CA1300918C - Cement tile reinforced with fibers and a method for the production of the same - Google Patents
Cement tile reinforced with fibers and a method for the production of the sameInfo
- Publication number
- CA1300918C CA1300918C CA000569226A CA569226A CA1300918C CA 1300918 C CA1300918 C CA 1300918C CA 000569226 A CA000569226 A CA 000569226A CA 569226 A CA569226 A CA 569226A CA 1300918 C CA1300918 C CA 1300918C
- Authority
- CA
- Canada
- Prior art keywords
- weight
- tile
- roof
- parts
- fibers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/52—Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B3/00—Producing shaped articles from the material by using presses; Presses specially adapted therefor
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
- E04D3/00—Roof covering by making use of flat or curved slabs or stiff sheets
- E04D3/24—Roof covering by making use of flat or curved slabs or stiff sheets with special cross-section, e.g. with corrugations on both sides, with ribs, flanges, or the like
- E04D3/26—Roof covering by making use of flat or curved slabs or stiff sheets with special cross-section, e.g. with corrugations on both sides, with ribs, flanges, or the like of concrete or ceramics
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Press-Shaping Or Shaping Using Conveyers (AREA)
Abstract
ABSTRACT OF THE DISCLOSURE
A tile made of cement reinforced with fibers having, per 100 parts by weight of cement, 0.3-7 parts by weight of synthetic fibers as reinforcing materials, and 200 parts by weight or less of an inorganic filler, wherein the tile is in the shape of a wave with alternating hills and valleys, which run in the direction of the slope of the roof when it is installed on the building material of the roof that is under the tiles of a sloping roof, the valley of the tile being 5-30% thicker than the hill, and/or the undersurface, except for the edges of the hills and valleys, being provided with a supporting stand, and a method for the manufacture of the said tile.
A tile made of cement reinforced with fibers having, per 100 parts by weight of cement, 0.3-7 parts by weight of synthetic fibers as reinforcing materials, and 200 parts by weight or less of an inorganic filler, wherein the tile is in the shape of a wave with alternating hills and valleys, which run in the direction of the slope of the roof when it is installed on the building material of the roof that is under the tiles of a sloping roof, the valley of the tile being 5-30% thicker than the hill, and/or the undersurface, except for the edges of the hills and valleys, being provided with a supporting stand, and a method for the manufacture of the said tile.
Description
1300gl8 BACK~RO~ND OF T~E INVENTION
1. Field of the invention:
This invention relates to a tile that is made of cement and reinforced with fibers, for which the reinforcing material is made of synthetic fibers.
1. Field of the invention:
This invention relates to a tile that is made of cement and reinforced with fibers, for which the reinforcing material is made of synthetic fibers.
2. Description of the prior art:
Tiles generally have as their main ingredients clay and cement, and are installed one after another along the slope of a roof from the eaves to the ridge. At that time, the ridge-facing edge of a tile that is placed at the edge of the eaves has placed on it the eaves-facing edge of the next tile. Each tile is supported by the attachment of the edge of the tile toward the ridge to the underlying building material such as flat boards, roofing, or the like, and by the placement of the edge of the tile toward the eaves on the top of the edge toward the ridge of the next tile. Thus, the edge of each tile toward the eaves ie placed in a higher position with respect to the building material under the tiles than the edge of that tile toward the ridge, resulting in a space between the underneath surface of the tile and said building materials under the tiles. For that reason, when a load is placed on the central part of tiles installed in such a way on a roof, bending stress affects this central part, and gives rise to the danger of breakage of the tiles.
In order to prevent this kind of bending stress, the entire body of the tile can be made thick. However, if the entire body of the tile is made thick, ~r ~3(~ B
the weight of the tile itself increases, which makes the tile costly. Moreover, the work load at the time of the installation of the tiles on the roof is increased, and there is an additional disadvantage that the durability of the building itself is decreased.
For these reasons, in order to increase the strength of the tiles, and also to increase the ease of the operation of the formation of the tiles, asbestos fibers have been mixed in as a reinforcing material.
For example, in wave-shaped tiles with alternating hills and valleys, a mixture made of cement, asbestos, pulp, and the like in water is used to make a form in a cement mold like the process of making hand-made paper, and this is formed with pressure in a liguid roller, etc., in a so-called paper-making process, by which the hills and valleys are formed wlth approximately the same thickness.
However, in recent years, it has been found that asbestos fibers are a carcinogenic material, and so there are problems with the use of asbestos fibers.
For that reason, in place of asbestos fibers, inorganic fibers such as glass fibers, inorganic fibers such as potassium titanate fibers, etc., organic fibers such as vinylon, acrylonitrile, polypropylene, polyamide, etc., or metallic fibers such as steel fibers, etc., have been developed for the use in tiles made of cement as reinforcing materials. For example, tiles made of a cement in which short fibers of polyester, glass, etc., as reinforcing materials are disclosed in Japanese Patent Publication No. 57-9009.
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In this kind of tile made from cement reinforced with fibers, the tiles are light-weight, so their production is made easier, and another advantage is the high strength conferred. However, with this kind of tile, the hardness is slightly decreased, and as mentioned above, when the tiles are installed on a roof and there is a load placed on the central part of the tiles, the tiles are largely deformed, and stress accumulates in the center part of the tiles, bringing about the possibility that the tiles will break.
Also, in a wave-shaped tile formed with alternating hills and valleys, when the tile is installed with its hills and valleys running along the slope of a roof, and when a load is placed on the upper surface of the tile, it is known that more force is exerted on the valleys than on the hills.
Tiles with this kind ~f shape are generally made with the hills and valleys of approximately the same thickness, so that when a large load is placed on the valleys, there is the disadvantage of the valleys being easily broken.
Japanese Laid-Open Patent Application 58-213666 discloses a molding method that gives tiles made of cement and reinforced with fibers, wherein an inorganic filler and synthetic fibers are mixed with cement and 15-30 parts by weight of water per 100 parts by weight of the cement are added and kneaded by a kneader in which the surfaces of the fibers are roughened, after which the amount of water needed for the formation of the particular shape is added, and molding is accomplished by, for example, the use of a press.
Kneaders that have sharp protuberances in the kneading 13V~918 chamber, pressure kneaders, pulpers, or the like can be used.
However, with this kind of method, the synthetic fibers may come to be twisted around each other, and there is the chance of their forming a fiber ball. In general, the chance of synthetic fibers becoming twisted around each other is greater than for asbestos fibers. Once a fiber ball has been formed, it is not easy to undo said ball, so there is a tendency for the synthetic fibers to be distributed unevenly in the cement matrix. Scratches are made in synthetic fibers in the kneader, so the strength of the said synthetic fibers themselves may be decreased. The result is that the molded products may not have the desired strength.
Also, when a mixture that contains 30 parts by weight or more of water ls molded under pressure, there may be separation out of the water portion in the mold before molding is complete. The result is that this mixture is not completely molded, and there is the possibility that the strength of the molded product will not be uniform.
SUM~ARY OF THE INVENTION
.
The tile made of cement reinforced with fibers of this invention, which overcomes the above-discussed and numerous other disadvantages and deficiencies of the prior art, has, per 100 parts by weight of cement, 0.3-7 parts by weight of synthetic fibers as reinforcing materials, and 200 parts by weight or less of an inorganic filler, wherein said t~le has a wave-shape with alternating hills and valleys, which run in the direction of the slope of the roof when it is installed on the building material of the roof that is under the tiles of a sloping roof, the valley of the tile being 5-30% th cker than the hill, and/or the undersurface, except for the edges of the hills and valleys, being provided with a supporting stand.
In a preferred embodiment, the supporting stand, when the tile is installed on the building material of the roof that is under the tile, has a length y along the direction of the slope of the said building material under the tile, a length ~ at right angles to the said direction of the slope, and a maximum height h wherein Y 2 3 mm, x 2 3 mm, and h ~ 60 mm.
The method for the manufacture of tiles made of cement reinforced with fibers of this invention comprisès the mixing of 200 parts by weight of an inorganic filler with an aqueous solution that has been or is being prepared by the dissolving of 1 part by weight or less of a water-soluble high polymer, if needed, into 30 parts by weight or more of water, the mixing by agitation of the mixture with 0.3-7 parts by weight of synthetic fibers, the mixing by agitation of the mixture with 100 parts by weight of cement, the putting of the mixture into a mold that can be opened and closed, and then the molding of the mixture at a rate of pressure of 0.3 mm/sec or more, resulting in 13(J~918 the desired tile reinforced with fibers.
Alternatively, the method of this invention comprises the mixing of 200 parts by weight of an inorganic filler and some of 100 parts by weight of cement with an aqueous solution that has been or is being prepared by the dissolving of 1 part by weight or less of a water-soluble high polymer, if needed, into 30 parts by weight or more of water, the mixing by agitation of the mixture with 0.3-7 parts by weight of synthetic fibers, the mixing by agitation of the mixture with the remaining cement, the putting of the mixture into a mold that can be opened and closed, and then the molding of the mixture at a rate of pressure of 0.3 mm/sec or more, resulting in a desired tile reinforced with fibers wherein said tile is in the shape of a wave with alternatlng hill~ and valleys, which run in the direction of the slope of the roof when the tile is installed on the building material of the roof thàt is under the tiles of a sloping roof, the valley of the tile being 5-30~ thicker than the hill, and/or the undersurface, except for the edges of the hills and valleys, being provided with a supporting stand.
Alternatively, the method of this invention comprises the mixing of some of 200 parts by weight of an inorganic filler and some of lO0 parts by weight of cement with an aqueous solution that has been or is being prepared by the dissolving of 1 part by weight or less of a water-soluble high polymer, if needed, into 30 parts by weight or more of water, the mixing by agitation of the mixture with 0.3-7 parts by weight of 13V~91~
synthetlc fibers, the mixing by agitation of the mixture with the remaining inorganic filler and the remaining cement, the putting of the mixture into a mold that can be opened and closed, and then the molding of the mixture at a rate of pressure of 0.3 mm/sec or more, resulting in the desired tile reinforced with fibers, wherein said tile is in the shape of a wave with alternating hills and valleys, which run in the direction of the slope of the roof when it is installed on the building material of the roof that is under the tiles of a sloping roof, the valley of the tile being 5-30% thic~er than the hill, and/or the undersurface, except for the edges of the hills and valleys, being provided with a supporting stand.
Alternatively, the method of thls inventlon comprises the mixing of 200 parts by weight of an inorganic f$11er and some of 100 parts by weight of cement with an aqueous solution that has been or is being prepared by the dissolving of 1 part by weight or less of a water-soluble high polymer, if needed, into 30 parts by weight or more of water, the mixing by agitation of the mixture with some of 0.3-7 parts by weight of synthetic fibers, the mixing by agitation of the mixture with the remaining synthetic fibers and 100 parts by weight of cement, the putting of the mixture into a mold that can be opened and closed, and then the molding of the mixture at a rate of pressure of 0.3 mm/sec or more, resulting in the desired tile reinforced with fibers, wherein said tile is in the shape of a wave with alternating hills and valleys, which run in the direction of the slope of the roof 130~:~9i~3 when it is installed on the building material of the roof that is under the tiles of a sloping roof, the valley of the tile being 5-30~ thicker than the hill, and/or the undersurface, except for the edges of the hills and valleys, being provided with a supporting stand.
In one method aspect the invention provides a method for the manufacture of tiles made of cement reinforced with fibers comprising the mixing of 200 parts by weight of an inorganic filler and some of 100 parts by weight of cement with an aqueous solution that has been or is being prepared by the dissolving of 1 part by weight or less of a water-soluble high polymer, if needed, into 30 parts by weight or more of water, the mixing by agitation of the mixture with 0.3-7 parts by weight of synthetic fibers, the mixing by agitation of the mixture with the remaining cement, the putting of the mixture into a mold that can be opened and closed, and then the molding of the mixture at a rate of pressure of 0.3 mm/sec or more, resulting in the desired tile reinforced with fibers wherein said tile is in the shape of a wave, with alternating hills and valleys, which run in the direction of the slope of the roof when it is installed on a sloping roof.
The invention also provides a roof tile for use on an essentially planar, sloped roof, comprising cement reinforced with fibers having, per 100 parts by weight of cement, about 0.3 to 7 parts by weight of synthetic fibers as reinforcing materials, and up to about 200 parts by weight of inorganic filler, wherein said tile is in the shape of a wave with alternating hills and valleys adapted to align with the slope of a roof when the tile is installed on a roof, the valley of the tile having an undersurface adapted to face the roof, and the undersurface including a supporting stand having a sloped lower surface which has the same slope as the roof under 13~9~
- 8a -said tile, the height of a portion of said supporting stand toward a lower portion of the roof when the tile-is installed on a roof being higher than the height of the portion of said supporting stand toward an upper portion of the roof.
The invention further provides a roof tile for use on an essentially planar, sloped roof comprising cement reinforced with fibers having, per 100 parts by weight of cement, about 0.3 to 7 parts by weight of synthetic fibers as reinforcing materials, and up to about 200 parts by weight of inorganic filler, wherein said tile is in the shape of a wave with alternating hills and valleys adapted to align with the slope of a roof when the tile is installed on a roof, the valley of the tile is about 5 to 30% thicker than the hill and has an undersurface adapted to face the roof, and a supporting stand is dispo~ed on the undersurface, caid supporting stand having a sloped lower surface which has the same slope as the roof under said tile, the height of a portion of said cupporting stand toward a lower portion of the roof being higher than the height of the portion of said supporting stand toward an upper portion of the roof.
The invention still further provides a roof tile for use on an essentially planar, sloped roof, comprising cement reinforced with fibers having, per 100 parts by weight of cement, about 0.3 to 7 parts by weight of synthetic fibers as reinforcing materials, and up to about 200 parts by weight of inorganic filler, wherein said tile is in the shape of a wave with alternating hills and valleys adapted to align with the slope of the roof when the tile is installed on a roof, and the valley of the tile is about 5 to 30% thicker than the hill.
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- 8b -Thus the invention described herein makes possible the objectives of (1) providing light-weight tiles with improved strength by which the tiles are not readily broken even when a weight is put thereon; and a method for the manufacture of tiles made of cement reinforced with fibers by which synthetic fibers that function as a reinforcing material are not damaged and cut, and accordingly are uniformly dispersed into the cement matrix.
BRIEF DESCRIPTION OF THE DRAWINGS
This invention may be better understood and its numerous objects and advantages will become apparent to those skilled in the art by reference to the accompanying drawings as follows:
Figure 1 i8 a per~pective view showing a tile of this invention.
Figure 2 is an elevation view showing the disposition of one tile on another tile manufactured by this invention.
1~' ..
~3~ 918 Figure 3 i8 a perspective view illustrating an experiment on the resistance to loading of a tile of this invention.
Figure 4 is a perspective view showing the underside of another tile of this invention.
Figure 5 is a sectional view showing the installation of tiles of Figure 4 on a roof.
Figure 6 is a perspective view showing another tile of this invention.
Figure 7 is a perspective view showing another tile of this invention.
DE~CRIPTION OF THE PR8FERR$D EMBODINENT8 Figure 1 shows a tile of this invention made of cement reinforced with fibers. The tile 1 is made from cement reinforced with fibers in which there are mixed, per 100 parts by weight of cement, 0.3-7 parts by weight of synthetic fibers as a reinforcing material, and 200 parts by weight or less of an inorganic filler, which mixture is stretched out to form a shape with alternating hills 2 and valleys 3. Each hill 2 and valley 3 is semicircular in cross-section; the thickness of the valleys, m, is 5-30% more than the thickness ~ of the hills 3. Also, the radius of curvature of the upper and lower surfaces of each valley 3 is approximately the same. For this reason, for example, as shown in Figure 2, when two of the same tiles 1 are placed one over the other, the bottom surface of the valleys 3 of the upper tile 1 and the top surface of the valleys 3 of the lower tile 1 touch each other. The result is that when a , . .- -~3~)11918 large number of tiles are placed one on the top of the other for shipping, each tile is protected, and there is no danger of breakage.
This kind of tile 1 is put on the top of the building material under the tiles provided on the roof, and the tiles are placed so that the hills 2 and the valleys 3 of the tile run in the direction of the slope of the roof. The tiles 1 are placed one after another from the bottom, the eaves side, to the top, the ridge side of the roof.
Accordingly, the top of the ridge-side edge of a tile is positioned under the eaves-side edge of another tile.
Because the valley parts of the tiles that are placed on the top of each other fit together as described above, the leakage of rainwater and the like under the tiles i8 prevented.
The thickness m of the valleys 3 is 5-30% more than the thickness ~ of the hills 2. If the thickness m of the valleys 3 is more than 30% more than the thickness ~ of the hills 2, the strength against breaXage of the hills declines markedly compared to the strength against breakage of the valleys 2; also, if the thickness m of the valleys 3 is less than 5% more than the thickness i of the hills 2, the strength against breakage of the valleys 3 is not sufficient.
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~13~)~91~
As cements that can be used for the tiles of this invention, Portland cement, alumina cement, blast furnace cement, and other hydraulic cements can be used.
As the synthetic f~bers, there are vinylon, polyamide, polyester, polypropylene, and other fibers, the thickness of which can be 2-40 deniers, and the length of which can be 2-30 mm.
~, 10 The amount of synthetic fibers to be added is 0.3-7 parts by weight. If the amount of synthetic fibers added is too small, the effect of reinforcement will not appear, and if the amount of synthetic fibers added is too large, the distribution of the said fibers will become poor, which decreases the flow durlng the time of molding, so that the efect of reinforcement by the said fibers will not appear. As the synthetic fibers, vinylon fibers are especially suitable because their flow characteristics are good, giving good formability.
As inorganic filler, silica, river sand, fly ash, silica flour, bentonite, sepiolite, wollastonite, calcium carbonate, mica, and so on can be listed.
For satisfactory distribution of the inorgan-- ic filler and synthetic fibers in the cement, a water-soluble polymer is used, if necessary. When the inorganic filler and synthetic fibers can be distributed in the cement satisfactorily by themselves, the addition of the ~id water-soluble polymer is not necessarily required.
13C~ 91&~
As the water-soluble polymer, methyl cellulose, carboxymethylcellulose, polyvinyl alcohol, hydroxyethylcellulose, polyacrylic acid, etc., are suitable. The ~ water-soluble polymers act to disperse aggregates and synthetic fibers such as vinylon fibers and the like uniformly throughout the cement, and can be added to prevent the formation of fiber balls made by the precipitation of a~gregates or by the mutual twisting together of the s~i~ fibers, for which purpose 1 part by weight or less can be added.
Also, for the preparation of the composition from which cement tiles are obtained, the method of mixture by agitation can be used. In this method, agitation blades are not used, but instead, agitation lnvolves the use of an apparatus to which is attached a vessel made of rubber that is pliable and is in the form of a disc-shaped agitating platform; the direction of the inclination of the agitating platform and the angle of the inclination c~n be continuously changed, so that the rubber vessel in which the materials to be mixed are placed is deformed and agitated, mixing them.
As the apparatus for mixture by agitation, 25 for example, the Omuni mixer of the Chiyoda Giken Kogyo Co. can be used.
~ tile of this invention is made from, for example, 100 parts by weight of cement, 30 parts by weight of fly ash, 2 parts by weight of vinylon fibers as the synthetic fibers, and 40 parts by weight of water, which are mixed to produce a cement composition that is reinforced with fiber, and the desired shape is 130091~
formed by the use of a water-remov~ng press on the said fiber-reinforced cement composition, after which the resulting mDlded product is heated at 60 C~and at the relative humidity of 95%~ in a steam room for 24 hours for steam curing.
In this way, a tile with four pairs of , .....
hills 2 having a thickness of 6 mm each and valleys 3 having a thickness of 7 mm each, which thickness is 16 thicker than the thickness of the hills, was obtained, and a test of resistance to loading was done. The experiment on the resistance to loading involved, as shown in Figure 3, a tile 1 with valleys 3, the edges of which were both supported by a pair of supporting rods 5; a load point 6 was put on the central portion of one of the hills 2 in the central part of the tile 1, and the ~oad on this point when the tile 1 broke was measured. The size of the load point 6 was 70 mm x 70 mm.
The load resisted at the time of breakage of the tile 1 of this experiment was 240 kg. For comparison, a reference tile was made in the same way as in the method of this invention, except that the thickness of the hills and valleys was a uniform 6 mm, and a test of resistance to loading was done. The load resisted at the time of breakage of the reference tile was 180 kg. Moreover, a tile was made in the same way as in the method of this invention, except that the thickness of the hills and the valleys was a uniform 7 mm, and a test of resistance to leading was done.
The load that was resisted at the time of breakage of the second reference tile was 240 kg, the same as the 13V09~8 value found for the tile of this invention.
In this way, when the thickness of the valleys was made thicker by a fixed amount than the thickness of the hills, it was found that the tile had the same resistance to a load as a tile that had hills with the same thickness as the thickness of the valleys on our tile. As a result, compared to a tile in which the thickness of the valleys and hills is uniform, it is possible to decrease the weight and cost of materials by the difference in the thickness of the hills. Thus, the tile of this invention is economical, and because the tile is relatively light-weight, the operation of installing the tile on a roof is eased.
Figure 4 shows another tlle of this lnvention. This tile 10 also i8 formed in a wave shape so that when it ls installed on a roo, there are alternate hills 14 and valleys 15 that follow the direction of the slope of the roof; in cross-section, the shape of each hill 14 and each valley 15 is a rectangle. When each tile 10 is installed on a roof, then, as shown in Figure 5, the eaves-side edge 12 of the tile 10 is placed on the ridge-side edge of the next tile 10.
The ~d tile 10 has at its edge that is ,; placed on the eaves side at the time of installation on the roof a downward-pro~ecting part 13 that pro~ects downward (in Figure 4, it is shown pro~ecting upward), which is provided continuously along each hill 14 and each valley 15. On the underside of this edge toward the eaves, there is a parallel groove 16 with a fixed 13~ 918 distance from the said downward pro;ecting part 13.
The groove 16 ls provided contlnuously along each hill 14 and each valley 15.
At the edge of the tile lO that is placed toward the ridge at the time of roofing, there is an upward-pro~ecting part 17 that projects upward. The upward-projecting part 17 is provided continuously along each hill 14 and each valley 15, and is fitted with the groove 16 mentioned above along the edge of the tile toward the eaves. On the upper side of the edge of the tile toward the ridge, there is a groove 18 that is parallel at a fixed distance from the said pro~ectlon 16. The groove 18 is provided continuously along each hill 14 and each valley 15, and the pro~ection 13 that is established along the eaves side, as mentioned above, flts into the ~groove 18.
On the underside of each valley 15, there are a pair of supporting stands 20 and 21 that project downward. The supporting stands 20 and 21 are both in the shape of a right-angled parallelepiped, and one of the supporting stands, 20, is placed near the edge of the tile toward the eaves, and the other supporting stand, 21, is placed near the edge of the tile toward the ridge. The position of the supporting stands 20 and 21, at the time of roofing, corresponds to the main roof crosspiece that is under the building materials 19 of the roof that are under the tiles. The height of each of the supporting stands 20 and 21 is set so that the supporting stands 20 and 21 can touch or can have a space from the building materials 19 when the tiles 10 are installed on the top of the building materials 19 13(~ 18 under the tiles on a roof, whereby the ridge-side edge of the tile 10 comes into contact with the building material 19; the pro~ection 13 on the eaves-side edge of the tile fits into the groove 18 on the ridge-side edge of the next tile that ls placed toward the eaves;
and moreover, the pro~ection 17 on the ridge-side edge of the tile is fit into the groove 16 on the eaves-side edge of the next tile. The lower surfaces of the supporting stands 20 and 21 have the same slope as the building materials 19 placed under the tile 10.
Therefore, the height of the supporting stand 20 on the eaves side of the tile is greater than the height of the supporting stand 21 on the ridge side. The bottom surfaces of said supporting stand 20 and 21, even when they are not directly connected with the building materials 19 under the tiles, come into direct contact wlth the building materials 19 under the tiles if a load i8 placed on the upper surface of the tile 10 and the tile 10 is deformed by the load.
The tile of this kind of shape, as in the tiles of the example given above, is also manufactured from a cement reinforced by fibers in which there are, per lO0 parts of cement by weight, 0.3-7 parts by weight of synthetic fibers as reinforcing material, and 200 parts by weight or less of an inorganic filler.
The supporting stands 20 and 21 are formed of the same material as the valleys and are made in one piece with the said valleys.
The supporting stands 20 and 21 for the tiles 10 undergo the same compressive stress as the ridge-side edge of a tile 10 when the ridge-side edge 13VC~9:~
of the tile 10 installed at the ridge side is placed on the eaves-side edge of the next tile 10. In general, cement that is reinforced with fibers has excellent strength against compression, but because the deformation of the tile 10 itself when a load is put on the ~ tile lO must be minimized, the measurement y of the direction of the slope of the roof of the ,~ supporting stands 20 and 21 should be 3 mm or more, and the measurement x at right angles to that direction should be 3 mm or more, with the maximum height h being preferably 60 mm or less. If both the measurement y of the supporting stands 20 and 21 in the direction of the roof slope and the measurement x in the direction at right angles to that direction are smaller than 3 mm, then when the tile 10 i8 produced from a cement composition reinforced wlth fibers by use of press molding, not ever~ part of the mold for the molding of the supporting stands 20 and 21 is filled satisfactorily with the composition, and gaps in the supporting stands 20 and 21 to be molded may occur.
Sufficient resistance to loading cannot be obtained with the supporting stands that have these kinds of gaps. If the maximum height h of the supporting stands 20 and 21 exceeds 60 mm, in the same way, not every part of the mold for the molding of the supporting stands is filled satisfactorily with the composition, and sufficient resistance to loading may not be obtained.
If the measurement x of the supporting stands 20 and 21 in the direction at right angles to the direction of the slope of the roof is the same as that maximum height h or more (x ~ h), then the cement 13~ 918 composition reinforced with fibers can fill every part of the molcl for the molding of the supporting stands, and the deformation of the supporting stands 20 and 21 in response to the loading of the tile 10 can be minimized. Moreover, if the measurement of the maximum height h of the supporting stands 20 and 21 i8 2 mm or less, the deformation in response to a load on the tile 10 is large, which is not desirable.
The shapes of the supporting stands 20 and 21 are not limited to right-angled parallelepipeds; as shown in Figure 6, they can be elliptical columns. In this case as well, it is preferable that the supporting stands 20 and 21 fulfill the conditions for measurements described above.
Accordingly, when a pair of supporting stands 20 and 21 are provided, one being near the eaves-side edge of the tile and the other being near the ridge-side edge thereof, if a load is placed on the tile 10, the hills 14 and the valleys 15 between the supporting stands 20 and 21 undergo bending stress, but because the distance between the supporting stands is relatively short, there is no danger of breakage of the tile 10. To support this kind of bending stress, there can be one supporting stand 22 that is in the shape of, for example, a right-angled parallelepiped, as shown if Figure 7, which stretches from near the eaves-side edge to near the ridge-side edge.
Because the space between the undersurface of the valleys 15 and the building materials under the tile is smaller than the space between the undersurface 13~Q9~3 of the hills 14 and the building materials under the tlle, by the provision of a supportlng stand on the undersurface of the said valley 15, it is possible to make the measurements of the supporting stand small, so that the increase in the weight of the entire tile becomes small and economical.
When such a tile is installed on a roof, even if the upper surface of the tile is stepped on, there is no danger of the breaking of the said tile, which increases the ease of the roofing operation.
Moreover, together with the provision of a supporting stand on the undersurface of the valleys 15, lf the thickness of the valleys i~ made 5-30~ thicker than the thlckne~s of the hllls, the strength of the tlle is yet more increased, and lf the upper surface of the tile is stepped on by a person, there is no danger of breakage.
Next, examples and comparative examples will be explained, in order to compare the strength of the tile of this invention that have supporting stands with the strength of conventional tlles.
Example 1 (1) Preparation of a composition for tiles made of cement reinforced wlth fibers:
Per 100 parts by weight of ordinary Portland cement, 45 parts by weight of water, 1.5 parts by weight of vinylon fibers (diameter, 18 ~m; length, 4 mm) as synthetic fibers, and 50 parts by weight of fly ash as aggregate were mixed in an Omuni mixer by agitation, which gave a composition for use in the making of til~s made of cement reinforced with fibers.
(2) Formation of tiles made of cement reinforced with fibers:
The composition described in Section l above was molded by a water-removing press, and as shown in Figure 6, each valley was provided on its underside with a pair of supporting stands 20 and 21 of elliptical shape, giving a tile 10 made of cement reinforced with fibers.
The supporting stand 20 that was provided on the eaves-side edge of the tile had a measurement y in the direction of the slope of the roof of 15 mm, a measurement x in the direction at right angles to that direction of 10 mm, and a mea~urement h for the maximum height of 15 mm; for the supporting stand 21 on the ridge-side edge, these measurements were 10 mm, 8 mm, and 7 mm, respectively.
Tiles generally have as their main ingredients clay and cement, and are installed one after another along the slope of a roof from the eaves to the ridge. At that time, the ridge-facing edge of a tile that is placed at the edge of the eaves has placed on it the eaves-facing edge of the next tile. Each tile is supported by the attachment of the edge of the tile toward the ridge to the underlying building material such as flat boards, roofing, or the like, and by the placement of the edge of the tile toward the eaves on the top of the edge toward the ridge of the next tile. Thus, the edge of each tile toward the eaves ie placed in a higher position with respect to the building material under the tiles than the edge of that tile toward the ridge, resulting in a space between the underneath surface of the tile and said building materials under the tiles. For that reason, when a load is placed on the central part of tiles installed in such a way on a roof, bending stress affects this central part, and gives rise to the danger of breakage of the tiles.
In order to prevent this kind of bending stress, the entire body of the tile can be made thick. However, if the entire body of the tile is made thick, ~r ~3(~ B
the weight of the tile itself increases, which makes the tile costly. Moreover, the work load at the time of the installation of the tiles on the roof is increased, and there is an additional disadvantage that the durability of the building itself is decreased.
For these reasons, in order to increase the strength of the tiles, and also to increase the ease of the operation of the formation of the tiles, asbestos fibers have been mixed in as a reinforcing material.
For example, in wave-shaped tiles with alternating hills and valleys, a mixture made of cement, asbestos, pulp, and the like in water is used to make a form in a cement mold like the process of making hand-made paper, and this is formed with pressure in a liguid roller, etc., in a so-called paper-making process, by which the hills and valleys are formed wlth approximately the same thickness.
However, in recent years, it has been found that asbestos fibers are a carcinogenic material, and so there are problems with the use of asbestos fibers.
For that reason, in place of asbestos fibers, inorganic fibers such as glass fibers, inorganic fibers such as potassium titanate fibers, etc., organic fibers such as vinylon, acrylonitrile, polypropylene, polyamide, etc., or metallic fibers such as steel fibers, etc., have been developed for the use in tiles made of cement as reinforcing materials. For example, tiles made of a cement in which short fibers of polyester, glass, etc., as reinforcing materials are disclosed in Japanese Patent Publication No. 57-9009.
13V~gl~
In this kind of tile made from cement reinforced with fibers, the tiles are light-weight, so their production is made easier, and another advantage is the high strength conferred. However, with this kind of tile, the hardness is slightly decreased, and as mentioned above, when the tiles are installed on a roof and there is a load placed on the central part of the tiles, the tiles are largely deformed, and stress accumulates in the center part of the tiles, bringing about the possibility that the tiles will break.
Also, in a wave-shaped tile formed with alternating hills and valleys, when the tile is installed with its hills and valleys running along the slope of a roof, and when a load is placed on the upper surface of the tile, it is known that more force is exerted on the valleys than on the hills.
Tiles with this kind ~f shape are generally made with the hills and valleys of approximately the same thickness, so that when a large load is placed on the valleys, there is the disadvantage of the valleys being easily broken.
Japanese Laid-Open Patent Application 58-213666 discloses a molding method that gives tiles made of cement and reinforced with fibers, wherein an inorganic filler and synthetic fibers are mixed with cement and 15-30 parts by weight of water per 100 parts by weight of the cement are added and kneaded by a kneader in which the surfaces of the fibers are roughened, after which the amount of water needed for the formation of the particular shape is added, and molding is accomplished by, for example, the use of a press.
Kneaders that have sharp protuberances in the kneading 13V~918 chamber, pressure kneaders, pulpers, or the like can be used.
However, with this kind of method, the synthetic fibers may come to be twisted around each other, and there is the chance of their forming a fiber ball. In general, the chance of synthetic fibers becoming twisted around each other is greater than for asbestos fibers. Once a fiber ball has been formed, it is not easy to undo said ball, so there is a tendency for the synthetic fibers to be distributed unevenly in the cement matrix. Scratches are made in synthetic fibers in the kneader, so the strength of the said synthetic fibers themselves may be decreased. The result is that the molded products may not have the desired strength.
Also, when a mixture that contains 30 parts by weight or more of water ls molded under pressure, there may be separation out of the water portion in the mold before molding is complete. The result is that this mixture is not completely molded, and there is the possibility that the strength of the molded product will not be uniform.
SUM~ARY OF THE INVENTION
.
The tile made of cement reinforced with fibers of this invention, which overcomes the above-discussed and numerous other disadvantages and deficiencies of the prior art, has, per 100 parts by weight of cement, 0.3-7 parts by weight of synthetic fibers as reinforcing materials, and 200 parts by weight or less of an inorganic filler, wherein said t~le has a wave-shape with alternating hills and valleys, which run in the direction of the slope of the roof when it is installed on the building material of the roof that is under the tiles of a sloping roof, the valley of the tile being 5-30% th cker than the hill, and/or the undersurface, except for the edges of the hills and valleys, being provided with a supporting stand.
In a preferred embodiment, the supporting stand, when the tile is installed on the building material of the roof that is under the tile, has a length y along the direction of the slope of the said building material under the tile, a length ~ at right angles to the said direction of the slope, and a maximum height h wherein Y 2 3 mm, x 2 3 mm, and h ~ 60 mm.
The method for the manufacture of tiles made of cement reinforced with fibers of this invention comprisès the mixing of 200 parts by weight of an inorganic filler with an aqueous solution that has been or is being prepared by the dissolving of 1 part by weight or less of a water-soluble high polymer, if needed, into 30 parts by weight or more of water, the mixing by agitation of the mixture with 0.3-7 parts by weight of synthetic fibers, the mixing by agitation of the mixture with 100 parts by weight of cement, the putting of the mixture into a mold that can be opened and closed, and then the molding of the mixture at a rate of pressure of 0.3 mm/sec or more, resulting in 13(J~918 the desired tile reinforced with fibers.
Alternatively, the method of this invention comprises the mixing of 200 parts by weight of an inorganic filler and some of 100 parts by weight of cement with an aqueous solution that has been or is being prepared by the dissolving of 1 part by weight or less of a water-soluble high polymer, if needed, into 30 parts by weight or more of water, the mixing by agitation of the mixture with 0.3-7 parts by weight of synthetic fibers, the mixing by agitation of the mixture with the remaining cement, the putting of the mixture into a mold that can be opened and closed, and then the molding of the mixture at a rate of pressure of 0.3 mm/sec or more, resulting in a desired tile reinforced with fibers wherein said tile is in the shape of a wave with alternatlng hill~ and valleys, which run in the direction of the slope of the roof when the tile is installed on the building material of the roof thàt is under the tiles of a sloping roof, the valley of the tile being 5-30~ thicker than the hill, and/or the undersurface, except for the edges of the hills and valleys, being provided with a supporting stand.
Alternatively, the method of this invention comprises the mixing of some of 200 parts by weight of an inorganic filler and some of lO0 parts by weight of cement with an aqueous solution that has been or is being prepared by the dissolving of 1 part by weight or less of a water-soluble high polymer, if needed, into 30 parts by weight or more of water, the mixing by agitation of the mixture with 0.3-7 parts by weight of 13V~91~
synthetlc fibers, the mixing by agitation of the mixture with the remaining inorganic filler and the remaining cement, the putting of the mixture into a mold that can be opened and closed, and then the molding of the mixture at a rate of pressure of 0.3 mm/sec or more, resulting in the desired tile reinforced with fibers, wherein said tile is in the shape of a wave with alternating hills and valleys, which run in the direction of the slope of the roof when it is installed on the building material of the roof that is under the tiles of a sloping roof, the valley of the tile being 5-30% thic~er than the hill, and/or the undersurface, except for the edges of the hills and valleys, being provided with a supporting stand.
Alternatively, the method of thls inventlon comprises the mixing of 200 parts by weight of an inorganic f$11er and some of 100 parts by weight of cement with an aqueous solution that has been or is being prepared by the dissolving of 1 part by weight or less of a water-soluble high polymer, if needed, into 30 parts by weight or more of water, the mixing by agitation of the mixture with some of 0.3-7 parts by weight of synthetic fibers, the mixing by agitation of the mixture with the remaining synthetic fibers and 100 parts by weight of cement, the putting of the mixture into a mold that can be opened and closed, and then the molding of the mixture at a rate of pressure of 0.3 mm/sec or more, resulting in the desired tile reinforced with fibers, wherein said tile is in the shape of a wave with alternating hills and valleys, which run in the direction of the slope of the roof 130~:~9i~3 when it is installed on the building material of the roof that is under the tiles of a sloping roof, the valley of the tile being 5-30~ thicker than the hill, and/or the undersurface, except for the edges of the hills and valleys, being provided with a supporting stand.
In one method aspect the invention provides a method for the manufacture of tiles made of cement reinforced with fibers comprising the mixing of 200 parts by weight of an inorganic filler and some of 100 parts by weight of cement with an aqueous solution that has been or is being prepared by the dissolving of 1 part by weight or less of a water-soluble high polymer, if needed, into 30 parts by weight or more of water, the mixing by agitation of the mixture with 0.3-7 parts by weight of synthetic fibers, the mixing by agitation of the mixture with the remaining cement, the putting of the mixture into a mold that can be opened and closed, and then the molding of the mixture at a rate of pressure of 0.3 mm/sec or more, resulting in the desired tile reinforced with fibers wherein said tile is in the shape of a wave, with alternating hills and valleys, which run in the direction of the slope of the roof when it is installed on a sloping roof.
The invention also provides a roof tile for use on an essentially planar, sloped roof, comprising cement reinforced with fibers having, per 100 parts by weight of cement, about 0.3 to 7 parts by weight of synthetic fibers as reinforcing materials, and up to about 200 parts by weight of inorganic filler, wherein said tile is in the shape of a wave with alternating hills and valleys adapted to align with the slope of a roof when the tile is installed on a roof, the valley of the tile having an undersurface adapted to face the roof, and the undersurface including a supporting stand having a sloped lower surface which has the same slope as the roof under 13~9~
- 8a -said tile, the height of a portion of said supporting stand toward a lower portion of the roof when the tile-is installed on a roof being higher than the height of the portion of said supporting stand toward an upper portion of the roof.
The invention further provides a roof tile for use on an essentially planar, sloped roof comprising cement reinforced with fibers having, per 100 parts by weight of cement, about 0.3 to 7 parts by weight of synthetic fibers as reinforcing materials, and up to about 200 parts by weight of inorganic filler, wherein said tile is in the shape of a wave with alternating hills and valleys adapted to align with the slope of a roof when the tile is installed on a roof, the valley of the tile is about 5 to 30% thicker than the hill and has an undersurface adapted to face the roof, and a supporting stand is dispo~ed on the undersurface, caid supporting stand having a sloped lower surface which has the same slope as the roof under said tile, the height of a portion of said cupporting stand toward a lower portion of the roof being higher than the height of the portion of said supporting stand toward an upper portion of the roof.
The invention still further provides a roof tile for use on an essentially planar, sloped roof, comprising cement reinforced with fibers having, per 100 parts by weight of cement, about 0.3 to 7 parts by weight of synthetic fibers as reinforcing materials, and up to about 200 parts by weight of inorganic filler, wherein said tile is in the shape of a wave with alternating hills and valleys adapted to align with the slope of the roof when the tile is installed on a roof, and the valley of the tile is about 5 to 30% thicker than the hill.
~30C~
- 8b -Thus the invention described herein makes possible the objectives of (1) providing light-weight tiles with improved strength by which the tiles are not readily broken even when a weight is put thereon; and a method for the manufacture of tiles made of cement reinforced with fibers by which synthetic fibers that function as a reinforcing material are not damaged and cut, and accordingly are uniformly dispersed into the cement matrix.
BRIEF DESCRIPTION OF THE DRAWINGS
This invention may be better understood and its numerous objects and advantages will become apparent to those skilled in the art by reference to the accompanying drawings as follows:
Figure 1 i8 a per~pective view showing a tile of this invention.
Figure 2 is an elevation view showing the disposition of one tile on another tile manufactured by this invention.
1~' ..
~3~ 918 Figure 3 i8 a perspective view illustrating an experiment on the resistance to loading of a tile of this invention.
Figure 4 is a perspective view showing the underside of another tile of this invention.
Figure 5 is a sectional view showing the installation of tiles of Figure 4 on a roof.
Figure 6 is a perspective view showing another tile of this invention.
Figure 7 is a perspective view showing another tile of this invention.
DE~CRIPTION OF THE PR8FERR$D EMBODINENT8 Figure 1 shows a tile of this invention made of cement reinforced with fibers. The tile 1 is made from cement reinforced with fibers in which there are mixed, per 100 parts by weight of cement, 0.3-7 parts by weight of synthetic fibers as a reinforcing material, and 200 parts by weight or less of an inorganic filler, which mixture is stretched out to form a shape with alternating hills 2 and valleys 3. Each hill 2 and valley 3 is semicircular in cross-section; the thickness of the valleys, m, is 5-30% more than the thickness ~ of the hills 3. Also, the radius of curvature of the upper and lower surfaces of each valley 3 is approximately the same. For this reason, for example, as shown in Figure 2, when two of the same tiles 1 are placed one over the other, the bottom surface of the valleys 3 of the upper tile 1 and the top surface of the valleys 3 of the lower tile 1 touch each other. The result is that when a , . .- -~3~)11918 large number of tiles are placed one on the top of the other for shipping, each tile is protected, and there is no danger of breakage.
This kind of tile 1 is put on the top of the building material under the tiles provided on the roof, and the tiles are placed so that the hills 2 and the valleys 3 of the tile run in the direction of the slope of the roof. The tiles 1 are placed one after another from the bottom, the eaves side, to the top, the ridge side of the roof.
Accordingly, the top of the ridge-side edge of a tile is positioned under the eaves-side edge of another tile.
Because the valley parts of the tiles that are placed on the top of each other fit together as described above, the leakage of rainwater and the like under the tiles i8 prevented.
The thickness m of the valleys 3 is 5-30% more than the thickness ~ of the hills 2. If the thickness m of the valleys 3 is more than 30% more than the thickness ~ of the hills 2, the strength against breaXage of the hills declines markedly compared to the strength against breakage of the valleys 2; also, if the thickness m of the valleys 3 is less than 5% more than the thickness i of the hills 2, the strength against breakage of the valleys 3 is not sufficient.
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~13~)~91~
As cements that can be used for the tiles of this invention, Portland cement, alumina cement, blast furnace cement, and other hydraulic cements can be used.
As the synthetic f~bers, there are vinylon, polyamide, polyester, polypropylene, and other fibers, the thickness of which can be 2-40 deniers, and the length of which can be 2-30 mm.
~, 10 The amount of synthetic fibers to be added is 0.3-7 parts by weight. If the amount of synthetic fibers added is too small, the effect of reinforcement will not appear, and if the amount of synthetic fibers added is too large, the distribution of the said fibers will become poor, which decreases the flow durlng the time of molding, so that the efect of reinforcement by the said fibers will not appear. As the synthetic fibers, vinylon fibers are especially suitable because their flow characteristics are good, giving good formability.
As inorganic filler, silica, river sand, fly ash, silica flour, bentonite, sepiolite, wollastonite, calcium carbonate, mica, and so on can be listed.
For satisfactory distribution of the inorgan-- ic filler and synthetic fibers in the cement, a water-soluble polymer is used, if necessary. When the inorganic filler and synthetic fibers can be distributed in the cement satisfactorily by themselves, the addition of the ~id water-soluble polymer is not necessarily required.
13C~ 91&~
As the water-soluble polymer, methyl cellulose, carboxymethylcellulose, polyvinyl alcohol, hydroxyethylcellulose, polyacrylic acid, etc., are suitable. The ~ water-soluble polymers act to disperse aggregates and synthetic fibers such as vinylon fibers and the like uniformly throughout the cement, and can be added to prevent the formation of fiber balls made by the precipitation of a~gregates or by the mutual twisting together of the s~i~ fibers, for which purpose 1 part by weight or less can be added.
Also, for the preparation of the composition from which cement tiles are obtained, the method of mixture by agitation can be used. In this method, agitation blades are not used, but instead, agitation lnvolves the use of an apparatus to which is attached a vessel made of rubber that is pliable and is in the form of a disc-shaped agitating platform; the direction of the inclination of the agitating platform and the angle of the inclination c~n be continuously changed, so that the rubber vessel in which the materials to be mixed are placed is deformed and agitated, mixing them.
As the apparatus for mixture by agitation, 25 for example, the Omuni mixer of the Chiyoda Giken Kogyo Co. can be used.
~ tile of this invention is made from, for example, 100 parts by weight of cement, 30 parts by weight of fly ash, 2 parts by weight of vinylon fibers as the synthetic fibers, and 40 parts by weight of water, which are mixed to produce a cement composition that is reinforced with fiber, and the desired shape is 130091~
formed by the use of a water-remov~ng press on the said fiber-reinforced cement composition, after which the resulting mDlded product is heated at 60 C~and at the relative humidity of 95%~ in a steam room for 24 hours for steam curing.
In this way, a tile with four pairs of , .....
hills 2 having a thickness of 6 mm each and valleys 3 having a thickness of 7 mm each, which thickness is 16 thicker than the thickness of the hills, was obtained, and a test of resistance to loading was done. The experiment on the resistance to loading involved, as shown in Figure 3, a tile 1 with valleys 3, the edges of which were both supported by a pair of supporting rods 5; a load point 6 was put on the central portion of one of the hills 2 in the central part of the tile 1, and the ~oad on this point when the tile 1 broke was measured. The size of the load point 6 was 70 mm x 70 mm.
The load resisted at the time of breakage of the tile 1 of this experiment was 240 kg. For comparison, a reference tile was made in the same way as in the method of this invention, except that the thickness of the hills and valleys was a uniform 6 mm, and a test of resistance to loading was done. The load resisted at the time of breakage of the reference tile was 180 kg. Moreover, a tile was made in the same way as in the method of this invention, except that the thickness of the hills and the valleys was a uniform 7 mm, and a test of resistance to leading was done.
The load that was resisted at the time of breakage of the second reference tile was 240 kg, the same as the 13V09~8 value found for the tile of this invention.
In this way, when the thickness of the valleys was made thicker by a fixed amount than the thickness of the hills, it was found that the tile had the same resistance to a load as a tile that had hills with the same thickness as the thickness of the valleys on our tile. As a result, compared to a tile in which the thickness of the valleys and hills is uniform, it is possible to decrease the weight and cost of materials by the difference in the thickness of the hills. Thus, the tile of this invention is economical, and because the tile is relatively light-weight, the operation of installing the tile on a roof is eased.
Figure 4 shows another tlle of this lnvention. This tile 10 also i8 formed in a wave shape so that when it ls installed on a roo, there are alternate hills 14 and valleys 15 that follow the direction of the slope of the roof; in cross-section, the shape of each hill 14 and each valley 15 is a rectangle. When each tile 10 is installed on a roof, then, as shown in Figure 5, the eaves-side edge 12 of the tile 10 is placed on the ridge-side edge of the next tile 10.
The ~d tile 10 has at its edge that is ,; placed on the eaves side at the time of installation on the roof a downward-pro~ecting part 13 that pro~ects downward (in Figure 4, it is shown pro~ecting upward), which is provided continuously along each hill 14 and each valley 15. On the underside of this edge toward the eaves, there is a parallel groove 16 with a fixed 13~ 918 distance from the said downward pro;ecting part 13.
The groove 16 ls provided contlnuously along each hill 14 and each valley 15.
At the edge of the tile lO that is placed toward the ridge at the time of roofing, there is an upward-pro~ecting part 17 that projects upward. The upward-projecting part 17 is provided continuously along each hill 14 and each valley 15, and is fitted with the groove 16 mentioned above along the edge of the tile toward the eaves. On the upper side of the edge of the tile toward the ridge, there is a groove 18 that is parallel at a fixed distance from the said pro~ectlon 16. The groove 18 is provided continuously along each hill 14 and each valley 15, and the pro~ection 13 that is established along the eaves side, as mentioned above, flts into the ~groove 18.
On the underside of each valley 15, there are a pair of supporting stands 20 and 21 that project downward. The supporting stands 20 and 21 are both in the shape of a right-angled parallelepiped, and one of the supporting stands, 20, is placed near the edge of the tile toward the eaves, and the other supporting stand, 21, is placed near the edge of the tile toward the ridge. The position of the supporting stands 20 and 21, at the time of roofing, corresponds to the main roof crosspiece that is under the building materials 19 of the roof that are under the tiles. The height of each of the supporting stands 20 and 21 is set so that the supporting stands 20 and 21 can touch or can have a space from the building materials 19 when the tiles 10 are installed on the top of the building materials 19 13(~ 18 under the tiles on a roof, whereby the ridge-side edge of the tile 10 comes into contact with the building material 19; the pro~ection 13 on the eaves-side edge of the tile fits into the groove 18 on the ridge-side edge of the next tile that ls placed toward the eaves;
and moreover, the pro~ection 17 on the ridge-side edge of the tile is fit into the groove 16 on the eaves-side edge of the next tile. The lower surfaces of the supporting stands 20 and 21 have the same slope as the building materials 19 placed under the tile 10.
Therefore, the height of the supporting stand 20 on the eaves side of the tile is greater than the height of the supporting stand 21 on the ridge side. The bottom surfaces of said supporting stand 20 and 21, even when they are not directly connected with the building materials 19 under the tiles, come into direct contact wlth the building materials 19 under the tiles if a load i8 placed on the upper surface of the tile 10 and the tile 10 is deformed by the load.
The tile of this kind of shape, as in the tiles of the example given above, is also manufactured from a cement reinforced by fibers in which there are, per lO0 parts of cement by weight, 0.3-7 parts by weight of synthetic fibers as reinforcing material, and 200 parts by weight or less of an inorganic filler.
The supporting stands 20 and 21 are formed of the same material as the valleys and are made in one piece with the said valleys.
The supporting stands 20 and 21 for the tiles 10 undergo the same compressive stress as the ridge-side edge of a tile 10 when the ridge-side edge 13VC~9:~
of the tile 10 installed at the ridge side is placed on the eaves-side edge of the next tile 10. In general, cement that is reinforced with fibers has excellent strength against compression, but because the deformation of the tile 10 itself when a load is put on the ~ tile lO must be minimized, the measurement y of the direction of the slope of the roof of the ,~ supporting stands 20 and 21 should be 3 mm or more, and the measurement x at right angles to that direction should be 3 mm or more, with the maximum height h being preferably 60 mm or less. If both the measurement y of the supporting stands 20 and 21 in the direction of the roof slope and the measurement x in the direction at right angles to that direction are smaller than 3 mm, then when the tile 10 i8 produced from a cement composition reinforced wlth fibers by use of press molding, not ever~ part of the mold for the molding of the supporting stands 20 and 21 is filled satisfactorily with the composition, and gaps in the supporting stands 20 and 21 to be molded may occur.
Sufficient resistance to loading cannot be obtained with the supporting stands that have these kinds of gaps. If the maximum height h of the supporting stands 20 and 21 exceeds 60 mm, in the same way, not every part of the mold for the molding of the supporting stands is filled satisfactorily with the composition, and sufficient resistance to loading may not be obtained.
If the measurement x of the supporting stands 20 and 21 in the direction at right angles to the direction of the slope of the roof is the same as that maximum height h or more (x ~ h), then the cement 13~ 918 composition reinforced with fibers can fill every part of the molcl for the molding of the supporting stands, and the deformation of the supporting stands 20 and 21 in response to the loading of the tile 10 can be minimized. Moreover, if the measurement of the maximum height h of the supporting stands 20 and 21 i8 2 mm or less, the deformation in response to a load on the tile 10 is large, which is not desirable.
The shapes of the supporting stands 20 and 21 are not limited to right-angled parallelepipeds; as shown in Figure 6, they can be elliptical columns. In this case as well, it is preferable that the supporting stands 20 and 21 fulfill the conditions for measurements described above.
Accordingly, when a pair of supporting stands 20 and 21 are provided, one being near the eaves-side edge of the tile and the other being near the ridge-side edge thereof, if a load is placed on the tile 10, the hills 14 and the valleys 15 between the supporting stands 20 and 21 undergo bending stress, but because the distance between the supporting stands is relatively short, there is no danger of breakage of the tile 10. To support this kind of bending stress, there can be one supporting stand 22 that is in the shape of, for example, a right-angled parallelepiped, as shown if Figure 7, which stretches from near the eaves-side edge to near the ridge-side edge.
Because the space between the undersurface of the valleys 15 and the building materials under the tile is smaller than the space between the undersurface 13~Q9~3 of the hills 14 and the building materials under the tlle, by the provision of a supportlng stand on the undersurface of the said valley 15, it is possible to make the measurements of the supporting stand small, so that the increase in the weight of the entire tile becomes small and economical.
When such a tile is installed on a roof, even if the upper surface of the tile is stepped on, there is no danger of the breaking of the said tile, which increases the ease of the roofing operation.
Moreover, together with the provision of a supporting stand on the undersurface of the valleys 15, lf the thickness of the valleys i~ made 5-30~ thicker than the thlckne~s of the hllls, the strength of the tlle is yet more increased, and lf the upper surface of the tile is stepped on by a person, there is no danger of breakage.
Next, examples and comparative examples will be explained, in order to compare the strength of the tile of this invention that have supporting stands with the strength of conventional tlles.
Example 1 (1) Preparation of a composition for tiles made of cement reinforced wlth fibers:
Per 100 parts by weight of ordinary Portland cement, 45 parts by weight of water, 1.5 parts by weight of vinylon fibers (diameter, 18 ~m; length, 4 mm) as synthetic fibers, and 50 parts by weight of fly ash as aggregate were mixed in an Omuni mixer by agitation, which gave a composition for use in the making of til~s made of cement reinforced with fibers.
(2) Formation of tiles made of cement reinforced with fibers:
The composition described in Section l above was molded by a water-removing press, and as shown in Figure 6, each valley was provided on its underside with a pair of supporting stands 20 and 21 of elliptical shape, giving a tile 10 made of cement reinforced with fibers.
The supporting stand 20 that was provided on the eaves-side edge of the tile had a measurement y in the direction of the slope of the roof of 15 mm, a measurement x in the direction at right angles to that direction of 10 mm, and a mea~urement h for the maximum height of 15 mm; for the supporting stand 21 on the ridge-side edge, these measurements were 10 mm, 8 mm, and 7 mm, respectively.
(3) Condition of filling with material for tiles made of cement reinforced with fibers:
Some of the tiles made of cement reinforced with fibers that were formed in Section 2 above were cut cross-sectionally, and the condition of the filling with the material of the supporting stands 20 and 21 was observed in cross-section. It was found that filling was satisfactory in every place.
,~, 13~)~9~8 (4) Quality of tiles made of cement rein-forced with fibers:
Some of the tiles 10 made of cement rein-forced with fibers that were formed in Section 2 abovewere cured by being placed in water for 14 days. Then they were installed on a roof, and a person bearing a weight walked on the tiles. The wei~ht required for the tiles to break when stepped on by a person bearing a weight was measured; it was 160 kg.
Example 2 (1) Preparation of a composition for use in the making of tiles made of cement reinforced with fibers:
Per 100 parts by welght of ordinary Portland cement, 45 parts by weight of water, 2.0 parts by weight of vinylon fibers (diameter, 18 ~m;, length, 6 mm), 40 parts by weight of silica powder as aggregate, and 0.1 part by weight of methyl cellulose as a water-soluble polymer were mixed in the same way as in Example 1 by agitation in an Omuni mixer, which gave a composition for use in the making of tiles made of cement reinforced with fibers.
(2) Molding of tiles made of cement rein-forced with fibers:
The composition described in Section l above was molded by a water-removing press to form tiles made of cement reinforced with fibers in the same shape as in Example 1.
~3~9~8 (3) Condition of filling with material for tiles made of cement reinforced with fibers:
In the same way as in Example 1, the condition of fllling with material was observed, and it was found that filling of all places was satisfactory.
(4) Quality of tiles made of cement rein-forced with fibers:
Some of the tiles 10 made of cement rein-forced with fibers that were formed in Section 2 above were cured by being placed in water for 14 days. Then, in the same way as in Example 1, the weight required for the tiles to break when stepped on by a person bearlng a weight was measured. It was 180 kg.
Example 3 (1) Preparation of a composition for use in the making of tiles made of cement reinforced with fibers:
Per 100 parts by weight of quick-hardening cement, 50 parts by weight of water, 2.5 parts by weight of vinylon fibers (diameter, 18 ~ m; length, 12 mm), 20 parts by weight of fly ash and 30 parts by weight of silica powder as aggregates, and 0.4 part by weight of methyl cellulose as a water-soluble polymer were mixéd in the same way as in Example 1 by agitation in an Omuni mixer, which gave a composition for use in the making of tiles made of cement reinforced with fibers.
~3~ 91~
(2) Molding of tiles made of cement rein-forced with fibers:
The composition described in Section 1 above was molded by a water-removing press to form tiles made of cement reinforced with fibers in the same shape as in Example 1.
(3) Condition of filling with material for tiles made of cement reinforced with fibers:
In the same way as in Example 1, the condition of filling with material was observed, and it was found that filling of all places was satisfactory.
(4) Quality of tiles made of cement rein-forced wlth fibers:
Some of the tiles 10 made of cement relnforced with fibers that were formed in Section 2 above were cured by being placed in water for 14 days.
Then, in the same way as in Example 1, the weight reguired for the tiles to break when stepped on by a person bearing a weight was measured. It was 230 kg.
Example 4 (1) Preparation of a composition for use in the making of tiles made of cement reinforced with fibers:
Per 100 parts by weight of ordinary Portland cement, 45 part by weight of water, 1.5 parts by weight 130(:~9~8 of vinylon fiber~ (diameter, 1~ ~m, length, 4 mm), and 50 parts by weight of fly ash as aggregate were agitated in an Omuni mixer, which gave a composition for use in the making S of tiles made of cement reinforced with vinylon fibers.
(2) Molding of tiles made of cement reinforced with fibers:
The composition described in Section 1 above was molded by a water-removing press to form the tiles 10 made of cement reinforced with fibers shown in Figure 7, with single supporting stands 22 in the shape of right-angled parallelepipeds on the undersurfaces of valleys 15.
The measurements of the supporting stand 22 were:
y, the measurement in the direction of the slope of the roof, 300 mm; x, the measurement in the direction at right angles to this direction, 15 mm, and the maximum height h, 7 mm.
(3) Condition of filling with material for tiles made of cement reinforced with fibers:
Some of the tiles made of cement reinforced with fibers that were formed in Section 2 above were out cross-sectionally, and the condition of the filling with material of the supporting stand 22 was observed in cross-section. It was found that filling was satisfactory in every place.
~.i ..
i3V0918 (4) Quality of tiles made of cement rein-forced with fibers:
Some of the tlles 10 formed in Section 2 above were cured by being placed in water for 14 days.
Then, in the same way as in Example 1, the weight required for the tiles to break when stepped on by a person bearing a weight was measured. It was 170 kg.
Example 5 (1) Preparation of a composition for use in the making of tiles made of cement reinforced with fibers:
Per 100 parts by weight of ordinary Portland cement, 45 parts by weight of water, 2.0 parts by weight of vinylon fiberQ (diameter, 18 ~m; length, 6 mm), 40 parts by weight of sllica powder as aggregate, and 0.1 part by weight of methyl cellulose as a water-soluble polymer were mixed by being agitated in an Omuni mixer, which gave a composition for use in the making of tiles made of cement reinforced with vinylon fibers.
(2) Molding of tiles made of cement rein-forced with fibers:
The composition described in Section 1 above was molded by a water-removing press as in Example 4 to give tiles 10 made of cement reinforced with vinylon fibers, wh~ch tiles had a supporting stand 22 in the shape of a right-angled parallelepiped.
130C~91~
(3) Condition of filling a with material for tiles made of cement reinforced with fibers:
Some of the tiles made in Section 2 above were cut cross-sectionally, and the condition of the filling with material of the supporting stand 22 in the shape of a right-angled parallelepiped were observed. It was found that filling was satisfactory in every place.
(4) Quality of tiles made of cement reinforced with fibers:
Some of the tiles 10 formed in Section 2 above were cured by being placed in water for 14 days. Then, in the same way as in Example 4, the weight required for the tiles to break when stepped on by a per~on bearing a weight was measured. It was 200 kg.
Exam~le 6 (1) Preparation of a composition for use in the making of tiles made of cement reinforced with fibers:
Per 100 parts by weight of quick-hardening cement, 50 parts by weight of water, 2.5 parts by weight of vinylon fibers (diameter, 18 ~m, length, 12 mm), 20 parts by weight of fly ash and 30 parts by weight of silica powder as aggregates, and 0.4 part by weight of methyl cellulose as a water-soluble polymer were mixed by being agitated in an Omuni mixer, which gave a composition for use in the making of tiles made of cement reinforced with fibers.
. .. -.
(2) Molding of tiles made of cement rein-forced with fibers:
The composition described in Section 1 above was molded by a water-removing press to form tiles made of cement reinforced with fibers in the same shape as in Example 4, with one supporting stand 22 in the shape of a right-angled parallelepipPd, giving tiles lO made of cement reinforced with vinylon fibers.
(3) Condition of filling with material for tiles made of cement reinforced with fibers:
Some of the tiles 10 formed in Section 2 above were cut cross-sectionally, and the conditions of fllling wlth material for the supporting stand 11 were observed in cross-section. It was found that filling was satisfactory in every place.
(4) Quality of tiles made of cement rein-forced with fibers:
Some of the tiles 10 formed in Section 2 above were cured by being placed in water for 14 days.
Then, in the same way as in Example 4, the weight - required for the tiles to break when stepped on by a person bearing a weight was measured. It was 220 kg.
~omparative Example 1 (1) Preparation of a composition for use ln the making of tiles made of cement reinforced with fibers:
13(~09~8 Per 100 parts by weight of ordinary Portland cement, 45 parts by weight of water, 1.5 parts by weight of vinylon fibers (diameter, 18 ~m; length, 4 mm), and 50 parts by weight of fly ash as aggregate were mixed by being agitated in an Omuni mixer, which gave a composition for use in the making of tiles made of cement reinforced with fibers.
(2) Molding of tiles made of cement reinforced with fibers:
The composition obtained in Section 1 above was molded by a water-removing press, and tiles made of cement reinforced with fibers were formed into a wave shape in which there were absolutely no supports formed on the undersurface.
(3) Condition of filling with material for tiles made of cement reinforced with fibers:
Some of the tiles formed of cement in Section 2 above were cut cross-sectionally, and the condition of the filling with material was observed in cross-section. It was found that filling was satisfactory in every place.
(4) Quality of tiles made of cement reinforced with fibers:
Some of the tiles 10 formed in Section 2 above were cured by being placed in water for 14 days. Then, in the same way as in Example 1, the weight required for the tiles to break when stepped on by a person bearing a weight was measured. It was 60 kg.
i3V~9~8 Comparative Examle 2 (l) Preparation of a composition for use in the making of tiles made of cement reinforced with fibers:
S Per 100 parts by weight of ordinary Portland cement, 45 parts by weight of water, 2.0 parts by weight of vinylon fibers (diameter, 18 ~m: length, 4 mm), 40 parts by weight of silica powder as aggregate, and 0.1 part by weight of methyl cellulose as a water-soluble polymer were mixed by being agitated in an Omuni mixer, which gave a composition for use in the making of tiles made of cement reinforced with fibers.
(2) Molding of tiles made of cement reinforced with fibers:
The composition described in Section l above was molded by a water-removing press to form tiles made of cement reinforced with fibers in the same shape as in Comparative Example 1.
(3) Condition of filling with material for tiles made of cement reinforced with fibers:
Some of the tiles formed in Section 2 above were cut cross-sectionally, and the condition of the filling with material was observed in cross-section. It was found that fîlling was satisfactory in every '~' 130Q9~ ~
place.
(4) Quality of tiles made of cement rein-forced with fibers:
Some of the tiles 10 formed in Section 2 above were cured by being placed in water for 14 days.
Then, in the same way as in Example 1, the weight required for the tiles to break when stepped on by a person bearing a weight was measured. It was 90 kg.
Comparative Example 3 (1) Preparation of a composition for use in the making of tiles made of cement reinforced with fibers:
Per 100 parts by weight of ordinary Portland cement, 50 parts of water by weight, 2.5 parts by weight of vinylon fibers (diameter, 18 ~m, length, 12 mm), 20 parts by weight of fly ash and 30 parts by weight of silica powder as aggregates, and 0.4 part by weight of methyl cellulose as a water-soluble polymer were mixed by being agitated in an Omuni mixer, which gave a composition for use in the making of tiles made of cement reinforced with fibers:
(2) Molding of tiles made of cement rein-forced with fibers:
The composition described in Section 1 above was molded by a water-removing press to form tiles made of cement reinforced with fibers in the same shape as in Comparative Example 1.
130Q91~
(3) Condition of filling with material for tiles made of cement reinforced with fibers:
Some of the tiles formed in Section 2 above were cut cross-sectionally, and the conditions of fill-ing with material were observed in cross-section. It was found that filling was satisfactory in every place.
(4) Quality of tiles made of cement rein-forced with fibers:
Some of the tiles formed in Section 2 above were cured by being placed in water for 14 days. Then, in the same way as in Example 1, the weight required for the tiles to break when stepped on by a person bearlng a weight was measured. It was 100 kg.
In all of the examples including the comparative examples, the shapes and the measurements of the tiles were exactly allke, except that the tiles of this invention were provided with supporting stands while the tiles of the comparative examples were not provided with supporting stands.
The compositions of the examples and the comparative examples given above are shown in Table 1, as are the shapes, measurements, numbers, and filling condition by the compositions of the supporting stands, together with the results of the weight-bearing test.
13U091~3 Table 1 Composltion lparts by weight) =
Ordinary Quick- Water Vinylon Fly Silica Methyl cement hardening fibers ash powder cellu-cement lose _ Examples 1 100 45 1.5 50 _ 2 100 45 2.0 _ 40 0.1 3 _ , ~ 100 50 2.5 20 30 0.4 _ 4 100 45 1.5 50 _ _ 100 45 2.0 _ 40 0.1 . 6 . 100 50 2.5 20 30 0.4 _ tCoimpeara- 1 100 _ 45 1.5 50 . _ examples 2 100 45 2,0 _ 40 0.1 ~ ' 100 50 2.5 20 30 0.4 i3(~918 U~
_ _ __ _ _ __ _ ~ ~ o ~7 ~_ o o ~ o o ~
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O ~ C~ ~ ~ ~ C~ ~ ~ ~ ~ ~ U~
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J~ ~ _ _ __ _ L X CO CO CO I I I I I I
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E .C _ _ _ -------- _ ~- O O
D~
D ~ ~ _ U~ u~ O O O l l . I
~e ~ E c~ c~ c~ 0 ~ 0 0 S: C
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~1 ~1 ~1 ~ ~ ~ ~ I ta o Cl~ ~ CZ. CL CZ, CL L- ~ ~ _ ~ _I
E e e E 13 e ~ c a~ ~ c . ~
x ~ x x x x c~, I c~ e c~ e ~
~3 ~3 ~ ~ ~3 o X o X o X Z
V ~ ~ ~ V ~-:
~ 3V~}91~
In this way, when the measurement y of the supportlng stands in the dlrection of the slope of the roof is 2 3 mm, the measurement x thereof in the direction at right angles to this direction is 2 3 mm, and the maximum height h thereof is < 60 mm, the resistance to loading on the tile greatly increases.
Next, the method for production of the tiles made of cement reinforced with fibers of this invention will be explained. First, 1 part by weight or less of a water-soluble polymer is dissolved into 30 parts of water by weight or more, if needed, resulting in an aqueous solution containing the water-soluble polymer.
To this aqueous solution (or an aqueous solution that is made while dissolving the said compound into the said water), 200 parts by weight or less of an inorganic filler is added and mixed, to which 0.3-7 parts by weight of synthetic fibers is added and mixed in by agitation. In th$s way, the synthetic fibers are not damaged or broken, and they can therefore be uniformly dispersed in the mixture. In these circumstances, if the mean diameter of the inorganic filler particles is more than 100 ~m, it is difficult for the particles to enter in the fiber spaces between the synthetic fibers, and there is thus a tendency for the particles to aggregate, so it is preferable for the mean diameter of particles of the inorganic filler to be 100 ~m or less. If the amount of synthetic fibers added is less than 0.3 part by weight, sufficient strength is not obtained at the time of molding of the tiles. If the amount of synthetic fibers added is more than 7 parts by weight, the dispersion of the fibers becomes poor, and flowability is also poor at the time ~3~10918 of molding of the tiles.
Then, to the mixture obtained above, 100 parts by weight of cement is added and mixed in by agitation, thereby attaining the dispersion of the fine particles of cement in the spaces b~tween the inorganic filler and the synthetic fibers.
Then, the mixture obtained above is put into a mold that can be opened and closed, and the desired shape is formed by the application of pressure. At this time, the mixture with 30 parts by weight of water or more readily undergoes the separation out of water.
For this reason, it is necessary that the molding of the tile be completed before the separation out of water occurs. If the rate of pressure of the mixture in the mold is 0.3 mm/sec or more, there is no ~eparation out of the water, and the desired shape can be made perfectly, as the entire mold is rapidly filled with the mixture.
A certain amount of water is removed from the molded product within the mold so that the molded product can keep its shape, after which it is removed from the mold, and cured and hardened by the well-known method~ In this way, a tile of the desired shape is obtained.
With this kind of method for the manufacture of tiles, even if part of the cement is added during the first step, the synthetic fibers are not damaged or broken in the first step, and can be mixed in uniformly. Then, even if the remaining cement to be ~3()091E3 added is added ln the second step, the dispersion of the fine particles of cement in the spaces between the inorganic filler and the synthetic fibers is readily attained. Also, even if part of the cement and part of the aggregate are added during the first step, the synthetic fibers are not damaged or broken in the first step, and uniform mixing can be attained. And, if the remaining part of the cement and the remaining part of the aggregate are added in the second step, it is still easy for the fine particles of cement to be dispersed in the spaces between the inorganic filler and the synthetic fibers.
In addition, if some of the synthetic fibers are added in the first step, and if the remaining synthetic fibers are added in the second step, the synthetic fibers are not damaged or broken, and uniform mixing can be attained. In this case, the fine particles of cement can easily be dispersed in the spaces between the inorganic filler and the synthetic fibers.
Next, the method of this invention will be explained by other examples of the manufacture of the above-mentioned tiles made of cement reinforced with fibers.
Example 7 To 30 parts by weight of water, 0.1 part by weight of methyl cellulose and 0.3 part by weight of vinylon fibers (fiber length, 6 mm; thickness, 5 deniers) as synthetic fibers were added, and these were mixed by being agitated in an Omuni mixer with a ~31~9~E~
5-~ capacity manufactured by Chiyoda Giken Kogyo Co.
To this mixture, 100 parts by weight of cement was added, and mixing by agitation was done again. This mixture was molded by a water-removing press at the surface pressure of 65 kg/cm2 and the rate of pressure of 3 mm/sec resulting in a tile. The tile was cured at 60 C and a relative humidity of 90% for one week. The condition of dispersal of the fibers before molding, the surface of the cured tile, and the strength against being bent were observed. These results are shown in Table 3, wherein the evaluation of the dispersion of the vinylon fibers was graded as follows: 0 means that the fibers were completely dispersed, with absolutely no agglutination of fibers, ~ means that dispersion was fairly complete but that some slight agglutination was observed, and ~ means that agglutlnation was marked.
Also, with the surface of the tiles, ~ means that the surface was glossy, with fibers being uniformly dispersed, ~ means that there was uneveness of the surface, with some fibers not being uniformly dispersed, and X means that the surface was uneven, and the fibers were dispersed without uniformity. The strength against being bent was measured according to the methods of JIS 1048U.
Example 8 To 40 parts by weight of water, 0.2 part by weight of methyl cellulose, 30 parts by weight of fly ash (mean particle diameter, lOO~m), and 2.0 parts by weight of vinylon fibers were added, and these were mixed by agitation, after which 100 parts by weight of cement was added to this mixture, and mixed by 130Q~18 agitation, with other steps being carried out as in Example 1. The results are shown in Table 3.
Example 9 A test was done in the same way as in Example 8 except that ins*ead of the fly ash, silica (mean diameter, 100 ~m) was used. The results are shown in Table 3.
Example 10 A test was done in the same way as in Example 8 except that instead of the fly ash, slag (mean diameter, 100 ~m) was used. The results are shown in Table 3.
Examle 11 A test was done in the same way as in Example 8 except that instead of the fly ash, silica flour (mean diameter, 100 ~m) was used. The results are shown in Table 3.
Example 12 A test was done in the same way as in Example 8 except that instead of the fly ash, bentonite (mean diameter, 100 ~m) was used. The results are shown in Table 3.
Example 13 A test was done in the same way as in Example 8 except that instead of the methyl cellulose, polyvinyl alcohol was used. The results are shown in Table 3.
130~918 ~xample 14 A test was done in the same way as in Example 8 except that instead of the methyl cellulose, hydroxyethylcellulose was used. The results are shown in Table 3.
Example 15 A test was done in the same way as in Example 8 except that instead of there being 0.2 part by weight of methyl cellulose, there were 2.0 parts by weight. The results are shown in Table 3.
Exam~le 16 A test was done in the same way as in Example 7 except that per 150 parts by weight of water, 1.0 part by weight of methyl cellulose, 200 parts by weight of fly ash (mean particle diameter, 100 ~m), and 7.0 parts by weight of vinylon fiber were added, and the whole was mixed by agitation. The results are shown in Table 3.
Example 17 A test was done in the same way as in Example 8 except that the rate of pressure was 5 mm/second. The results are shown in Table 3.
Exam~le 18 A test was done in the same way as in Example 8 except that the rate of pressure was 7.5 mm/second. The results are shown in Table 3.
~3~)0918 Example 19 A test was done in the same way as in Example 7 except that per 30 parts of water, methyl cellulose was not added, but 30 parts by weight of fly ash, 10 parts by weight of cement, and 0.5 part by weight of vinylon fibers were added and mixed by agitation; to this mixture, ~0 parts by weight of the cement was added, and mixing by agitation was done once more. The results are shown in Table 3.
Example 20 A test was done in the same way as in Example 7 except that per 40 parts of water, methyl cellulose was not added, but 20 parts by weight of fly ash (mean particle diameter, 100 ~m), 10 parts by weight of cement, and 2.2 parts by weight of vinylon fibers were added and mixed by agitation; to this mixture, 20 parts by weight of fly ash (mean particle diameter, 100 ~m) and 90 parts by weight of cement were added, and mixing by agitation was done once more. The results are shown in Table 3.
Example 21 A test was done in the same way as in Example 7 except that per 40 parts of water, methyl cellulose was not added, but 30 parts by weight of silica (mean particle diameter, 100 ~m), 10 parts by weight of cement, and 1.2 parts by weight of vinylon fibers were added and mixed by agitation; to this mixture, 1.0 part by weight of vinylon fibers and 100 parts by weight of cement were added, and mixing by agitation was done once more. The results are shown in Table 3.
~3V091~
Comparative Example 4 A test was done in the same way as in Example 7 except that the amount of vinylon fibers used was 0.2 part by weight. The results are shown in Table 3.
Comparative Example 5 A test was done in the same way as in Example 7 except that per 150 parts of water by weight, 0.2 part by weight of methyl cellulose and 200 parts by weight of fly ash (mean particle diametert 100 ~m) were added and mixing was done by agitation. The results are shown in Table 3.
Comparative Example 6 A test was done in the same way as ln Exa~ple 7 except that per 150 parts by weight of water, 0.2 part by weight of methyl cellulose, 220 parts by weight of fly ash (mean particle diameter, 100 ~m), and 2.0 parts by weight of vinylon fibers were added and mixed by agitation; to this mixture, 100 parts by weight of cement was added and mixing by agitation was done once more. The results are shown in Table 3.
Comparative Example 7 A test was done in the same way as in Example 8 except that instead of mixing being done by agitation, a mixer with blades was used. The results are shown in Table 3.
130Q91~3 It ls seen from Table 3 that according to the method of thls invention, tiles with superior strength against being bent are obtained, and that the caid tiles are not readily broken when a weight is put on their upper surfaces, so the said tiles ease the operation of roofing when the tiles are being installed on a roof.
13~(~91t3 ~ ~ LT ~ ~ ~4 1 = O O 1 r _ O ~ ~ O O ~ O
--r ~ O r O O ~ O
¦ a ~l t ~ ~
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~ ~o ~ ~ L~ - ~L~ ~L~I~
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. . , 13009~8 It is understood that various other modifica-tions will be apparent to and can be readily made by those skilled in the art without departing from the scope and spirit of this invention. Accordingly, it is not intended that the scope of the claims appended hereto be limited to the description as set forth herein, but rather that the claims be construed as encompassing all the features of patentable novelty that reside in the present invention, including all fea~ures that would be treated as equivalents thereof by those skilled in the art to which this invention pertains.
Some of the tiles made of cement reinforced with fibers that were formed in Section 2 above were cut cross-sectionally, and the condition of the filling with the material of the supporting stands 20 and 21 was observed in cross-section. It was found that filling was satisfactory in every place.
,~, 13~)~9~8 (4) Quality of tiles made of cement rein-forced with fibers:
Some of the tiles 10 made of cement rein-forced with fibers that were formed in Section 2 abovewere cured by being placed in water for 14 days. Then they were installed on a roof, and a person bearing a weight walked on the tiles. The wei~ht required for the tiles to break when stepped on by a person bearing a weight was measured; it was 160 kg.
Example 2 (1) Preparation of a composition for use in the making of tiles made of cement reinforced with fibers:
Per 100 parts by welght of ordinary Portland cement, 45 parts by weight of water, 2.0 parts by weight of vinylon fibers (diameter, 18 ~m;, length, 6 mm), 40 parts by weight of silica powder as aggregate, and 0.1 part by weight of methyl cellulose as a water-soluble polymer were mixed in the same way as in Example 1 by agitation in an Omuni mixer, which gave a composition for use in the making of tiles made of cement reinforced with fibers.
(2) Molding of tiles made of cement rein-forced with fibers:
The composition described in Section l above was molded by a water-removing press to form tiles made of cement reinforced with fibers in the same shape as in Example 1.
~3~9~8 (3) Condition of filling with material for tiles made of cement reinforced with fibers:
In the same way as in Example 1, the condition of fllling with material was observed, and it was found that filling of all places was satisfactory.
(4) Quality of tiles made of cement rein-forced with fibers:
Some of the tiles 10 made of cement rein-forced with fibers that were formed in Section 2 above were cured by being placed in water for 14 days. Then, in the same way as in Example 1, the weight required for the tiles to break when stepped on by a person bearlng a weight was measured. It was 180 kg.
Example 3 (1) Preparation of a composition for use in the making of tiles made of cement reinforced with fibers:
Per 100 parts by weight of quick-hardening cement, 50 parts by weight of water, 2.5 parts by weight of vinylon fibers (diameter, 18 ~ m; length, 12 mm), 20 parts by weight of fly ash and 30 parts by weight of silica powder as aggregates, and 0.4 part by weight of methyl cellulose as a water-soluble polymer were mixéd in the same way as in Example 1 by agitation in an Omuni mixer, which gave a composition for use in the making of tiles made of cement reinforced with fibers.
~3~ 91~
(2) Molding of tiles made of cement rein-forced with fibers:
The composition described in Section 1 above was molded by a water-removing press to form tiles made of cement reinforced with fibers in the same shape as in Example 1.
(3) Condition of filling with material for tiles made of cement reinforced with fibers:
In the same way as in Example 1, the condition of filling with material was observed, and it was found that filling of all places was satisfactory.
(4) Quality of tiles made of cement rein-forced wlth fibers:
Some of the tiles 10 made of cement relnforced with fibers that were formed in Section 2 above were cured by being placed in water for 14 days.
Then, in the same way as in Example 1, the weight reguired for the tiles to break when stepped on by a person bearing a weight was measured. It was 230 kg.
Example 4 (1) Preparation of a composition for use in the making of tiles made of cement reinforced with fibers:
Per 100 parts by weight of ordinary Portland cement, 45 part by weight of water, 1.5 parts by weight 130(:~9~8 of vinylon fiber~ (diameter, 1~ ~m, length, 4 mm), and 50 parts by weight of fly ash as aggregate were agitated in an Omuni mixer, which gave a composition for use in the making S of tiles made of cement reinforced with vinylon fibers.
(2) Molding of tiles made of cement reinforced with fibers:
The composition described in Section 1 above was molded by a water-removing press to form the tiles 10 made of cement reinforced with fibers shown in Figure 7, with single supporting stands 22 in the shape of right-angled parallelepipeds on the undersurfaces of valleys 15.
The measurements of the supporting stand 22 were:
y, the measurement in the direction of the slope of the roof, 300 mm; x, the measurement in the direction at right angles to this direction, 15 mm, and the maximum height h, 7 mm.
(3) Condition of filling with material for tiles made of cement reinforced with fibers:
Some of the tiles made of cement reinforced with fibers that were formed in Section 2 above were out cross-sectionally, and the condition of the filling with material of the supporting stand 22 was observed in cross-section. It was found that filling was satisfactory in every place.
~.i ..
i3V0918 (4) Quality of tiles made of cement rein-forced with fibers:
Some of the tlles 10 formed in Section 2 above were cured by being placed in water for 14 days.
Then, in the same way as in Example 1, the weight required for the tiles to break when stepped on by a person bearing a weight was measured. It was 170 kg.
Example 5 (1) Preparation of a composition for use in the making of tiles made of cement reinforced with fibers:
Per 100 parts by weight of ordinary Portland cement, 45 parts by weight of water, 2.0 parts by weight of vinylon fiberQ (diameter, 18 ~m; length, 6 mm), 40 parts by weight of sllica powder as aggregate, and 0.1 part by weight of methyl cellulose as a water-soluble polymer were mixed by being agitated in an Omuni mixer, which gave a composition for use in the making of tiles made of cement reinforced with vinylon fibers.
(2) Molding of tiles made of cement rein-forced with fibers:
The composition described in Section 1 above was molded by a water-removing press as in Example 4 to give tiles 10 made of cement reinforced with vinylon fibers, wh~ch tiles had a supporting stand 22 in the shape of a right-angled parallelepiped.
130C~91~
(3) Condition of filling a with material for tiles made of cement reinforced with fibers:
Some of the tiles made in Section 2 above were cut cross-sectionally, and the condition of the filling with material of the supporting stand 22 in the shape of a right-angled parallelepiped were observed. It was found that filling was satisfactory in every place.
(4) Quality of tiles made of cement reinforced with fibers:
Some of the tiles 10 formed in Section 2 above were cured by being placed in water for 14 days. Then, in the same way as in Example 4, the weight required for the tiles to break when stepped on by a per~on bearing a weight was measured. It was 200 kg.
Exam~le 6 (1) Preparation of a composition for use in the making of tiles made of cement reinforced with fibers:
Per 100 parts by weight of quick-hardening cement, 50 parts by weight of water, 2.5 parts by weight of vinylon fibers (diameter, 18 ~m, length, 12 mm), 20 parts by weight of fly ash and 30 parts by weight of silica powder as aggregates, and 0.4 part by weight of methyl cellulose as a water-soluble polymer were mixed by being agitated in an Omuni mixer, which gave a composition for use in the making of tiles made of cement reinforced with fibers.
. .. -.
(2) Molding of tiles made of cement rein-forced with fibers:
The composition described in Section 1 above was molded by a water-removing press to form tiles made of cement reinforced with fibers in the same shape as in Example 4, with one supporting stand 22 in the shape of a right-angled parallelepipPd, giving tiles lO made of cement reinforced with vinylon fibers.
(3) Condition of filling with material for tiles made of cement reinforced with fibers:
Some of the tiles 10 formed in Section 2 above were cut cross-sectionally, and the conditions of fllling wlth material for the supporting stand 11 were observed in cross-section. It was found that filling was satisfactory in every place.
(4) Quality of tiles made of cement rein-forced with fibers:
Some of the tiles 10 formed in Section 2 above were cured by being placed in water for 14 days.
Then, in the same way as in Example 4, the weight - required for the tiles to break when stepped on by a person bearing a weight was measured. It was 220 kg.
~omparative Example 1 (1) Preparation of a composition for use ln the making of tiles made of cement reinforced with fibers:
13(~09~8 Per 100 parts by weight of ordinary Portland cement, 45 parts by weight of water, 1.5 parts by weight of vinylon fibers (diameter, 18 ~m; length, 4 mm), and 50 parts by weight of fly ash as aggregate were mixed by being agitated in an Omuni mixer, which gave a composition for use in the making of tiles made of cement reinforced with fibers.
(2) Molding of tiles made of cement reinforced with fibers:
The composition obtained in Section 1 above was molded by a water-removing press, and tiles made of cement reinforced with fibers were formed into a wave shape in which there were absolutely no supports formed on the undersurface.
(3) Condition of filling with material for tiles made of cement reinforced with fibers:
Some of the tiles formed of cement in Section 2 above were cut cross-sectionally, and the condition of the filling with material was observed in cross-section. It was found that filling was satisfactory in every place.
(4) Quality of tiles made of cement reinforced with fibers:
Some of the tiles 10 formed in Section 2 above were cured by being placed in water for 14 days. Then, in the same way as in Example 1, the weight required for the tiles to break when stepped on by a person bearing a weight was measured. It was 60 kg.
i3V~9~8 Comparative Examle 2 (l) Preparation of a composition for use in the making of tiles made of cement reinforced with fibers:
S Per 100 parts by weight of ordinary Portland cement, 45 parts by weight of water, 2.0 parts by weight of vinylon fibers (diameter, 18 ~m: length, 4 mm), 40 parts by weight of silica powder as aggregate, and 0.1 part by weight of methyl cellulose as a water-soluble polymer were mixed by being agitated in an Omuni mixer, which gave a composition for use in the making of tiles made of cement reinforced with fibers.
(2) Molding of tiles made of cement reinforced with fibers:
The composition described in Section l above was molded by a water-removing press to form tiles made of cement reinforced with fibers in the same shape as in Comparative Example 1.
(3) Condition of filling with material for tiles made of cement reinforced with fibers:
Some of the tiles formed in Section 2 above were cut cross-sectionally, and the condition of the filling with material was observed in cross-section. It was found that fîlling was satisfactory in every '~' 130Q9~ ~
place.
(4) Quality of tiles made of cement rein-forced with fibers:
Some of the tiles 10 formed in Section 2 above were cured by being placed in water for 14 days.
Then, in the same way as in Example 1, the weight required for the tiles to break when stepped on by a person bearing a weight was measured. It was 90 kg.
Comparative Example 3 (1) Preparation of a composition for use in the making of tiles made of cement reinforced with fibers:
Per 100 parts by weight of ordinary Portland cement, 50 parts of water by weight, 2.5 parts by weight of vinylon fibers (diameter, 18 ~m, length, 12 mm), 20 parts by weight of fly ash and 30 parts by weight of silica powder as aggregates, and 0.4 part by weight of methyl cellulose as a water-soluble polymer were mixed by being agitated in an Omuni mixer, which gave a composition for use in the making of tiles made of cement reinforced with fibers:
(2) Molding of tiles made of cement rein-forced with fibers:
The composition described in Section 1 above was molded by a water-removing press to form tiles made of cement reinforced with fibers in the same shape as in Comparative Example 1.
130Q91~
(3) Condition of filling with material for tiles made of cement reinforced with fibers:
Some of the tiles formed in Section 2 above were cut cross-sectionally, and the conditions of fill-ing with material were observed in cross-section. It was found that filling was satisfactory in every place.
(4) Quality of tiles made of cement rein-forced with fibers:
Some of the tiles formed in Section 2 above were cured by being placed in water for 14 days. Then, in the same way as in Example 1, the weight required for the tiles to break when stepped on by a person bearlng a weight was measured. It was 100 kg.
In all of the examples including the comparative examples, the shapes and the measurements of the tiles were exactly allke, except that the tiles of this invention were provided with supporting stands while the tiles of the comparative examples were not provided with supporting stands.
The compositions of the examples and the comparative examples given above are shown in Table 1, as are the shapes, measurements, numbers, and filling condition by the compositions of the supporting stands, together with the results of the weight-bearing test.
13U091~3 Table 1 Composltion lparts by weight) =
Ordinary Quick- Water Vinylon Fly Silica Methyl cement hardening fibers ash powder cellu-cement lose _ Examples 1 100 45 1.5 50 _ 2 100 45 2.0 _ 40 0.1 3 _ , ~ 100 50 2.5 20 30 0.4 _ 4 100 45 1.5 50 _ _ 100 45 2.0 _ 40 0.1 . 6 . 100 50 2.5 20 30 0.4 _ tCoimpeara- 1 100 _ 45 1.5 50 . _ examples 2 100 45 2,0 _ 40 0.1 ~ ' 100 50 2.5 20 30 0.4 i3(~918 U~
_ _ __ _ _ __ _ ~ ~ o ~7 ~_ o o ~ o o ~
3 D ~ _ _ _ ~
C ~
S- ~ ~ ~ ~ '1:5 ~ ~ ~ ~ ~ S~
~ O O O O O O O O O
V O~ O O O O O O O O O
O ~ C~ ~ ~ ~ C~ ~ ~ ~ ~ ~ U~
_ _ __ e _ __ ~ _ _____ o e e ~ O O O I I I I I I E~
J~ ~ _ _ __ _ L X CO CO CO I I I I I I
_ _ _ __ _ _ _ ~o~ 3~
E .C _ _ _ -------- _ ~- O O
D~
D ~ ~ _ U~ u~ O O O l l . I
~e ~ E c~ c~ c~ 0 ~ 0 0 S: C
~ C n X o o o _ _ _ _ ~ _ h O h h ~ 0 00 DE ~D ~D ~D ~ ~ ~ l l l O S S S
~ )~
. ~ _ ____ _ H O O
. S ~ ~ ~-1 C L = L _ __ h h N ~ 3 ~1 ~O ~ ~ ;~ 0 o ~ o a) ~ ~7 ~ ~ J ~ ~ Z ~
~1 ~1 ~1 ~ ~ ~ ~ I ta o Cl~ ~ CZ. CL CZ, CL L- ~ ~ _ ~ _I
E e e E 13 e ~ c a~ ~ c . ~
x ~ x x x x c~, I c~ e c~ e ~
~3 ~3 ~ ~ ~3 o X o X o X Z
V ~ ~ ~ V ~-:
~ 3V~}91~
In this way, when the measurement y of the supportlng stands in the dlrection of the slope of the roof is 2 3 mm, the measurement x thereof in the direction at right angles to this direction is 2 3 mm, and the maximum height h thereof is < 60 mm, the resistance to loading on the tile greatly increases.
Next, the method for production of the tiles made of cement reinforced with fibers of this invention will be explained. First, 1 part by weight or less of a water-soluble polymer is dissolved into 30 parts of water by weight or more, if needed, resulting in an aqueous solution containing the water-soluble polymer.
To this aqueous solution (or an aqueous solution that is made while dissolving the said compound into the said water), 200 parts by weight or less of an inorganic filler is added and mixed, to which 0.3-7 parts by weight of synthetic fibers is added and mixed in by agitation. In th$s way, the synthetic fibers are not damaged or broken, and they can therefore be uniformly dispersed in the mixture. In these circumstances, if the mean diameter of the inorganic filler particles is more than 100 ~m, it is difficult for the particles to enter in the fiber spaces between the synthetic fibers, and there is thus a tendency for the particles to aggregate, so it is preferable for the mean diameter of particles of the inorganic filler to be 100 ~m or less. If the amount of synthetic fibers added is less than 0.3 part by weight, sufficient strength is not obtained at the time of molding of the tiles. If the amount of synthetic fibers added is more than 7 parts by weight, the dispersion of the fibers becomes poor, and flowability is also poor at the time ~3~10918 of molding of the tiles.
Then, to the mixture obtained above, 100 parts by weight of cement is added and mixed in by agitation, thereby attaining the dispersion of the fine particles of cement in the spaces b~tween the inorganic filler and the synthetic fibers.
Then, the mixture obtained above is put into a mold that can be opened and closed, and the desired shape is formed by the application of pressure. At this time, the mixture with 30 parts by weight of water or more readily undergoes the separation out of water.
For this reason, it is necessary that the molding of the tile be completed before the separation out of water occurs. If the rate of pressure of the mixture in the mold is 0.3 mm/sec or more, there is no ~eparation out of the water, and the desired shape can be made perfectly, as the entire mold is rapidly filled with the mixture.
A certain amount of water is removed from the molded product within the mold so that the molded product can keep its shape, after which it is removed from the mold, and cured and hardened by the well-known method~ In this way, a tile of the desired shape is obtained.
With this kind of method for the manufacture of tiles, even if part of the cement is added during the first step, the synthetic fibers are not damaged or broken in the first step, and can be mixed in uniformly. Then, even if the remaining cement to be ~3()091E3 added is added ln the second step, the dispersion of the fine particles of cement in the spaces between the inorganic filler and the synthetic fibers is readily attained. Also, even if part of the cement and part of the aggregate are added during the first step, the synthetic fibers are not damaged or broken in the first step, and uniform mixing can be attained. And, if the remaining part of the cement and the remaining part of the aggregate are added in the second step, it is still easy for the fine particles of cement to be dispersed in the spaces between the inorganic filler and the synthetic fibers.
In addition, if some of the synthetic fibers are added in the first step, and if the remaining synthetic fibers are added in the second step, the synthetic fibers are not damaged or broken, and uniform mixing can be attained. In this case, the fine particles of cement can easily be dispersed in the spaces between the inorganic filler and the synthetic fibers.
Next, the method of this invention will be explained by other examples of the manufacture of the above-mentioned tiles made of cement reinforced with fibers.
Example 7 To 30 parts by weight of water, 0.1 part by weight of methyl cellulose and 0.3 part by weight of vinylon fibers (fiber length, 6 mm; thickness, 5 deniers) as synthetic fibers were added, and these were mixed by being agitated in an Omuni mixer with a ~31~9~E~
5-~ capacity manufactured by Chiyoda Giken Kogyo Co.
To this mixture, 100 parts by weight of cement was added, and mixing by agitation was done again. This mixture was molded by a water-removing press at the surface pressure of 65 kg/cm2 and the rate of pressure of 3 mm/sec resulting in a tile. The tile was cured at 60 C and a relative humidity of 90% for one week. The condition of dispersal of the fibers before molding, the surface of the cured tile, and the strength against being bent were observed. These results are shown in Table 3, wherein the evaluation of the dispersion of the vinylon fibers was graded as follows: 0 means that the fibers were completely dispersed, with absolutely no agglutination of fibers, ~ means that dispersion was fairly complete but that some slight agglutination was observed, and ~ means that agglutlnation was marked.
Also, with the surface of the tiles, ~ means that the surface was glossy, with fibers being uniformly dispersed, ~ means that there was uneveness of the surface, with some fibers not being uniformly dispersed, and X means that the surface was uneven, and the fibers were dispersed without uniformity. The strength against being bent was measured according to the methods of JIS 1048U.
Example 8 To 40 parts by weight of water, 0.2 part by weight of methyl cellulose, 30 parts by weight of fly ash (mean particle diameter, lOO~m), and 2.0 parts by weight of vinylon fibers were added, and these were mixed by agitation, after which 100 parts by weight of cement was added to this mixture, and mixed by 130Q~18 agitation, with other steps being carried out as in Example 1. The results are shown in Table 3.
Example 9 A test was done in the same way as in Example 8 except that ins*ead of the fly ash, silica (mean diameter, 100 ~m) was used. The results are shown in Table 3.
Example 10 A test was done in the same way as in Example 8 except that instead of the fly ash, slag (mean diameter, 100 ~m) was used. The results are shown in Table 3.
Examle 11 A test was done in the same way as in Example 8 except that instead of the fly ash, silica flour (mean diameter, 100 ~m) was used. The results are shown in Table 3.
Example 12 A test was done in the same way as in Example 8 except that instead of the fly ash, bentonite (mean diameter, 100 ~m) was used. The results are shown in Table 3.
Example 13 A test was done in the same way as in Example 8 except that instead of the methyl cellulose, polyvinyl alcohol was used. The results are shown in Table 3.
130~918 ~xample 14 A test was done in the same way as in Example 8 except that instead of the methyl cellulose, hydroxyethylcellulose was used. The results are shown in Table 3.
Example 15 A test was done in the same way as in Example 8 except that instead of there being 0.2 part by weight of methyl cellulose, there were 2.0 parts by weight. The results are shown in Table 3.
Exam~le 16 A test was done in the same way as in Example 7 except that per 150 parts by weight of water, 1.0 part by weight of methyl cellulose, 200 parts by weight of fly ash (mean particle diameter, 100 ~m), and 7.0 parts by weight of vinylon fiber were added, and the whole was mixed by agitation. The results are shown in Table 3.
Example 17 A test was done in the same way as in Example 8 except that the rate of pressure was 5 mm/second. The results are shown in Table 3.
Exam~le 18 A test was done in the same way as in Example 8 except that the rate of pressure was 7.5 mm/second. The results are shown in Table 3.
~3~)0918 Example 19 A test was done in the same way as in Example 7 except that per 30 parts of water, methyl cellulose was not added, but 30 parts by weight of fly ash, 10 parts by weight of cement, and 0.5 part by weight of vinylon fibers were added and mixed by agitation; to this mixture, ~0 parts by weight of the cement was added, and mixing by agitation was done once more. The results are shown in Table 3.
Example 20 A test was done in the same way as in Example 7 except that per 40 parts of water, methyl cellulose was not added, but 20 parts by weight of fly ash (mean particle diameter, 100 ~m), 10 parts by weight of cement, and 2.2 parts by weight of vinylon fibers were added and mixed by agitation; to this mixture, 20 parts by weight of fly ash (mean particle diameter, 100 ~m) and 90 parts by weight of cement were added, and mixing by agitation was done once more. The results are shown in Table 3.
Example 21 A test was done in the same way as in Example 7 except that per 40 parts of water, methyl cellulose was not added, but 30 parts by weight of silica (mean particle diameter, 100 ~m), 10 parts by weight of cement, and 1.2 parts by weight of vinylon fibers were added and mixed by agitation; to this mixture, 1.0 part by weight of vinylon fibers and 100 parts by weight of cement were added, and mixing by agitation was done once more. The results are shown in Table 3.
~3V091~
Comparative Example 4 A test was done in the same way as in Example 7 except that the amount of vinylon fibers used was 0.2 part by weight. The results are shown in Table 3.
Comparative Example 5 A test was done in the same way as in Example 7 except that per 150 parts of water by weight, 0.2 part by weight of methyl cellulose and 200 parts by weight of fly ash (mean particle diametert 100 ~m) were added and mixing was done by agitation. The results are shown in Table 3.
Comparative Example 6 A test was done in the same way as ln Exa~ple 7 except that per 150 parts by weight of water, 0.2 part by weight of methyl cellulose, 220 parts by weight of fly ash (mean particle diameter, 100 ~m), and 2.0 parts by weight of vinylon fibers were added and mixed by agitation; to this mixture, 100 parts by weight of cement was added and mixing by agitation was done once more. The results are shown in Table 3.
Comparative Example 7 A test was done in the same way as in Example 8 except that instead of mixing being done by agitation, a mixer with blades was used. The results are shown in Table 3.
130Q91~3 It ls seen from Table 3 that according to the method of thls invention, tiles with superior strength against being bent are obtained, and that the caid tiles are not readily broken when a weight is put on their upper surfaces, so the said tiles ease the operation of roofing when the tiles are being installed on a roof.
13~(~91t3 ~ ~ LT ~ ~ ~4 1 = O O 1 r _ O ~ ~ O O ~ O
--r ~ O r O O ~ O
¦ a ~l t ~ ~
~ o ~ ~ ~ i o ~ o ~
~i ~ +
~ o ~L ~ .. ~ ~ o ~
~ ~o ~ ~ L~ - ~L~ ~L~I~
. .,~ ~
~30C~918 ~=~
_ i ~t 1 ~
E . o o o o x ¦ O ~ ¦ ~ ~
~ - ~
E _ o o ~ ~~ x ~ O u~ o:
- ` ~ ; L ~
. . , 13009~8 It is understood that various other modifica-tions will be apparent to and can be readily made by those skilled in the art without departing from the scope and spirit of this invention. Accordingly, it is not intended that the scope of the claims appended hereto be limited to the description as set forth herein, but rather that the claims be construed as encompassing all the features of patentable novelty that reside in the present invention, including all fea~ures that would be treated as equivalents thereof by those skilled in the art to which this invention pertains.
Claims (12)
1. A method for the manufacture of tiles made of cement reinforced with fibers comprising the mixing of 200 parts by weight of an inorganic filler with an aqueous solution that has been or is being prepared by the dissolving of 1 part by weight or less of a water-soluble high polymer, if needed, into 30 parts by weight or more of water, the mixing by agitation of the mixture with 0.3-7 parts by weight of synthetic fibers, the mixing by agitation of the mixture with 100 parts by weight of cement, the putting of the mixture into a mold that can be opened and closed, and then the molding of the mixture at a rate of pressure of 0.3 mm/sec or more, resulting in the desired tile reinforced with fibers.
2. A method for the manufacture of tiles made of cement reinforced with fibers comprising the mixing of some of 200 parts by weight of an inorganic filler and some of 100 parts by weight of cement with an aqueous solution that has been or is being prepared by the dissolving of 1 part by weight or less of a water-soluble high polymer, if needed, into 30 parts by weight or more of water, the mixing by agitation of the mixture with 0.3-7 parts by weight of synthetic fibers, the mixing by agitation of the mixture with the remaining inorganic filler and the remaining cement, the putting of the mixture into a mold that can be opened and closed, and then the molding of the mixture at a rate of pressure of 0.3 mm/sec or more, resulting in the desired tile reinforced with fibers, wherein said tile is in the shape of a wave with alternating hills and valleys, which run in the direction of the slope of the roof when it is installed on the building material of the roof that is under the tiles of a sloping roof, and either the valley of the tile being 5-30% thicker than the hill, or the undersurface, except for the edges of the hills and valleys, being provided with a supporting stand.
3. A method for the manufacture of tiles made of cement reinforced with fibers comprising the mixing of 200 parts by weight of an inorganic filler and some of 100 parts by weight of cement with an aqueous solution that has been or is being prepared by the dissolving of 1 part by weight or less of a water-soluble high polymer, if needed, into 30 parts by weight or more of water, the mixing by agitation of the mixture with some of 0.3-7 parts by weight of synthetic fibers, the mixing by agitation of the mixture with the remaining synthetic fibers and 100 parts by weight of cement, the putting of the mixture into a mold that can be opened and closed, and then the molding of the mixture at a rate of pressure of 0.3 mm/sec or more, resulting in the desired tile reinforced with fibers, wherein said tile is in the shape of a wave with alternating hills and valleys, which run in the direction of the slope of the roof when it is installed on the building material of the roof that is under the tiles of a sloping roof, and either the valley of the tile being 5-30% thicker than the hill, or the undersurface, except for the edges of the hills and valleys, being provided with a supporting stand.
4. A roof tile for use on an essentially planar, sloped roof, comprising cement reinforced with fibers having, per 100 parts by weight of cement, about 0.3 to 7 parts by weight of synthetic fibers as reinforcing materials, and up to about 200 parts by weight of inorganic filler, wherein said tile is in the shape of a wave with alternating hills and valleys adapted to align with the slope of a roof when the tile is installed on a roof, the valley of the tile having an undersurface adapted to face the roof, and the undersurface including a supporting stand having a sloped lower surface which has the same slope as the roof under said tile, the height of a portion of said supporting stand toward a lower portion of the roof when the tile is installed on a roof being higher than the height of the portion of said supporting stand toward an upper portion of the roof.
5. A roof tile as defined in claim 4, wherein said supporting stand has a length y parallel to the slope of the roof, a length x along the roof at right angles to the slope, when said tile is installed on a roof, and a maximum height h, wherein y > 3 mm, x > 3 mm, and h < 60 mm.
6. A roof tile for use on an essentially planar, sloped roof comprising cement reinforced with fibers having, per 100 parts by weight of cement, about 0.3 to 7 parts by weight of synthetic fibers as reinforcing materials, and up to about 200 parts by weight of inorganic filler, wherein said tile is in the shape of a wave with alternating hills and valleys adapted to align with the slope of a roof when the tile is installed on a roof, the valley of the tile is about 5 to 30% thicker than the hill and has an undersurface adapted to face the roof, and a supporting stand is disposed on the undersurface, said supporting stand having a sloped lower surface which has the same slope as the roof under said tile, the height of a portion of said supporting stand toward a lower portion of the roof being higher than the height of the portion of said supporting stand toward an upper portion of the roof.
7. A roof tile as defined in claim 6, wherein said supporting stand has a length y parallel to the slope of the roof, a length x along the roof at right angles to the slope, when said tile is installed on a roof, and a maximum height h, wherein y > 3 mm, x > 3 mm, and h < 60 mm.
8. A roof tile for use on an essentially planar, sloped roof, comprising cement reinforced with fibers having, per 100 parts by weight of cement, about 0.3 to 7 parts by weight of synthetic fibers as reinforcing materials, and up to about 200 parts by weight of inorganic filler, wherein said tile is in the shape of a wave with alternating hills and valleys adapted to align with the slope of the roof when the tile is installed on a roof, and the valley of the tile is about 5 to 30% thicker than the hill.
9. A method for the manufacture of tiles made of cement reinforced with fibers comprising the mixing of 200 parts by weight of an inorganic filler and some of 100 parts by weight of cement with an aqueous solution that has been or is being prepared by the dissolving of 1 part by weight or less of a water-soluble high polymer, if needed, into 30 parts by weight or more of water, the mixing by agitation of the mixture with 0.3-7 parts by weight of synthetic fibers, the mixing by agitation of the mixture with remaining cement, the putting of the mixture into a mold that can be opened and closed, and then the molding of the mixture at a rate of pressure of 0.3 mm/sec or more, resulting in the desired tile reinforced with fibers wherein said tile is in the shape of a wave, with alternating hills and valleys, which run in the direction of the slope of the roof when it is installed on a sloping roof.
10. A method for the manufacture of tiles as defined in claim 9, wherein said step of molding of the mixture comprises forming the valley of the tile to be 5-30% thicker than the hill.
11. A method for the manufacture of tiles as defined in claim 10, wherein said step of molding of the mixture comprises forming a supporting stand on an undersurface of the tile.
12. A method for the manufacture of tiles as defined in claim 9, wherein said step of molding of the mixture comprises forming a supporting stand on an undersurface of the tile.
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62-147737 | 1987-06-12 | ||
JP14773787 | 1987-06-12 | ||
JP7157988A JPH01242446A (en) | 1988-03-24 | 1988-03-24 | 'vinylon(r)' fiber reinforced cement tile |
JP63-71579 | 1988-03-24 | ||
JP63-72205 | 1988-03-25 | ||
JP7220588A JPS6477503A (en) | 1987-06-12 | 1988-03-25 | Manufacture of fiber reinforced cement molded body |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1300918C true CA1300918C (en) | 1992-05-19 |
Family
ID=27300694
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA000569226A Expired - Lifetime CA1300918C (en) | 1987-06-12 | 1988-06-10 | Cement tile reinforced with fibers and a method for the production of the same |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP0295153B1 (en) |
CA (1) | CA1300918C (en) |
DE (1) | DE3870317D1 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
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FR2735415B1 (en) * | 1995-06-15 | 1997-07-18 | Mci Sa | METHOD FOR MANUFACTURING A PLATE-SHAPED ARTICLE AND ARTICLE MANUFACTURED |
EP1317442B1 (en) * | 2000-09-11 | 2005-11-16 | Chiron Corporation | Quinolinone derivatives as tyrosine kinase inhibitors |
EP3067178A4 (en) | 2013-11-06 | 2017-08-09 | Kuraray Co., Ltd. | Concrete tile and molding material for same |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2672670A (en) * | 1949-02-18 | 1954-03-23 | Eugene T Rhodes | Method of making building material |
FR1010876A (en) * | 1950-02-06 | 1952-06-16 | New canal tiles | |
US3224205A (en) * | 1962-08-29 | 1965-12-21 | Johns Manville | Asbestos-cement structural sheet |
FR1371646A (en) * | 1963-10-16 | 1964-09-04 | Braas & Co Gmbh | Improvements to mechanical interlocking tiles |
FR2217937A5 (en) * | 1973-02-14 | 1974-09-06 | Frapart Jacques | Monolithic multilayer composite construction panels - with enhanced aggregate bonding and surface impermeability |
CH587397A5 (en) * | 1974-09-25 | 1977-04-29 | Marchioli Giorgio | |
NZ185576A (en) * | 1976-11-05 | 1981-12-15 | Kubota Ltd | Preparing cement product |
DE2743934A1 (en) * | 1977-09-29 | 1979-04-12 | Dante A Raponi | Settable compsn. for moulding lightweight structural units - comprises polyethylene strips, aggregate, hydraulic cement and water |
US4414030A (en) * | 1981-11-25 | 1983-11-08 | Restrepo Jose M | Fiber-reinforced cement, and process |
GB8301450D0 (en) * | 1983-01-19 | 1983-02-23 | Ici Plc | Fibre-reinforced cementitious compositions |
MX163147B (en) * | 1984-08-24 | 1991-08-30 | Marley Tile Ag | METHOD FOR PRODUCING FLAT CONCRETE TILES AND RESULTING PRODUCT |
-
1988
- 1988-06-10 CA CA000569226A patent/CA1300918C/en not_active Expired - Lifetime
- 1988-06-13 EP EP19880305401 patent/EP0295153B1/en not_active Expired
- 1988-06-13 DE DE8888305401T patent/DE3870317D1/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
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EP0295153B1 (en) | 1992-04-22 |
DE3870317D1 (en) | 1992-05-27 |
EP0295153A1 (en) | 1988-12-14 |
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