Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
  • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
  • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
  • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
  • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
  • B41M5/382—Contact thermal transfer or sublimation processes
  • B41M5/392—Additives, other than colour forming substances, dyes or pigments, e.g. sensitisers, transfer promoting agents
  • B41M5/395—Macromolecular additives, e.g. binders

Definitions

• the present invention relates to an ink sheet for thermal transfer recording. Particularly, it relates to an ink composition which forms a coloring material layer (ink layer) of such an ink sheet.
• An ink sheet for thermal transfer recording comprises a support such as paper or plastic film and a coloring material layer applied thereon and printing is carried out by fusing a solid ink and transferring the fused ink to a recording paper.
• the heating is carried out by the use of a heating element either from the coloring material-coated surface of the sheet via paper or from the other surface (i.e., coloring material-uncoated surface) thereof. Alternatively, it may be carried out by applying an electric current to a resistant layer formed in an ink sheet.
• the coloring material layer is composed of a composition comprising a heat-fusible material and a pigment or dyestuff as a coloring material.
• carnauba wax or paraffin wax is generally used as the heat-fusible material
• polyethylene terephthalate film or polycarbonate film excellent in surface smoothness and dimensional stability is generally sued as the support.
• Transfer of an image from an ink sheet for thermal transfer recording to paper or the like is generally carried out with a thermal transfer printer having a thermal head and it is preferred in this transfer that the heat energy required for printing be as low as possible, because a decrease in heat energy required for printing serves not only to shorten the heating-cooling cycle time of the head to thereby accelerate printing and protect the head from thermal deterioration, but also to miniaturize the electric source of a line printer. Further, the decrease can make up a deficiency in heat resistance of base film. However, when an ink sheet containing a low-melting ink composition.
• thermo-plastic polymers to ink compositions.
• processes characterized by the addition of polyethylene wax Japanese Patent Laid-Open No. 101094/1983
• ethylene-alkyl acrylate copolymer Japanese Patent Laid-Open No. 120092/1985
• 1,2-polybutadiene Japanese Patent Laid-Open No. 127193/1985
• the inventors of the present invention have studied to solve the above problems and have found that an ink composition which can form a fast coating film, exhibits a high transfer sensitivity enough to carry out low-energy printing and does not stain a non-image area can be obtained by using an ester oligomer having a specified melting point and a specified molecular weight as a main component of the heat-fusible material of the ink composition.
• the invention provides an ink sheet for the thermal transfer recording which comprises a base layer coated with an ink layer, said ink layer comprising a colouring material and/or an inorganic or organic fine powder and a heat-fusible material containing 40 or more percent by weight of an ester oligomer having a number-average molecular weight of 500 to 6,000 and a melting point of 60 to 110°c.
• the above object is attained by using an ester oligomer having a melting point of 60 to 110°C and a number-average molecular weight of 500 to 6000. Therefore, the present invention is different in this point from the process of the prior art characterized by using a composition comprising a heat-fusible material (for example, wax) having a low melting point which serves to allow low-energy printing as a main component and a small amount of a high-melting thermoplastic resin which serves to prevent a non-image area from being stained with the low-melting material.
• a heat-fusible material for example, wax
• the ink sheet according to the present invention comprises a support and a coloring material layer containing a heat-fusible material applied thereon, wherein said heat-fusible material contains at least 40% by weight of the above ester oligomer to thereby attain the above object. If the ester oligomer content is less than 40% by weight, the obtained ink sheet will not exhibit high transfer sensitivity inherent in the ester oligomer.
• the ink sheet for thermal transfer recording comprises a base film as a support and at least one coloring material layer applied thereon and the coloring material layer contains at least one ester oligomer.
• the coloring material layer further contains at least one coloring material or/and an inorganic or organic fine powder.
• the coloring material is not particularly limited and may be any ordinary dye or pigment of yellow, red, blue, black or the like. For example, carbon black or oil black can be used as a black pigment.
• the fine powder to be used in the present invention can be selected depending upon the object and may be magnetic powder, other metal powder or conductive fine powder.
• the ester oligomer to be used in the present invention is synthesized by the condensation polymerization between a polyhydric alcohol and a polybasic acid, preferably between a dihydroxy compound and a dibasic acid or anhydride thereof and has a lower degree of polymerization than that of the polyethylene terephthalate of the prior art. Therefore, the ester oligomer melts at a relatively low temperature and in a narrow temperature range, thus being suitable as a heat-fusible material for a thermal transfer ink.
• the number-average molecular weight and melting point of the ester oligomer is 300 to 10000 (calculated by the end-group analysis) and from 40 to 120°C, respectively, preferably 500 to 6000 and 60 to 110°C (determined by the ring-and-ball method), respectively.
• the above condensation polymerization may be carried out by an ordinary process.
• dibasic acid examples include adipic, azelaic, sebacic, succinic and dodecanedoic acids
• dihydroxy compound examples include ethylene glycol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, 1,8-octanediol, 1,9-nonanediol, 1,10-decanediol and neopentyl glycol.
• ester oligomers may be used or a mixture of two or more of them may be used.
• the ester oligomer may be used together with an ordinary wax (for example, paraffin or carnauba wax), a rosin derivative (for example, hydrogenated rosin or ester gum), polyethylene wax, ethylene-alkyl acrylate or the like.
• the ink sheet according to the present invention comprises a base film and at least one coloring material layer applied thereon and, if necessary, other layers such as a topcoat or a resistance layer for electric heating.
• the support to be used in the ink sheet according to the present invention is preferably one which is resistant to heat and excellent in dimensional stability and surface smoothness.
• polyethylene terephthalate films which have been used as the base film up to this time and resin films having a thickness of 2 to 20 ⁇ and made of polycarbonate, polyethylene, polystyrene, polypropylene, polyimide or the like can be preferably used.
• the ink sheet for thermal transfer recording according to the present invention contains an ester oligomer having a low melting point of 60 to 110°C as a heat-fusible material, so that the ink sheet exhibits high transfer sensitivity and allows low-energy printing, thus being suitable for high-speed printing. Further, the ink sheet gives a printing having no unevenness without lowering the fastness thereof and is not in danger of causing blocking, because the ink sheet contains only a very small amount of low-melting components having a melting point of lower than 55°C.
• polydecamethylene adipate (number-average molecular weight : 1600 80 parts melting point : 73°C) rosin ester HS (a product of Arakawa Chemical) 5 carbon black 15
• a mixture comprising the above components was kneaded with 200 parts of toluene in a ball mill for 12 hours to obtain a homogeneous coating fluid.
• This coating fluid was applied to a polyethylene terephthalate film having a thickness of 6 ⁇ (a product of Toray Industries, Inc.; Lumirror) with a wire bar to form a coloring material layer having a thickness after drying of 3.5 ⁇ on the film, thus producing an ink sheet for thermal transfer recording.
• Printing on paper was carried out by the use of the obtained ink sheet and a thermal transfer printer of line type (NIP 5234, 9.4 dots/mm, a product of Nippon Electric Co., Ltd.) to determine the density of the transferred image.
• line type Nippon Electric Co., Ltd.
• the pulse width of the voltage to be applied was changed between 0.65 and 0.85 second by operating a density-controlling lever to measure the density of transferred image at each pulse width with a Macbeth densitometer (RD 514 type).
• RD 514 type Macbeth densitometer
• the pulse width of the voltage applied for the formation of transferred image having a density of 1.2 was found to be 0.66 millisecond. No stain was observed in the non-image area.
• Five ink sheets for thermal transfer were piled up and preserved under a pressure of 500g/cm2 for one week. The sheets were taken out and examined for blocking. No blocking was observed at all.
• polyhexamethylene sebacate (number-average molecular weight : 3200 80 parts melting point : 75°C rosin ester HS (A product of Arakawa Chemical) 5 parts carbon black 15
• Example 2 The same procedure as the one described in Example 1 was repeated except that a mixture comprising the above components was used insted of the mixture used in Example 1 to carry out the production of an ink sheet and printing.
• the density of transferred image was measured with a Macbeth densitometer (RD 514 type).
• the pulse width of the voltage applied for the formation of transferred image having a density of 1.2 was 0.66 millisecond.
• a mixture comprising the above components was dispersed with an attritor of 100°C for 4 hours to obtain an ink.
• This ink was applied to a polyethylene terephthalate film having a thickness of 6 ⁇ by hot-melt coating to produce an ink sheet having an ink layer having a thickness of 3.5 ⁇ .

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• Physics & Mathematics (AREA)
• Optics & Photonics (AREA)
• Thermal Transfer Or Thermal Recording In General (AREA)

Applications Claiming Priority (2)

Publications (3)

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Family Applications (1)

Country Status (7)

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• 1986
  • 1986-03-19 JP JP61061767A patent/JPS62216790A/ja active Granted
• 1987
  • 1987-03-09 ES ES198787301997T patent/ES2028068T3/es not_active Expired - Lifetime
  • 1987-03-09 EP EP87301997A patent/EP0238242B1/en not_active Expired - Lifetime
  • 1987-03-09 DE DE8787301997T patent/DE3775440D1/de not_active Expired - Fee Related
  • 1987-03-10 MY MYPI87000268A patent/MY100923A/en unknown
  • 1987-03-14 KR KR1019870002294A patent/KR910007068B1/ko not_active IP Right Cessation
• 1992
  • 1992-12-09 SG SG1247/92A patent/SG124792G/en unknown

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