EP0688356B1 - Compositions aqueuses d'adoucissants textiles - Google Patents

Compositions aqueuses d'adoucissants textiles Download PDF

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Publication number
EP0688356B1
EP0688356B1 EP94909087A EP94909087A EP0688356B1 EP 0688356 B1 EP0688356 B1 EP 0688356B1 EP 94909087 A EP94909087 A EP 94909087A EP 94909087 A EP94909087 A EP 94909087A EP 0688356 B1 EP0688356 B1 EP 0688356B1
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EP
European Patent Office
Prior art keywords
alkyl
alkenyl
weight
carbon atoms
sulfate salt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP94909087A
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German (de)
English (en)
Other versions
EP0688356A1 (fr
Inventor
Rolf Puchta
Fred Schambil
Theodor Völkel
Anneliese Wilsch-Irrgang
Miguel Osset Hernandez
Xavier Closa Cruxens
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
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Henkel AG and Co KGaA
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Publication of EP0688356A1 publication Critical patent/EP0688356A1/fr
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Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D06M13/17—Polyoxyalkyleneglycol ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2065—Polyhydric alcohols
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D06M13/148—Polyalcohols, e.g. glycerol or glucose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/262—Sulfated compounds thiosulfates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C11D3/2044—Dihydric alcohols linear
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention a pour objet des compositions aqueuses d'adoucissants textiles renfermant 1 à 40 % en poids d'un adoucissant cationique dispersé, du type des composés à base d'ammonium quaternaire, et au moins deux restes de matières grasses, compositions dont la viscosité est augmentée par addition de 0,1 à 5 % en poids de sels d'alkylsulfates en C12-C22 ou d'alcénylsulfates ou de sels d'estersulfates. De préférence, on ajoute, en plus, un diol, polyol ou polyalkylèneglycol aliphatique, soluble dans l'eau.

Claims (4)

  1. Compositions aqueuses d'adoucissants textiles qui contiennent :
    (A) 1-40 % en poids d'un adoucissant cationique dispersé du type des composés d'ammonium quaternaire avec au moins deux groupes alkyles, alcényles, acyloxyalkyles ou acylamidoalkyles de 12-22 atomes de C dans le groupe alkyle, alcényle ou acyle,
    caractérisées en ce que
    pour augmenter la viscosité,
    (B) sont inclus 0,1-5 % en poids d'un sel de sulfate d'alkyle ou d'alcényle ou d'un sel d' éthersulfate d'alcényle ayant 12-22 atomes de C dans le groupe alkyle ou alcényle.
    dans un rapport pondéral de l'adoucissant cationique (A) au sel de sulfate d'alkyle ou d'alcényle ou au sel d'éthersulfate d'alkyle ou d'alcényle (B) doit être supérieur à (A:B) = 5:1.
  2. Compositions aqueuses d'adoucissants textiles,
    caractérisées en ce qu'
    en plus est présent,
    (C) 0,1-1% en poids d'un diol aliphatique ou d'un polyol avec 2-6 atomes de C et 2-6 groupes hydroxydes ou un polyalkylèneglycol hydrosoluble.
  3. Compositions aqueuses d'adoucissants textiles selon la revendication 1 ou 2,
    caractérisées en ce que
    les composés d'ammonium quaternaire répondent à la formule I :
    Figure imgb0005
     où en moyenne 2 à 3 des groupes R1 à R4 correspondent à la formule R5CO(OCnH2n)x- où R5CO est un groupe acyle de 12-22 atomes de C, n = 2 ou 3 et x = 1 à 10 et en outre existe un groupe alkyle de 1-4 atomes de C et/ou un groupe hydroxy(alcoxy)alkyle de formule H-(OCnH2n)x-, ou n = 2 ou 3 et x = 1 à 13 et A(-) est un anion chlorure ou CH3OSO3 (-).
  4. Procédé pour augmenter la viscosité d'une composition aqueuse d'adoucissants textiles qui contient sous forme dispersée :
    (A) 1-40 % en poids d'un composé d'ammonium quaternaire avec au moins deux groupes alkyles, alcényles, acyloxyalkyles ou acylamidoalkyles de 12-22 atomes de C dans le groupe alkyle, alcényle ou acyle,
    caractérisé en ce qu'on converti
    (B) 0,15 % en poids d'un sel de sulfate d'alkyle ou d'alcényle ou d'un sel d'éthersulfate d'alcényle ayant 12-22 atomes de C dans le groupe alkyle ou alcényle et le cas échéant (C) un diol ou un polyol avec 2-6 atomes de C et 2-6 groupes hydroxydes ou un polyalkylèneglycol en une quantité de 0,1-1% en poids par rapport à la totalité de la composition, en présence du composant (A) dans une fusion homogène et qu'on disperse ce mélange par cisaillement dans l'eau, tandis qu'on utilise l'adoucissant cationique (A) et le sel de sulfate d'alkyle ou d'alcényle ou le sel d'éthersulfate d'alkyle ou d'alcényle (B) en un rapport pondéral supérieur à (A:B) = 5:1.
EP94909087A 1993-03-08 1994-02-28 Compositions aqueuses d'adoucissants textiles Expired - Lifetime EP0688356B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4307186 1993-03-08
DE4307186A DE4307186A1 (de) 1993-03-08 1993-03-08 Wäßrige Textilweichmacher-Zusammensetzung
PCT/EP1994/000580 WO1994020596A1 (fr) 1993-03-08 1994-02-28 Compositions aqueuses d'adoucissants textiles

Publications (2)

Publication Number Publication Date
EP0688356A1 EP0688356A1 (fr) 1995-12-27
EP0688356B1 true EP0688356B1 (fr) 1997-04-23

Family

ID=6482189

Family Applications (1)

Application Number Title Priority Date Filing Date
EP94909087A Expired - Lifetime EP0688356B1 (fr) 1993-03-08 1994-02-28 Compositions aqueuses d'adoucissants textiles

Country Status (4)

Country Link
EP (1) EP0688356B1 (fr)
DE (2) DE4307186A1 (fr)
ES (1) ES2100703T3 (fr)
WO (1) WO1994020596A1 (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4420514A1 (de) * 1994-06-13 1995-12-14 Henkel Kgaa Wäßrige Dispersionen anionischer und kationischer Tenside
HUP9802207A3 (en) * 1995-07-11 2000-11-28 Procter And Gamble Company Cin Concentrated, stable fabric softening compositions including chelants
BR9609820A (pt) 1995-07-11 1999-07-06 Procter & Gamble Composições amaciantes de tecidos concentrados dispersíveis em água e estáveis
CA2438655A1 (fr) * 1995-07-11 1997-01-30 Errol Hoffman Wahl Composition d'adoucisseur de tissus stable et concentre ayant une faible teneur en solvant organique
CN1098350C (zh) * 1996-03-22 2003-01-08 普罗格特-甘布尔公司 织物柔软化合物/组合物
DE19629666A1 (de) * 1996-07-23 1998-01-29 Henkel Kgaa Verfahren zur hydrophilen Ausrüstung von Fasern oder Vliesstoffen
EP0923631A2 (fr) * 1996-08-30 1999-06-23 The Procter & Gamble Company Premelange concentre avec inflammabilite reduite pour former des compositions d'adoucissants textiles
GB9810656D0 (en) * 1998-05-18 1998-07-15 Unilever Plc Stable ammonium compositions
GB9810655D0 (en) * 1998-05-18 1998-07-15 Unilever Plc Stable ammonium compositions

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS598392B2 (ja) * 1979-06-29 1984-02-24 花王株式会社 洗浄剤組成物
DE3069767D1 (en) * 1979-09-29 1985-01-17 Procter & Gamble Detergent compositions
EP0315126A3 (fr) * 1987-11-05 1990-03-21 Colgate-Palmolive Company Compositions détergentes liquides ayant des propriétés de stabilité et d'adoucissement améliorées
US4857213A (en) * 1988-02-08 1989-08-15 The Procter & Gamble Company Liquid detergent containing conditioning agent and high levels of alkyl sulfate/alkyl ethoxylated sulfate

Also Published As

Publication number Publication date
DE4307186A1 (de) 1994-09-15
WO1994020596A1 (fr) 1994-09-15
DE59402536D1 (de) 1997-05-28
ES2100703T3 (es) 1997-06-16
EP0688356A1 (fr) 1995-12-27

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