EP0375572B1 - Tiefziehbare Aluminiumlegierung, die Silicium, Magnesium und Kupfer enthält - Google Patents
Tiefziehbare Aluminiumlegierung, die Silicium, Magnesium und Kupfer enthält Download PDFInfo
- Publication number
- EP0375572B1 EP0375572B1 EP89420499A EP89420499A EP0375572B1 EP 0375572 B1 EP0375572 B1 EP 0375572B1 EP 89420499 A EP89420499 A EP 89420499A EP 89420499 A EP89420499 A EP 89420499A EP 0375572 B1 EP0375572 B1 EP 0375572B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alloy
- content
- less
- elements
- solution treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052710 silicon Inorganic materials 0.000 title claims abstract description 9
- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 7
- 229910052749 magnesium Inorganic materials 0.000 title claims abstract description 7
- 229910052802 copper Inorganic materials 0.000 title abstract description 4
- 239000010949 copper Substances 0.000 title abstract 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title abstract 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title 1
- 239000011777 magnesium Substances 0.000 title 1
- 239000010703 silicon Substances 0.000 title 1
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 13
- 239000000956 alloy Substances 0.000 claims abstract description 13
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 8
- 238000000265 homogenisation Methods 0.000 claims abstract description 7
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 6
- 238000004519 manufacturing process Methods 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims abstract 6
- 239000000203 mixture Substances 0.000 claims description 8
- 238000011282 treatment Methods 0.000 claims description 5
- 238000005452 bending Methods 0.000 claims description 3
- 238000010791 quenching Methods 0.000 claims description 3
- 230000000171 quenching effect Effects 0.000 claims description 3
- 238000009749 continuous casting Methods 0.000 claims description 2
- 230000032683 aging Effects 0.000 claims 1
- 238000005482 strain hardening Methods 0.000 claims 1
- 230000009466 transformation Effects 0.000 abstract description 7
- 238000004090 dissolution Methods 0.000 abstract description 4
- 238000007493 shaping process Methods 0.000 abstract description 3
- 238000000137 annealing Methods 0.000 abstract 1
- 238000005266 casting Methods 0.000 abstract 1
- 238000013000 roll bending Methods 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 description 5
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000001953 recrystallisation Methods 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 229910019064 Mg-Si Inorganic materials 0.000 description 1
- 229910019752 Mg2Si Inorganic materials 0.000 description 1
- 229910019406 Mg—Si Inorganic materials 0.000 description 1
- 241001080024 Telles Species 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 230000008685 targeting Effects 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
- C22C21/08—Alloys based on aluminium with magnesium as the next major constituent with silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/12—Alloys based on aluminium with copper as the next major constituent
- C22C21/14—Alloys based on aluminium with copper as the next major constituent with silicon
Definitions
- the invention relates to an Al alloy essentially containing Si, Mg and Cu intended for the manufacture of stampable sheets or strips, in particular sheets used in automobile bodywork.
- US-A-4,614,552 describes an Al alloy for stamping containing essentially from 0.65 to 0.79% (by weight) Cu; from 0.62 to 0.82% Mg; from 0.6 to 1.0% Si; 0.1 to 0.5% Mn; up to 0.4% Fe; up to 0.10% Ti; remains Al.
- anti-recrystallizing elements such as Mn, Cr and / or Zr, however in limited quantities.
- a preferred composition of the alloy according to the invention therefore comprises an Mn content of less than or equal to 0.2% and contents of Cr and Zr ⁇ 0.05% each.
- the manufacturing range used generally includes the following operations: . continuous or semi-continuous casting of blanks, possible homogenization, hot transformation, possible cold transformation, dissolution and tempering.
- homogenization at high temperature between 520 ° C and 560 ° C with a holding time of 6 to 24 hours is desirable. Homogenization is preferably preceded by a slow rise in temperature.
- the temperature at the end of hot transformation to avoid these recrystallizations, must imperatively be between 270 ° and 320 ° C.
- the alloy After possible cold transformation, the alloy is put into a complete solution. This takes place in the temperature range between 520 and 560 ° C, and preferably between 530 ° and 550 ° C by targeting the temperature of 550 ° C.
- the rise in temperature before dissolving must be rapid (V ⁇ 10 ° C / sec) and dissolving preferably performed either in a pass-through oven or in a sheet-to-sheet processing oven.
- the processing time varies from a few seconds to a few minutes, without being able to exceed one hour.
- the sheets and strips thus obtained have good isotropy and an average grain size generally not exceeding 60 ⁇ m.
- the quenching must be rapid and depends on the thickness of the product. For sheets and strips, it is generally carried out in calm or pulsed air.
- the parts undergo hardening income, under the usual conditions; the hardening is due to the precipitation of the Mg2Si phase and of AlCuMgSi complex phases. Tempering is typically carried out between 8 and 12 hrs around 165 ° C.
- FIG. 1 giving the field of composition of alloys in the Mg-Si plane and is illustrated by the following example: - A 1100x300x2850 mm3 plate of the following weight composition was poured semi-continuously:
- This plate was homogenized at 530 ° C-8h and immediately hot rolled; up to 4 mm thick, the final rolling temperature was 300 ° C; the strip thus obtained has been cold rolled until 1.2 mm thick, then dissolved in a passing oven at 550 ° C (about 1 min at temperature) at a speed of 20 m / min and quenched in a mist (air + water).
- an alloy with the following weight composition If: 1%; Mg: 0.4%; Cu: 0.15%; Mn: 0.1%; rest Al and usual impurities having followed the same range of transformation and heat treatment as above, has the following characteristics in state T4:
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cookers (AREA)
- Continuous Casting (AREA)
- Conductive Materials (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
- Shaping Metal By Deep-Drawing, Or The Like (AREA)
- Lead Frames For Integrated Circuits (AREA)
Claims (7)
- Aluminiumlegierung zur Herstellung tiefziehbarer Bleche, dadurch gekennzeichnet, daß ihre Zusammensetzung die folgende (in Gew.%) ist:- das Cu liegt im Bereich von 0,5 bis 0,8 %- die Elemente Cr und Zr jeweils unter 0,2 %- Mn < 0,3 %- Fe < 0,35 %- andere Elemente: jedes < 0,05 %, insgesamt < 0,15 %- Rest Al.
- Legierung nach dem Anspruch 1, dadurch gekennzeichnet, daß der Mn-Gehalt unter oder gleich 0,2 % ist und Cr und Zr jeweils < 0,05 % ist.
- Legierung nach einem der Ansprüche 1 oder 2, dadurch gekennzeichnet, daß die mittlere Korngröße unter 80 µm und vorzugsweise unter 60 µm ist.
- Verfahren zum Erhalten der Produkte nach einem der Ansprüche 1 bis 3, das den kontinuierlichen oder halbkontinuierlichen Guß von Rohblöcken, eine eventuelle Homogenisierung, eine Warmverformung, eine eventuelle Kaltverformung, eine Lösungsglühung, ein Abschrecken, eine Formgebung, beispielsweise durch Tiefziehen, Falzen, Biegen, und schließlich ein Anlassen vorsieht, dadurch gekennzeichnet, daß die Endwarmverformung zwischen 270 und 320 °C erfolgt.
- Verfahren nach dem Anspruch 4, dadurch gekennzeichnet, daß die Homogenisierung oder die vollständige Lösungsglühung zwischen 520 und 560 °C durchgeführt werden.
- Verfahren nach dem Anspruch 5, dadurch gekennzeichnet, daß die Homogenisierung oder die Lösungsglühung zwischen 530 und 550 °C erfolgen.
- Verfahren nach einem der Ansprüche 5 oder 6, dadurch gekennzeichnet, daß der Lösungsglühung ein Temperaturanstieg mit einer Geschwindigkeit über 10 °C/s vorausgeht.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT89420499T ATE90978T1 (de) | 1988-12-21 | 1989-12-19 | Tiefziehbare aluminiumlegierung, die silicium, magnesium und kupfer enthaelt. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8817621A FR2642436B1 (fr) | 1988-12-21 | 1988-12-21 | Alliage d'a1 contenant essentiellement du si, du mg et du cu pour emboutissage |
FR8817621 | 1988-12-21 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0375572A1 EP0375572A1 (de) | 1990-06-27 |
EP0375572B1 true EP0375572B1 (de) | 1993-06-23 |
Family
ID=9373742
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89420499A Expired - Lifetime EP0375572B1 (de) | 1988-12-21 | 1989-12-19 | Tiefziehbare Aluminiumlegierung, die Silicium, Magnesium und Kupfer enthält |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0375572B1 (de) |
AT (1) | ATE90978T1 (de) |
DE (1) | DE68907332T2 (de) |
ES (1) | ES2041438T3 (de) |
FR (1) | FR2642436B1 (de) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2713664B1 (fr) * | 1993-11-17 | 1996-05-24 | Pechiney Rhenalu | Alliage type Al-Si-Mg à ductilité et emboutissabilité améliorées et procédé d'obtention. |
CH688379A5 (de) * | 1994-11-29 | 1997-08-29 | Alusuisse Lonza Services Ag | Tiefziehbare und schweissbare Aluminiumlegierung vom Typ AlMgSi |
FR2748035B1 (fr) * | 1996-04-29 | 1998-07-03 | Pechiney Rhenalu | Alliage aluminium-silicium-magnesium pour carrosserie automobile |
WO1997047779A1 (en) * | 1996-06-14 | 1997-12-18 | Aluminum Company Of America | Highly formable aluminum alloy rolled sheet |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4082578A (en) * | 1976-08-05 | 1978-04-04 | Aluminum Company Of America | Aluminum structural members for vehicles |
US4424084A (en) * | 1980-08-22 | 1984-01-03 | Reynolds Metals Company | Aluminum alloy |
JPS6055586B2 (ja) * | 1982-11-30 | 1985-12-05 | 株式会社神戸製鋼所 | ろう付用高強度耐蝕アルミニウム合金 |
US4614552A (en) * | 1983-10-06 | 1986-09-30 | Alcan International Limited | Aluminum alloy sheet product |
ATE68529T1 (de) * | 1985-11-04 | 1991-11-15 | Aluminum Co Of America | Fahrzeugteil aus aluminiumlegierung. |
-
1988
- 1988-12-21 FR FR8817621A patent/FR2642436B1/fr not_active Expired - Fee Related
-
1989
- 1989-12-19 EP EP89420499A patent/EP0375572B1/de not_active Expired - Lifetime
- 1989-12-19 AT AT89420499T patent/ATE90978T1/de active
- 1989-12-19 ES ES198989420499T patent/ES2041438T3/es not_active Expired - Lifetime
- 1989-12-19 DE DE89420499T patent/DE68907332T2/de not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0375572A1 (de) | 1990-06-27 |
ES2041438T3 (es) | 1993-11-16 |
FR2642436B1 (fr) | 1991-06-14 |
DE68907332T2 (de) | 1993-11-11 |
DE68907332D1 (de) | 1993-07-29 |
FR2642436A1 (fr) | 1990-08-03 |
ATE90978T1 (de) | 1993-07-15 |
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