EP0349307B1 - Procédé de fabrication de fibres de carbone à base de brai avec des propriétés physiques de compressivité supérieures - Google Patents

Procédé de fabrication de fibres de carbone à base de brai avec des propriétés physiques de compressivité supérieures Download PDF

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Publication number
EP0349307B1
EP0349307B1 EP89306590A EP89306590A EP0349307B1 EP 0349307 B1 EP0349307 B1 EP 0349307B1 EP 89306590 A EP89306590 A EP 89306590A EP 89306590 A EP89306590 A EP 89306590A EP 0349307 B1 EP0349307 B1 EP 0349307B1
Authority
EP
European Patent Office
Prior art keywords
pitch
vol
carbon fiber
optically anisotropic
fiber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP89306590A
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German (de)
English (en)
Other versions
EP0349307A3 (en
EP0349307A2 (fr
Inventor
Hiroaki Takashima
Osamu Kato
Kiyoshi Azami
Hajime Nakajima
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eneos Corp
Original Assignee
Nippon Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Oil Corp filed Critical Nippon Oil Corp
Publication of EP0349307A2 publication Critical patent/EP0349307A2/fr
Publication of EP0349307A3 publication Critical patent/EP0349307A3/en
Application granted granted Critical
Publication of EP0349307B1 publication Critical patent/EP0349307B1/fr
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Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
    • C10C3/00—Working-up pitch, asphalt, bitumen
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
    • D01F9/145—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from pitch or distillation residues

Definitions

  • the carbonaceous pitch used in the present invention is not specially limited, but a petroleum pitch or a coal pitch is preferred.
  • organic solvents each having a solubility parameter of 9.2 to 11.0 there are mentioned carbon disulfide (10.0), chloroform (9.3), dichloromethane (9.7), 1,1,2-trichloroethane (9.6), acetone (10.0), methyl ethyl ketone (9.3), pyridine (10.6), dichlorobenzene (10.0), chlorobenzene (9.5), benzene (9.2), naphthalene (10.6) and nitrobenzene (10.2).
  • a spinning pitch to be used in the invention which pitch has an optically anisotropic phase content in the range of 5-40 vol.%, preferably 5-35 vol.% more preferably 10-30 vol.%.
  • the pitch fiber thus obtained was heated up to 300°C at a rate of 2°C/min in oxygen containing 2 vol.% of NO2 and held at this temperature for 2 minutes, then heated up to 650°C at a rate of 10°C/min in nitrogen and held at this temperature for 30 minutes, and then heated up to 2,500°C at a rate of 100°C/min in nitrogen to afford carbon fiber.
  • the optically anisotropic pitch having a mesophase content of 50 vol.% used in Example 2 was pulverized, then subjected to an extraction treatment at 60°C using a mixed solvent (solubility parameter: 7.9) of hexane (50 vol.%) and benzene (50 vol.%) at a rate of 100 ml for 3 grams of the pitch, and insolubles in the mixed hexane-benzene solvent were collected.
  • a mixed solvent solubility parameter: 7.9

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Fibers (AREA)
  • Working-Up Tar And Pitch (AREA)

Claims (2)

  1. Procédé pour la production d'une fibre de carbone à base de brai, comprenant l'hydrogénation d'un brai carboné en présence d'un catalyseur d'hydrogénation pour ajouter au brai deux moles d'hydrogène ou plus par mole de brai; puis le traitement à chaud du brai hydrogéné à la pression atmosphérique ou sous une pression réduite pour obtenir un brai optiquement anisotrope; la récupération à partir de ce brai optiquement anisotrope d'un composant qui est insoluble dans un solvant organique ayant un paramètre de solubilité à 25°C de 7,4 à 9,0 et soluble dans un solvant organique ayant un paramètre de solubilité à 25°C de 9,2 à 11,0, pour obtenir un brai à filer ayant une teneur en phase optiquement anisotrope de 5% à 40% en volume; puis le filage de ce brai à filer; puis l'infusibilisation de la fibre de brai résultante et ensuite la carbonisation de la fibre de brai ainsi infusibilisée.
  2. Procédé suivant la revendication 1, dans lequel le brai carboné est hydrogéné à une température comprise dans la gamme de 150°C à 450°C, à une pression comprise dans la gamme de 30 à 250 kg/cm² et à une vitesse spatiale (LHSV) comprise dans la gamme de 0,15 à 3,0.
EP89306590A 1988-06-30 1989-06-29 Procédé de fabrication de fibres de carbone à base de brai avec des propriétés physiques de compressivité supérieures Expired - Lifetime EP0349307B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP63160683A JP2535207B2 (ja) 1988-06-30 1988-06-30 圧縮物性に優れたピッチ系炭素繊維およびその製造法
JP160683/88 1988-06-30

Publications (3)

Publication Number Publication Date
EP0349307A2 EP0349307A2 (fr) 1990-01-03
EP0349307A3 EP0349307A3 (en) 1990-03-07
EP0349307B1 true EP0349307B1 (fr) 1994-11-09

Family

ID=15720210

Family Applications (1)

Application Number Title Priority Date Filing Date
EP89306590A Expired - Lifetime EP0349307B1 (fr) 1988-06-30 1989-06-29 Procédé de fabrication de fibres de carbone à base de brai avec des propriétés physiques de compressivité supérieures

Country Status (4)

Country Link
EP (1) EP0349307B1 (fr)
JP (1) JP2535207B2 (fr)
KR (1) KR960007715B1 (fr)
DE (1) DE68919283T2 (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0482560B1 (fr) * 1990-10-22 1998-01-21 Mitsubishi Chemical Corporation Brai pour le filage de fibres de carbone et procédé de fabrication
EP0551878A1 (fr) * 1992-01-14 1993-07-21 Mitsubishi Chemical Corporation Fibres de carbone et procédé pour leur production
JPH10298829A (ja) * 1997-04-24 1998-11-10 Nippon Oil Co Ltd ピッチ系炭素繊維の製造方法
WO2007018136A1 (fr) 2005-08-09 2007-02-15 Toray Industries, Inc. Fibre ininflammable, fibre de carbone, et procede de production des deux types de fibres
KR101703423B1 (ko) * 2015-04-29 2017-02-10 충남대학교산학협력단 방사선을 이용한 피치계 섬유의 제조방법
US10386874B2 (en) 2016-03-14 2019-08-20 Kabushiki Kaisha Toshiba Voltage to current converter
CN106435840B (zh) * 2016-10-21 2018-09-11 中国石油大学(华东) 一种沥青基碳纤维的制备方法
CN107201248A (zh) * 2017-07-17 2017-09-26 青岛科技大学 一种fcc油浆组分切割‑沉降分离制备中间相沥青的方法
CN108565401B (zh) * 2018-05-18 2020-12-15 国家能源投资集团有限责任公司 无定形碳材料及制备方法与用途
CN110921646B (zh) * 2019-12-06 2022-01-07 大连理工大学 基于重质芳烃分的硬炭材料的类石墨微晶尺寸和层间距的选择性调控方法
KR102529745B1 (ko) * 2021-04-19 2023-05-08 재단법인 포항산업과학연구원 인조흑연용 피치의 제조 방법
KR102583031B1 (ko) * 2021-07-01 2023-09-27 한국화학연구원 헤테로상 바인더 피치 제조방법 및 이로부터 제조된 헤테로상 바인더 피치
KR102389550B1 (ko) * 2021-09-24 2022-04-21 한국화학연구원 2단 용매 추출 방식에 기반하는 중질유 유래 탄소섬유용 이방성피치의 제조방법

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0633530B2 (ja) * 1984-09-14 1994-05-02 呉羽化学工業株式会社 炭素繊維及びその製造方法
JPH0670220B2 (ja) * 1984-12-28 1994-09-07 日本石油株式会社 炭素繊維用ピッチの製造法
JPS62270685A (ja) * 1986-05-19 1987-11-25 Maruzen Petrochem Co Ltd メソフェ−ズピッチの製造法
JPH0672223B2 (ja) * 1986-12-15 1994-09-14 三菱化成株式会社 炭素繊維用水添ピツチの製造方法

Also Published As

Publication number Publication date
EP0349307A3 (en) 1990-03-07
JPH0214023A (ja) 1990-01-18
EP0349307A2 (fr) 1990-01-03
DE68919283D1 (de) 1994-12-15
KR960007715B1 (ko) 1996-06-08
JP2535207B2 (ja) 1996-09-18
DE68919283T2 (de) 1995-03-23
KR910001104A (ko) 1991-01-30

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