EP0313889A1 - Vacuum furnace for the heat treatment of metallic work-pieces - Google Patents

Vacuum furnace for the heat treatment of metallic work-pieces Download PDF

Info

Publication number
EP0313889A1
EP0313889A1 EP88116478A EP88116478A EP0313889A1 EP 0313889 A1 EP0313889 A1 EP 0313889A1 EP 88116478 A EP88116478 A EP 88116478A EP 88116478 A EP88116478 A EP 88116478A EP 0313889 A1 EP0313889 A1 EP 0313889A1
Authority
EP
European Patent Office
Prior art keywords
vacuum furnace
batch
cooling gas
thermal insulation
gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP88116478A
Other languages
German (de)
French (fr)
Other versions
EP0313889B1 (en
Inventor
Paul Dipl.-Ing. Heilmann
Erwin Dipl.-Ing. Heumüller
Fritz Kalbfleisch
Friedrich Dr. Dipl.-Phys. Preisser
Rolf Schuster
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Degussa GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6339264&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0313889(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Degussa GmbH filed Critical Degussa GmbH
Priority to AT88116478T priority Critical patent/ATE65800T1/en
Publication of EP0313889A1 publication Critical patent/EP0313889A1/en
Application granted granted Critical
Publication of EP0313889B1 publication Critical patent/EP0313889B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B5/00Muffle furnaces; Retort furnaces; Other furnaces in which the charge is held completely isolated
    • F27B5/06Details, accessories, or equipment peculiar to furnaces of these types
    • F27B5/16Arrangements of air or gas supply devices
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/74Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
    • C21D1/767Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material with forced gas circulation; Reheating thereof
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/74Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
    • C21D1/773Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material under reduced pressure or vacuum
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D7/00Forming, maintaining, or circulating atmospheres in heating chambers
    • F27D7/04Circulating atmospheres by mechanical means
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B5/00Muffle furnaces; Retort furnaces; Other furnaces in which the charge is held completely isolated
    • F27B5/06Details, accessories, or equipment peculiar to furnaces of these types
    • F27B2005/062Cooling elements
    • F27B2005/064Cooling elements disposed in the furnace, around the chamber, e.g. coils
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B5/00Muffle furnaces; Retort furnaces; Other furnaces in which the charge is held completely isolated
    • F27B5/06Details, accessories, or equipment peculiar to furnaces of these types
    • F27B5/14Arrangements of heating devices
    • F27B2005/143Heating rods disposed in the chamber
    • F27B2005/146Heating rods disposed in the chamber the heating rods being in the tubes which conduct the heating gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B5/00Muffle furnaces; Retort furnaces; Other furnaces in which the charge is held completely isolated
    • F27B5/06Details, accessories, or equipment peculiar to furnaces of these types
    • F27B5/16Arrangements of air or gas supply devices
    • F27B2005/161Gas inflow or outflow
    • F27B2005/164Air supply through a set of tubes with openings
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B5/00Muffle furnaces; Retort furnaces; Other furnaces in which the charge is held completely isolated
    • F27B5/06Details, accessories, or equipment peculiar to furnaces of these types
    • F27B5/16Arrangements of air or gas supply devices
    • F27B2005/166Means to circulate the atmosphere
    • F27B2005/167Means to circulate the atmosphere the atmosphere being recirculated through the treatment chamber by a turbine

Definitions

  • the invention relates to a vacuum furnace for the heat treatment of metallic workpieces with a cylindrical pressure housing, in which a batch space surrounded by axially aligned heat conductors and provided with thermal insulation and a gas cooling device are arranged, with which a cooling gas is passed through nozzles through the batch space and over a heat exchanger can.
  • Such vacuum furnaces are used in particular for the hardening of tools and components of all kinds made of various types of steel. Some of them can also be used for other heat treatments, e.g. B. Annealing and soldering.
  • DE-PSs 28 39 807 and 28 44 843 describe generic vacuum ovens. They essentially consist of a cylindrical pressure housing in which there is a batch chamber, which is delimited by thermal insulation walls and heated by heating elements, and a gas cooling device. The tools and components are heated in the batch chamber under vacuum to the austenitizing temperature and a cooled inert gas is circulated under pressure in the furnace for quenching. The cooling gas flows at high speed onto the hot batch, removes this thermal energy and is passed through a heat exchanger, where it is cooled and returned to the batch chamber. The cooling gas is introduced into the batch chamber according to DE-PS 28 39 807 via nozzles which are attached to separate, axially aligned gas inlet pipes.
  • This vacuum oven should ensure the fastest possible, even cooling of the heated batches, be as simple as possible and be able to be heated as quickly as possible.
  • heat conductors are designed as tubes, are provided with bores towards the batch space and are connected to a cooling gas distribution device via electrical insulating pieces.
  • the cooling gas distribution device is preferably provided with a fan which pushes the cooling gas through the heating pipes and sucks it in again from the batch space.
  • the wall of the thermal insulation in the area of the cooling gas distribution device is provided with a closable opening. This means that a heating gas flow can be maintained in the furnace interior bypassing the heat exchanger during the heating period of the batches.
  • Figures 1 and 2 schematically show longitudinal sections through an embodiment of a vacuum oven according to the invention, Figure 1 showing the oven in the heating phase up to about 750 ° C and Figure 2 in the cooling phase.
  • the furnace consists of a cylindrical pressure housing (1), one end face of which is designed as a door (2) through which the furnace can be loaded and unloaded.
  • the batch space (3) is delimited on the outside by thermal insulation (4) in the form of a cylindrical tube, which consists of a thermal insulation material and is provided on the end faces with corresponding walls, at least one wall (5) of which is movable.
  • This thermal insulation (4) shields the radiation in the batch space (3) from the outside, so that only slight energy losses occur.
  • the electrical heating conductors (6) are arranged axially in the batch space (3), which are designed as heating pipes and are provided with holes (7) towards the batch space (3).
  • These heating tubes (6) have, for example, a wall thickness of 1 to 3 mm and a clear width of 40 to 150 mm.
  • the diameter of the bores (7) is dimensioned such that the sum of the areas of the bores of a heating tube corresponds to the area of the clear width.
  • the heating pipes (6) are attached to the cooling gas distribution device (9) via electrical insulating pieces (8), which are connected to the drive motor (10) and the fan (11) on the side opposite the door (2) is housed in the pressure housing.
  • the wall of the thermal insulation (4) adjacent to the cooling gas distribution device (9) is provided with an opening (12) which can be closed and opened with a slide (13).
  • the water-cooled heat exchanger tubes (14) are accommodated between the pressure housing (1) and the thermal insulation (4).
  • the batch space (3) After loading the batch space (3) with tools, for example, it is flooded with an inert gas and heated.
  • the slide (13) opens the opening (12) in the thermal insulation ( Figure 1) so that the inert gas can be pressed by the fan (11) into the heating pipes (6), from where it passes through the holes (7) , which are distributed over the length of the heating pipes, penetrates into the batch space (3) and is returned to the fan (11) through the opening (12) in the thermal insulation.
  • the inert gas Since the inert gas is fed in via the heating pipes (6), it quickly increases in temperature, which results in the batch being heated quickly and homogeneously by the hot gas in the dark radiation region. Due to the hot gas flowing directly onto the batch, the batch is evenly heated internally.
  • This heating process under protective gas is used up to about 750 ° C. In the case of hardening treatments in which heating has to be carried out up to approximately 1300 ° C., the inert gas is then removed from the furnace and the further heating is carried out only by heat radiation
  • the furnace is flooded with cold inert gas with excess pressure when the opening (12) is closed.
  • the wall (5) of the thermal insulation (4) is lifted off the cylindrical tube, so that a gap is created and the batch space (3) with the space between Pressure housing (1) and thermal insulation (4) is connected ( Figure 2).
  • the cooling gas is pressed by the fan (11) over the cooled heating pipes (6) at high speed into the batch space (3), from where it flows back through the heat exchanger pipes (14) into the cooling gas distribution device (9) and is circulated again.
  • inert gases are used, combined with high gas pressures and gas velocities, quenching intensities are achieved with the vacuum furnaces according to the invention which are comparable to those achievable in oil quenching baths.
  • other types of steel than previously can be quenched and hardened with gas cooling.
  • the heating tubes (6) which also serve as gas supply tubes, preferably consist of carbon fiber-reinforced carbon.
  • the electrically conductive cross-section of the heating pipes, which is decisive for heat generation, and the internal width of the heating pipes, which is decisive for the gas volume flow, must be coordinated.
  • the combination of the heating element and the gas supply pipe results in a significant simplification of the manufacturing process in the manufacture of these furnaces.
  • the cooling gas is pumped out of the furnace interior with a compressor after the quenching process and conveyed into a high-pressure accumulator, from where it is available for further applications.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Furnace Details (AREA)
  • Muffle Furnaces And Rotary Kilns (AREA)
  • Heat Treatments In General, Especially Conveying And Cooling (AREA)
  • Thermally Insulated Containers For Foods (AREA)
  • Meat, Egg Or Seafood Products (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

A vacuum furnace for heat treatment of metallic workpieces wherein the heat conductors are formed as conduits fitted with bore holes and connected by electrical insulators to coolant gas distributor.

Description

Die Erfindung betrifft einen Vakuumofen zur Wärmebehandlung metallischer Werkstücke mit einem zylindrischen Druckgehäuse, in dem ein von axial ausgerichteten Heizleitern umgebener, mit einer thermischen Isolierung versehener Chargenraum und eine Gaskühleinrichtung angeordnet sind, mit der ein Kühlgas über Düsen durch den Chargenraum und über einen Wärmetauscher geleitet werden kann. Solche Vakuumöfen werden insbesondere für das Härten von Werkzeugen und Bauteilen aller Art aus vielerlei Stahlsorten benutzt. Zum Teil sind sie auch für andere Wärmebehandlungen einsetzbar, z. B. Glühen und Löten.The invention relates to a vacuum furnace for the heat treatment of metallic workpieces with a cylindrical pressure housing, in which a batch space surrounded by axially aligned heat conductors and provided with thermal insulation and a gas cooling device are arranged, with which a cooling gas is passed through nozzles through the batch space and over a heat exchanger can. Such vacuum furnaces are used in particular for the hardening of tools and components of all kinds made of various types of steel. Some of them can also be used for other heat treatments, e.g. B. Annealing and soldering.

In den DE-PSen 28 39 807 und 28 44 843 werden gattungsgemäße Vakuumöfen beschrieben. Sie bestehen im wesentlichen aus einem zylindrischen Druckgehäuse, in dem sich eine von thermischen Isolationswänden begrenzte, mit Heizelementen beheizte Chargenkammer und eine Gaskühleinrichtung befinden. Die Werkzeuge und Bauteile werden in der Chargenkammer unter Vakuum auf die Austenitisierungstemperatur aufgeheizt und zum Abschrecken wird ein gekühltes Inertgas unter Druck im Ofen umgewälzt. Das Kühlgas strömt dabei mit hoher Geschwin­digkeit auf die heiße Charge, entzieht dieser Wärmeenergie und wird über einen Wärmetauscher geleitet, wo es abgekühlt und wieder der Chargenkammer zugeführt wird. Die Einleitung des Kühlgases in die Chargenkammer erfolgt gemäß DE-PS 28 39 807 über Düsen, die auf gesonderten, axial ausgerichte­ten Gaseinleitrohren angebracht sind. Nachteil dieser Konstuktion ist der hohe Material- und Fertigungsaufwand für die Gaseinleitrohre im Ofen. Rohre und Düsen müssen aus hochtemperaturbeständigem Material bestehen. Die in der DE-PS 28 44 843 verwendeten Ventilatoren besitzen den Nachteil, daß das Kühlgas im beträchtlichen Umfang nur an der heißen Chargeoberfläche entlangströmt und nicht ins Chargeninnere eindringt.DE-PSs 28 39 807 and 28 44 843 describe generic vacuum ovens. They essentially consist of a cylindrical pressure housing in which there is a batch chamber, which is delimited by thermal insulation walls and heated by heating elements, and a gas cooling device. The tools and components are heated in the batch chamber under vacuum to the austenitizing temperature and a cooled inert gas is circulated under pressure in the furnace for quenching. The cooling gas flows at high speed onto the hot batch, removes this thermal energy and is passed through a heat exchanger, where it is cooled and returned to the batch chamber. The cooling gas is introduced into the batch chamber according to DE-PS 28 39 807 via nozzles which are attached to separate, axially aligned gas inlet pipes. The disadvantage of this design is the high cost of materials and manufacturing for the gas inlet pipes in the furnace. Pipes and nozzles must be made of high temperature resistant material. The fans used in DE-PS 28 44 843 have the disadvantage that the cooling gas flows to a considerable extent only along the hot batch surface and does not penetrate into the interior of the batch.

Aus der DE-OS 19 19 493 ist es bekannt, im Temperaturbereich zwischen Raumtemperatur und etwa 750 °C das Aufheizen der Charge zu beschleunigen, indem man im Ofen ein Inertgas mittels eines Ventilators umwälzt und so neben der Strahlung eine Konvektion erzeugt. Aber auch hierbei ist der Wärmeübergang zwischen Heizleiter und Charge nicht optimal.From DE-OS 19 19 493 it is known to accelerate the heating of the batch in the temperature range between room temperature and about 750 ° C. by circulating an inert gas in the furnace by means of a fan and thus producing a convection in addition to the radiation. But even here the heat transfer between the heating conductor and the batch is not optimal.

Es war daher Aufgabe der vorliegenden Erfindung, einen Vakuumofen zur Wärmebehandlung metallischer Werkstücke mit einem zylindrischen Druckgehäuse zu konstruieren, in dem ein von axial ausgerichteten Heizleitern umgebener, mit einer thermischen Isolierung versehender Chargenraum und eine Gaskühleinrichtung angeordnet sind, mit der ein Kühlgas über Düsen durch den Chargenraum und über einen Wärmetauscher geleitet werden kann. Dieser Vakuumofen sollte eine möglichst schnelle und gleichmäßige Abkühlung der aufgeheizten Chargen gewährleisten, eine möglichst einfache Konstruktion besitzen und möglichst rasch aufheizbar sein.It was therefore an object of the present invention to construct a vacuum furnace for the heat treatment of metallic workpieces with a cylindrical pressure housing in which a batch space surrounded by axially aligned heating conductors, provided with thermal insulation, and a gas cooling device are arranged, with which a cooling gas is passed through nozzles through the Batch room and can be passed through a heat exchanger. This vacuum oven should ensure the fastest possible, even cooling of the heated batches, be as simple as possible and be able to be heated as quickly as possible.

Diese Aufgabe wird erfindungsgemäß dadurch gelöst, daß die Heizleiter als Rohre ausgebildet, zum Chargenraum hin mit Bohrungen versehen und über elektrische Isolierstücke mit einer Kühlgasverteilungsvorrichtung verbunden sind.This object is achieved in that the heat conductors are designed as tubes, are provided with bores towards the batch space and are connected to a cooling gas distribution device via electrical insulating pieces.

Vorzugsweise ist die Kühlgasverteilungsvorrichtung mit einem Ventilator versehen, der das Kühlgas durch die Heizrohre drückt und aus dem Chargenraum wieder ansaugt.The cooling gas distribution device is preferably provided with a fan which pushes the cooling gas through the heating pipes and sucks it in again from the batch space.

Weiterhin ist es von Vorteil, wenn die Wand der thermischen Isolierung im Bereich der Kühlgasverteilungsvorrichtung mit einer verschließbaren Öffnung versehen ist. Damit kann während der Aufheizperiode der Chargen eine Heizgasströmung unter Umgehung des Wärmetauschers im Ofeninnenraum aufrechterhalten werden.It is also advantageous if the wall of the thermal insulation in the area of the cooling gas distribution device is provided with a closable opening. This means that a heating gas flow can be maintained in the furnace interior bypassing the heat exchanger during the heating period of the batches.

Bei teuren Kühlgasen ist es ebenfalls vorteilhaft, den Ofen mit einer Rückgewinnungsanlage für das Kühlgas zu versehen.In the case of expensive cooling gases, it is also advantageous to provide the furnace with a recovery system for the cooling gas.

Die Abbildungen 1 und 2 zeigen schematisch Längsschnitte durch ein Ausführungsbeispiel eines erfindungsgemäßen Vakuumofens, wobei Abbildung 1 den Ofen in der Aufheizphase bis etwa 750 °C und Abbildung 2 in der Abkühlphase widergibt.Figures 1 and 2 schematically show longitudinal sections through an embodiment of a vacuum oven according to the invention, Figure 1 showing the oven in the heating phase up to about 750 ° C and Figure 2 in the cooling phase.

Der Ofen besteht aus einem zylindrischen Druckgehäuse (1), dessen eine Stirnfläche als Tür (2) ausgebildet ist, über die der Ofen be- und entladen werden kann. Der Chargenraum (3) wird nach außen von einer thermischen Isolierung (4) in Form eines zylindrischen Rohres begrenzt, das aus einem thermischen Isoliermaterial besteht und an den Stirnflächen mit entsprechenden Wänden versehen ist, von denen wenigstens eine Wand (5) bewegbar ist. Diese thermische Isolierung (4) schirmt die Strahlung im Chargenraum (3) nach außen ab, so daß nur geringe Energieverluste entstehen. Innerhalb der thermischen Isolierung (4) sind im Chargenraum (3) ringsum die elektrischen Heizleiter (6) axial angeordnet, die als Heizrohre ausgebildet und zum Chargenraum (3) hin mit Bohrungen (7) versehen sind. Diese Heizrohre (6) haben beispielsweise eine Wandstärke von 1 bis 3 mm und eine lichten Weite von 40 bis 150 mm. Der Durchmesser der Bohrungen (7) wird so bemessen, daß die Summe der Flächen der Bohrungen eines Heizrohres der Fläche der lichten Weite entspricht. Die Heizrohre (6) sind über elektrische Isolierstücke (8) an der Kühlgas­verteilungsvorrichtung (9) befestigt, die mit dem Antriebs­ motor (10) und dem Ventilator (11) an der der Tür (2) gegenüberliegenden Seite im Druckgehäuse untergebracht ist. Die der Kühlgasverteilungsvorrichtung (9) benachbarte Wand der thermischen Isolierung (4) ist mit einer Öffnung (12) versehen, die mit einem Schieber (13) verschlossen und geöffnet werden kann. Zwischen dem Druckgehäuse (1) und der thermischen Isolierung (4) sind die wassergekühlten Wärmeaustauscherrohre (14) untergebracht.The furnace consists of a cylindrical pressure housing (1), one end face of which is designed as a door (2) through which the furnace can be loaded and unloaded. The batch space (3) is delimited on the outside by thermal insulation (4) in the form of a cylindrical tube, which consists of a thermal insulation material and is provided on the end faces with corresponding walls, at least one wall (5) of which is movable. This thermal insulation (4) shields the radiation in the batch space (3) from the outside, so that only slight energy losses occur. Within the thermal insulation (4), the electrical heating conductors (6) are arranged axially in the batch space (3), which are designed as heating pipes and are provided with holes (7) towards the batch space (3). These heating tubes (6) have, for example, a wall thickness of 1 to 3 mm and a clear width of 40 to 150 mm. The diameter of the bores (7) is dimensioned such that the sum of the areas of the bores of a heating tube corresponds to the area of the clear width. The heating pipes (6) are attached to the cooling gas distribution device (9) via electrical insulating pieces (8), which are connected to the drive motor (10) and the fan (11) on the side opposite the door (2) is housed in the pressure housing. The wall of the thermal insulation (4) adjacent to the cooling gas distribution device (9) is provided with an opening (12) which can be closed and opened with a slide (13). The water-cooled heat exchanger tubes (14) are accommodated between the pressure housing (1) and the thermal insulation (4).

Nach dem Beladen des Chargenraums (3) mit beispielsweise Werkzeugen wird dieser mit einem Inertgas geflutet und aufgeheizt. Der Schieber (13) gibt die Öffnung (12) in der thermischen Isolierung frei (Abbildung 1), so daß das Inertgas durch den Ventilator (11) in die Heizrohre (6) gedrückt werden kann, von wo es über die Bohrungen (7), die über die Länge der Heizrohre verteilt sind, in den Chargenraum (3) eindringt und durch die Öffnung (12) in der thermischen Isolierung wieder zum Ventilator (11) zurückgeführt wird. Da das Inertgas über die Heizrohre (6) zugeleitet wird, nimmt es sehr rasch deren Temperatur an, was ein schnelles und homogenes Aufheizen der Charge durch das heiße Gas im Dunkelstrahlungsbereich zur Folge hat. Durch das direkte Anströmen der Charge mit dem heißen Gas wird die Charge gleichmäßig auch im Innern aufgeheizt. Dieser Aufheizungs­vorgang unter Schutzgas wird bis etwa 750 °C genutzt. Bei Härtebehandlungen, bei denen bis etwa 1300 °C erhitzt werden muß, wird dann das Inertgas aus dem Ofen entfernt und die weitere Erwärmung nur durch Wärmestrahlung vorgenommen, die in diesem Temperaturbereich sehr wirksam ist.After loading the batch space (3) with tools, for example, it is flooded with an inert gas and heated. The slide (13) opens the opening (12) in the thermal insulation (Figure 1) so that the inert gas can be pressed by the fan (11) into the heating pipes (6), from where it passes through the holes (7) , which are distributed over the length of the heating pipes, penetrates into the batch space (3) and is returned to the fan (11) through the opening (12) in the thermal insulation. Since the inert gas is fed in via the heating pipes (6), it quickly increases in temperature, which results in the batch being heated quickly and homogeneously by the hot gas in the dark radiation region. Due to the hot gas flowing directly onto the batch, the batch is evenly heated internally. This heating process under protective gas is used up to about 750 ° C. In the case of hardening treatments in which heating has to be carried out up to approximately 1300 ° C., the inert gas is then removed from the furnace and the further heating is carried out only by heat radiation, which is very effective in this temperature range.

Zum Abschrecken der erhitzten Charge wird bei geschlossener Öffnung (12) der Ofen mit kaltem Inertgas mit Überdruck geflutet. Dabei wird die Wand (5) der thermischen Isolierung (4) von dem zylindrischen Rohr abgehoben, so daß ein Spalt entsteht und der Chargenraum (3) mit dem Raum zwischen Druckgehäuse (1) und thermischer Isolierung (4) in Verbindung steht (Abbildung 2). Das Kühlgas wird vom Ventilator (11) über die erkalteten Heizrohre (6) mit großer Geschwindigkeit in den Chargenraum (3) gedrückt, von wo aus es über die Wärmetauscherrohre (14) in die Kühlgasverteilungsvorrichtung (9) zurückfließt und erneut umgewälzt wird. Bei Verwendung entsprechender Inertgase, verbunden mit hohen Gasdrücken und Gasgeschwindigkeiten, erreicht man mit den erfindungsgemäßen Vakuumöfen Abschreck­intensitäten, die mit den in Ölabschreckbädern erreichbaren vergleichbar sind. Dadurch können auch andere Stahltypen als bisher mit einer Gaskühlung abgeschreckt und gehärtet werden.To quench the heated batch, the furnace is flooded with cold inert gas with excess pressure when the opening (12) is closed. The wall (5) of the thermal insulation (4) is lifted off the cylindrical tube, so that a gap is created and the batch space (3) with the space between Pressure housing (1) and thermal insulation (4) is connected (Figure 2). The cooling gas is pressed by the fan (11) over the cooled heating pipes (6) at high speed into the batch space (3), from where it flows back through the heat exchanger pipes (14) into the cooling gas distribution device (9) and is circulated again. If appropriate inert gases are used, combined with high gas pressures and gas velocities, quenching intensities are achieved with the vacuum furnaces according to the invention which are comparable to those achievable in oil quenching baths. As a result, other types of steel than previously can be quenched and hardened with gas cooling.

Die Heizrohre (6), die gleichzeitig als Gaszuleitungsrohre dienen, bestehen bevorzugt aus carbonfaserverstärktem Kohlenstoff. Der elektrisch leitende Querschnitt der Heizrohre, der für die Wärmeerzeugung maßgebend ist, und die für den Gasvolumenstrom maßgeblische innere Weite der Heizrohre müssen dabei aufeinander abgestimmt sein. Die Kombination von Heizelement und Gaszuleitungsrohr bringt eine wesentliche fertigungstechnische Vereinfachung bei der Herstellung dieser Öfen mit sich.The heating tubes (6), which also serve as gas supply tubes, preferably consist of carbon fiber-reinforced carbon. The electrically conductive cross-section of the heating pipes, which is decisive for heat generation, and the internal width of the heating pipes, which is decisive for the gas volume flow, must be coordinated. The combination of the heating element and the gas supply pipe results in a significant simplification of the manufacturing process in the manufacture of these furnaces.

Wird zum Abschrecken ein teures Inertgas verwendet, so ist es vorteilhaft, dieses wieder zurückzugewinnen. Zu diesem Zweck wird das Kühlgas nach Beendigung des Abschreckvorganges mit einem Kompressor aus dem Ofeninnenraum abgepumpt und in einen Hochdruckspeicher gefördert, von wo aus es für weitere Anwendungen zur Verfügung steht.If an expensive inert gas is used for quenching, it is advantageous to recover it. For this purpose, the cooling gas is pumped out of the furnace interior with a compressor after the quenching process and conveyed into a high-pressure accumulator, from where it is available for further applications.

Claims (4)

1. Vakuumofen zur Wärmebehandlung metallischer Werkstücke mit einem zylindrischen Druckgehäuse, in dem ein von axial ausgerichteten Heizleitern umgebener, mit einer thermischen Isolierung versehener Chargenraum und eine Gaskühleinrich­tung angeordnet sind, mit der ein Kühlgas über Düsen durch den Chargenraum und über einen Wärmetauscher geleitet werden kann,
dadurch gekennzeichnet,
daß die Heizleiter (6) als Rohre ausgebildet, zum Chargen­raum hin mit Bohrungen (7) versehen und über elektrische Isolierstücke (8) mit einer Kühlgasverteilungsvorrichtung (9) verbunden sind.
1.Vacuum furnace for the heat treatment of metallic workpieces with a cylindrical pressure housing, in which a batch space surrounded by axially aligned heating conductors and provided with thermal insulation and a gas cooling device are arranged, with which a cooling gas can be passed through nozzles through the batch space and over a heat exchanger,
characterized,
that the heating conductors (6) are designed as tubes, are provided with holes (7) towards the batch space and are connected to a cooling gas distribution device (9) via electrical insulating pieces (8).
2. Vakuumofen nach Anspruch 1,
dadurch gekennzeichnet,
daß die Kühlgasverteilungsvorrichtung (9) mit einem Ventilator (11) versehen ist.
2. Vacuum furnace according to claim 1,
characterized,
that the cooling gas distribution device (9) is provided with a fan (11).
3. Vakuumofen nach Anspruch 1 und 2,
dadurch gekennzeichnet,
daß die Wand der thermischen Isolierung (4) im Bereich der Kühlgasverteilungsvorrichtung (9) mit einer verschließbaren Öffnung (12) versehen ist.
3. Vacuum furnace according to claim 1 and 2,
characterized,
that the wall of the thermal insulation (4) in the area of the cooling gas distribution device (9) is provided with a closable opening (12).
4. Vakuumofen nach Anspruch 1 bis 3,
dadurch gekennzeichnet,
daß er mit einer Rückgewinnungsanlage für das Kühlgas versehen ist.
4. Vacuum furnace according to claim 1 to 3,
characterized,
that it is provided with a recovery system for the cooling gas.
EP88116478A 1987-10-28 1988-10-05 Vacuum furnace for the heat treatment of metallic work-pieces Expired - Lifetime EP0313889B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT88116478T ATE65800T1 (en) 1987-10-28 1988-10-05 VACUUM FURNACE FOR HEAT TREATMENT OF METALLIC WORKPIECES.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3736502 1987-10-28
DE3736502A DE3736502C1 (en) 1987-10-28 1987-10-28 Vacuum furnace for the heat treatment of metallic workpieces

Publications (2)

Publication Number Publication Date
EP0313889A1 true EP0313889A1 (en) 1989-05-03
EP0313889B1 EP0313889B1 (en) 1991-07-31

Family

ID=6339264

Family Applications (1)

Application Number Title Priority Date Filing Date
EP88116478A Expired - Lifetime EP0313889B1 (en) 1987-10-28 1988-10-05 Vacuum furnace for the heat treatment of metallic work-pieces

Country Status (24)

Country Link
US (1) US4869470A (en)
EP (1) EP0313889B1 (en)
JP (1) JPH01142018A (en)
CN (1) CN1015474B (en)
AT (1) ATE65800T1 (en)
AU (1) AU601084B2 (en)
BG (1) BG49829A3 (en)
BR (1) BR8805558A (en)
CA (1) CA1313043C (en)
CS (1) CS276378B6 (en)
DD (1) DD283455A5 (en)
DE (2) DE3736502C1 (en)
DK (1) DK164747C (en)
ES (1) ES2023994B3 (en)
FI (1) FI85386C (en)
HU (1) HU199903B (en)
IL (1) IL87761A (en)
IN (1) IN170643B (en)
NO (1) NO169783C (en)
PL (1) PL156379B1 (en)
PT (1) PT88895B (en)
SU (1) SU1813194A3 (en)
YU (1) YU46575B (en)
ZA (1) ZA886832B (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0344413B1 (en) * 1988-05-31 1993-05-12 Ipsen Industries International Gesellschaft Mit Beschränkter Haftung Furnace for the heat treatment of iron and steel parts
WO1994016278A1 (en) * 1993-01-14 1994-07-21 Seco/Warwick Spólka Z O.O. (Ltd) Vacuum furnace for thermal treatment
EP0727498A1 (en) * 1995-01-23 1996-08-21 ALD Vacuum Technologies GmbH Process and installation for cooling workpieces, in particular for hardening
WO1997000974A1 (en) * 1995-06-22 1997-01-09 Aga Aktiebolag (Publ) A method and an apparatus for the treatment of components by a gas mixture
DE10117987A1 (en) * 2001-04-10 2002-10-31 Ald Vacuum Techn Ag Charging frame used for heat treatment and cooling of metal parts, e.g. roller bearing parts, to be hardened is partially screened over the height of one side
DE102019204869A1 (en) * 2019-04-05 2020-10-08 Audi Ag Quenching device for batch cooling of metal components

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3735186C1 (en) * 1987-10-17 1988-09-15 Ulrich Wingens Vacuum chamber furnace
DE3736501C1 (en) * 1987-10-28 1988-06-09 Degussa Process for the heat treatment of metallic workpieces
DE3910234C1 (en) * 1989-03-30 1990-04-12 Degussa Ag, 6000 Frankfurt, De
DE3933423C2 (en) * 1989-10-06 1994-12-22 Nokia Deutschland Gmbh Device for heat treatment, in particular for LCD substrate plates
JP2656839B2 (en) * 1989-12-15 1997-09-24 神鋼コベルコツール株式会社 Vacuum heat treatment furnace
DE4034085C1 (en) * 1990-10-26 1991-11-14 Degussa Ag, 6000 Frankfurt, De
JPH0569595U (en) * 1992-02-27 1993-09-21 中外炉工業株式会社 Vacuum heat treatment furnace with furnace cooling promotion function
TW366409B (en) * 1997-07-01 1999-08-11 Exxon Production Research Co Process for liquefying a natural gas stream containing at least one freezable component
KR100307996B1 (en) * 1999-06-25 2001-09-24 이용익 The vacuum furnace for quenching of the metallic tools
KR100495267B1 (en) * 2002-10-29 2005-06-16 주식회사제4기한국 Automatic vacuum mold heat treatment apparatus
JP4280981B2 (en) * 2003-06-27 2009-06-17 株式会社Ihi Cooling gas air path switching device for vacuum heat treatment furnace
PL202005B1 (en) * 2004-11-19 2009-05-29 Politechnika & Lstrok Odzka In Hardening heater with closed hydrogen circuit
CN101804489B (en) * 2010-04-23 2011-10-05 山东高唐杰盛半导体科技有限公司 Direct heating type vacuum welding furnace
JP5496828B2 (en) * 2010-08-27 2014-05-21 東京エレクトロン株式会社 Heat treatment equipment
KR101439380B1 (en) * 2012-10-31 2014-09-11 주식회사 사파이어테크놀로지 Heat Treatment Method and Apparatus for Sapphier Single Crystal
CN104180668A (en) * 2013-05-23 2014-12-03 上海颐柏热处理设备有限公司 Device for rapidly cooling heating chamber of box-type heat treatment furnace
CN105296899B (en) * 2015-10-26 2017-08-04 陈芬芬 A kind of guiding device in Al alloy parts heat-treatment furnace
CN106148883A (en) * 2016-08-31 2016-11-23 潍坊丰东热处理有限公司 A kind of well formula nitriding furnace internal cooling system
WO2018099149A1 (en) * 2016-11-29 2018-06-07 张跃 Hot-air oxygen-free brazing system
CN108213639A (en) * 2016-12-12 2018-06-29 张跃 A kind of soldering oven heat-insulating circulating system
CN107164627B (en) * 2017-04-18 2018-10-16 燕山大学 A kind of aluminium-alloy pipe cycle annealing processing equipment stove
DE102017128076A1 (en) 2017-11-28 2019-05-29 Gautschi Engineering Gmbh Batch furnace for annealed material and method for heat treatment of a furnace material
RU2705186C1 (en) * 2019-01-14 2019-11-05 Общество с ограниченной ответственностью "Катод" Method of workpiece cooling in vacuum heating chamber of vacuum furnace and vacuum furnace
KR102014809B1 (en) * 2019-04-26 2019-08-27 이준연 Heat treatment furnace using inert gas
CN111153406B (en) * 2019-12-24 2021-06-04 山东天岳先进科技股份有限公司 Synthetic furnace and synthetic method for preparing silicon carbide powder
CN113847805B (en) * 2021-09-28 2023-07-21 山东交通学院 Superhigh temperature sintering furnace

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1259919B (en) * 1964-06-12 1968-02-01 Harold Norregard Ipsen Furnace for the heat treatment of metal workpieces
DE1919493A1 (en) 1969-04-17 1970-11-05 Ipsen Ind Internat Gmbh Atmospheric vacuum furnace
US4113977A (en) * 1977-08-19 1978-09-12 Brown Boveri Corporation Preheating system with gas recirculation
DE2839807A1 (en) 1978-09-13 1980-03-27 Degussa VACUUM OVEN WITH GAS COOLING DEVICE
DE2844843A1 (en) 1978-10-14 1980-04-30 Ipsen Ind Int Gmbh INDUSTRIAL STOVES FOR HEAT TREATMENT OF METAL WORKPIECES
US4235592A (en) * 1979-08-29 1980-11-25 Autoclave Engineers, Inc. Autoclave furnace with mechanical circulation
EP0163906A2 (en) * 1984-05-08 1985-12-11 Schmetz GmbH & Co. KG Unternehmensverwaltung Method and vacuum furnace for heat treatment a charge

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1617056A (en) * 1926-04-10 1927-02-08 Charles F Kenworthy Inc Furnace

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1259919B (en) * 1964-06-12 1968-02-01 Harold Norregard Ipsen Furnace for the heat treatment of metal workpieces
DE1919493A1 (en) 1969-04-17 1970-11-05 Ipsen Ind Internat Gmbh Atmospheric vacuum furnace
US4113977A (en) * 1977-08-19 1978-09-12 Brown Boveri Corporation Preheating system with gas recirculation
DE2839807A1 (en) 1978-09-13 1980-03-27 Degussa VACUUM OVEN WITH GAS COOLING DEVICE
DE2839807C2 (en) * 1978-09-13 1986-04-17 Degussa Ag, 6000 Frankfurt Vacuum furnace with gas cooling device
DE2844843A1 (en) 1978-10-14 1980-04-30 Ipsen Ind Int Gmbh INDUSTRIAL STOVES FOR HEAT TREATMENT OF METAL WORKPIECES
DE2844843C2 (en) * 1978-10-14 1985-09-12 Ipsen Industries International Gmbh, 4190 Kleve Industrial furnace for the heat treatment of metallic workpieces
US4235592A (en) * 1979-08-29 1980-11-25 Autoclave Engineers, Inc. Autoclave furnace with mechanical circulation
EP0163906A2 (en) * 1984-05-08 1985-12-11 Schmetz GmbH & Co. KG Unternehmensverwaltung Method and vacuum furnace for heat treatment a charge

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0344413B1 (en) * 1988-05-31 1993-05-12 Ipsen Industries International Gesellschaft Mit Beschränkter Haftung Furnace for the heat treatment of iron and steel parts
WO1994016278A1 (en) * 1993-01-14 1994-07-21 Seco/Warwick Spólka Z O.O. (Ltd) Vacuum furnace for thermal treatment
EP0727498A1 (en) * 1995-01-23 1996-08-21 ALD Vacuum Technologies GmbH Process and installation for cooling workpieces, in particular for hardening
WO1997000974A1 (en) * 1995-06-22 1997-01-09 Aga Aktiebolag (Publ) A method and an apparatus for the treatment of components by a gas mixture
US5938866A (en) * 1995-06-22 1999-08-17 Aga Aktiebolag Method and an apparatus for the treatment of components by a gas mixture
DE10117987A1 (en) * 2001-04-10 2002-10-31 Ald Vacuum Techn Ag Charging frame used for heat treatment and cooling of metal parts, e.g. roller bearing parts, to be hardened is partially screened over the height of one side
DE102019204869A1 (en) * 2019-04-05 2020-10-08 Audi Ag Quenching device for batch cooling of metal components

Also Published As

Publication number Publication date
JPH01142018A (en) 1989-06-02
YU46575B (en) 1993-11-16
FI884514A (en) 1989-04-29
FI884514A0 (en) 1988-09-30
FI85386B (en) 1991-12-31
AU2440588A (en) 1989-05-04
PL156379B1 (en) 1992-03-31
ZA886832B (en) 1989-05-30
DE3864008D1 (en) 1991-09-05
BG49829A3 (en) 1992-02-14
AU601084B2 (en) 1990-08-30
BR8805558A (en) 1989-07-11
DE3736502C1 (en) 1988-06-09
NO169783B (en) 1992-04-27
EP0313889B1 (en) 1991-07-31
FI85386C (en) 1992-04-10
DK164747B (en) 1992-08-10
CN1033840A (en) 1989-07-12
DK164747C (en) 1992-12-28
YU193888A (en) 1990-04-30
DK596488A (en) 1989-04-29
DK596488D0 (en) 1988-10-27
NO169783C (en) 1992-08-05
HUT49652A (en) 1989-10-30
ES2023994B3 (en) 1992-02-16
NO884390L (en) 1989-05-02
CS711288A3 (en) 1992-05-13
ATE65800T1 (en) 1991-08-15
US4869470A (en) 1989-09-26
PT88895A (en) 1989-09-14
CN1015474B (en) 1992-02-12
DD283455A5 (en) 1990-10-10
HU199903B (en) 1990-03-28
PT88895B (en) 1997-02-28
IL87761A0 (en) 1989-02-28
NO884390D0 (en) 1988-10-04
CS276378B6 (en) 1992-05-13
CA1313043C (en) 1993-01-26
PL275470A1 (en) 1989-05-02
IN170643B (en) 1992-04-25
SU1813194A3 (en) 1993-04-30
IL87761A (en) 1993-01-31

Similar Documents

Publication Publication Date Title
EP0313889B1 (en) Vacuum furnace for the heat treatment of metallic work-pieces
DE102008012594B4 (en) Vacuum carburizing method and vacuum carburizing device
EP0735149A1 (en) Device for the vacuum heat treatment of metallic articles
DE102013006589A1 (en) Method and device for the thermochemical hardening of workpieces
DE2254769A1 (en) OVEN FOR FLUX-LESS SOLDERING OF ALUMINUM MATERIALS UNDER PROTECTIVE GAS
EP0225501A2 (en) Process and apparatus for treating semiconductor materials
DE2722065A1 (en) OVEN FOR ISOSTATIC HOT PRESSING
EP2330372B1 (en) Electrically heated retort furnace for thermal treatment of metallic workpieces
EP1236810A1 (en) Process and apparatus for the partial thermochemical treatment of metallic workpieces
EP0535319B1 (en) Vacuum furnace for plasma carburization of metallic workpieces
EP0163906B1 (en) Method and vacuum furnace for heat treatment a charge
DE2812888A1 (en) HIGH TEMPERATURE AUTOCLAVE
DE4429340C2 (en) Crucibles for inductive melting or overheating of metals, alloys or other electrically conductive materials
DE4007123C2 (en)
DE19628383A1 (en) Furnace for heat treatment of batches of metal workpieces - with a heating chamber which can be isolated from the pressure and suction chambers of the cooling gas fan
EP1294512B1 (en) Method and device for sintering aluminium based sintered parts
EP0829554B2 (en) Low pressure carburising device with a plurality of sequentially arranged chambers
DE3209245A1 (en) TURNING OVENS
DE3205501A1 (en) Vacuum furnace for dewaxing and sintering hard metals
DE10030514C1 (en) Sintering aluminum-based sintered parts comprises removing binder from sintered parts, bringing to sintering temperature in inert gas atmosphere and holding at this temperature, and cooling in controlled manner
EP1627696B1 (en) Device and method for heating extrusion dies before mounting them into an extrusion apparatus
EP0189759A1 (en) Method and apparatus for heat treating work pieces
DE2158734C3 (en) Oven for coating particles at high temperature
DE19924696C2 (en) Oven with high cooling rate
WO2020058195A1 (en) System and method for sintering components

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19881005

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH DE ES FR GB IT LI LU NL SE

17Q First examination report despatched

Effective date: 19900928

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE ES FR GB IT LI LU NL SE

REF Corresponds to:

Ref document number: 65800

Country of ref document: AT

Date of ref document: 19910815

Kind code of ref document: T

ITF It: translation for a ep patent filed

Owner name: JACOBACCI & PERANI S.P.A.

ET Fr: translation filed
REF Corresponds to:

Ref document number: 3864008

Country of ref document: DE

Date of ref document: 19910905

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)
REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2023994

Country of ref document: ES

Kind code of ref document: B3

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

26 Opposition filed

Opponent name: IPSEN INDUSTRIES INTERNATIONAL GMBH

Effective date: 19920227

NLR1 Nl: opposition has been filed with the epo

Opponent name: IPSEN INDUSTRIES INTERNATIONAL GMBH.

EPTA Lu: last paid annual fee
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: LU

Payment date: 19940901

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 19940922

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 19940927

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 19941011

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 19941013

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 19941014

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 19941028

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 19941031

Year of fee payment: 7

EAL Se: european patent in force in sweden

Ref document number: 88116478.4

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 19950929

Year of fee payment: 8

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19951005

Ref country code: GB

Effective date: 19951005

Ref country code: AT

Effective date: 19951005

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19951006

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Effective date: 19951031

Ref country code: CH

Effective date: 19951031

Ref country code: BE

Effective date: 19951031

PLBN Opposition rejected

Free format text: ORIGINAL CODE: 0009273

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: OPPOSITION REJECTED

27O Opposition rejected

Effective date: 19951005

NLR2 Nl: decision of opposition
BERE Be: lapsed

Owner name: DEGUSSA A.G.

Effective date: 19951031

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Effective date: 19960501

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 19951005

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Effective date: 19960628

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

Effective date: 19960501

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Effective date: 19961006

EUG Se: european patent has lapsed

Ref document number: 88116478.4

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 19990503

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20050425

Year of fee payment: 17

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED.

Effective date: 20051005

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20060503