EP0251192B1 - Schmiermittel für die Metallumformung - Google Patents

Schmiermittel für die Metallumformung Download PDF

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Publication number
EP0251192B1
EP0251192B1 EP87109098A EP87109098A EP0251192B1 EP 0251192 B1 EP0251192 B1 EP 0251192B1 EP 87109098 A EP87109098 A EP 87109098A EP 87109098 A EP87109098 A EP 87109098A EP 0251192 B1 EP0251192 B1 EP 0251192B1
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EP
European Patent Office
Prior art keywords
weight
lubricant
resin
wax
monomer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP87109098A
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German (de)
English (en)
French (fr)
Other versions
EP0251192A2 (de
EP0251192A3 (en
Inventor
Yoshio Nagae
Takashi Kawakami
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nihon Parkerizing Co Ltd
Original Assignee
Nihon Parkerizing Co Ltd
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Publication date
Application filed by Nihon Parkerizing Co Ltd filed Critical Nihon Parkerizing Co Ltd
Priority to AT87109098T priority Critical patent/ATE75770T1/de
Publication of EP0251192A2 publication Critical patent/EP0251192A2/de
Publication of EP0251192A3 publication Critical patent/EP0251192A3/de
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Publication of EP0251192B1 publication Critical patent/EP0251192B1/de
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    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
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    • C10M2213/06—Perfluoro polymers
    • C10M2213/062—Polytetrafluoroethylene [PTFE]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/08—Amides [having hydrocarbon substituents containing less than thirty carbon atoms]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/08—Amides [having hydrocarbon substituents containing less than thirty carbon atoms]
    • C10M2215/082—Amides [having hydrocarbon substituents containing less than thirty carbon atoms] containing hydroxyl groups; Alkoxylated derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
    • C10M2215/26—Amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
    • C10M2215/28—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/024—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/026—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrile group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2225/02—Macromolecular compounds from phosphorus-containg monomers, obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
    • C10M2225/041—Hydrocarbon polymers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/015—Dispersions of solid lubricants
    • C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating

Definitions

  • the invention relates to an aqueous lubricant for the cold forming of metals and a method for facilitating the cold forming of metallic workpieces with the aid of this lubricant.
  • a lubricant coating in order to reduce the frictional resistance between the metal surface of the workpiece and the forming tool.
  • two methods are used for this.
  • One is to use lubricants with high pressure additives or viscosity regulators when lower degrees of deformation are required.
  • the other provides for a resin-based lubricant film to be applied first from the organic phase and then a lubricating oil if heavy reshaping is intended.
  • EP-A-175 547 describes lubricants for cold forming metals which contain an acrylate-based resin with a glass transition point of -10 to 20 ° C., a fatty acid or a fatty acid ester and a surfactant.
  • the object of the invention is to provide a lubricant for the cold forming of metals, with the help of which even heavy forming can be carried out satisfactorily, which can do without organic solvents and whose residues can be removed in a simple manner after the forming.
  • aqueous lubricant containing 10 to 35% by weight of a thermosetting resin based on acrylate with a glass transition temperature of -10 to 25 ° C, 3 to 15% by weight wax and 0.5 to 5% by weight.
  • thermosetting resin the weight ratio of thermosetting resin to wax being 2 to 12, characterized by a thermosetting resin of the general formula (Ra - Rb - Rc - Rd) n, in which Ra is at least one monomer from the group consisting of vinyltoluene, styrene, methyl methacrylic, and acrylonitrile and has a proportion of 20 to 70% by weight of the resin, Rb is at least one monomer from the group of an acrylic ester, obtained by reaction of acrylic acid with a primary aliphatic alcohol with 1 to 12 C atoms, or a methacrylic ester obtained by reaction of methacrylic acid with a primary aliphatic alcohol with 3 to 12 C atoms, and has a proportion of 20 to 70% by weight of the resin, Rc is at least one monomer from the group consisting of acrylic acid, methacrylic acid, maleic acid, itaconic acid, 2-hydroxyethyl methacrylate phosphoric acid ester or salts thereof and has
  • the aqueous lubricant is allowed to air dry, if necessary by additional heating.
  • the order of the individual monomers in the resin is irrelevant.
  • the value for "n" within the limits of 1,000 and 50,000 should be selected so that a resin with a glass transition point of -10 ° C to + 25 ° C results.
  • the resin can be prepared by polymerizing a mixture of the monomers at a temperature of 50 to 60 ° C for a period of 5 to 7 hours.
  • the monomers can also be polymerized in solution or dispersion.
  • different from water Solvents e.g. As ethanol or isopropanol, can be used or used.
  • Suitable waxes include paraffin wax, animal or vegetable oil, higher fatty acids, higher alcohols, esters of higher fatty acids and higher alcohols, higher fatty acid amides, higher fatty acid amines and the like.
  • waxes with a melting point above 45 ° C.
  • One way to increase the melting point of the wax is to add hydrogen to double bonds.
  • Particularly suitable surfactants are those of the anionic and / or nonionic type.
  • anionic surfactants are sodium alkylnaphthyl sulfonate, sodium alkylbenzenesulfonate and Turkish red oil.
  • nonionic surfactants are polyoxyethylene alkyl ethers with the alkyl group of a higher alcohol, polyoxyethylene nonylphenol ether, polyethylene glycol fatty acid esters and sorbitol fatty acid esters.
  • the surfactant is particularly responsible for the emulsification or dispersion of the wax in water.
  • stirring can be carried out mechanically with the addition of a homogenizing agent.
  • aqueous lubricant consists in an additional content of solid lubricant additive.
  • solid lubricant additive examples include graphite, molydand disulfide, talc, Teflon, boron nitride, calcium carbonate, melamine, cyanuric acid adducts and the like.
  • thermosetting resin based on acrylate arises from the following facts.
  • the cold forming of metals generates heat that increases the temperature of the workpiece and tool.
  • the heavier the forming the greater the heat development and thus the higher the temperature.
  • heat accumulation also occurs.
  • thermoplastic resins based on acrylate which soften when heated above the glass transition point and therefore cannot prevent contact between the workpiece and the tool, this contact and consequently corrosion is avoided with heat-curable resins based on acrylate.
  • Thermosetting resins do not have this advantage par excellence. Many resins harden in such a way that they cannot follow the expansion of the workpiece associated with the deformation. As a result, the film of lubricant tears and there is the aforementioned contact between the workpiece and the tool. Many of the thermosetting resins are also no longer easy to remove after forming, e.g. with the help of an alkaline cleaner.
  • thermosetting resins based on acrylate with a glass transition point from - 10 ° C to + 25 ° C, the advantages of excellent adhesion on the Metal surface, the flexibility or adaptability to the elongation and the ease of removal of the lubricant film after the forming united.
  • the lubricant coating becomes too soft so that it can be removed during the forming process.
  • the coating becomes too hard and the adaptability to the elongation of the workpiece is no longer sufficient.
  • a lubricant that contains an acrylic-based resin with a glass transition point from 0 to + 5 ° C.
  • the monomer amounts Ra - in the amounts specified in each case - are in particular for the hardness and tensile strength, that of Rb in particular for the extensibility, that of Rc in particular for the adhesion to the metal surface and the dispersibility of the resin and that of Rd in particular responsible for an additional improvement in liability.
  • the lubricant coating can become too soft, if it exceeds 70% by weight it can become too hard. In both cases, a perfect separation effect for the workpiece / tool is not guaranteed with certainty.
  • the proportion of the monomer Rb is below 20% by weight, the glass transition point is increased and the coating formation at room temperature can deteriorate. At a If the proportion exceeds 70% by weight, the hardness of the lubricant coating can become too low.
  • the adhesion of the coating can be too low and the removability of the remaining lubricant film with an alkaline cleaner can be impaired (at less than 1% by weight).
  • the viscosity of the lubricant can increase significantly, which would make it more difficult to apply, and its hygroscopicity may increase, which would be associated with reduced adhesion due to the absorption of water (at more than 15% by weight).
  • the degree of crosslinking can increase so much that the flexibility of the lubricant coating is lost.
  • a proportion of 5 to 15% by weight is optimal for the hydroxyalkyl methacrylate, and a proportion of 1 to 5% by weight is optimal for N-methylolacrylamide or glycidyl methacrylate.
  • thermosetting resin to wax is important insofar as the adhesion of the lubricant coating decreases when it falls below 2, so that the coating tears. If l2 is exceeded the lubricating effect after.
  • the preferred range is 4 to 6.
  • surfactant content It is important for the surfactant content that the dispersibility decreases too much when the concentrations are too low and that the lubricity of the coating is impaired when the concentrations are too high.
  • anionic or nonionic type surfactants cationic or amphoteric surfactants can also be used.
  • the lubricant is applied to the cleaned workpieces by dipping, spraying, brushing, pouring or roller application at room temperature. Then it is dried. The mixture is expediently dried in air, then heated to 80 to 120 ° C. and finally hardened. The procedure improves the adhesion of the lubricant coating.
  • the height of the coating weight depends essentially on the intended forming. Among other things, are regulated by the concentration of the lubricant components.
  • lubricant coatings with dry weights of 0.5 to 30 g / m 2 can be applied, with which any conventional cold forming can be carried out.
  • the coating has excellent adhesion and release properties.
  • Frictional heat follows the shape of the workpiece without breaking the film, effectively preventing it from seizing. After the deformation, the remaining lubricant film can be removed in a simple manner using an alkaline cleaner.
  • the layer weight produced was within the range from 10 to 15 g / m2.
  • the tubes were then drawn on a drawing bench and evaluated for their appearance and the removability of the lubricant film remaining on the surface.
  • the drawing conditions were Pipe dimensions: 25 mm diameter 2.5 mm wall thickness 2,000 mm length Cross-section reduction: 32% Pulling speed: 17.8 m / min.
  • the tubes were immersed in an alkaline solution at 90 ° C. for a period of 1 hour.
  • the solution contained 3% by weight sodium hydroxide, 1.5% by weight sodium tripolyphosphate and surfactant. The degree of removability was assessed visually.
  • Sheets of the same steel quality with the dimensions 50 x 100 x 0.8 mm were treated with the same lubricants under identical conditions as stated above for the pipes. They were then subjected to the Bauden test to determine the friction coefficient and the sliding number until the occurrence of contact marks.
  • Example 1 Steel pipes with the quality and pretreatment as in Example 1 were provided with an oxalate coating using a commercially available oxalation solution (Ferrbond A; 35 g / l, accelerator 16; 1 g / l from Nihon Parkerizing Co.) (treatment temperature 90 ° C., treatment time 10 min.). After water rinsing the tubes were at 80 ° C for 3 min. treated in a lubricant solution (Bonderlube 235 from Nihon Parkerizing Co; 70 g / l) and dried. Steel sheets were treated in the same way. The tests described in Example 1 were then carried out.
  • a commercially available oxalation solution Ferrbond A; 35 g / l, accelerator 16; 1 g / l from Nihon Parkerizing Co.
  • Example 1 Steel pipes of the quality and pretreatment described in Example 1 were min. dipped in a resin diluted with toluene in a ratio of 1: 1 (Hangsterfer III QD from Hangsterfer) and then air-dried for 1 day. The layer weight produced was 10 g / m2. After further application of a lubricating oil (J-1 from Hangsterfer), the tubes were drawn and evaluated as indicated in Example 1. Correspondingly treated sheets were subjected to the Bauden test.
  • Example 2 The experiment according to Example 1 was repeated with lubricant 1, but the resin no. l not the networking component Rd (HEMA).
  • the layer weight ranged from 10 to 15 g / m2.
  • Example 1 The test according to Example 1 was carried out with lubricant no. 3 repeated, but the resin contained No. 3 not the cross-linking component Rd (HPA).
  • Table 3 Drawing results Appearance of the drawn tube Removability of the lubricant film after pulling Examples 1 okay Good 2nd okay Good 3rd okay Good 4th okay Good 5 okay Good Comparative examples 1 okay not good 2nd okay not good 3rd Occurrence of contact marks Good 4th Occurrence of contact marks Good Bauden test Friction coefficient (1) Glide number until occurrence of contact marks (2) Examples 1 0.055 430 2nd 0.056 400 3rd 0.052 350 4th 0.051 360 5 0.060 450 Comparative examples 1 0.11 170 2nd 0.13 210 3rd 0.058 250 4th 0.056 260 (1) Lower values indicate better lubrication properties. (2) Larger glide ratio shows higher resistance to seizure.
  • the lubricant coatings produced with the lubricants according to the invention have excellent lubricating properties. They are significantly better than the lubricant coatings produced using the comparison tests. Furthermore, the lubricant coatings produced according to the invention are far superior to the other lubricant coatings in terms of removability after drawing.
  • Table 4 illustrates the better friction coefficient and the higher resistance to seizure phenomena obtained with the coatings according to the invention compared to known coatings.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Lubricants (AREA)
  • Paints Or Removers (AREA)
  • Forging (AREA)
EP87109098A 1986-06-27 1987-06-24 Schmiermittel für die Metallumformung Expired - Lifetime EP0251192B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT87109098T ATE75770T1 (de) 1986-06-27 1987-06-24 Schmiermittel fuer die metallumformung.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP151178/86 1986-06-27
JP61151178A JPS638489A (ja) 1986-06-27 1986-06-27 金属の冷間加工用潤滑剤

Publications (3)

Publication Number Publication Date
EP0251192A2 EP0251192A2 (de) 1988-01-07
EP0251192A3 EP0251192A3 (en) 1988-05-04
EP0251192B1 true EP0251192B1 (de) 1992-05-06

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EP (1) EP0251192B1 (enrdf_load_stackoverflow)
JP (1) JPS638489A (enrdf_load_stackoverflow)
AT (1) ATE75770T1 (enrdf_load_stackoverflow)
DE (2) DE3720841A1 (enrdf_load_stackoverflow)

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DE3916128A1 (de) * 1989-05-18 1990-11-22 Roehm Gmbh Waessrige funktionsfluessigkeiten enthaltend verdickungsmittel auf poly(meth)acrylat-basis
WO1992016603A1 (en) * 1991-03-22 1992-10-01 Henkel Corporation Lubrication for cold forming of metals
DE4445993A1 (de) * 1994-12-22 1996-06-27 Metallgesellschaft Ag Schmiermittel für die Metallumformung
US5547595A (en) * 1995-02-07 1996-08-20 Henkel Corporation Aqueous lubricant and process for cold forming metal, particularly pointing thick-walled metal tubes
US6899770B1 (en) 1999-03-04 2005-05-31 Henkel Corporation Composition and process for treating metal surfaces
US6291407B1 (en) 1999-09-08 2001-09-18 Lafrance Manufacturing Co. Agglomerated die casting lubricant
US6432886B1 (en) 1999-09-08 2002-08-13 Mary R. Reidmeyer Agglomerated lubricant
DE10258291A1 (de) * 2002-12-13 2004-07-08 Henkel Kgaa Verfahren zur Beschichtung von Metallsubstraten mit einem radikalisch polymerisierbaren Überzugsmittel und beschichtete Substrate
US7696136B2 (en) 2004-03-11 2010-04-13 Crompton Corporation Lubricant compositions containing hydroxy carboxylic acid and hydroxy polycarboxylic acid esters
CN101993770B (zh) * 2010-11-18 2013-08-21 江南大学 一种用于高速拉丝的润滑剂及其制备方法
JP2015183150A (ja) * 2014-03-26 2015-10-22 貴和化学薬品株式会社 塑性加工用潤滑剤
CN110144255A (zh) * 2019-04-30 2019-08-20 厦门加美石油集团有限公司 一种易清洗冷镦成型油及其制备方法
CN112588846A (zh) * 2020-11-23 2021-04-02 江阴法尔胜泓昇不锈钢制品有限公司 一种冷镦用合金钢丝的生产工艺

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JPS5234704B2 (enrdf_load_stackoverflow) * 1972-09-01 1977-09-05
JPS5337817B2 (enrdf_load_stackoverflow) * 1974-07-08 1978-10-12
US4474669A (en) * 1980-06-02 1984-10-02 United States Steel Corporation Can-making lubricant
US4403490A (en) * 1981-06-24 1983-09-13 E/M Lubricants, Inc. Metal forming lubricant and method of use thereof
JPS6160792A (ja) * 1984-08-31 1986-03-28 Nippon Kokan Kk <Nkk> 鋼板用冷間圧延油
JPS6187795A (ja) * 1984-09-19 1986-05-06 Kobe Steel Ltd 金属管の冷間加工用潤滑剤

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DE3778764D1 (de) 1992-06-11
ATE75770T1 (de) 1992-05-15
DE3720841A1 (de) 1988-01-14
EP0251192A2 (de) 1988-01-07
JPH0437878B2 (enrdf_load_stackoverflow) 1992-06-22
JPS638489A (ja) 1988-01-14
EP0251192A3 (en) 1988-05-04

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