EP0418273A1 - Assouplissant pour textiles. - Google Patents

Assouplissant pour textiles.

Info

Publication number
EP0418273A1
EP0418273A1 EP89906104A EP89906104A EP0418273A1 EP 0418273 A1 EP0418273 A1 EP 0418273A1 EP 89906104 A EP89906104 A EP 89906104A EP 89906104 A EP89906104 A EP 89906104A EP 0418273 A1 EP0418273 A1 EP 0418273A1
Authority
EP
European Patent Office
Prior art keywords
fabric
composition according
fabric softener
quaternary ammonium
ammonium compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP89906104A
Other languages
German (de)
English (en)
Other versions
EP0418273B1 (fr
Inventor
Theodor Voelkel
Rolf Puchta
Eric Sung
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to AT89906104T priority Critical patent/ATE79899T1/de
Publication of EP0418273A1 publication Critical patent/EP0418273A1/fr
Application granted granted Critical
Publication of EP0418273B1 publication Critical patent/EP0418273B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/047—Arrangements specially adapted for dry cleaning or laundry dryer related applications
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C11D1/652—Mixtures of anionic compounds with carboxylic amides or alkylol amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/521—Carboxylic amides (R1-CO-NR2R3), where R1, R2 and R3 are alkyl or alkenyl groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/528—Carboxylic amides (R1-CO-NR2R3), where at least one of the chains R1, R2 or R3 is interrupted by a functional group, e.g. a -NH-, -NR-, -CO-, or -CON- group
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/667—Neutral esters, e.g. sorbitan esters

Definitions

  • the present invention relates to a fabric softening agent for treating textiles in a tumble dryer with a rotating drum.
  • fabric softening agents for use in automatic tumble dryers with a rotating drum have become known.
  • Such fabric softening agents often consist of a more or less absorbent substrate impregnated with fabric softeners and, if appropriate, auxiliaries and additives, which is generally in the form of a sheet.
  • fabric softening agents of this kind are described in DE-A-19 65 470 or in DE-A-30 03 249.
  • the impregnated flat structures are added to the drum of the tumble dryer together with the still moist, freshly washed laundry, where they release a more or less large proportion of their softening active ingredients and auxiliary substances under the conditions of laundry drying and transfer them to the washed textiles through contact with them.
  • a problem with this type of softening of textiles is the often unsatisfactory rate of drug delivery.
  • the reason for this is the fact that the softening agents naturally have an affinity for their substrates as well as for the textiles to which they are to be transferred. Therefore, when using the impregnated substrates, there is a balance between the loading of the substrates with active substances on the one hand and the loading of the washed textiles these active ingredients on the other hand. There has therefore been no shortage of attempts to improve the rate of active substance release by means of suitable additives.
  • Known solutions to this problem are, for example, the application of a separating layer between the substrate and the active substance support or the use of dispersing or emulsifying substances when impregnating the substrates with the active substances.
  • the materials of the separating layer or the dispersants or emulsifiers in turn either have no or only a slight softening effect, as a result of which the absorption capacity of the substrates for the actual softening active ingredients is reduced. Also for economic reasons, the above suggestions are not a satisfactory solution.
  • the fabric softening agents intended for use in the tumble dryer are very popular with consumers, especially in the private household, because of their simple handling, it is still desirable to reduce or eliminate these disadvantages.
  • the object of the present invention is therefore to provide a fabric softening agent for treating textiles in a tumble dryer with a rotating drum, the fabric softening agent having an improved active ingredient release rate compared to the known agents for the same purpose.
  • a fabric softener for treating textiles in a tumble dryer which a) a fabric softener, which is used as an impregnation in combination with b. a substrate is present, and which is characterized in that the fabric softener a) contains a fabric softening agent a1) which is liquid at room temperature in admixture with at least one further constituent a2) which is selected such that the fabric softener a) has a softening point in the range from 35 to 60 ° C, has an unexpectedly high rate of drug delivery.
  • the fabric softening agent al) is a quaternary ammonium compound with two 2-acyloxyalkyl groups.
  • the acyl groups of the quaternary ammonium compounds are derived from saturated or unsaturated carboxylic acids having 10 to 22 carbon atoms, in particular from tallow fatty acid, from oleic acid, from coconut oil fatty acid or from rapeseed oil fatty acid.
  • Typical representatives of this class of compounds are the compounds of the dimethyl-di type known, for example, from DE-A-16 99 058, DE-A-17 94 068, DE-A-19 35 499 and DE-B-24 30 140 - (2-acyloxyalkyl) ammonium methosulfate.
  • the molecule can contain C 6 - to C 4 -alkyl or hydroxyalkyl groups, which can optionally also be alkoxylated.
  • the anion can also be, for example, the chloride, bromide or ethyl sulfate anion or can be derived from phosphonic acid.
  • the acyl groups are bonded to the nitrogen atom via oxyalkyl groups having 2 to 4 carbon atoms. In the case of oxyalkyl groups with 3 or 4 carbon atoms, the carbon chain can be linear or branched. Compounds with 3 carbon atoms in the particularly branched carbon chain are of particular importance. A typical preferred representative of these compounds is dimethyl di (acyloxyisopropyl) ammonium methosulfate. These compounds, known as fabric softeners, are flowable at room temperature. They are therefore unsuitable as the sole component of the impregnation composition a).
  • the constituent being selected in this way is that the blend has a softening point in the range of 35 to 60 ° C.
  • Substances suitable as component a2) are selected from the group of fatty acids, fatty acid esters, fatty acid amides, aminoamides or mixtures thereof.
  • the fatty acid component is derived from saturated or unsaturated carboxylic acids with 8 to 24 carbon atoms.
  • the alcohol or amine component of the fatty acid esters or fatty acid amides has 1 to 8 carbon atoms.
  • Aminoamides are derived from fatty acids or fatty acid derivatives whose fatty acid component also has 8 to 24 carbon atoms, the fatty acid or the fatty acid derivatives having been reacted with polyamines in such a ratio that some of the amino groups are present as amide bonds and some are unchanged amino groups.
  • component B2) is a quaternary ammonium compound which also has a fabric softening effect.
  • fabric softener a] is therefore an active ingredient combination of at least one quaternary ammonium compound with two 2-acyloxyalkyl groups and at least one further quaternary ammonium compound with two C 10 - to C 22 alkyl or alkenyl groups, the ratio of these two quaternary ammonium compounds to one another being selected such that the combination has a softening point in the range from 35 to 60 ° C.
  • the quaternary ammonium compound with two 2-acyloxyalkyl groups and the quaternary ammonium compound with two C 10 to C 22 alkyl or alkenyl groups are present in the combination in a weight ratio of 1:10 to 2: 1. Active ingredient combinations with a softening point of 35 to 60 ° C can be produced within these limits. Since the quaternary ammonium compounds with two C 10 to C 22 alkyl or alkenyl groups are themselves excellent textile detergents, such active substance combinations represent particularly interesting fabric softeners in the sense of the present invention.
  • the weight ratio of fabric softener a) to substrate b) is generally in the range from 10: 1 to 1: 3.
  • fabric softener a may also contain other auxiliaries or additives, for example dispersants or emulsifiers.
  • Addition products of 4 to 40, preferably 4 to 20, moles of ethylene oxide and / or propylene oxide and 1 mole of an aliphatic C 10 to C 20 alcohol or an alkylphenol in which the alkyl radical has 8 to 18 carbon atoms are primarily suitable for this purpose. as well as fatty acids or alkylamines with 10 to 20 carbon atoms.
  • ethoxylation products of the fatty alcohols in particular coconut oil and tallow fatty alcohol, as well as cetyl and oleyl alcohol, and the ethoxylation products of the oxo alcohols and the secondary alcohols of the corresponding chain length are particularly preferred.
  • Further suitable dispersants or emulsifiers are nonionic, water-soluble, 20 to 250 ethylene glycol ether groups and 10 to 100 propylene glycol ether groups containing adducts of ethylene oxide with polypropylene glycol or with alkylenediamine poiypropylene glycol or with alkyl polypropylene glycols with 1 to 10 carbon atoms, in which the polypropylene glycol chain is hydrophobic.
  • the products can additionally contain 0.5 to 5% by weight.
  • -% dispersing and softening polyglycol ethers.
  • Suitable polyglycol ethers are derived from ethylene oxide and have a molecular weight in the range from 200 to 8,000, preferably in the range from 200 to 1,000 and in particular in the range from 400 to 600.
  • additives having a dispersing action are addition products of ethylene oxide and / or propylene oxide Fatty alcohols, fatty amines, fatty acid or sulfonic acid amides, polyethylene glycols or polypropylene glycols, epoxy glycols, alkylene diamine or also aliphatic C 1 - to C 8 -, preferably C 3 - to C 6 -alcohols.
  • I amines are also suitable in the same way Formula R- (C 2 H 4 O) -NR 1 R 2 . In this formula, R means one
  • R 1 and R 2 which can be the same or different, mean -C 2 H 4 OH or their esters with C 10 - to C 20 -monocarboxylic acids or with sulfosuccinic acid or alkali metal salts of these acids.
  • R 1 and R 2 also suitable are the corresponding quaternary compounds of the aforementioned ether amines, in which a further alkyl group with 1 to 18 carbon atoms is attached to the nitrogen atom with the formation of a positive charge, the positive charge being caused by a negative charge, which an Anton, as a rule, the Chloride or methosulfate anion, carries, is balanced.
  • esters of fatty alcohols especially tallow alcohols with optionally hydroxyl-substituted monocarboxylic acids with 1 to 3 carbon atoms.
  • high molecular weight polyglycol ethers whose molecular weight is in the range from about 10,000 to about 80,000 are also suitable in some compositions according to the invention.
  • 2-benzylalkanol polyglycol ethers with 2 to 10 moles of ethylene oxide as additives, especially when the underlying alcohol component is 2-benzyloctanol.
  • Addition products of 2 to 10 moles of ethylene oxide with branched alcohols can in many cases be used successfully as additives.
  • 1, 4-Alkylglycoside and 2, 2-alkylglycosides with alkyl radicals containing 10 to 20 carbon atoms are also suitable additives.
  • Paraffin oil and polyhydric alcohols for example ethyl glycol, propylene glycol, glycerol and their esters with fatty acids, are also suitable.
  • the fabric-washing component a) can additionally contain an inorganic or preferably organic acid, in particular which contain a hydroxycarboxylic acid, for example glycolic acid or in particular citric acid.
  • Antimicrobial agents may also be present in the fabric softener component a). Active ingredients for soil release finishing for textiles can also be present, which improve the ability to remove dirt during washing. These include compounds of the type of polyacrylic polyphenyl alcohols, modified fluorocarbons and hydrophilic polymers. Polyphenylacetates, paraffins or even borax are suitable additives that make ironing the laundry easier. Additives such as talc, layered silicates, finely divided zeolites, aerosil or aluminum oxide occasionally improve the shelf life or make the handling of the products according to the invention more pleasant.
  • the substrate b) is a paper or a woven or non-woven cloth made of natural or synthetic fibers or a foam-like sheet with an adsorption capacity of 1.5 to 25.
  • Suitable fibers for the production of the substrates mentioned are, above all, fibers made of cellulose, polyester, polyolefin, polyalkyl nitrile, polyamide, polyurethane or viscose or mixtures thereof. Natural sponges or synthetic foams, in particular made of polyurethane, are also suitable.
  • the values for the adsorption capacity are determined according to a modified test in (U.S. Federal Specifications UU-T-595 b) with changes as described in the already cited DE-A-19 65 470, new page 14.
  • adsorption capacity there is a large number of fabric-like or fleece-like fabrics which are used for fabric-softening agents according to the invention can. Those fabrics which have an adsorption capacity in the lower to middle range are preferred, that is to say that the adsorption capacity is in the range from approximately 1.5 to 8.
  • An example of a particularly suitable substrate is a non-woven cloth made of polyester fiber. Such flat structures are, for example, commercially available nonwovens with a basis weight of approx. 25 to approx. 50 g / m 2 and have a size of about 0.01 to 0.2 m 2 for an application.
  • the suitable substrates can also have a lower or higher basis weight, for example in the range from about 10 to about 100 g / m 2 .
  • polyester fiber nonwovens are around 4.
  • a suitable nonwoven is a nonwoven made from viscose fibers. It has a weight per unit area of approx. 55 g / m 2 and an adsorption capacity of approx. 3.5.
  • Nonwovens with a fiber mixture of, for example, 40% polyester and 60% viscose are also suitable substrates.
  • Other suitable substrates are, for example, polyurethane foams with an adsorption capacity in the range from 4 to 7.
  • Foam fabrics made of polyethylene or polypropylene are also suitable substrates.
  • the fabric softening composition a) can be applied to the substrate b) in any desired manner, for example by spraying or by soaking the nonwoven, the impregnated substrates then being applied, for example by squeezing in one, to apply a certain amount or to improve the uniformity of the application Roll nip can be made.
  • the non-volatile constituents are melted, applied to the substrate and, if appropriate, volatile constituents are then added, for example
  • Fragrances or volatile solvents that can be added to regulate the consistency.
  • About 30 to about 200 g of fabric softener a) are applied per m 2 of substrate.
  • the fabric softening agents according to the invention have a significantly higher active ingredient release rate when used in a tumble dryer compared to known fabric softening agents. This manifests itself in an improved softness performance of the products according to the invention and in a better utilization of the fabric softening active ingredients used, as is shown in the following examples.
  • a polyester fiber fleece b) with a weight per unit area of 35 g per m 2 was impregnated with fabric changer a) of the following compositions (in% by weight):
  • Dimethyl di (oleoylisopropyl) ammonium methosulfate was used as the liquid plasticizer a1).
  • the melting point of the compositions in 1 to 5 was between 30 and 55 ° C.
  • the substrate was impregnated by impregnating the nonwoven fabric with the mixtures 1 to 5 heated to 65 ° C. and then squeezing them off in a roll nip.
  • a comparative product according to the prior art was produced with dimethyldistearylammonium chloride as fabric softener.
  • the fabric softener application was uniformly 86 g per m 2 of nonwoven fabric.
  • the release rate (in%) of the fabric softener mixtures was determined by weighing the impregnated substrates before and after use. The results of both tests are shown in Table 1.
  • a textile-softening agent for treating textiles in an automatic spin drier consists of a flexible nonwoven impregnated with textile softener containing a textile-softening substance which flows at ambient temperature admixed with at least one other co stituent chosen so that the combination of textile softener and the other constituent has a softening point in the ranks 30 to 60 °
  • Preferred textile-softening substances are quaternary ammonium compounds with two 2-acyloxyalkyl groups.
  • Fabric softening agent for the treatment of textiles in an automatic clothes dryer consisting of a flexible sheet which is impregnated with a fabric softener which contains a fabric softening agent which is flowable at room temperature in admixture with at least one further ingredient which is selected such that the combination of fabric softener and the further constituent has a softening point in the range from 30 to 60 ° C. ha.
  • Preferred fabric-softening active ingredients are quaternary ammonium compounds with two 2-acyloxyalkyl groups.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Un assouplissant pour traiter des textiles dans un sèche-linge automatique est constitué d'une structure en nappe souple imprégnée d'un assouplissant pour textile renfermant une substance assouplissante de textile qui coule à température ambiante, en mélange avec un autre constituant choisi de telle manière que la combinaison de l'assouplissant et de l'autre constituant présente un point de ramollissement dans la plage de 30 à 60 °C. Des substances assouplissantes préférées sont des composés d'ammonium quaternaire à deux groupes 2-acyloxyalkyl.
EP89906104A 1988-05-27 1989-05-18 Assouplissant pour textiles Expired - Lifetime EP0418273B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT89906104T ATE79899T1 (de) 1988-05-27 1989-05-18 Gewebeweichmachungsmittel.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3818013 1988-05-27
DE3818013A DE3818013A1 (de) 1988-05-27 1988-05-27 Gewebeweichmachungsmittel

Publications (2)

Publication Number Publication Date
EP0418273A1 true EP0418273A1 (fr) 1991-03-27
EP0418273B1 EP0418273B1 (fr) 1992-08-26

Family

ID=6355233

Family Applications (2)

Application Number Title Priority Date Filing Date
EP89906104A Expired - Lifetime EP0418273B1 (fr) 1988-05-27 1989-05-18 Assouplissant pour textiles
EP89108905A Withdrawn EP0345495A3 (fr) 1988-05-27 1989-05-18 Agent adoucissant pour tissus

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP89108905A Withdrawn EP0345495A3 (fr) 1988-05-27 1989-05-18 Agent adoucissant pour tissus

Country Status (4)

Country Link
EP (2) EP0418273B1 (fr)
DE (2) DE3818013A1 (fr)
DK (1) DK218790D0 (fr)
WO (1) WO1989011527A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6221363B1 (en) 1991-07-11 2001-04-24 Baxter Aktiengesellschaft Vaccine for the prevention of lyme disease

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5221794A (en) 1990-01-31 1993-06-22 Sherex Chemical Company, Inc. Process and composition for multicomponent one hundred percent solid fabric softeners
US5223628A (en) * 1990-02-02 1993-06-29 Sherex Chemical Company, Inc. Process for making high solids fabric softeners using low amounts of solvents and no side reactions
CA2035238C (fr) * 1990-02-02 2004-09-21 David Edward Whittlinger Procede de fabrication d'assouplisseurs de tissu faisant appel a une faible quantite de solvants et eliminants les reactions secondaires
US5128053A (en) * 1991-02-06 1992-07-07 Sherex Chemical Company, Inc. Composition and process for treating fabrics in clothes dryers
CA2134640C (fr) * 1992-05-12 1998-11-03 Ellen Schmidt Baker Compositions concentrees d'assouplissants pour tissus contenant des assouplissants biodegradables
DE4224067A1 (de) * 1992-07-21 1994-01-27 Henkel Kgaa Tumblerhilfsmittel
EP0656935A1 (fr) * 1992-08-21 1995-06-14 Colgate-Palmolive Company Assouplisseur de tissus pour le cycle de rin age
WO1995004802A1 (fr) * 1993-08-06 1995-02-16 The Procter & Gamble Company Compositions antistatiques et d'adoucissement des tissus activees lors du sechage en machine et contenant des composes biodegradables non satures
US5470492A (en) * 1993-09-10 1995-11-28 The Procter & Gamble Company Dryer-activated fabric conditioning articles with soft polyester substrate
EP0717772A1 (fr) * 1993-09-10 1996-06-26 The Procter & Gamble Company Articles pour le traitement de linge, actives dans le seche-linge et comprenant un substrat en polyester doux au toucher
US5474690A (en) * 1994-11-14 1995-12-12 The Procter & Gamble Company Concentrated biodegradable quaternary ammonium fabric softener compositions containing intermediate iodine value fatty acid chains
US6906025B2 (en) * 1996-01-05 2005-06-14 Stepan Company Articles and methods for treating fabrics based on acyloxyalkyl quaternary ammonium compositions
AU1693197A (en) * 1996-01-05 1997-08-01 Stepan Company Articles and methods for treating fabrics based on acyloxyalkyl quaternary ammonium compositions
US5883069A (en) * 1996-05-02 1999-03-16 The Procter & Gamble Company Dryer-activated fabric conditioning articles with improved substrate
GB0207483D0 (en) 2002-03-28 2002-05-08 Unilever Plc Fabric conditioning compositions
GB2419360A (en) * 2004-10-20 2006-04-26 Reckitt Benckiser Fabric softener comprising a sublimable carrier

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3686025A (en) * 1968-12-30 1972-08-22 Procter & Gamble Textile softening agents impregnated into absorbent materials
DE3003249A1 (de) * 1980-01-30 1981-08-06 Henkel KGaA, 4000 Düsseldorf Mittel zum nachbehandeln gewaschener waesche in einem waeschetrockner
DE3608093A1 (de) * 1986-03-12 1987-09-17 Henkel Kgaa Konfektioniertes textilweichmacher-konzentrat

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6221363B1 (en) 1991-07-11 2001-04-24 Baxter Aktiengesellschaft Vaccine for the prevention of lyme disease

Also Published As

Publication number Publication date
EP0418273B1 (fr) 1992-08-26
DK218790A (da) 1990-09-12
EP0345495A3 (fr) 1990-01-31
WO1989011527A3 (fr) 1989-12-28
DE58902159D1 (de) 1992-10-01
DK218790D0 (da) 1990-09-12
WO1989011527A2 (fr) 1989-11-30
EP0345495A2 (fr) 1989-12-13
DE3818013A1 (de) 1989-11-30

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