EP0279913B1 - Brenner zum Verbrennen von flüssigen oder gasförmigen Brennstoffen - Google Patents
Brenner zum Verbrennen von flüssigen oder gasförmigen Brennstoffen Download PDFInfo
- Publication number
- EP0279913B1 EP0279913B1 EP87116550A EP87116550A EP0279913B1 EP 0279913 B1 EP0279913 B1 EP 0279913B1 EP 87116550 A EP87116550 A EP 87116550A EP 87116550 A EP87116550 A EP 87116550A EP 0279913 B1 EP0279913 B1 EP 0279913B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- chamber
- air
- burner
- nozzles
- fuel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 33
- 238000002485 combustion reaction Methods 0.000 title claims abstract description 28
- 239000007788 liquid Substances 0.000 title claims abstract description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000003546 flue gas Substances 0.000 claims abstract description 15
- 238000010438 heat treatment Methods 0.000 claims abstract description 5
- 239000003344 environmental pollutant Substances 0.000 abstract description 5
- 231100000719 pollutant Toxicity 0.000 abstract description 3
- 239000000919 ceramic Substances 0.000 abstract 1
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 21
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000003921 oil Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 241001156002 Anthonomus pomorum Species 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000010763 heavy fuel oil Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C7/00—Combustion apparatus characterised by arrangements for air supply
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C9/00—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
- F23C9/08—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber for reducing temperature in combustion chamber, e.g. for protecting walls of combustion chamber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D17/00—Burners for combustion conjointly or alternatively of gaseous or liquid or pulverulent fuel
- F23D17/002—Burners for combustion conjointly or alternatively of gaseous or liquid or pulverulent fuel gaseous or liquid fuel
Definitions
- the invention relates to a burner for burning liquid or gaseous fuels according to the preamble of claim 1.
- Such a burner is known with regard to the division of the combustion air into primary air, secondary air and tertiary air and supply of the tertiary air via a separate air box (US Pat. No. 4,347,052). This reduces the formation of nitrogen oxides during combustion. It is also known that in burners with a central oil lance and three-part air supply (DE-OS 33 27 597) flue gas is supplied to the beginning of the flame between the primary air and secondary air supply. In the known, equipped with a central fuel lance and operated with heavy oil burners can operate in narrow burner spaces, for. B. in flame tube three-pass boilers difficulties arise in the way that low-pollutant combustion can be associated with an impermissibly high solid emissions.
- the invention has for its object to design the generic burner in such a way that the formation of nitrogen oxides can be considerably reduced, especially when burning heavy heating oil, while maintaining the specified solid ejection value.
- the fireproof-lined chamber now has the effect that the oxidation process is largely completed, so that the intermediate products and incomplete combustion products, such as carbon monoxide, soot and hydrogen, which are initially formed are burned at the end of the chamber and that flue gas can be cooled in the heat exchanger immediately following the chamber .
- the retaining ring at the end of the chamber swirls the combustion products and accelerates the complete burnout of the fuel.
- the burner according to the invention is distinguished by the fact that the prescribed limit values for the emission of gaseous pollutants such as nitrogen oxide and carbon monoxide as well as of solid pollutants are observed equally.
- the burner contains several fuel lances, namely a central lance 1 and several, in the present case three outer satellite lances 2, which surround the central lance 1 on a pitch circle.
- the central lance 1 and the satellite lances 2 open into a fireproof-lined chamber 4 provided with an end wall 3.
- the fuel lances can be designed as oil lances or as gas lances for the combustion of liquid or gaseous fuel. All fuel lances can be moved axially.
- This burner is designed for the low-pollutant combustion of particularly heavy heating oil in narrow fireboxes.
- the internal mixer is used as the atomizer lance for the liquid fuel. Compressed air can be used as an atomizing agent or steam can be used.
- the quantity distribution of the fuel is provided so that each fuel lance is evenly d. in the case of a central lance 1 and n satellite lances 2, 100 / n + 1% of the total fuel quantity is applied.
- the fuel injection with the central lance 1 takes place via uniformly arranged nozzle bores, the spray angle being adapted to the design of the chamber 4.
- the fuel outflow from the satellite lances 2 is provided in one direction via a plurality of nozzle bores arranged one behind the other.
- the spray jet from the satellite lances 2 can be selected such that it is directed into the center or tangentially to any imaginary circle within the chamber 4.
- the injection position can be shifted axially.
- the fuel quantity is divided between the central lance 1 and the satellite lances 2 in this way so that coke formation is avoided and the gasification of the fuel is accelerated.
- the variable and graduated fuel injection keeps the local flame temperatures and the oxygen concentration as low as possible, which counteracts the formation of thermal nitrogen oxide and fuel nitrogen oxide.
- the central lance 1 is enclosed by a protective tube 5, which in turn is surrounded by two ring channels 6, 7, which are connected to a first air chamber 8.
- the combustion air entering through the first air chamber 8 via an air inlet connection 9 is divided by the ring channels 6, 7 into an internal primary air flow and an external secondary air flow.
- Air guiding bodies 10 are arranged in the entrance of the ring channels 6, 7, which are axially displaceable via a rear linkage and via which the pressure and speed relationships of the air flows can be mutually coordinated.
- a control flap 11 is arranged in the entrance of the air box 8, by means of which the amount of combustion air supplied to the ring channels 6, 7 is regulated.
- a swirler 12 which forces a swirl on the primary air flow. Additional swirl generators can be provided at the inlet end of the ring channel 7.
- the outer ring duct 7 for guiding the secondary air is surrounded by a flue gas ring duct 13 which is connected via a flue gas chamber 14 to a separate flue gas inlet connection 15.
- the flue gas inlet connection 15 is supplied with flue gas, which is drawn in from the boiler connected to the burner by means of a fan.
- the flue gas enters the chamber 4 via the flue gas ring channel 13 and envelops the fuel jet of the central lance 1 and the primary air jet and the secondary air jet over a certain path length.
- a second air chamber 16 which is used to supply a further partial flow of the combustion air as tertiary air, is connected to the air inlet connection 9, separated by the flue gas chamber 14.
- a regulating flap 17 for regulating the amount of air entering is arranged in the entrance of the second air chamber 16.
- a first set of air nozzles 18 Arranged in the end wall 3 of the chamber 4 is a first set of air nozzles 18 which open into the second air chamber 16 and protrude into the chamber 4 with the end that is angled or straight to the longitudinal axis of the chamber 4.
- the outlet openings of these air nozzles 18 lie on a pitch circle, the diameter of which is smaller than the pitch circle of the satellite lance 2 and larger than the diameter of the outlet opening of the flue gas ring duct 13.
- the outlet openings of the air nozzles 18 also lie in the flow direction of the flue gas in front of the nozzle bores of the satellite lances 2.
- the second air chamber 16 is connected via a series of through bores 19 to an annular chamber 20 which surrounds the chamber 4. At a distance from the outlet openings of the air nozzles 18 and the nozzle bores of the satellite lances 2 are guided obliquely through the side wall of the chamber 4 further nozzles 21 which open into the annular chamber 20 and protrude into the chamber 4.
- the outlet openings of these nozzles 21 lie on a pitch circle, the diameter of which is larger than the diameter of the pitch circle on which the satellite lances 2 are arranged.
- the combustion air supplied to the second air chamber 16 is supplied to the chamber 4 as tertiary air I through the air nozzles 18 and at a distance therefrom as tertiary air II through the further nozzles 21.
- the direction of the air jets emerging from the air nozzles 18 and the further nozzles 21 is indicated in the drawing by dash-dotted lines. It can be seen from FIGS. 1 and 2 that the tertiary air jets are directed at a spatial angle against the longitudinal axis of the chamber 4.
- the flame tube 23, cooled by a water jacket 22, of a flame tube boiler is connected directly to the outlet end of the chamber 4.
- the combustion products emerging from the chamber 4 are thus immediately cooled.
- a retaining ring 24 composed of stone segments is provided.
- the retaining ring 24 creates a constriction zone, whereby a further swirling of the combustion products is achieved and the complete burnout of the fuel is thereby accelerated.
- the retaining ring 24 can be arranged at different points in the longitudinal direction of the chamber 4 to influence the combustion process. In the event of a shift towards the burner lances, the further nozzles 21 for blowing in the tertiary air II also lie behind the retaining ring 24 in the direction of flow of the flue gas.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Combustion Of Fluid Fuel (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Feeding And Controlling Fuel (AREA)
- Pre-Mixing And Non-Premixing Gas Burner (AREA)
- Nozzles For Spraying Of Liquid Fuel (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT87116550T ATE61466T1 (de) | 1987-02-26 | 1987-11-10 | Brenner zum verbrennen von fluessigen oder gasfoermigen brennstoffen. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3706234 | 1987-02-26 | ||
DE19873706234 DE3706234A1 (de) | 1987-02-26 | 1987-02-26 | Brenner zum verbrennen von fluessigen oder gasfoermigen brennstoffen |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0279913A2 EP0279913A2 (de) | 1988-08-31 |
EP0279913A3 EP0279913A3 (en) | 1989-05-03 |
EP0279913B1 true EP0279913B1 (de) | 1991-03-06 |
Family
ID=6321850
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP87116550A Expired - Lifetime EP0279913B1 (de) | 1987-02-26 | 1987-11-10 | Brenner zum Verbrennen von flüssigen oder gasförmigen Brennstoffen |
Country Status (7)
Country | Link |
---|---|
US (1) | US4815966A (zh) |
EP (1) | EP0279913B1 (zh) |
JP (1) | JPS63226515A (zh) |
AT (1) | ATE61466T1 (zh) |
DE (2) | DE3706234A1 (zh) |
DK (1) | DK165138C (zh) |
ES (1) | ES2020544B3 (zh) |
Families Citing this family (51)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5193995A (en) * | 1987-12-21 | 1993-03-16 | Asea Brown Boveri Ltd. | Apparatus for premixing-type combustion of liquid fuel |
CH679692A5 (zh) * | 1989-04-24 | 1992-03-31 | Asea Brown Boveri | |
US5092760A (en) * | 1990-08-01 | 1992-03-03 | Maxon Corporation | Oxygen-fuel burner assembly and operation |
US5275554A (en) * | 1990-08-31 | 1994-01-04 | Power-Flame, Inc. | Combustion system with low NOx adapter assembly |
US5334012A (en) * | 1990-12-27 | 1994-08-02 | Astec Industries, Inc. | Combustion chamber having reduced NOx emissions |
IT1255613B (it) * | 1992-09-24 | 1995-11-09 | Eniricerche Spa | Sistema di combustione a basse emissioni inquinanti per turbine a gas |
US5441404A (en) * | 1993-01-29 | 1995-08-15 | Gordan-Piatt Energy Group, Inc. | Burner assembly for reducing nitrogen oxides during combustion of gaseous fuels |
US5460512A (en) * | 1993-05-27 | 1995-10-24 | Coen Company, Inc. | Vibration-resistant low NOx burner |
US5542839A (en) * | 1994-01-31 | 1996-08-06 | Gas Research Institute | Temperature controlled low emissions burner |
DE4420140C2 (de) * | 1994-06-09 | 2001-03-01 | Jasper Ges Fuer Energiewirtsch | Brenner für eine Öl- oder Gasfeuerung |
US5562438A (en) * | 1995-06-22 | 1996-10-08 | Burnham Properties Corporation | Flue gas recirculation burner providing low Nox emissions |
FR2771798B1 (fr) * | 1997-12-02 | 1999-12-31 | Air Liquide | Bruleur oxy-combustible |
FR2772887B1 (fr) | 1997-12-24 | 2000-03-17 | Pillard Chauffage | Bruleur a faible emission d'oxyde d'azote avec circuit de gaz recycle |
US6007325A (en) * | 1998-02-09 | 1999-12-28 | Gas Research Institute | Ultra low emissions burner |
US5984665A (en) * | 1998-02-09 | 1999-11-16 | Gas Research Institute | Low emissions surface combustion pilot and flame holder |
US5993193A (en) * | 1998-02-09 | 1999-11-30 | Gas Research, Inc. | Variable heat flux low emissions burner |
US5944503A (en) * | 1998-05-20 | 1999-08-31 | Selas Corporation Of America | Low NOx floor burner, and heating method |
AU4694099A (en) * | 1998-06-17 | 2000-01-05 | John Zink Company Llc | Low no chi and low co burner and method for operating same |
US6102687A (en) * | 1998-09-28 | 2000-08-15 | U.S. Department Of Energy | Simplified configuration for the combustor of an oil burner using a low pressure, high flow air-atomizing nozzle |
AT408796B (de) * | 1999-04-29 | 2002-03-25 | Dumag Ohg | Brenner |
FR2794221B1 (fr) * | 1999-05-31 | 2001-08-24 | Pillard Chauffage | PERFECTIONNEMENTS AUX BRULEURS A COMBUSTIBLE LIQUIDE A BASSE EMISSION DE NOx ET DE POUSSIERES, ET AUX ATOMISEURS |
DE60025933T2 (de) * | 1999-11-02 | 2006-11-09 | Ebara Corp. | Brennvorrichtung zur behandlung von abgas |
US6488496B1 (en) * | 2001-09-06 | 2002-12-03 | Hauck Manufacturing Co. | Compact combination burner with adjustable spin section |
US6893251B2 (en) | 2002-03-16 | 2005-05-17 | Exxon Mobil Chemical Patents Inc. | Burner design for reduced NOx emissions |
WO2003081132A2 (en) * | 2002-03-16 | 2003-10-02 | Exxonmobil Chemical Patents Inc. | Improved burner with low nox emissions |
US6887068B2 (en) | 2002-03-16 | 2005-05-03 | Exxonmobil Chemical Patents Inc. | Centering plate for burner |
US6846175B2 (en) * | 2002-03-16 | 2005-01-25 | Exxonmobil Chemical Patents Inc. | Burner employing flue-gas recirculation system |
US6986658B2 (en) | 2002-03-16 | 2006-01-17 | Exxonmobil Chemical Patents, Inc. | Burner employing steam injection |
US6866502B2 (en) | 2002-03-16 | 2005-03-15 | Exxonmobil Chemical Patents Inc. | Burner system employing flue gas recirculation |
US6869277B2 (en) * | 2002-03-16 | 2005-03-22 | Exxonmobil Chemical Patents Inc. | Burner employing cooled flue gas recirculation |
US6890172B2 (en) | 2002-03-16 | 2005-05-10 | Exxonmobil Chemical Patents Inc. | Burner with flue gas recirculation |
US6893252B2 (en) | 2002-03-16 | 2005-05-17 | Exxonmobil Chemical Patents Inc. | Fuel spud for high temperature burners |
US7322818B2 (en) * | 2002-03-16 | 2008-01-29 | Exxonmobil Chemical Patents Inc. | Method for adjusting pre-mix burners to reduce NOx emissions |
US20030175635A1 (en) * | 2002-03-16 | 2003-09-18 | George Stephens | Burner employing flue-gas recirculation system with enlarged circulation duct |
WO2003081129A1 (en) | 2002-03-16 | 2003-10-02 | Exxonmobil Chemical Patents Inc. | Burner tip and seal for optimizing burner performance |
US6881053B2 (en) | 2002-03-16 | 2005-04-19 | Exxonmobil Chemical Patents Inc. | Burner with high capacity venturi |
ATE484713T1 (de) * | 2002-03-16 | 2010-10-15 | Exxonmobil Chem Patents Inc | Lösbarer zündelementdeckel für einen brenner |
US20030175634A1 (en) * | 2002-03-16 | 2003-09-18 | George Stephens | Burner with high flow area tip |
US7163392B2 (en) * | 2003-09-05 | 2007-01-16 | Feese James J | Three stage low NOx burner and method |
SE0501840L (sv) * | 2005-08-19 | 2007-02-20 | Aga Ab | Förfarande jämte för övervakning av en brännare |
US7901204B2 (en) * | 2006-01-24 | 2011-03-08 | Exxonmobil Chemical Patents Inc. | Dual fuel gas-liquid burner |
US8075305B2 (en) * | 2006-01-24 | 2011-12-13 | Exxonmobil Chemical Patents Inc. | Dual fuel gas-liquid burner |
US7909601B2 (en) * | 2006-01-24 | 2011-03-22 | Exxonmobil Chemical Patents Inc. | Dual fuel gas-liquid burner |
KR100969857B1 (ko) * | 2008-11-21 | 2010-07-13 | 한국생산기술연구원 | 연료 연소장치 |
US9089811B2 (en) | 2012-04-30 | 2015-07-28 | Highvac Corp. | Coaxial / coaxial treatment module |
US9909755B2 (en) * | 2013-03-15 | 2018-03-06 | Fives North American Combustion, Inc. | Low NOx combustion method and apparatus |
CN103185342B (zh) * | 2013-04-03 | 2015-09-30 | 大唐韩城第二发电有限责任公司 | 一种油气复合燃烧器 |
AU2017244041B2 (en) | 2016-03-30 | 2022-12-01 | Marine Canada Acquisition Inc. | Vehicle heater and controls therefor |
CN109855096B (zh) * | 2019-03-30 | 2024-06-07 | 华侨大学 | 一种多级旋流燃烧器 |
RU207013U1 (ru) * | 2021-05-11 | 2021-10-06 | Федеральное государственное автономное образовательное учреждение высшего образования «Дальневосточный федеральный университет» (ДВФУ) | Циклонный предтопок |
US12025311B2 (en) * | 2021-08-24 | 2024-07-02 | Solar Turbines Incorporated | Micromix fuel injection air nozzles |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3868211A (en) * | 1974-01-11 | 1975-02-25 | Aqua Chem Inc | Pollutant reduction with selective gas stack recirculation |
US4023921A (en) * | 1975-11-24 | 1977-05-17 | Electric Power Research Institute | Oil burner for NOx emission control |
US4347052A (en) * | 1978-06-19 | 1982-08-31 | John Zink Company | Low NOX burner |
DE3048201A1 (de) * | 1980-12-20 | 1982-07-08 | L. & C. Steinmüller GmbH, 5270 Gummersbach | "brenner zur verminderung der no(pfeil abwaerts)x(pfeil abwaerts)-emission" |
JPS57204706A (en) * | 1981-06-09 | 1982-12-15 | Babcock Hitachi Kk | Combusting method of preventing corrosion and blockade of air preheater |
DE3327597A1 (de) * | 1983-07-30 | 1985-02-07 | Deutsche Babcock Werke AG, 4200 Oberhausen | Verfahren und brenner zum verbrennen von fluessigen oder gasfoermigen brennstoffen unter verminderter bildung von nox |
-
1987
- 1987-02-26 DE DE19873706234 patent/DE3706234A1/de active Granted
- 1987-11-10 DE DE8787116550T patent/DE3768486D1/de not_active Expired - Fee Related
- 1987-11-10 ES ES87116550T patent/ES2020544B3/es not_active Expired - Lifetime
- 1987-11-10 AT AT87116550T patent/ATE61466T1/de not_active IP Right Cessation
- 1987-11-10 EP EP87116550A patent/EP0279913B1/de not_active Expired - Lifetime
- 1987-12-04 JP JP62308479A patent/JPS63226515A/ja active Pending
-
1988
- 1988-02-16 DK DK078088A patent/DK165138C/da not_active IP Right Cessation
- 1988-02-19 US US07/157,960 patent/US4815966A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US4815966A (en) | 1989-03-28 |
DK165138B (da) | 1992-10-12 |
EP0279913A3 (en) | 1989-05-03 |
DE3706234C2 (zh) | 1989-06-01 |
ATE61466T1 (de) | 1991-03-15 |
DK165138C (da) | 1993-02-22 |
EP0279913A2 (de) | 1988-08-31 |
DE3768486D1 (de) | 1991-04-11 |
JPS63226515A (ja) | 1988-09-21 |
DE3706234A1 (de) | 1988-09-08 |
DK78088D0 (da) | 1988-02-16 |
ES2020544B3 (es) | 1991-08-16 |
DK78088A (da) | 1988-08-27 |
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