EP0295153B1 - Faserverstärkter Zementdachziegel und Verfahren zu dessen Herstellung - Google Patents

Faserverstärkter Zementdachziegel und Verfahren zu dessen Herstellung Download PDF

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Publication number
EP0295153B1
EP0295153B1 EP19880305401 EP88305401A EP0295153B1 EP 0295153 B1 EP0295153 B1 EP 0295153B1 EP 19880305401 EP19880305401 EP 19880305401 EP 88305401 A EP88305401 A EP 88305401A EP 0295153 B1 EP0295153 B1 EP 0295153B1
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EP
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Prior art keywords
weight
parts
cement
tiles
tile
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Expired - Lifetime
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EP19880305401
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English (en)
French (fr)
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EP0295153A1 (de
Inventor
Masataka Kamitani
Takeshi Kawaguchi
Yasuo Inukai
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Sekisui Chemical Co Ltd
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Sekisui Chemical Co Ltd
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Priority claimed from JP7157988A external-priority patent/JPH01242446A/ja
Priority claimed from JP7220588A external-priority patent/JPS6477503A/ja
Application filed by Sekisui Chemical Co Ltd filed Critical Sekisui Chemical Co Ltd
Publication of EP0295153A1 publication Critical patent/EP0295153A1/de
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00—Producing shaped prefabricated articles from the material
    • B28B1/52—Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00—Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D3/00—Roof covering by making use of flat or curved slabs or stiff sheets
    • E04D3/24—Roof covering by making use of flat or curved slabs or stiff sheets with special cross-section, e.g. with corrugations on both sides, with ribs, flanges, or the like
    • E04D3/26—Roof covering by making use of flat or curved slabs or stiff sheets with special cross-section, e.g. with corrugations on both sides, with ribs, flanges, or the like of concrete or ceramics

Definitions

  • This invention relates to a tile that is made of cement and reinforced with fibers, for which the reinforcing material is made of synthetic fibers.
  • Tiles generally have as their main ingredients clay and cement, and are installed one after another along the slope of a roof from the eaves to the ridge. At that time, the edge toward the ridge of a tile that is placed at the edge of the eaves has placed on the edge toward the eaves of the next tile. Each tile is supported by the attachment of the edge of the tile toward the ridge to the underlying building material such as flat boards, roofing, or the like, and by the placement of the edge of the tile toward the eaves on the top of the edge toward the ridge of the next tile.
  • each tile toward the eaves is placed in a higher position with respect to the building material under the tiles than the edge of that tile toward the ridge, resulting in a space between the underneath surface of the tile and said building materials under the tiles. For that reason, when a load is placed on the central part of tiles installed in such a way on a roof, bending stress affects this central part, and gives rise to the danger of breakage of the tiles.
  • the entire body of the tile can be made thick.
  • the weight of the tile itself increases, which makes the tile costly.
  • the work load at the time of the installation of the tiles on the roof is increased, and there is an additional disadvantage that the durability of the building itself is decreased.
  • asbestos fibers have been mixed in as a reinforcing material.
  • a mixture made of cement, asbestos, pulp, and the like in water is used to make a form in a cement mold like the process of making hand-made paper, and this is formed with pressure in a liquid roller, etc., in a so-called paper-making process, by which the hills and valleys are formed with approximately the same thickness.
  • inorganic fibers such as glass fibers, inorganic fibers such as potassium titanate fibers, etc., organic fibers such as vinylon, acrylonitrile, polypropylene, polyamide, etc., or metallic fibers such as steel fibers, etc.
  • tiles made of a cement in which short fibers of polyester, glass, etc., as reinforcing materials are disclosed in Japanese Patent Publication No. 57-9009.
  • the tiles are light-weight, so their production is made easier, and another advantage is the high strength conferred.
  • the hardness is slightly decreased, and as mentioned above, when the tiles are installed on a roof and there is a load placed on the central part of the tiles, the tiles are largely deformed, and stress accumulates in the centre part of the tiles, bringing about the possibility that the tiles will break.
  • tiles with this kind of shape are generally made with the hills and valleys of approximately the same thickness, so that when a large load is placed on the valleys, there is the disadvantage of the valleys being easily broken.
  • FR-A-1010876 discloses a wave-shaped tile having parallelepiped shaped stops on respectively the upper surface and undersurface of the tile.
  • FR-A-2 286 254 discloses a wave-shaped tile made of fibre-reinforced cement in which the valleys of the tile are thicker than the alternating hills.
  • Japanese Laid-Open Patent Application 58-213666 discloses a molding method that gives tiles made of cement and reinforced with fibres, wherein an inorganic filler and synthetic fibres are mixed with cement and 15-30 parts by weight of water per 100 parts by weight of the cement are added and kneaded by a kneader in which the surfaces of the fibres are scratched, after which the amount of water needed for the formation of the particular shape is added, and molding is accomplished by, for example, the use of a press. Kneaders that have sharp protuberances in the kneading chamber, pressure kneaders, pulpers, or the like can be used.
  • the synthetic fibers may come to be twisted around each other, and there is the chance of their forming a fiber ball.
  • the chance of synthetic fibers becoming twisted around each other is greater than for asbestos fibers.
  • the tile made of cement reinforced with fibers of this invention which overcomes the above-discussed and numerous other disadvantages and deficiencies of the prior art, has, per 100 parts by weight of cement, 0.3-7 parts by weight of synthetic fibres as reinforcing materials, and 200 parts by weight or less of an inorganic filler, wherein said tile has a wave-shape with alternating hills and valleys, which run in the direction of the slope of the roof when it is installed on the building material of the roof that is under the tiles of a sloping roof, the valley of the tile being provided on its undersurface, except for the edges of the hills and valleys, with at least one supporting member having a length y along the direction of the slope of the said building material under the tile, a length x at right angles to the said direction of the slope, and a maximum height h such that y 3 3 mm, x 3 3 mm, and h 60 mm.
  • the method for the manufacture of tiles made of cement reinforced with fibres of this invention comprises mixing 200 parts by weight of an inorganic filler with an aqueous solution that has been or is being prepared by dissolving 1 part by weight or less of a water-soluble high polymer, if needed, into 30 parts by weight or more of water; mixing by agitation the mixture with 0.3-7 parts by weight of synthetic fibres; mixing by agitation the mixture with 100 parts by weight of cement; putting the mixture into a mold that can be opened and closed; and then molding the mixture at a rate of pressure of 0.3 mm/sec or more, resulting in the desired tile reinforced with fibres.
  • the invention described herein makes possible the objectives of (1) providing light-weight tiles with improved strength by which the tiles are not readily broken even when a weight is put thereon; and a method for the manufacture of tiles made of cement reinforced with fibres by which synthetic fibres that function as a reinforcing material are not damaged and cut, and accordingly are uniformly dispersed into the cement matrix.
  • cements that can be used for the tiles of this invention Portland cement, alumina cement, blast furnace cement, and other hydraulic cements can be used.
  • synthetic fibers there are vinylon, polyamide, polyester, polypropylene, and other fibers, the thickness of which can be 2-40 deniers, and the length of which can be 2-30 mm.
  • the amount of synthetic fibers to be added is 0.3-7 parts by weight. If the amount of synthetic fibers added is too small, the effect of reinforcement will not appear, and if the amount of synthetic fibers added is too large, the distribution of the said fibers will become poor, which decreases the flow during the time of molding, so that the effect of reinforcement by the said fibers will not appear.
  • vinylon fibers are especially suitable because their flow characteristics are good, giving good formability.
  • silica As inorganic filler, silica, river sand, fly ash, silica flour, bentonite, sepiolite, wollastonite, calcium carbonate, mica, and so on can be listed.
  • a water-soluble polymer is used, if necessary.
  • the addition of the said water-soluble polymer is not necessarily required.
  • water-soluble polymer methyl cellulose, carboxymethylcellulose, polyvinyl alcohol, hydroxyethylcellulose, polyacrylic acid, etc.
  • the said water-soluble polymers act to disperse aggregates and synthetic fibers such as vinylon fibers and the like uniformly throughout the cement, and can be added to prevent the formation of fiber balls made by the precipitation of aggregates or by the mutual twisting together of the said fibers, for which purpose 1 part by weight or less can be added.
  • the method of mixture by agitation can be used.
  • agitation blades are not used, but instead, agitation involves the use of an apparatus to which is attached a vessel made of rubber that is pliable and is in the form of a disc-shaped agitating platform; the direction of the inclination of the agitating platform and the angle of the inclination can be continuously changed, so that the rubber vessel in which the materials to be mixed are placed is deformed and agitated, mixing them.
  • the Omuni mixer of the Chiyoda Giken Kogyo Co. can be used as the apparatus for mixture by agitation.
  • the tile of this invention is made from, for example, 100 parts by weight of cement, 30 parts by weight of fly ash, 2 parts by weight of vinylon fibers as the synthetic fibers, and 40 parts by weight of water, which are mixed to produce a cement composition that is reinforced with fiber, and the desired shape is formed by the use of a water-removing press on the said fibre-reinforced cement composition, after which the resulting molded product is heated at 60 ° C and at the relative humidity of 95% in a steam room for 24 hours for steam curing.
  • FIG 1 shows a tile of this invention.
  • This tile 10 is formed in a wave shape so that when it is installed on a roof, there are alternate hills 14 and valleys 15 that follow the direction of the slope of the roof; in cross-section, the shape of each hill 14 and each valley 15 is a rectangle.
  • the eaves-side edge 12 of the tile 10 is placed on the ridge-side edge of the next tile 10.
  • the said tile 10 has at its edge that is placed on the eaves side at the time of installation on the roof a downward-projecting part 13 that projects downward (in Figure 1, it is shown projecting upward), which is provided continuously along each hill 14 and each valley 15.
  • a downward-projecting part 13 that projects downward (in Figure 1, it is shown projecting upward), which is provided continuously along each hill 14 and each valley 15.
  • the groove 16 is provided continuously along each hill 14 and each valley 15.
  • an upward-projecting part 17 that projects upward.
  • the upward-projecting part 17 is provided continuously along each hill 14 and each valley 15, and is fitted with the groove 16 mentioned above along the edge of the tile toward the eaves.
  • On the upper side of the edge of the tile toward the ridge there is a groove 18 that is parallel at a fixed distance from the said projection 16.
  • the groove 18 is provided continuously along each hill 14 and each valley 15, and the projection 13 that is established along the eaves side, as mentioned above, fits into the said groove 18.
  • each valley 15 there is a pair of supporting members 20 and 21 that project downward.
  • the supporting members 20 and 21 are both in the shape of a right-angled parallelepiped, and one of the supporting members, 20, is placed near the edge of the tile toward the eaves, and the other supporting member, 21, is placed near the edge of the tile toward the ridge.
  • the position of the supporting members 20 and 21, at the time of roofing corresponds to the main roof crosspiece that is under the building materials 19 of the roof that are under the tiles.
  • each of the supporting members 20 and 21 is set so that the supporting members 20 and 21 can touch or can have a space from the building materials 19 when the tiles 10 are installed on the top of the building materials 19 under the tiles on a roof, whereby the ridge-side edge of the tile 10 comes into contact with the building material 19; the projection 13 on the eaves-side edge of the tile fits into the groove 18 on the ridge-side edge of the next tile that is placed toward the eaves; and moreover, the projection 17 on the ridge-side edge of the tile is fit into the groove 16 on the eaves-side edge of the next tile.
  • the lower surfaces of the supporting members 20 and 21 have the same slope as the building materials 19 placed under the tile 10.
  • the height of the supporting member 20 on the eaves side of the tile is greater than the height of the supporting member 21 on the ridge side.
  • the tile of this kind of shape is manufactured from a cement reinforced by fibres in which there are, per 100 parts of cement by weight, 0.2-7 parts by weight of synthetic fibres as reinforcing material, and 200 parts by weight or less of an inorganic filler.
  • the supporting members 20 and 21 are formed of the same material as the valleys and are made in one piece with the said valleys.
  • the supporting members 20 and 21 for the tiles 10 undergo the same compressive stress as the ridge-side edge of a tile 10 when the ridge-side edge of the tile 10 installed at the ridge side is placed on the eaves-side edge of the next tile 10.
  • cement that is reinforced with fibres has excellent strength against compression, but because the deformation of the tile 10 itself when a load is put on the said tile 10 must be minimized, the measurement y of the direction of the slope of the roof of the supporting members 20 and 21 should be 3 mm or more, and the measurement x at right angles to that direction should be 3 mm or more, with the maximum height h being preferably 60 mm or less.
  • both the measurement y of the supporting members 20 and 21 in the direction of the roof slope and the measurement x in the direction at right angles to that direction are smaller than 3 mm, then when the tile 10 is produced from a cement composition reinforced with fibres by use of press moulding, not every part of the mold for the molding of the supporting members 20 and 21 is filled satisfactorily with the composition, and gaps in the supporting members 20 and 21 to be molded may occur. Sufficient resistance to loading cannot be obtained with the supporting members that have these kinds of gaps. If the maximum height h of the supporting members 20 and 21 exceeds 60 mm, in the same way, not every part of the mold for the molding of the supporting stands is filled satisfactorily with the composition, and sufficient resistance to loading may not be obtained.
  • the cement composition reinforced with fibres can fill every part of the mold for the molding of the supporting stands, and the deformation of the supporting members 20 and 21 in response to the loading of the tile 10 can be minimized.
  • the measurement of the maximum height h of the supporting members 20 and 21 is 2 mm or less, the deformation in response to a load on the tile 10 is large, which is not desirable.
  • the shapes of the supporting members 20 and 21 are not limited to right-angled parallelepipeds; as shown in Figure 3, they can be elliptical columns. In this case as well, it is preferable that the supporting members 20 and 21 fulfil the conditions for measurements described above.
  • the space between the undersurface of the valleys 15 and the building materials under the tile is smaller than the space between the undersurface of the hills 14 and the building materials under the tile, by the provision of a supporting member on the undersurface of the said valley 15, it is possible to make the measurements of the supporting stand small, so that the increase in the weight of the entire tile becomes small and economical.
  • the strength of the tile is yet more increased, and if the upper surface of the tile is stepped on by a person, there is no danger of breakage.
  • each valley was provided on its underside with a pair of supporting members 20 and 21 of elliptical shape, giving a tile 10 made of cement reinforced with fibres.
  • the supporting member 20 that was provided on the eaves-side edge of the tile had a measurement y in the direction of the slope of the roof of 15 mm, a measurement x in the direction at right angles to that direction of 10 mm, and a measurement h for the maximum height of 15 mm; for the supporting member 21 on the ridge-side edge, these measurements were 10 mm, 8 mm, and 7 mm, respectively.
  • Some of the tiles 10 made of cement reinforced with fibers that were formed in Section 2 above were cured by being placed in water for 14 days. Then they were installed on a roof, and a person bearing a weight walked on the tiles. The weight required for the tiles to break when stepped on by a person bearing a weight was measured; it was 160 kg.
  • composition described in Section 1 above was molded by a water-removing press to form tiles made of cement reinforced with fibers in the same shape as in Example 1.
  • composition described in Section 1 above was molded by a water-removing press to form tiles made of cement reinforced with fibers in the same shape as in Example 1.
  • composition described in Section 1 above was molded by a water-removing press to form the tiles 10 made of cement reinforced with fibres shown in Figure 4, with single supporting member 22 in the shape of right-angled parallelepipeds on the undersurfaces of valleys 15.
  • the measurements of the supporting member 22 were: y, the measurement in the direction of the slope of the roof, 300 mm; x, the measurement in the direction at right angles to this direction, 15 mm, and the maximum height h, 7 mm.
  • composition described in Section 1 above was molded by a water-removing press as in Example 4 to give tiles 10 made of cement reinforced with vinylon fibres, which tiles had a supporting member 22 in the shape of a right-angled parallelepiped.
  • composition described in Section 1 above was molded by a water-removing press to form tiles made of cement reinforced with fibres in the same shape as in Example 4, with one supporting member 22 in the shape of a right-angled parallelepiped, giving tiles 10 made of cement reinforced with vinylon fibres.
  • composition obtained in Section 1 above was molded by a water-removing press, and tiles made of cement reinforced with fibers were formed into a wave shape in which there were absolutely no supports formed on the undersurface.
  • composition described in Section 1 above was molded by a water-removing press to form tiles made of cement reinforced with fibers in the same shape as in Comparative Example 1.
  • composition described in Section 1 above was molded by a water-removing press to form tiles made of cement reinforced with fibers in the same shape as in Comparative Example 1.
  • compositions of the examples and the comparative examples given above are shown in Table 1, as are the shapes, measurements, numbers, and filling condition by the compositions of the supporting members, together with the results of the weight-bearing test.
  • the mean diameter of the inorganic filler particles is more than 100 /1.m, it is difficult for the particles to enter in the fiber spaces between the synthetic fibers, and there is thus a tendency for the particles to aggregate, so it is preferable for the mean diameter of particles of the inorganic filler to be 100 ⁇ m or less. If the amount of synthetic fibers added is less than 0.3 part by weight, sufficient strength is not obtained at the time of molding of the tiles. If the amount of synthetic fibers added is more than 7 parts by weight, the dispersion of the fibers becomes poor, and flowability is also poor at the time of molding of the tiles.
  • the mixture obtained above is put into a mold that can be opened and closed, and the desired shape is formed by the application of pressure.
  • the mixture with 30 parts by weight of water or more readily undergoes the separation out of water. For this reason, it is necessary that the molding of the tile be completed before the separation out of water occurs. If the rate of pressure of the mixture in the mold is 0.3 mm/sec or more, there is no separation out of the water, and the desired shape can be made perfectly, as the entire mold is rapidly filled with the mixture.
  • a certain amount of water is removed from the molded product within the mold so that the molded product can keep its shape, after which it is removed from the mold, and cured and hardened by the well-known method. In this way, a tile of the desired shape is obtained.
  • the synthetic fibers are not damaged or broken, and uniform mixing can be attained.
  • the fine particles of cement can easily be dispersed in the spaces between the inorganic filler and the synthetic fibers.
  • 0 means that the surface was glossy, with fibers being uniformly dispersed
  • A means that there was uneveness of the surface, with some fibers not being uniformly dispersed
  • X means that the surface was uneven, and the fibers were dispersed without uniformity.
  • the strength against being bent was measured according to the methods of JIS 1048U.
  • Example 8 A test was done of the same way as in Example 8 except that instead of the fly ash, bentonite (mean diameter, 100 ⁇ m) was used. The results are shown in Table 3.
  • Example 7 A test was done in the same way as in Example 7 except that per 150 parts by weight of water, 1.0 part by weight of methyl cellulose, 200 parts by weight of fly ash (mean particle diameter, 100 ⁇ m), and 7.0 parts by weight of vinylon fiber were added, and the whole was mixed by agitation. The results are shown in Table 3.
  • Example 7 A test was done in the same way as in Example 7 except that per 30 parts of water, methyl cellulose was not added, but 30 parts by weight of fly ash, 10 parts by weight of cement, and 0.5 part by weight of vinylon fibers were added and mixed by agitation; to this mixture, 90 parts by weight of the cement was added, and mixing by agitation was done once more.
  • Table 3 The results are shown in Table 3.
  • Example 7 A test was done in the same way as in Example 7 except that per 40 parts of water, methyl cellulose was not added, but 20 parts by weight of fly ash (mean particle diameter, 100 /1.m), 10 parts by weight of cement, and 2.2 parts by weight of vinylon fibers were added and mixed by agitation; to this mixture, 20 parts by weight of fly ash (mean particle diameter, 100 ⁇ m) and 90 parts by weight of cement were added, and mixing by agitation was done once more. The results are shown in Table 3.
  • Example 7 A test was done in the same way as in Example 7 except that per 40 parts of water, methyl cellulose was not added, but 30 parts by weight of silica (mean particle diameter, 100 ⁇ m), 10 parts by weight of cement, and 1.2 parts by weight of vinylon fibers were added and mixed by agitation; to this mixture, 1.0 part by weight of vinylon fibers and 100 parts by weight of cement were added, and mixing by agitation was done once more. The results are shown in Table 3.
  • Example 7 A test was done in the same way as in Example 7 except that the amount of vinylon fibers used was 0.2 part by weight. The results are shown in Table 3.
  • Example 7 A test was done in the same way as in Example 7 except that per 150 parts of water by weight, 0.2 part by weight of methyl cellulose and 200 parts by weight of fly ash (mean particle diameter, 100 ⁇ m) were added and mixing was done by agitation. The results are shown in Table 3.
  • Example 7 A test was done in the same way as in Example 7 except that per 150 parts by weight of water, 0.2 part by weight of methyl cellulose, 220 parts by weight of fly ash (mean particle diameter, 100 ⁇ m), and 2.0 parts by weight of vinylon fibers were added and mixed by agitation; to this mixture, 100 parts by weight of cement was added and mixing by agitation was done once more.
  • Table 3 The results are shown in Table 3.
  • Example 8 A test was done in the same way as in Example 8 except that instead of mixing being done by agitation, a mixer with blades was used. The results are shown in Table 3.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Press-Shaping Or Shaping Using Conveyers (AREA)

Claims (2)

1. Ziegel (10) zur Verwendung als Dachmaterial auf einem im wesentlichen ebenen Schrägdach, der faserverstärkten Zement mit 0,3 bis 7 Gewichtsteilen synthetischer Fasern und bis zu 200 Gewichtsteilen eines anorganischen Füllstoffs pro 100 Gewichtsteile Zement umfaßt, wobei der Ziegel in einem wellenartigen Muster geformt ist und an seiner Unterseite in einer Richtung verlaufende Erhebungen (14) und Vertiefungen (15) aufweist, und
mindestens ein auf der Unterseite jeder Vertiefung (15) angeordnetes, zur Aufnahme von Last ausgebildetes Stützelement (20, 21) mit einer Höhe h besitzt, wobei die Oberfläche des oder jedes der Stützelemente eine Schräge aufweist, welche die gleiche wie die Schräge des Dachs ist, die Höhe des Teils des Stützelements, der in Richtung eines niedrigeren Teils des Dachs weist, größer ist als die Höhe des Teils des Stützelements, der in Richtung eines höheren Teils des Dachs weist, und das oder jedes der Stützelemente eine solche parallel zur Schräge des Daches verlaufende Länge y, im rechten Winkel zur Schräge am Dach entlang verlaufende Länge x und maximale Höhe h aufweist, daß y 3 3 mm, x 3 3 mm und h 60 mm sind.
2. Verfahren zur Herstellung eines Ziegels gemäß Anspruch 1, bei dem 200 Gewichtsteile eines anorganischen Füllstoffs und bis zu 100 Gewichtsteile Zement mit einer wäßrigen Lösung gemischt werden, die hergestellt worden ist oder wird, indem 1 Gewichtsteil oder weniger eines wasserlöslichen Hochpolymeren, falls nötig, in 30 Gewichtsteilen oder mehr Wasser gelöst werden, die erhaltene Mischung mit 0,3 bis 7 Gewichtsteilen synthetischer Fasern unter Rühren gemischt wird, die erhaltene Mischung mit 100 Gewichtsteilen Zement oder dem restlichen Zement unter Rühren gemischt wird, die Mischung in eine Form gegeben wird, die geöffnet und geschlossen werden kann, und dann mit einer Drückgeschwindigkeit von 0,3 mm/s oder mehr geformt wird, wobei sich der gewünschte mit Fasern verstärkte Ziegel ergibt.
EP19880305401 1987-06-12 1988-06-13 Faserverstärkter Zementdachziegel und Verfahren zu dessen Herstellung Expired - Lifetime EP0295153B1 (de)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP14773787 1987-06-12
JP147737/87 1987-06-12
JP7157988A JPH01242446A (ja) 1988-03-24 1988-03-24 ビニロン繊維補強セメント瓦
JP71579/87 1988-03-24
JP7220588A JPS6477503A (en) 1987-06-12 1988-03-25 Manufacture of fiber reinforced cement molded body
JP72205/87 1988-03-25

Publications (2)

Publication Number Publication Date
EP0295153A1 EP0295153A1 (de) 1988-12-14
EP0295153B1 true EP0295153B1 (de) 1992-04-22

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2735415B1 (fr) * 1995-06-15 1997-07-18 Mci Sa Procede de fabrication d'un article en forme de plaque et article fabrique
AU9327501A (en) * 2000-09-11 2002-03-26 Chiron Corp Quinolinone derivatives
EP3067178A4 (de) 2013-11-06 2017-08-09 Kuraray Co., Ltd. Betonfliese und formmasse dafür

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2672670A (en) * 1949-02-18 1954-03-23 Eugene T Rhodes Method of making building material
FR1010876A (fr) * 1950-02-06 1952-06-16 Nouvelles tuiles canal
US3224205A (en) * 1962-08-29 1965-12-21 Johns Manville Asbestos-cement structural sheet
FR1371646A (fr) * 1963-10-16 1964-09-04 Braas & Co Gmbh Perfectionnements apportés aux tuiles mécaniques à emboîtements
FR2217937A5 (en) * 1973-02-14 1974-09-06 Frapart Jacques Monolithic multilayer composite construction panels - with enhanced aggregate bonding and surface impermeability
CH587397A5 (de) * 1974-09-25 1977-04-29 Marchioli Giorgio
NZ185576A (en) * 1976-11-05 1981-12-15 Kubota Ltd Preparing cement product
DE2743934A1 (de) * 1977-09-29 1979-04-12 Dante A Raponi Abbindbare zementmasse
US4414030A (en) * 1981-11-25 1983-11-08 Restrepo Jose M Fiber-reinforced cement, and process
GB8301450D0 (en) * 1983-01-19 1983-02-23 Ici Plc Fibre-reinforced cementitious compositions
GB2163421B (en) * 1984-08-24 1988-06-22 Marley Lightweight concrete roof tiles

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CA1300918C (en) 1992-05-19
DE3870317D1 (de) 1992-05-27
EP0295153A1 (de) 1988-12-14

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