EP0257319A1 - Procédé pour la réalisation de revêtements protecteurs - Google Patents
Procédé pour la réalisation de revêtements protecteurs Download PDFInfo
- Publication number
- EP0257319A1 EP0257319A1 EP87110805A EP87110805A EP0257319A1 EP 0257319 A1 EP0257319 A1 EP 0257319A1 EP 87110805 A EP87110805 A EP 87110805A EP 87110805 A EP87110805 A EP 87110805A EP 0257319 A1 EP0257319 A1 EP 0257319A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- suspension
- component
- temperature
- freeze
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 24
- 239000011253 protective coating Substances 0.000 title 1
- 239000010410 layer Substances 0.000 claims abstract description 23
- 239000000725 suspension Substances 0.000 claims abstract description 21
- 239000000843 powder Substances 0.000 claims abstract description 14
- 238000004108 freeze drying Methods 0.000 claims abstract description 11
- 238000007654 immersion Methods 0.000 claims abstract description 7
- 239000011241 protective layer Substances 0.000 claims abstract description 6
- 239000000126 substance Substances 0.000 claims abstract description 5
- 239000007858 starting material Substances 0.000 claims abstract description 3
- 239000002904 solvent Substances 0.000 claims abstract 9
- 238000007710 freezing Methods 0.000 claims abstract 6
- 230000008014 freezing Effects 0.000 claims abstract 6
- 238000010438 heat treatment Methods 0.000 claims description 8
- 238000005245 sintering Methods 0.000 claims description 8
- 239000011230 binding agent Substances 0.000 claims description 5
- 239000000919 ceramic Substances 0.000 claims description 3
- 238000003618 dip coating Methods 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000000463 material Substances 0.000 description 8
- 239000002131 composite material Substances 0.000 description 5
- 238000011282 treatment Methods 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 238000000137 annealing Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000009189 diving Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 238000001513 hot isostatic pressing Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000011089 mechanical engineering Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000002347 wear-protection layer Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
Definitions
- the invention relates to a method for producing protective layers against thermal and / or chemical and / or mechanical stresses on components, in particular on complexly shaped components, such as turbine blades.
- Known protective layers or layered composites make use of the fact that it is possible with today's process technology to produce different properties in the surface of a component than those of the base material.
- Examples of such layers or composite materials with layers of this type are thermal insulation layers (pitting corrosion), wear protection layers (including tribological layers), rub-on and run-in coverings.
- the layers mentioned are predominantly applied by thermal spray processes.
- the object of the invention is to provide components or layered composite bodies with a protected surface, on parts already subjected to a shaping, in particular parts of complex shape, and to be able to cover them in a uniform layer thickness without great effort.
- the solution of the invention consists in a method for the deposition of layers in a physical way.
- a starting powder in a suspension is applied to a cooled component by immersion in the bath in the suspension and the component provided with the dip coating is subjected to freeze-drying.
- any desired layer thickness can be produced uniformly with the invention, and individual steps of the method can be repeated as often as desired, e.g. the production of the diving cover.
- a heat treatment and other treatments of the coated component can be carried out after the production of the coating, such as e.g. sealing sintering or sealing on the surface.
- a sintering or pressing program can also be combined for special requirements (hot isostatic pressing).
- Energy beam treatments of the surface, doping, infiltration of substances other than layer material and in a form other than powder can also be used within the scope of the present invention.
- a binder in particular an organic binder, can be dissolved in the suspension liquid, which brings about an increased green strength of the powder layer, in particular if a powder is used as the layer material, the mean grain size of which is above 25 ⁇ m. The organic binder is removed again at the beginning of the sintering process or in a separate heat treatment.
- the applications of the invention are not limited to the given exemplary embodiments, but generally in the case of layered materials or layered composite materials, the surfaces of which have a different property from the base material, ie the base of the component should.
- the invention is preferably used for protective layers, and here in particular for those which are subject to combined requirements.
- the main area of application is general mechanical engineering, components for vehicles of all kinds, but also stationary systems such as manufacturing systems, especially apparatus engineering.
- the base body of the composite body to be counted as the end product of the invention can be selected from almost any materials, such as metallic materials, metal compounds, intermetallic phases, ceramics, metal ceramics, metal glass, glass ceramics and / or combinations of the above materials with plastics.
- the devices which are necessary for carrying out the method according to the invention are of a simple and customary type, in particular as regards the containers required for the immersion method or the coolants for the component, such as refrigerators.
- the freeze dryers commonly used in food technology can be used for freeze drying, and the annealing and sintering ovens or presses or other post-treatment devices are also known per se.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Powder Metallurgy (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3628363 | 1986-08-21 | ||
DE19863628363 DE3628363A1 (de) | 1986-08-21 | 1986-08-21 | Verfahren zum herstellen von schutzschichten |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0257319A1 true EP0257319A1 (fr) | 1988-03-02 |
EP0257319B1 EP0257319B1 (fr) | 1990-06-27 |
Family
ID=6307854
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP87110805A Expired - Lifetime EP0257319B1 (fr) | 1986-08-21 | 1987-07-25 | Procédé pour la réalisation de revêtements protecteurs |
Country Status (4)
Country | Link |
---|---|
US (1) | US4902536A (fr) |
EP (1) | EP0257319B1 (fr) |
JP (1) | JPS6353278A (fr) |
DE (2) | DE3628363A1 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3821819A1 (de) * | 1988-06-29 | 1990-02-08 | Nokia Unterhaltungselektronik | Verfahren zum herstellen einer duennen schicht |
ES2009355A6 (es) * | 1988-10-17 | 1989-09-16 | Sintermetal Sa | Procedimiento para preparar recubrimientos aplicables por tecnicas pulvimetalurgicas en piezas mecanicas. |
JPH0765232B2 (ja) * | 1989-10-12 | 1995-07-12 | 三菱レイヨン株式会社 | 非晶質合金の製法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1126103A (fr) * | 1954-06-17 | 1956-11-15 | Birmingham Small Arms Co Ltd | Objet en acier ou en alliage résistant à la chaleur |
FR1428311A (fr) * | 1964-03-06 | 1966-02-11 | Siemens Planiawerke Ag | Procédé de fabrication de gaine, ainsi que les gaines obtenues par le présent procédé ou procédé similaire |
FR1502325A (fr) * | 1965-11-26 | 1967-11-18 | Procédé et dispositif pour améliorer l'état de surface des pièces métalliques | |
US3475161A (en) * | 1967-03-14 | 1969-10-28 | Howmet Corp | Method of forming cemented carbide coatings on metal surfaces by employing volatile,organic liquid solvents and organic binders |
FR2179251A1 (fr) * | 1972-04-07 | 1973-11-16 | Rca Corp | |
DE2718758A1 (de) * | 1977-04-27 | 1978-11-02 | Siemens Ag | Verfahren zum metallisieren von roehren aus keramik und vorrichtutung zur durchfuehrung dieses verfahrens |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1271281A (en) * | 1968-07-31 | 1972-04-19 | Ethyl Corp | Coating of webs by freeze-drying and products therefrom |
US4328285A (en) * | 1980-07-21 | 1982-05-04 | General Electric Company | Method of coating a superalloy substrate, coating compositions, and composites obtained therefrom |
-
1986
- 1986-08-21 DE DE19863628363 patent/DE3628363A1/de not_active Withdrawn
-
1987
- 1987-07-25 EP EP87110805A patent/EP0257319B1/fr not_active Expired - Lifetime
- 1987-07-25 DE DE8787110805T patent/DE3763430D1/de not_active Expired - Lifetime
- 1987-07-28 US US07/079,166 patent/US4902536A/en not_active Expired - Fee Related
- 1987-08-11 JP JP62201683A patent/JPS6353278A/ja active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1126103A (fr) * | 1954-06-17 | 1956-11-15 | Birmingham Small Arms Co Ltd | Objet en acier ou en alliage résistant à la chaleur |
FR1428311A (fr) * | 1964-03-06 | 1966-02-11 | Siemens Planiawerke Ag | Procédé de fabrication de gaine, ainsi que les gaines obtenues par le présent procédé ou procédé similaire |
FR1502325A (fr) * | 1965-11-26 | 1967-11-18 | Procédé et dispositif pour améliorer l'état de surface des pièces métalliques | |
US3475161A (en) * | 1967-03-14 | 1969-10-28 | Howmet Corp | Method of forming cemented carbide coatings on metal surfaces by employing volatile,organic liquid solvents and organic binders |
FR2179251A1 (fr) * | 1972-04-07 | 1973-11-16 | Rca Corp | |
DE2718758A1 (de) * | 1977-04-27 | 1978-11-02 | Siemens Ag | Verfahren zum metallisieren von roehren aus keramik und vorrichtutung zur durchfuehrung dieses verfahrens |
Also Published As
Publication number | Publication date |
---|---|
DE3763430D1 (de) | 1990-08-02 |
JPS6353278A (ja) | 1988-03-07 |
US4902536A (en) | 1990-02-20 |
DE3628363A1 (de) | 1988-02-25 |
EP0257319B1 (fr) | 1990-06-27 |
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