 (fr) * 1993-07-14 1995-01-18 Asahi Glass Company Ltd. Fluide de revêtement à base de sol d'alumine et support d'impression
US5523149A (en) * 1993-07-14 1996-06-04 Asahi Glass Company Ltd. Alumina sol coated recording sheet
EP0734882A2 (fr) * 1995-03-31 1996-10-02 Nippon Paper Industries Co., Ltd. Papier d'enregistrement
EP0734882A3 (fr) * 1995-03-31 1997-10-08 Jujo Paper Co Ltd Papier d'enregistrement
US5725946A (en) * 1995-03-31 1998-03-10 Nippon Paper Industries, Co., Ltd. Recording paper
CN1087371C (zh) * 1995-03-31 2002-07-10 日本制纸株式会社 记录纸
DE19602793C1 (de) * 1996-01-26 1997-09-25 Schoeller Felix Jun Foto Aufzeichnungsmaterial für das Tintenstrahl-Druckverfahren
EP0888904A1 (fr) * 1997-07-01 1999-01-07 Konica Corporation Méthode pour l'enregistrement par jet d'encre
US6217166B1 (en) 1997-07-01 2001-04-17 Konica Corporation Ink jet recording method
EP1111452A3 (fr) * 1999-12-17 2002-05-08 Eastman Kodak Company Méthode d'obtention d'une couche ayant une viscosité élevée sur un support en mouvement et articles obtenus par cette méthode
EP1111452A2 (fr) * 1999-12-17 2001-06-27 Eastman Kodak Company Méthode d'obtention d'une couche ayant une viscosité élevée sur un support en mouvement et articles obtenus par cette méthode
US6746713B2 (en) 2001-04-19 2004-06-08 Stora Enso North America Corporation Method of making ink jet recording media
EP1318026A3 (fr) * 2001-12-04 2004-10-20 Eastman Kodak Company Elément pour l'enregistrement au jet d'encre et procédé d'impression
US7172793B2 (en) 2002-07-01 2007-02-06 Ilford Imaging Switzerland Gmbh Method for coating a moving web and articles made thereby
EP1378369A1 (fr) * 2002-07-01 2004-01-07 ILFORD Imaging Switzerland GmbH Procédé pour le revêtement d'un support en mouvement et articles préparés par ce procédé
EP1386751A3 (fr) * 2002-07-31 2004-10-20 Eastman Kodak Company Elément pour impression par jet d'encre et procédé d'impression
US6908191B2 (en) * 2002-07-31 2005-06-21 Eastman Kodak Company Ink jet printing method
EP1671805A2 (fr) 2004-12-16 2006-06-21 Agfa-Gevaert Procédé d'impression avec encre durcissable par rayonnement utilisant un liquide pour contrôler la taille des points
US7575314B2 (en) 2004-12-16 2009-08-18 Agfa Graphics, N.V. Dotsize control fluid for radiation curable ink-jet printing process
US8247045B2 (en) 2007-11-08 2012-08-21 Eastman Kodak Company Inkjet recording element
US8247044B2 (en) 2007-11-08 2012-08-21 Eastman Kodak Company Inkjet recording element
US8273435B2 (en) 2009-06-01 2012-09-25 Polymer Ventures, Inc. Polyol coatings, articles, and methods
US8287974B2 (en) 2009-06-01 2012-10-16 Polymer Ventures, Inc. Polyol-based release paper, articles, and methods
EP2420619A1 (fr) * 2010-08-20 2012-02-22 Polymer Ventures, Inc. Revêtements améliorés de polyol, articles et procédés

Also Published As

Publication number Publication date
AU8806091A (en) 1992-07-02
JPH04223190A (ja) 1992-08-13
JPH0737175B2 (ja) 1995-04-26

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