EP0342997A2 - Allzweckreinigerzusammensetzungen - Google Patents

Allzweckreinigerzusammensetzungen Download PDF

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Publication number
EP0342997A2
EP0342997A2 EP19890305082 EP89305082A EP0342997A2 EP 0342997 A2 EP0342997 A2 EP 0342997A2 EP 19890305082 EP19890305082 EP 19890305082 EP 89305082 A EP89305082 A EP 89305082A EP 0342997 A2 EP0342997 A2 EP 0342997A2
Authority
EP
European Patent Office
Prior art keywords
weight
composition
nonionic
cationic
surfactant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP19890305082
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English (en)
French (fr)
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EP0342997B2 (de
EP0342997A3 (en
EP0342997B1 (de
Inventor
George Kerr Rennie
Paolo Bernardi
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Unilever PLC
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Unilever PLC
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Application filed by Unilever PLC filed Critical Unilever PLC
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Publication of EP0342997A3 publication Critical patent/EP0342997A3/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776—Heterocyclic compounds, e.g. lactam
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • the present invention relates to general-purpose cleaning compositions with improved properties. More particularly, it relates to general-purpose cleaning compositions which have a sanitizing effect and a streak-free cleaning benefit.
  • General-purpose cleaning compositions are compositions which are intended for use in the cleaning of hard surfaces, such as tiles, walls, floors, kitchen furniture, glass, plastic/covered doors, etc. Such general-purpose cleaning compositions are well known in the art and have found substantial commercial use.
  • compositions are usually provided in the form of a particulate composition, from which the user prepares an aqueous solution, or in the form of a liquid composition which contains a suitable solvent, such as water, or a mixture of these.
  • a suitable solvent such as water, or a mixture of these.
  • a disadvantage of such detergent sanitizers based on a mixture of nonionic and cationic detergent surfactants is that they frequently give rise to streak formation on the surfaces when dry, which, as explained above, is unattractive to the consumer.
  • nonionic detergent surfactant used in the present invention can be any suitable type of nonionic detergent known.
  • nonionic detergent surfactants consist of a hydrophobic moiety, such as a C8-C20 fatty acid amide, and a hydrophilic moiety which consists of alkylene oxide units.
  • These nonionic detergent surfactants are, for instance, alkoxylation products of the above hydrophobic moieties containing from 2 to 30 moles of alkylene oxide.
  • alkylene oxides ethylene, propylene and butylene oxides and mixtures thereof are used.
  • nonionic detergents are C9-C11 primary, straight chain alcohols condensed with from 4-9 moles of ethylene oxide, C12-C15 primary straight chain alcohols condensed with 6-12 moles of ethylene oxide, or with 7-9 moles of a mixture of ethylene oxide and propylene oxide, C11-C15 secondary alcohols condensed with from 3-15 moles of ethylene oxide, and C10-C18 fatty acid diethanolamides.
  • Further examples of nonionic detergent surfactants may be found in M.Schick's textbook "Nonionic Surfactants", M.Dekker Inc., New York, 1967. Mixtures of various nonionic surfactants may also be used.
  • Tertiary amine oxides such as higher alkyl di(lower alkyl) amine oxides, e.g. lauryl dihyroxyethyl amine oxide, may also be used as a suitable nonionic surfactant.
  • Nonionic detergent surfactants known in the art as “topped” or “peaked” nonionic detergent surfactants are also useful in the present invention.
  • Topped nonionic detergent surfactants can be made by subjecting the usual nonionic detergent surfactant to a steam distillation treatment, by which the free and low alkoxylated alcohol can be removed, and peaked nonionic detergent surfactants can be made by carrying out the alkoxylation with special catalysts, which results in products with a much sharper peak in the alkoxylate distribution.
  • Topped nonionic detergent surfactants are e.g. described in US Patent Specification 3 682 849.
  • Topped or peaked nonionic detergent surfactants suitable for the present invention contain an average number of alkylene oxide units of between 3 and 15, preferably between 4 and 12, per molecule of the hydrophobic moiety, i.e. a C6-C18 primary or secondary, straight or branched chain alcohol, and preferably contain less than 2% by weight of non-alkoxylated alcohol, and less than 4% by weight of mono-alkoxylated alcohol.
  • nonionic detergent surfactants with these specifications and prepared from C11-C15 linear primary alcohols condensed with 7-11 moles of ethylene oxide, C9-C11 oxo-alcohols condensed with 5 moles of ethylene oxide, and C6-C10 linear primary alcohols condensed with 4-5 moles of ethylene oxide.
  • the shorter alkyl chain length nonionic surfactants are preferred, particularly when the degree of alkoxylation is relatively low.
  • the alkoxylated C9-C11 alcohols are preferred to the correspondingly alkoxylated C12-C15 alcohols, and the C9-C11 alcohols condensed with 5 moles of ethylene oxide are preferred to the same alcohols but condensed with 8 moles of ethylene oxide.
  • the HLB-value of the nonionic surfactant or mixture of nonionic surfactants should lie between 10 and 15.
  • Nonionic surfactants with an HLB-value of below 11 are generally not soluble in water to any appreciable extent without another active detergent present, but it is possible to dissolve higher levels of such low HLB-nonionic surfactants in mixtures of water and an organic solvent.
  • the nonionic surfactant should preferably provide a cloud point of the aqueous solution of the final composition above the temperature of normal use of the diluted solution.
  • nonionic surfactants From 0.01 to 90% by weight with respect to the final composition of one or more nonionic surfactants will be present in the final composition. Usually, this amount will range from 0.1 to 30% by weight, and it has been found that at least 1% should be present to obtain both a reduced streaking and an improved cleaning effect. Preferably therefore, the amount of nonionic detergent surfactant will range from 1% to 30%, and especially preferably from 1% to 10% by weight of the final composition.
  • the cationic detergent surfactant to be used in the present invention can be any cationic detergent surfactant with a sanitizing action well known in the art.
  • cationic detergent surfactants are the quaternary ammonium compounds, such as the mono- or di(long chain alkyl) tri- or di(short chain) alkyl quaternary ammonium salts; mono- or di(long chain alkyl) imidazolinium compounds; substituted long chain alkyl polyamine salts; alkyl pyridinium salts and so on. Further suitable examples can be found in Schwartz, Perry and Berch, Vol.II (1958), "Surface-active Agents and Detergents" under the heading "Cationic Surface Active Agents".
  • Suitable cationic detergent surfactants are the long chain (C8 and higher) alkyldimethylbenzylammonium chlorides (e.g. the commercial product Dodigen ex American Hoechst Corp.), the alkyl (C12 and higher) trimethylammonium chloride, tetradecyl pyridinium chloride, alkyl (C12-C16) trimethylammonium bromide, di-isobutyl-phenoxy- ethoxyethyl dimethylbenzylammonium chloride. Quaternary phosphonium and sulphonium compounds can also be used. These examples are, however, not limiting the scope of the invention; other detergent surfactants with a sanitizing action can be suitably used.
  • the amount of cationic detergent surfactant used in the present invention ranges from 0.005 to 50%, usually from 0.1 to 15%, and preferably from 0.25 to 5% by weight.
  • the non-anionic polymer to be used in the present invention should have an adsorptive affinity to the hard surface and should be hydrophilic. Preferably, it should bear a positive charge on its molecular structure (either as such or under the conditions of use), and consequently cationic polymers are clearly preferred to nonionic polymers.
  • Suitable cationic polymers for use in the present invention are those which adsorb on to the hard surface at least as quickly as, and preferably, more quickly than, the cationic detergent surfactant.
  • Typical examples of such cationic polymers are Busan 77 (ex Buckman) which is a poly[oxyethylene (dimethyliminio) ethylene (dimethyliminio) ethylene dichloride] with a polymerization degree of about 20, Busan 79 (ex Buckman) which is a poly [hydroxy-ethylene (dimethyliminio) ethylene (dimethyliminio) methylene dichloride], Busan 1055 (ex Buckman) which is a poly[2-­hydroxyethylenedimethyliminio-2-­hydroxypropylenedimethyliminio methylene) dichloride and structurally related cationic polymers such as 4/polyethylene glycol Ionene bromides where the molecular weights of the PEG portion are 6000 and 1500 respectively, Zetag 57 and Zetag 87 which are high molecular weight cationic acylamides ex Allied Colloids, Merquat 100 which is a polydimethyldiallylammonium chloride ex Merck, Mirapol A15 which
  • Particularly preferred cationic polymers for use in the present invention are Busan 77 (ex Buckman) Merquat 100 (ex Merck) and Mirapol A15 (ex Miranol).
  • nonionic polymers examples include Jaguar HP 8 and HP60 (ex Meyhall), which are nonionic substituted hydroxypropyl guar gums, and polyvinylpyrrolidones and poly(2-vinylpyridines) which are especially suitable for very low pH compositions.
  • the cationic polymers are clearly preferred to the nonionic polymers.
  • contact angle measurements may provide a guide as to the suitability of non-anionic polymers for use in the composition.
  • low contact angles are an indication of suitability.
  • the contact angle is measured as the receding angle of a drop of water (approximately 0.4cm3 forced to spread by tilting movements on a horizontal black ceramic tile which has been previously treated with a formulation comprising 1.5% C8-C18 alkyldimethylbenzylammonium chloride, 1.2% C11 alkyl polyoxyethylene (3EO), 0.6% C9-C11 linear alcohol condensed with 5 moles of ethylene oxide and 0.8% by weight of the non-anionic polymer, and then allowed to dry.
  • a formulation comprising 1.5% C8-C18 alkyldimethylbenzylammonium chloride, 1.2% C11 alkyl polyoxyethylene (3EO), 0.6% C9-C11 linear alcohol condensed with 5 moles of ethylene oxide and 0.8% by weight of the non-anionic polymer, and then allowed to dry.
  • the non-anionic polymers have contact angles of less than 15° and more preferably less than 10°.
  • contact angles can only be used as a guide.
  • Some polymers moreover are not soluble at the levels of the above test and yet still give a streak free benefit.
  • a more reliable guide to suitable non-anionic polymers is provided by an adsorption test which, by way of surface tension measurements, determines the adsorptive affinity of the non-anionic polymer compared to that of a typical cationic surfactant when the components are in competition for an "ideal" surface such as colloidal silica.
  • the adsorption test comprises the following steps:
  • the quantity of silica added is chosen so that the non-anionic polymer and the surfactant must compete for adsorption sites. It has been found that the preferred cationic polymers according to the invention cause a less than 15 dyne change in surface tension when tested according to the adsorption test defined above, particularly preferred cationic polymers cause a less than 10 dyne change in surface tension according to the adsorption test.
  • the amount of non-anionic polymer in the compositions of the invention may range from 0.003 to 20%, usually from 0.01 to 15%, and preferably from 0.1 to 5% by weight.
  • particularly preferred formulations of the invention have ratios of cationic surfactant: non-anionic polymer within the range 150:1 to 0.3:1 and most preferably 15:1 to 1:2.
  • compositions may furthermore contain optional ingredients, such as preservatives, bactericides, bleaching agents, enzymes, thickening agents, colouring agents, perfumes, alkaline materials, sequestering agents, solvents and the like.
  • optional ingredients such as preservatives, bactericides, bleaching agents, enzymes, thickening agents, colouring agents, perfumes, alkaline materials, sequestering agents, solvents and the like.
  • They may also contain particulate abrasive, such as particulate calcite, to form an abrasive cleaning composition.
  • They may be made in any physical form, such as powders, blocks, aqueous and non-aqueous liquids etc. Preferably, they are in liquid form, the balance of the formulation being an aqueous or non-aqueous medium. They may be applied as such, i.e. neat, or they may be made up into a solution before use to a concentration of generally 0.1 to 10%.
  • streak-free benefit is independent of the pH of the composition.
  • An exception is a polymer such as poly(2-vinylpyridine) in which case a composition of very low pH is necessary for optimum streak-free results to be obtained.
  • the invention will further be illustrated by way of Example.
  • the following formulation is a liquid abrasive cleaning composition with an improved streak-free benefit.
  • % Topped C9-C11 alcohol condensed with 5 moles of ethylene oxide 4.8 C12-C16 alkyldimethylbenzyl ammonium chloride 1.5 Particulate calcite 45.0 Nonionic polymer (Jaguar HP-8) 0.4 Perfume 0.2 Water balance
  • the adsorptive affinity of a range of non-anionic polymers was determined by the following adsorption test.
  • the adsorption test comprises the following steps:
  • non-anionic polymer from (ii) above was then incorporated in the following composition. 1.5% Alkyl (C8-C18) benzyldimethylammonium chloride 1.2% Alkyl (C11) polyoxyethylene (3EO) 0.6% Alkyl (C9-C11) polyoxyethylene (5EO) 0.8% Non-anionic polymer balance water to 100%

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
EP89305082A 1988-05-20 1989-05-19 Allzweckreinigerzusammensetzungen Expired - Lifetime EP0342997B2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB888811953A GB8811953D0 (en) 1988-05-20 1988-05-20 General-purpose cleaning compositions
GB8811953 1988-05-20

Publications (4)

Publication Number Publication Date
EP0342997A2 true EP0342997A2 (de) 1989-11-23
EP0342997A3 EP0342997A3 (en) 1990-05-02
EP0342997B1 EP0342997B1 (de) 1994-08-10
EP0342997B2 EP0342997B2 (de) 1997-10-01

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Family Applications (1)

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EP89305082A Expired - Lifetime EP0342997B2 (de) 1988-05-20 1989-05-19 Allzweckreinigerzusammensetzungen

Country Status (10)

Country Link
EP (1) EP0342997B2 (de)
JP (1) JP2857168B2 (de)
KR (1) KR960000201B1 (de)
AU (1) AU619545B2 (de)
BR (1) BR8902331A (de)
DE (1) DE68917371T2 (de)
ES (1) ES2058522T5 (de)
GB (1) GB8811953D0 (de)
TR (1) TR25242A (de)
ZA (1) ZA893779B (de)

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DE4334368A1 (de) * 1993-10-08 1995-04-13 Henkel Kgaa Schwach schäumende Reinigungsmittel
WO1997009408A1 (de) * 1995-09-04 1997-03-13 Henkel Kommanditgesellschaft Auf Aktien Klarspülmittel mit kationischen polymeren
US5756443A (en) * 1994-08-22 1998-05-26 Kao Corporation Detergent composition for hard surface
WO1998024314A1 (en) * 1996-12-06 1998-06-11 Reckitt & Colman Inc. Aqueous disinfecting cleaning composition
EP0875555A1 (de) * 1997-04-30 1998-11-04 The Procter & Gamble Company Verwendung von Polysacchariden in flüssigen sauren Zusammensetzungen
US6017869A (en) * 1998-04-14 2000-01-25 Reckitt & Colman Inc. Aqueous cleaning and disinfecting compositions which include quaternary ammonium compounds, block copolymer surfactants and further mitigating compounds which compositions feature reduced irritation
US6022841A (en) * 1998-04-14 2000-02-08 Reckitt & Colman Inc. Aqueous cleaning and disinfecting compositions based on quaternary ammonium compounds including alkoxylated fatty acid amines having reduced irritation characteristics
EP0985458A3 (de) * 1998-09-09 2000-06-21 Kabushiki Kaisha Hanogumi Verfahren zum Unterhalten von Konstruktionen wie Gebäuden und beschichteten Strassen
US6143710A (en) * 1998-04-14 2000-11-07 Reckitt Benckiser Inc. Aqueous cleaning and disinfecting compositions having reduced irritation characteristics based on quaternary ammonium compounds including block copolymer surfactants and further surfactants
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US6221820B1 (en) 1997-12-31 2001-04-24 Henkel Kommanditgesellschaft Auf Aktien Granular component containing alkylaminotriazole for use in machine dishwashing detergents
WO2001042415A1 (en) * 1999-12-08 2001-06-14 Unilever N.V. Use of polymeric material in the treatment of hard surfaces
US6268327B1 (en) 1998-04-14 2001-07-31 Reckitt Benckiser Inc. Aqueous cleaning and disinfecting compositions based on quaternary ammonium componunds including alkylamphoacetates having reduced irritation characteristics
WO2002016536A1 (fr) * 2000-08-23 2002-02-28 Kao Corporation Detergent bactericide antisalissures, destine aux surfaces dures
US6410500B1 (en) 1997-12-30 2002-06-25 Henkel Kommanditgesellschaft Auf Aktien Moulded body dishwasher detergents with soil release polymers
US6559116B1 (en) 1999-09-27 2003-05-06 The Procter & Gamble Company Antimicrobial compositions for hard surfaces
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WO2003070867A1 (en) * 2002-02-22 2003-08-28 Kao Corporation Antifouling detergent for hard surfaces
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US6992056B1 (en) 1997-12-30 2006-01-31 Henkel Kgaa Process for preparing detergent tablets having two or more regions
EP1845152A1 (de) * 2006-04-14 2007-10-17 The Procter and Gamble Company Verfahren zur Reinigung einer harten Oberfläche mit zwitterionischem Polymer
WO2008059453A1 (en) * 2006-11-14 2008-05-22 The Procter & Gamble Company Liquid hard surfaces cleaning compositions
US7695637B2 (en) * 2006-11-27 2010-04-13 Cheil Industries Inc. Slurry composition for chemical mechanical polishing and precursor composition thereof
US7708900B2 (en) 2005-11-04 2010-05-04 Cheil Industries, Inc. Chemical mechanical polishing slurry compositions, methods of preparing the same and methods of using the same
US7741265B2 (en) 2007-08-14 2010-06-22 S.C. Johnson & Son, Inc. Hard surface cleaner with extended residual cleaning benefit
US8512593B2 (en) * 2005-11-04 2013-08-20 Cheil Industries, Inc. Chemical mechanical polishing slurry compositions, methods of preparing the same and methods of using the same
JP2013542279A (ja) * 2010-10-01 2013-11-21 ロディア オペレーションズ 硬質表面用洗浄組成物
JP2013542280A (ja) * 2010-10-01 2013-11-21 ロディア オペレーションズ スポット形成防止効果及び／又は皮膜形成防止効果を有する洗剤組成物
WO2017058560A1 (en) * 2015-10-02 2017-04-06 The Procter & Gamble Company Hard surface cleaning compositions comprising ethoxylated alkoxylated nonionic surfactants or a copolymer and cleaning pads and methods for using such cleaning compositions
US10119105B2 (en) 2015-10-02 2018-11-06 The Procter & Gamble Company Hard surface cleaning composition and method of improving drying time using the same
CN111732898A (zh) * 2019-03-25 2020-10-02 三星Sdi株式会社 Cmp浆料组成物和使用其抛光图案化钨晶片的方法
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US8975220B1 (en) 2014-08-11 2015-03-10 The Clorox Company Hypohalite compositions comprising a cationic polymer
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DE3614336A1 (de) * 1986-04-28 1987-10-29 Henkel Kgaa Fluessige waessrige reinigungsmittel fuer harte oberflaechen
DE3726912A1 (de) * 1987-08-13 1989-02-23 Henkel Kgaa Fluessige mittel zum reinigen harter oberflaechen
JPH01168612A (ja) * 1987-12-25 1989-07-04 Lion Corp 液体洗浄剤組成物

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US5756443A (en) * 1994-08-22 1998-05-26 Kao Corporation Detergent composition for hard surface
US6025314A (en) * 1995-09-04 2000-02-15 Henkel Kommanditgesellschaft Auf Aktien Clear-rinsing agents with cationic polymers
WO1997009408A1 (de) * 1995-09-04 1997-03-13 Henkel Kommanditgesellschaft Auf Aktien Klarspülmittel mit kationischen polymeren
WO1998024314A1 (en) * 1996-12-06 1998-06-11 Reckitt & Colman Inc. Aqueous disinfecting cleaning composition
EP0875555A1 (de) * 1997-04-30 1998-11-04 The Procter & Gamble Company Verwendung von Polysacchariden in flüssigen sauren Zusammensetzungen
US6992056B1 (en) 1997-12-30 2006-01-31 Henkel Kgaa Process for preparing detergent tablets having two or more regions
US6410500B1 (en) 1997-12-30 2002-06-25 Henkel Kommanditgesellschaft Auf Aktien Moulded body dishwasher detergents with soil release polymers
US6221820B1 (en) 1997-12-31 2001-04-24 Henkel Kommanditgesellschaft Auf Aktien Granular component containing alkylaminotriazole for use in machine dishwashing detergents
US6017869A (en) * 1998-04-14 2000-01-25 Reckitt & Colman Inc. Aqueous cleaning and disinfecting compositions which include quaternary ammonium compounds, block copolymer surfactants and further mitigating compounds which compositions feature reduced irritation
US6022841A (en) * 1998-04-14 2000-02-08 Reckitt & Colman Inc. Aqueous cleaning and disinfecting compositions based on quaternary ammonium compounds including alkoxylated fatty acid amines having reduced irritation characteristics
US6143710A (en) * 1998-04-14 2000-11-07 Reckitt Benckiser Inc. Aqueous cleaning and disinfecting compositions having reduced irritation characteristics based on quaternary ammonium compounds including block copolymer surfactants and further surfactants
US6930081B1 (en) 1998-04-14 2005-08-16 Reckitt Benckiser Inc. Aqueous cleaning and disinfecting compositions based on quaternary ammonium compounds including alkylpolyglycoside surfactants having reduced irritation characteristics
US6268327B1 (en) 1998-04-14 2001-07-31 Reckitt Benckiser Inc. Aqueous cleaning and disinfecting compositions based on quaternary ammonium componunds including alkylamphoacetates having reduced irritation characteristics
AU750105B2 (en) * 1998-04-14 2002-07-11 Reckitt Benckiser Inc. Aqueous cleaning and disinfecting compositions based on quaternary ammonium compounds including alkoxylated fatty acid amines having reduced irration characteristics
EP0985458A3 (de) * 1998-09-09 2000-06-21 Kabushiki Kaisha Hanogumi Verfahren zum Unterhalten von Konstruktionen wie Gebäuden und beschichteten Strassen
US6730654B2 (en) 1999-09-27 2004-05-04 The Procter & Gamble Company Antimicrobial compositions for hard surfaces containing biguanide compounds
US6559116B1 (en) 1999-09-27 2003-05-06 The Procter & Gamble Company Antimicrobial compositions for hard surfaces
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US6653274B1 (en) 1999-09-27 2003-11-25 The Proctor & Gamble Company Detergent composition comprising a soil entrainment system
WO2001042415A1 (en) * 1999-12-08 2001-06-14 Unilever N.V. Use of polymeric material in the treatment of hard surfaces
US6573229B2 (en) 2000-04-12 2003-06-03 Unilever Home & Personal Care Usa Division Of Conopco Inc. Laundry wash compositions
US6596684B2 (en) 2000-04-20 2003-07-22 Unilever Home & Personal Care Usa Divison Of Conopco, Inc. Granular detergent component and process for its preparation
WO2002016536A1 (fr) * 2000-08-23 2002-02-28 Kao Corporation Detergent bactericide antisalissures, destine aux surfaces dures
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US7544649B2 (en) 2002-02-22 2009-06-09 Kao Corporation Antifouling detergent for hard surfaces
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US7708900B2 (en) 2005-11-04 2010-05-04 Cheil Industries, Inc. Chemical mechanical polishing slurry compositions, methods of preparing the same and methods of using the same
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US7741265B2 (en) 2007-08-14 2010-06-22 S.C. Johnson & Son, Inc. Hard surface cleaner with extended residual cleaning benefit
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Also Published As

Publication number Publication date
JPH0218499A (ja) 1990-01-22
AU3480789A (en) 1989-11-23
KR890017350A (ko) 1989-12-15
ZA893779B (en) 1991-01-30
ES2058522T5 (es) 1997-12-16
DE68917371D1 (de) 1994-09-15
GB8811953D0 (en) 1988-06-22
EP0342997B2 (de) 1997-10-01
EP0342997A3 (en) 1990-05-02
BR8902331A (pt) 1990-01-09
KR960000201B1 (ko) 1996-01-03
ES2058522T3 (es) 1994-11-01
JP2857168B2 (ja) 1999-02-10
DE68917371T2 (de) 1994-12-01
AU619545B2 (en) 1992-01-30
TR25242A (tr) 1992-12-01
EP0342997B1 (de) 1994-08-10

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