EP0354863B1 - Mehrfarbengewebeschreibband - Google Patents
Mehrfarbengewebeschreibband Download PDFInfo
- Publication number
- EP0354863B1 EP0354863B1 EP19890480106 EP89480106A EP0354863B1 EP 0354863 B1 EP0354863 B1 EP 0354863B1 EP 19890480106 EP19890480106 EP 19890480106 EP 89480106 A EP89480106 A EP 89480106A EP 0354863 B1 EP0354863 B1 EP 0354863B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- ribbon
- pigments
- fabric
- flushed
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004744 fabric Substances 0.000 title claims description 19
- 239000000049 pigment Substances 0.000 claims description 42
- 239000003086 colorant Substances 0.000 claims description 20
- 239000002245 particle Substances 0.000 claims description 15
- 238000004040 coloring Methods 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 5
- 230000009969 flowable effect Effects 0.000 claims 3
- 239000003981 vehicle Substances 0.000 description 26
- 239000000976 ink Substances 0.000 description 14
- 238000002156 mixing Methods 0.000 description 10
- 239000000975 dye Substances 0.000 description 6
- LVGKNOAMLMIIKO-UHFFFAOYSA-N Elaidinsaeure-aethylester Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC LVGKNOAMLMIIKO-UHFFFAOYSA-N 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 125000006226 butoxyethyl group Chemical group 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- 229940093471 ethyl oleate Drugs 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- 241000723353 Chrysanthemum Species 0.000 description 1
- 235000005633 Chrysanthemum balsamita Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000009950 felting Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 1
- JYNBEDVXQNFTOX-FMQUCBEESA-N lithol rubine Chemical compound OS(=O)(=O)C1=CC(C)=CC=C1\N=N\C1=C(O)C(C(O)=O)=CC2=CC=CC=C12 JYNBEDVXQNFTOX-FMQUCBEESA-N 0.000 description 1
- 235000010187 litholrubine BK Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J31/00—Ink ribbons; Renovating or testing ink ribbons
- B41J31/02—Ink ribbons characterised by the material from which they are woven
Definitions
- This invention relates to fabric ribbons which are impacted by a print element to print more than one color.
- the print elements typically are fully formed character images on a daisy wheel or one or more columns of individual wires. Transferable colors are held in the fabric and expressed on to paper or other print-receiving medium by the pressure of printing.
- the colors are commonly located on the ribbon in strips which extend along the length of the ribbon or in blocks of one color alternating with blocks of another color along the length of the ribbon. Such ribbons become virtually useless if the colors blend together during storage or use.
- multicolored fabric ribbons were typically made using standard pigments as the coloring matter or dyes as part of the coloring matter with the different colors separated by some physical barrier or gap.
- the average particle size of standard pigments is nominally 4 to 5 microns, while dyes are molecular in size.
- Inks with only standard pigments do not blend together in ordinary storage and use. This can be attributed to the fact that the pigment particles are relatively large in comparison with dye molecules, and ambient energy (which includes thermal, osmotic, capillary, Brownian, and other forces) is insufficient to move such pigment particles significantly.
- Different colored liquid inks with standard pigments only have been applied side-by-side on fabric ribbons without blending, but such ribbons do not replenish used areas well.
- the ribbon has been designed in a way to block color movement.
- the weave or continuity of the ribbon is physically interrupted at the boundary between colors, such as by adding an adhesive which is hardened or by crushing or melting the ribbon.
- This invention completely avoids any change of the weave of the ribbon.
- a particular coloring matter specifically flushed pigments, are used (average nominally 1/2 to 1 micron, agglomerations up to 2 microns). These are pigments of very small particle size, but do not tend to mix even though the woven fabric of the ribbon is continuous at the boundary between inks of different colors.
- the very small particle size has been found to provide good ribbon life, the particles exhibiting sufficient limited mobility that colors reconstitute themselves sufficiently near locations from which impact printing has occurred.
- U.S. Patent No. 385,391 to Underwood et al has an embodiment shown in its Fig. 2 in which no difference in the ribbon at the boundary between colors is specified.
- the other embodiments of this patent show embodiments in which barriers to mixing of colors are created by the manner the ribbon is woven or formed. Since the nature of the coloring matter in the Fig. 2 embodiment is only generally described, the use of flushed pigments is not suggested.
- U.S. Patent No. 2,590,200 to Neidich teaches a ribbon in which the fiber of the ribbon is predominantly in the direction of the boundaries of the different colors to prevent mixing across the colors.
- flushed pigments are not widely used, flushed pigments are known and generally available, and flushed pigments have been used in woven ribbons. No use of flushed pigments in multicolored ribbons is known.
- U.S. Patent No. 4,574,623 to Neumann is cited merely as illustrative that flushed pigments are known.
- This instant invention is a fabric ribbon having multicolored regions of coloring matter in a liquid vehicle.
- the coloring matter of the regions is essentially only flushed pigments, which are pigments of particle size generally less than 2 microns and of average particle size of nominally 1/2 to 1 micron. (By contrast, standard pigments are nominally 4 to 5 microns in particle size.) Flushed pigments do not migrate between colored regions under normal conditions, and therefore mixing of the colors is avoided without alteration of the fabric or use of a fabric with special characteristics or regions.
- the vehicles of the different colored regions are not significant in preventing migration, as the flushed pigments do not migrate with the vehicles. Nevertheless, the flushed pigments have sufficient mobility in regions from which ink has been depleted by printing to refill used areas of the ribbon with pigment, thus providing a ribbon of long useful life.
- the 12-MO-1434 is described by its supplier as 25% flushed yellow pigment and treated mineral oil as a vehicle.
- the approximate proportion of pigment to vehicle in the yellow ink therefore is 12.5% by weight pigment to 87.5% by weight vehicle.
- the 45-MO-1998 is described by its supplier as 35% flushed red pigment and treated mineral oil as a vehicle.
- the approximate proportion of pigment to vehicle in the red ink is therefore 19% by weight pigment to 81% by weight vehicle.
- the 70-MO-2324 is described by its supplier as 37% flushed blue pigment, 58% vehicle solids, and treated mineral oil vehicle.
- the approximate proportion of pigment to vehicle in the blue ink is therefore 14% by weight pigment to 86% by weight vehicle and vehicle solids.
- the fabric may be a conventional nylon woven fabric commonly used for impact printer ribbons. More specifically, in this preferred embodiment the fabric is highest quality filament nylon type 6,6; pH of 4.5 - 7, 4.0 mil (approximately 0.01016 cm) diameter; weight of 1.6 ounce per square yard (approximately 54.3 grams per square meter); warp (long direction) 174.0 threads per inch (approximately 68.5 threads per cm) and fill (cross direction) 114 threads per inch (approximately 45.7 threads per cm).
- the details of the fabric are not considered limiting, and fabrics of other materials, such as cotton and other man-made polymers, are considered alternatives for use with this invention.
- the threads of the fabric may be woven, felted, or otherwise intermixed. However, if the interstices are exceptionally large, which would result from a very loose felting, for example, the boundaries between the colors would be uneven.
- the fabric is entirely continuous and no change is made at the boundaries between the ink regions.
- the ink regions may be along the length of the ribbon, resulting in yellow, red, and blue strips side by side, each extending along the full length of a ribbon which typically is stuffed in the chamber of a ribbon cartridge or wound in a spool.
- the flushed pigments perform like dyes with respect to ribbon life, providing a ribbon which may be reused extensively, a characteristic of ribbons having dyes as the coloring matter. Yet, the ribbon colors do not bleed together, a characteristic of pigments.
- Flushed pigments are understood to be made in a manner in which the pigments are never a dry solid.
- the resulting pigments are of much smaller particle size as compared to standard pigments.
- Agglomerations in flushed pigments may be as large as 2 microns, while the average particle size is nominally 1/2 to 1 micron. By comparison, the average particle size of standard pigments is nominally 4 to 5 microns.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Impression-Transfer Materials And Handling Thereof (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
Claims (5)
- Stoffband, umfassend nebeneinanderliegende Bereiche mit fließbarer Tinte mit verschiedenen Farben in den genannten Bereichen, dadurch gekennzeichent, daß der genannte Stoff zwischen den genannten Bereichen kontinuierlich vorhanden ist und der Farbstoff der genannten fließbaren Tinte im wesentlichen aus geflushten Pigmenten besteht.
- Band nach Anspruch 1, in dem der genannte Stoff gewebt und die genannte Webung kontinuierlich zwischen den genannten nebeneinanderliegenden Bereichen vorhanden ist.
- Band nach Anspruch 2, bei dem die genannte Tinte jeder der genannten verschiedenen Farben einen aus einem geflushten Pigment bestehenden Farbstoff aufweist und auch einen flüssigen Trägerstoff enthält.
- Band nach Anspruch 1, bei dem die genannte Tinte jeder der genannten verschiedenen Farben einen aus einem geflushten Pigment bestehenden Farbstoff aufweist und auch einen flüssigen Trägerstoff enthält.
- Stoffband nach einem der Ansprüche 1 bis 4, bei dem die genannte fließbare Tinte im wesentlichen aus Pigmenten besteht, die eine durchschnittliche Teilchengröße in der Größenordnung von 0,5 bis 1,5 µm und im wesentlichen keine Teilchengröße über 4 µm aufweisen.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US22919488A | 1988-08-08 | 1988-08-08 | |
US229194 | 1988-08-08 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0354863A2 EP0354863A2 (de) | 1990-02-14 |
EP0354863A3 EP0354863A3 (de) | 1991-03-13 |
EP0354863B1 true EP0354863B1 (de) | 1994-04-13 |
Family
ID=22860187
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19890480106 Expired - Lifetime EP0354863B1 (de) | 1988-08-08 | 1989-06-29 | Mehrfarbengewebeschreibband |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0354863B1 (de) |
JP (1) | JPH0737166B2 (de) |
CA (1) | CA1337183C (de) |
DE (1) | DE68914546T2 (de) |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB885813A (en) * | 1958-01-21 | 1961-12-28 | Caribonum Ltd | Improvements in or relating to inked ribbons |
US3817773A (en) * | 1970-02-25 | 1974-06-18 | Ncr Co | Woven fabric printing ribbon having rupturable microcapsules bonded to its surface |
US4309320A (en) * | 1979-01-03 | 1982-01-05 | Basf Wyandotte Corporation | Pigment flushing |
DE3118980A1 (de) * | 1981-05-09 | 1982-11-25 | Pelikan Ag, 3000 Hannover | Multicarbon-material zur schrifterzeugung |
DE3321998A1 (de) * | 1983-06-18 | 1984-12-20 | Hoechst Ag, 6230 Frankfurt | Pigmentpraeparation, verfahren zu ihrer herstellung und ihre verwendung |
JPH07396B2 (ja) * | 1985-04-25 | 1995-01-11 | 沖電気工業株式会社 | インクリボン |
-
1989
- 1989-05-29 JP JP13292189A patent/JPH0737166B2/ja not_active Expired - Lifetime
- 1989-06-08 CA CA 602208 patent/CA1337183C/en not_active Expired - Fee Related
- 1989-06-29 DE DE1989614546 patent/DE68914546T2/de not_active Expired - Fee Related
- 1989-06-29 EP EP19890480106 patent/EP0354863B1/de not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0354863A3 (de) | 1991-03-13 |
DE68914546D1 (de) | 1994-05-19 |
CA1337183C (en) | 1995-10-03 |
EP0354863A2 (de) | 1990-02-14 |
JPH0737166B2 (ja) | 1995-04-26 |
DE68914546T2 (de) | 1994-10-13 |
JPH02147374A (ja) | 1990-06-06 |
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