EP1002033B1 - Dispersion de faible viscosite destinee au traitement du papier et du textile - Google Patents

Dispersion de faible viscosite destinee au traitement du papier et du textile Download PDF

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Publication number
EP1002033B1
EP1002033B1 EP98941384A EP98941384A EP1002033B1 EP 1002033 B1 EP1002033 B1 EP 1002033B1 EP 98941384 A EP98941384 A EP 98941384A EP 98941384 A EP98941384 A EP 98941384A EP 1002033 B1 EP1002033 B1 EP 1002033B1
Authority
EP
European Patent Office
Prior art keywords
dispersion
dispersions
weight
carbon atoms
paper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP98941384A
Other languages
German (de)
English (en)
Other versions
EP1002033A1 (fr
Inventor
Ansgar Behler
Bernd Wahle
Ludwig BÖNNIGER
Yvonne Reichert
Almud Folge
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Personal Care and Nutrition GmbH
Original Assignee
Cognis Deutschland GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cognis Deutschland GmbH and Co KG filed Critical Cognis Deutschland GmbH and Co KG
Publication of EP1002033A1 publication Critical patent/EP1002033A1/fr
Application granted granted Critical
Publication of EP1002033B1 publication Critical patent/EP1002033B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D06M13/148—Polyalcohols, e.g. glycerol or glucose
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C11D3/2044—Dihydric alcohols linear
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D06M13/17—Polyoxyalkyleneglycol ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2243—Mono-, di-, or triglycerides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/22—Agents rendering paper porous, absorbent or bulky
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/667—Neutral esters, e.g. sorbitan esters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Definitions

  • the dispersions according to the invention contain a system of cationic and nonionic emulsifiers.
  • Particularly suitable nonionic emulsifiers are fatty acids and fatty alcohols or their derivatives, in particular their reaction products with alkoxides such as ethylene oxide, propylene oxide and / or butylene oxide.
  • Cationic emulsifiers are preferably compounds with at least one cationically charged nitrogen atom.
  • the raw dispersion is first at low pressures, ie in the range from 10 to 50 bar and then at higher pressures, above 50 bar. homogenized. It may be advantageous to homogenize the dispersions several times at different pressures. It is further preferred to carry out the homogenization at temperatures between 20 and 100 ° C., preferably between 25 and 70 ° C. Depending on the auxiliary and Additives may therefore also be preferred. add these to the dispersions only after homogenization.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paper (AREA)

Claims (14)

  1. Dispersion aqueuse, concentrée, peu visqueuse pour l'apprêtage assouplissant de textiles ou de papiers, qui renferme
    a) un composant d'assouplissant non ionique qui est choisi parmi les mono- et les diesters du glycérol avec des acides gras en C8-C22 et les mélanges de ceux-ci,
    b) un composé polyol,
    c) des agents émulsionnants cationiques et non ioniques,
    d) de 70 à 90 % en poids d'eau et le cas échéant d'autres adjuvants et additifs, avec un rapport pondéral des composants a) et b) compris entre 2,5 : 1 et 1 : 2,5,
    caractérisée en ce que
    les agents émulsionnants cationiques sont présents en quantités comprises entre 0,5 et 3,0 % en poids.
  2. Dispersion selon la revendication 1,
    caractérisée en ce que
    les dispersions possèdent une viscosité selon Brookfield mesurée à 20°C avec une tige (1) à 20 t/min, comprise entre 1 et 100 mPas et de préférence entre 1 et 50 mPas.
  3. Dispersion selon l'une des revendications 1 ou 2,
    caractérisée en ce que
    le composé polyol est choisi parmi le glycérol, le diéthylèneglycol, le polyéthylèneglycol et le 1,2-propylèneglycol et des mélanges de ceux-ci.
  4. Dispersion selon l'une des revendications 1 à 3,
    caractérisée en ce que
    comme agents émulsionnants cationiques sont des composés d'ammonium quaternaires de formule (I) ou (II) dans laquelle R représente un reste alkyle acyclique ayant de 12 à 24 atomes de carbone, R1 représente un reste alkyle saturé en C1 à C4 ou un reste hydroxyalkyle, R2 est identique soit à R soit à R1 , et COR3 représente un reste acyle aliphatique ayant de 12 à 22 atomes de carbone comportant 0, 1, 2 ou 3 double-liaisons, ainsi que R4 est de l'hydrogène ou signifie OH, avec n valant 1, 2 ou 3 et X est un ion soit halogénure, soit méthosulfate ou métaphosphate.
  5. Dispersion selon l'une des revendications 1 à 4,
    caractérisée en ce que
    les agents émulsionnants non ioniques sont des acides gras alkoxylés ayant de 8 à 22 atomes de carbone, des esters d'acide gras alkoxylés à base d'acides gras ayant de 8 à 22 atomes de carbone avec des alcools ayant de 1 à 10 atomes de carbone et/ou des alcools gras alkoxylés ayant de 8 à 22 atomes de carbone, les composés alkoxylés possédant des valeurs de HLB comprises entre 3 et 20.
  6. Dispersion selon l'une quelconque des revendications 1 à 5,
    caractérisée en ce que
    le composant d'assouplissement a) est présent en quantités comprises entre 1 et 14 % en poids et de préférence en quantités comprises entre 5 et 10 %en poids.
  7. Dispersion selon l'une des revendications 1 à 6,
    caractérisée en ce que
    l'agent émulsionnant non ionique est présent en quantités allant de 0,1 à 3,0 % en poids.
  8. Dispersion selon l'une des revendications 1 à 7,
    caractérisée en ce que
    le composant b) est un mélange à base de glycérol et de polyéthylèneglycol .
  9. Dispersion selon la revendication 8,
    caractérisée en ce que
    le rapport pondéral entre le gycérol et le polyéthylèneglycol est compris entre 10:1 1 et 6:1.
  10. Procédé de préparation de dispersions conformes à la revendication 1,
    caractérisé en ce que
    les composants a à c) et les adjuvants éventuellement présents sont dispersés dans l'eau , et on homogénéise cette dispersion brute ensuite avec un homogénéiseur sous haute pression à des pressions comprises entre 10 et 600 bars.
  11. Procédé selon la revendication 10,
    caractérisé en ce qu'
    on homogénéise la dispersion brute à des pressions entre 25 et 250 bars.
  12. Utilisation des dispersions conformes à la revendication 1,
    en vue du-raffinage assouplissant du papier.
  13. Utilisation des dispersions conformes à la revendication 1,
    en vue de l'apprêtage assouplissant d'articles textiles en morceaux.
  14. Utilisation des dispersions conformes à la revendication 1,
    en tant que produit de rinçage assouplissant.
EP98941384A 1997-07-28 1998-07-20 Dispersion de faible viscosite destinee au traitement du papier et du textile Expired - Lifetime EP1002033B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19732396A DE19732396A1 (de) 1997-07-28 1997-07-28 Niedrigviskose Dispersion zur Papier- und Textilbehandlung
DE19732396 1997-07-28
PCT/EP1998/004534 WO1999005246A1 (fr) 1997-07-28 1998-07-20 Dispersion de faible viscosite destinee au traitement du papier et du textile

Publications (2)

Publication Number Publication Date
EP1002033A1 EP1002033A1 (fr) 2000-05-24
EP1002033B1 true EP1002033B1 (fr) 2004-03-31

Family

ID=7837108

Family Applications (1)

Application Number Title Priority Date Filing Date
EP98941384A Expired - Lifetime EP1002033B1 (fr) 1997-07-28 1998-07-20 Dispersion de faible viscosite destinee au traitement du papier et du textile

Country Status (5)

Country Link
EP (1) EP1002033B1 (fr)
DE (2) DE19732396A1 (fr)
ES (1) ES2218847T3 (fr)
PT (1) PT1002033E (fr)
WO (1) WO1999005246A1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19859294A1 (de) * 1998-12-22 2000-06-29 Bayer Ag Textilbehandlungsmittel, Verfahren zu deren Herstellung sowie deren Verwendung
EP1171663A1 (fr) 1999-03-29 2002-01-16 Bayer Aktiengesellschaft Agents de traitement pour textiles, procede de preparation desdits agents et leur utilisation
EP1264631A1 (fr) * 2001-06-08 2002-12-11 Cognis Iberia, S.L. Emulsionnants polymères
AU2009319793B2 (en) * 2008-11-26 2012-08-16 Colgate-Palmolive Company Fabric softening compositions and methods
AR084057A1 (es) * 2010-12-01 2013-04-17 Procter & Gamble Composiciones para el cuidado de telas
US8603960B2 (en) 2010-12-01 2013-12-10 The Procter & Gamble Company Fabric care composition

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2540901B1 (fr) * 1983-02-14 1986-08-29 Elf Aquitaine Compositions concentrees d'adoucissants textiles
DE3501521A1 (de) * 1985-01-18 1986-07-24 Henkel KGaA, 4000 Düsseldorf Waessriges konzentriertes textilweichmachungsmittel
US5116520A (en) * 1989-09-06 1992-05-26 The Procter & Gamble Co. Fabric softening and anti-static compositions containing a quaternized di-substituted imidazoline ester fabric softening compound with a nonionic fabric softening compound
US5223096A (en) * 1991-11-01 1993-06-29 Procter & Gamble Company Soft absorbent tissue paper with high permanent wet strength
US5385642A (en) * 1993-05-13 1995-01-31 The Procter & Gamble Company Process for treating tissue paper with tri-component biodegradable softener composition
DE4420188A1 (de) * 1994-06-09 1995-12-14 Hoechst Ag Wäscheweichspülmittelkonzentrate

Also Published As

Publication number Publication date
WO1999005246A1 (fr) 1999-02-04
EP1002033A1 (fr) 2000-05-24
DE19732396A1 (de) 1999-02-04
DE59811110D1 (de) 2004-05-06
ES2218847T3 (es) 2004-11-16
PT1002033E (pt) 2004-08-31

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