EP1972717B1 - Utilisation d'un agent pour améliorer l'absorption d'eau de textiles - Google Patents

Utilisation d'un agent pour améliorer l'absorption d'eau de textiles Download PDF

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Publication number
EP1972717B1
EP1972717B1 EP07005749A EP07005749A EP1972717B1 EP 1972717 B1 EP1972717 B1 EP 1972717B1 EP 07005749 A EP07005749 A EP 07005749A EP 07005749 A EP07005749 A EP 07005749A EP 1972717 B1 EP1972717 B1 EP 1972717B1
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EP
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Prior art keywords
weight
quantities
textiles
acid
water
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Expired - Fee Related
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EP07005749A
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German (de)
English (en)
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EP1972717A1 (fr
Inventor
Erik Paff
Manfred Dr. Weuthen
Rolf Dr. Wachter
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Cognis IP Management GmbH
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Cognis IP Management GmbH
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Priority to ES07005749T priority Critical patent/ES2375742T3/es
Priority to EP07005749A priority patent/EP1972717B1/fr
Priority to US12/050,380 priority patent/US20080230736A1/en
Publication of EP1972717A1 publication Critical patent/EP1972717A1/fr
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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/047—Arrangements specially adapted for dry cleaning or laundry dryer related applications
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D06M13/148—Polyalcohols, e.g. glycerol or glucose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • D06M13/217—Polyoxyalkyleneglycol ethers with a terminal carboxyl group; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/667—Neutral esters, e.g. sorbitan esters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Definitions

  • the present invention relates to the use of certain aqueous agents for improving the water absorption of textiles.
  • the sensory properties of textiles resulting from conventional washing and cleaning operations are an important criterion for the consumer to judge.
  • This is not only about the softness, but there are also other criteria demanded by consumers.
  • This includes the smoothness, the fact that residues remain on the fiber, the grip, the elasticity of the material, its flexibility but also, for example, the noise that occurs when crumpling or folding the laundry.
  • a particular issue is the moisture absorption of the fabric, as e.g. When sweating large amounts of water are released, which, in order to convey a pleasant feel of the textiles, must be quickly dissipated.
  • aqueous textile finishing agents which contain a lipophilic wax matrix, wherein the waxes have a melting point in the range of 35-60 ° C in combination with emulsifiers and so-called Kristalllsationsregulatoren.
  • aqueous textile finishing agents which contain a lipophilic wax matrix, wherein the waxes have a melting point in the range of 35-60 ° C in combination with emulsifiers and so-called Kristalllsationsregulatoren.
  • liquid, nitrogen-free fabric softeners known in addition to water or anionic surfactants and fatty substances selected from the group of fatty alcohols and the mono- or diesters of fatty acids with saurithol, trimethylolpropane, neopentyl glycol, ethylene glycol, polyethylene glycols, glycerols and
  • Plasticizer formulations can no longer meet the requirements of the modern consumer for the comfort of washed textiles.
  • the present invention is therefore based on the problem of providing a method which significantly enhances the sensory properties of fabrics after washing can improve. It has now been found that certain aqueous formulated agents are suitable to fulfill this task.
  • the above-described aqueous agents are applied to textiles.
  • Suitable methods here can be, in particular, the spraying of the aqueous compositions with suitable technical aids.
  • it is quite possible to apply the aqueous agents differently to the textiles for example in the sense of a laundry after-treatment, possibly at elevated temperature, by bringing the items of laundry into contact with the aqueous agents for a suitable period of time in the context of the present technical teaching.
  • This can also be achieved, for example, by using a correspondingly equipped so-called "dryer sheet", which is preferably brought into contact with the laundry to be treated in the tumble dryer, and its active ingredients are thus transferred to the textile.
  • the finishing of the textiles is preferably temporary, and thus distinguishable from the permeant equipment used in textile manufacturing.
  • the agents described are applied to the textiles in the form of encapsulated active ingredients during or after the wash cycle.
  • a preferred embodiment provides that the aqueous agents are applied to the items of laundry or textiles by spray application in the sense of the present technical teaching.
  • Such agents are usually offered as "care sprays" to the consumer, and serve, for example, a textile subsequently provided with care additives.
  • Such additives For example, they can be aids that facilitate ironing but also fragrances that give a fresh impression.
  • Spray products may preferably be used in the present process.
  • Particularly preferred is an additive in the form of an ironing aid that the consumer applied before or after ironing the textiles.
  • the agents in the sense of the described technical teaching are formulated aqueous and preferably contain between 50 to 99 wt .-% water, each based on the total amount of the composition. It may be advantageous to use only 75 to 99 wt .-% water or in particular 85 to 99 wt .-% water.
  • the aqueous agents used necessarily contain two components (a) and (b) side by side.
  • component (b) are mixtures of esters based on diols or polyols with selected fatty acids.
  • APG alkyl (oligo) glycosides
  • component (b) are mixtures of esters based on diols or polyols with selected fatty acids.
  • Alkyl and / or alkenyl oligoglycosides are known nonionic surfactants which follow formula (I), R 1 O- [G] p (I) in which R 1 is an alkyl and / or alkenyl radical having 4 to 22 carbon atoms, G is a sugar radical having 5 or 6 carbon atoms and p is a number from 1 to 10. They can be obtained by the relevant methods of preparative organic chemistry.
  • the alkyl and / or alkenyl oligoglycosides can be derived from aldoses or ketoses having 5 or 6 carbon atoms, preferably glucose.
  • the preferred alkyl and / or alkenyl oligoglycosides are thus alkyl and / or alkenyl oligoglucosides.
  • alkyl and / or alkenyl oligoglycosides having an average degree of oligomerization p of from 1.1 to 3.0. From an application point of view, those alkyl and / or alkenyl oligoglycosides whose degree of oligomerization is less than 1.7 and in particular between 1.2 and 1.4 are preferred.
  • the alkyl or alkenyl radical R 1 may differ from primary Derive alcohols having 4 to 11, preferably 8 to 10 carbon atoms.
  • Typical examples are butanol, caproic alcohol, caprylic alcohol, capric alcohol and undecyl alcohol and technical mixtures thereof, as obtained, for example, in the hydrogenation of technical fatty acid methyl esters or in the hydrogenation of aldehydes from Roelen's oxosynthesis.
  • the alkyl or alkenyl radical R 1 can also be derived from primary alcohols having 12 to 22, preferably 12 to 14 carbon atoms. Typical examples are lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol, brassidyl alcohol, and technical mixtures thereof which can be obtained as described above. Preference is given to alkyl oligoglucosides based on hydrogenated C 12/14 coconut alcohol having a DP of 1 to 3.
  • the component (b) consists in turn of several different components, namely esters of diols, preferably glycol or its oligo- or polymers, and also esters of polyols, preferably esters of glycerol, these glycerol esters preferably in the form of their Partialester, so as a mono- and / or diester use find.
  • Suitable diol esters for the purposes of the present invention are in particular the esters of diols, preferably glycol and its oligomers or polymers.
  • Suitable oligomers are polyethylene glycols and, as polymers, ethylene glycols having molecular weights of 100 and greater, preferably 100 to 1,000 , These are esterified in a conventional manner with fatty acids.
  • fatty acids saturated fatty acids having 16 to 22 carbon atoms are used, with stearic acid being particularly preferred.
  • a particularly preferred diester component is a glycol stearic acid diester.
  • Fatty acid partial glycerides ie monoglycerides, diglycerides and their technical mixtures may contain small quantities of di- and triglycerides as a result of the preparation.
  • low Amounts means that preferably only 1 to at most 10% by weight, in particular up to a maximum of 5% by weight, based on the total amount of glycerides, represent triglycerides.
  • such glycerides ie, if necessary, mixtures of di- and monoglycerides
  • the partial glycerides preferably follow the formula (II), in the R 2 CO for a linear or branched, saturated and / or unsaturated acyl radical having 6 to 22, preferably 12 to 18 carbon atoms, R 3 and R 4 independently of one another R 2 CO or OH and the sum (m + n + p ) is 0 or numbers from 1 to 100, preferably 5 to 25, with the proviso that at least one of the two radicals R 3 and R 4 is OH.
  • Typical examples are mono- and / or diglycerides based on caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachidic acid, Gadoleic acid, behenic acid and erucic acid and their technical mixtures.
  • longer-chain partial glycerides for example based on oleic acid or stearic acid, are used in particular mixtures of glycerides based on saturated and unsaturated fatty acids.
  • the partial esters as described above are preferably used as a mixture of mono- and diesters of glycerol with saturated and unsaturated fatty acids having in each case 16 to 22 C atoms.
  • saturated fatty acid stearic acid is again of particular importance, whereas oleic acid is to be selected as the unsaturated fatty acid.
  • those agents are preferred which contain side by side in the mixture of component b) glycerol partial esters based on stearic acid and oleic acid.
  • the components a) and b) of the agents used are preferably in a weight ratio of 1: 3 to 3: 1, preferably 1: 3 to 1: 1 and in particular of 1: 2 to 1: 1 next to each other.
  • the weight of component b) refers to all ingredients described above, ie both the diesters of the diols and the partial esters based on the polyols, preferably of glycerol. It is further preferred to use those agents in which the components a) and b) together in an amount of 0.1 to 15 wt .-% and in particular in amounts of 0.5 to 10 wt .-%, but preferably 1 to 5 wt .-% are included.
  • the compounds according to the description of component b) are preferably water-insoluble, which means that they can be dissolved at 21 ° C. to less than 10, in particular less than 5,% by weight in water.
  • the agents used according to the invention may, in addition to water and the obligatory component (a) and (b) optionally contain further auxiliaries or additives.
  • auxiliaries or additives in particular perfumes, dyes, other surfactants, non-aqueous solvents and thickeners can be used.
  • a thickener is used as an additive, ie a substance which increases the viscosity of the agent.
  • Polymeric thickeners are typically selected from the groups of polyvinyl alcohols, polyacrylic acid and polymethacrylic acids and their salts, the polyacrylamides, polyvinylpyrrolidones, polyethylene glycols, styrene-maleic anhydride copolymers and salts thereof.
  • polymers with thickening properties in this case preferably those based on acrylate and (meth) acrylate, are preferred. Both homo- and copolymers or terpolymers can be used.
  • thickeners based on cellulose or derivatives thereof with success within the meaning of the present technical teaching. Examples of such thickeners are hydroxyethylcellulose, carboxymethylcellulose, hydroxypropylmethylcellulose, hydroxypropylcellulose or ethylhydroxyethylcellulose.
  • polyethylene glycols preferably those having molecular weights of 100 or greater, in particular having a molecular weight of from 100 to 500.
  • Component c) is used in the compositions according to the invention in amounts of preferably from 1 to 25% by weight, preferably from 2 to 20% by weight and particularly preferably from 5 to 18% by weight. It is at this point, however, again It has been pointed out that component c) is optional and therefore possibly completely dispensable.
  • agents which do not contain any additional cationic or other plasticizing substances, it being possible in exceptional cases to use such compounds. In such cases, textile softeners of the type of quaternized ammonium compounds and in particular of the so-called ester quats are particularly preferred.
  • nonionic anionic amphoteric or cationic surfactants can be used, with the emphasis on the co-use of other conventional nonionic surfactants such as fatty alcohol or Fettklarealkoxylaten and / or whose derivatives are located.
  • textiles are understood to mean all textile fabrics which are usually processed into linen. However, those fabrics and textiles that contain cotton or consist of cotton are particularly preferred.
  • V1 represents a comparison means that has been formulated without the additive essential to the invention - the means E1 to E3 relate to the teaching of the present invention.
  • Table 1 ⁇ / u> Ingredients in% by weight V1 E1 E2 E3 Plantatex ® HCC - 5 5 5 5 glycerin 17 17 10 - Cosmedia ® HC 40 - - 0.5 - PEG 200 - - - 20 Phenonip ® 0.4 0.4 0.4 0.4 0.4 0.4 Water that. ad 100 ad 100 ad 100 ad 100 PH value - 3.0 3.0 3.0
  • the means V1 and E1 to E3 were each subjected to a sensory test. The experiment took place in a room with approx. 40% humidity and 22 ° C temperature. 11 subjects were available for the test. Each subject was given 2 new test fabrics each for direct comparison. The specified test criteria (eg slip, softness, etc.) were queried one after the other. The subjects had tested in pairs a treated against an untreated comparison tissue. In detail, the criteria were gloss, smoothness, residue / film formation, grip, elasticity, flexibility, comfort, softness, care, volume (when the lumps of the lumps) and Overall acceptance checked. The statements were made during the entire sensory survey. The assessments were entered in an online registration program and evaluated.
  • the specified test criteria eg slip, softness, etc.
  • test fabrics standard cotton WFK 10 A in 20x30 cm, Wfk GmbH was used. To remove any applied pretreatments, all lobules were washed at 95 ° C with 0.075 kg Persil Megaperls TM 3 times with city water and then 2x at 95 ° C. (Miele Softtronic W467, 1600 rpm). The means V1, E1 to E3 were evenly sprayed with an airbrush gun at a distance of 20 cm. A total of 4 g per textile were applied. All test fabrics were treated with this apparatus according to the same procedure.
  • the treated lobes E1 to E3 were found to be better than the untreated standard in all measured criteria. Significant differences were found in the criteria of elasticity, pliability, comfort, care and softness.
  • the aqueous medium each contained 2 wt .-% of a conventional quaternary fabric softener (Dehyquart ® AU46, Fa. Cognis) (V2), and, in addition as an example of an inventive agent even 5 wt .-% Plantatex ® HCC (E4). All agent further containing as a preservative 0.4 wt .-% Phenonip ®. Subsequently, the wetting time of the cotton was measured with water.
  • a test strip of 1.5 x 16 cm was cut out and placed on a measuring table. Thereafter, 12 .mu.l distilled water was applied to the tissue from a metering device (distance about 0.5 cm). The behavior of the water droplet was recorded by means of a high speed camera and the time to complete absorption was measured. The untreated tissue absorbed the tropic in less than 1 second. The agent V2 showed a wetting time of 23 seconds that treated according to the invention Medium E4 but only 8 seconds. It was found that the water absorption on cotton could be significantly improved by the process according to the invention
  • the same measuring method was used to test the effect of the inventive method on wool and silk.
  • the test fabric used was wool (Wfk 60A) or silk (Wfk 70A).
  • Untreated wool gave an absorption time of over 33 seconds, untreated silk 22 seconds.
  • wool treated with an agent according to the invention (composed analogously to E1 but containing 3, 5 or 10% by weight of Plantatex® HCC) shows absorption times of 6, 3 and 2 seconds.
  • an absorption time of 3 seconds was measured when treated with an aqueous agent composed as E1 but containing 10% by weight of Plantatex® HCC.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Claims (10)

  1. Utilisation d'un agent aqueux qui, outre de l'eau, au moins contient
    (a) des alkyl(oligo)glycosides conjointement avec
    (b) un mélange de mono- et diesters d'acides gras saturés et insaturés ayant de 16 à 22 atomes de carbone avec des diols et des polyols,
    et en option
    (c) d'autres additifs et adjuvants,
    pour l'absorption d'eau par des textiles.
  2. Utilisation selon la revendication 1, caractérisée en ce que comme composant (a) on choisit des composés de formule générale R1O- [G]p, dans laquelle R1 représente un radical alkyle et/ou alcényle ayant de 4 à 22 atomes de carbone, G représente un radical glucidique ayant 5 ou 6 atomes de carbone et p représente des nombres valant de 1 à 10.
  3. Utilisation selon au moins l'une des revendications 1 ou 2, caractérisée en ce que le composant (b) contient des diesters d'acides gras saturés ayant de 16 à 22 atomes de carbone, de préférence de l'acide stéarique, avec le glycol.
  4. Utilisation selon au moins l'une des revendications 1 à 3, caractérisée en ce que le mélange (b) contient conjointement des monoesters d'acides gras saturés et insaturés ayant de 16 à 22 atomes de carbone, choisis de préférence parmi les acides stéariques et l'acide oléique avec le glycérol.
  5. Utilisation selon au moins l'une des revendications 1 à 4, caractérisée en ce que comme additifs et adjuvants on choisit des diols et/ou des polyols, de préférence le glycérol, le glycol et/ou le polyéthylèneglycol.
  6. Utilisation selon au moins l'une des revendications 1 à 5, caractérisée en ce que comme additifs et adjuvants sont contenus des polymères, de préférence ceux à base d'acides acryliques et/ou méthacryliques.
  7. Utilisation selon au moins l'une des revendications 1 à 6, caractérisée en ce que les agents contiennent de l'eau en quantités de 50 à 99 % en poids, de préférence de 75 à 99 % en poids et en particulier de 85 à 99 % en poids.
  8. Utilisation selon au moins l'une des revendications 1 à 7, caractérisée en ce que les agents contiennent les composants (a) et (b) ensemble en une quantité de 0,1 à 15 % en poids, en particulier en quantités de 0,5 à 10 % en poids et de préférence de 1,0 à 5,0 % en poids.
  9. Utilisation selon au moins l'une des revendications 1 à 8, caractérisée en ce que les composants (a) et (b) sont présents conjointement en un rapport pondéral de 1 : 3 à 3 : 1, de préférence de 1 : 3 à 1 : 1 et en particulier de 1 : 2 à 1 : 1.
  10. Utilisation selon au moins l'une des revendications 1 à 9, caractérisée en ce que le composant (c) est contenu en quantités de 1 à 25 % en poids, de préférence de 2 à 20 % en poids et en particulier de 5 à 18 % en poids.
EP07005749A 2007-03-21 2007-03-21 Utilisation d'un agent pour améliorer l'absorption d'eau de textiles Expired - Fee Related EP1972717B1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
ES07005749T ES2375742T3 (es) 2007-03-21 2007-03-21 Empleo de un agente para la mejora de la absorción de agua de materiales textiles.
EP07005749A EP1972717B1 (fr) 2007-03-21 2007-03-21 Utilisation d'un agent pour améliorer l'absorption d'eau de textiles
US12/050,380 US20080230736A1 (en) 2007-03-21 2008-03-18 Process for improving the sensory properties of fabrics

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP07005749A EP1972717B1 (fr) 2007-03-21 2007-03-21 Utilisation d'un agent pour améliorer l'absorption d'eau de textiles

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EP1972717A1 EP1972717A1 (fr) 2008-09-24
EP1972717B1 true EP1972717B1 (fr) 2011-10-19

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US (1) US20080230736A1 (fr)
EP (1) EP1972717B1 (fr)
ES (1) ES2375742T3 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2267216A1 (fr) 2009-06-27 2010-12-29 Cognis IP Management GmbH Utilisation de dispersions de résine aqueuse destinée à l'amélioration des caractéristiques mécaniques de fibres textiles
DE102012220466A1 (de) * 2012-11-09 2014-05-15 Henkel Ag & Co. Kgaa Textilpflegemittel
JP6322040B2 (ja) * 2013-04-30 2018-05-09 三洋化成工業株式会社 透水性付与剤

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19732073C1 (de) * 1997-07-25 1998-08-20 Henkel Kgaa Flüssiger stickstofffreier Textilweichmacher
US20030224960A1 (en) * 1998-09-30 2003-12-04 The Procter & Gamble Co. Liquid bleaching compositions packaged in spray-type dispenser and a process for pretreating fabrics therewith
CA2442753A1 (fr) * 2001-05-04 2002-11-14 The Procter & Gamble Company Agents adoucissants s'utilisant dans un seche-linge et procede associe
DE10301575A1 (de) * 2003-01-16 2004-07-29 Henkel Kgaa Textilschonendes Textilpflegemittel
DE10305552A1 (de) * 2003-02-10 2004-08-19 Cognis Deutschland Gmbh & Co. Kg Textilausrüstungsmittel

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EP1972717A1 (fr) 2008-09-24
US20080230736A1 (en) 2008-09-25
ES2375742T3 (es) 2012-03-05

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