EP0215451A2 - Produit de nettoyage pour surfaces dures - Google Patents
Produit de nettoyage pour surfaces dures Download PDFInfo
- Publication number
- EP0215451A2 EP0215451A2 EP86112626A EP86112626A EP0215451A2 EP 0215451 A2 EP0215451 A2 EP 0215451A2 EP 86112626 A EP86112626 A EP 86112626A EP 86112626 A EP86112626 A EP 86112626A EP 0215451 A2 EP0215451 A2 EP 0215451A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- water
- cleaning agent
- floor cleaning
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 27
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 48
- 239000004094 surface-active agent Substances 0.000 claims abstract description 14
- 239000008139 complexing agent Substances 0.000 claims abstract description 8
- 229920006037 cross link polymer Polymers 0.000 claims abstract description 5
- -1 alkanesulfonates Chemical class 0.000 claims description 19
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 17
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 16
- 229920000642 polymer Polymers 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 11
- 150000001298 alcohols Chemical class 0.000 claims description 11
- 239000012459 cleaning agent Substances 0.000 claims description 11
- 229920001577 copolymer Polymers 0.000 claims description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 10
- 239000000654 additive Substances 0.000 claims description 9
- 239000003960 organic solvent Substances 0.000 claims description 9
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 8
- 230000003113 alkalizing effect Effects 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- 150000002191 fatty alcohols Chemical class 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- MTHSVFCYNBDYFN-UHFFFAOYSA-N anhydrous diethylene glycol Natural products OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 6
- 239000002736 nonionic surfactant Substances 0.000 claims description 6
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 5
- 239000003945 anionic surfactant Substances 0.000 claims description 5
- 125000005397 methacrylic acid ester group Chemical group 0.000 claims description 5
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 3
- 125000005396 acrylic acid ester group Chemical group 0.000 claims description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims 1
- 125000000129 anionic group Chemical group 0.000 claims 1
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 230000001681 protective effect Effects 0.000 abstract description 2
- 230000009477 glass transition Effects 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 229920001519 homopolymer Polymers 0.000 description 7
- 238000004321 preservation Methods 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000004435 Oxo alcohol Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000004815 dispersion polymer Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 150000003138 primary alcohols Chemical class 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 150000003333 secondary alcohols Chemical class 0.000 description 2
- 239000000176 sodium gluconate Substances 0.000 description 2
- 235000012207 sodium gluconate Nutrition 0.000 description 2
- 229940005574 sodium gluconate Drugs 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- NPSJHQMIVNJLNN-UHFFFAOYSA-N 2-ethylhexyl 4-nitrobenzoate Chemical compound CCCCC(CC)COC(=O)C1=CC=C([N+]([O-])=O)C=C1 NPSJHQMIVNJLNN-UHFFFAOYSA-N 0.000 description 1
- 239000004808 2-ethylhexylester Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229940096386 coconut alcohol Drugs 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 150000003470 sulfuric acid monoesters Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- 239000001226 triphosphate Substances 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 235000019263 trisodium citrate Nutrition 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
Definitions
- the present invention relates to the cleaning and care of hard surfaces, in particular floors, in the household and in commercial cleaning with the aid of aqueous cleaning agents.
- numerous methods and agents have already been developed for the various purposes. The choice of agents is essentially determined by whether cleaning or preservation of the surface should be achieved as a matter of priority.
- the compositions contain, usually in emulsified form, waxes or film-forming polymers and crosslinking active ingredients, as a rule heavy metal salts, which together form self-glossy or polishable films on the treated surfaces after drying.
- a rule heavy metal salts which together form self-glossy or polishable films on the treated surfaces after drying.
- a disadvantage of these agents is that removal of the firmly adhering films, if it becomes necessary, for example because of dirt or damage, is only possible under extreme conditions.
- agents that focus on cleaning contain high levels of surfactants, often together with alkaline substances, organic solvents or abrasives. In many cases, these agents can be used to thoroughly remove dirt and old coverings, but the surfaces cleaned in this way are usually exposed to re-soiling without protection, unless a preservation treatment is followed.
- agents that contain the usual film formers in very low concentrations together with surfactants often lead to a disruptive film addition, which requires additional cleaning after certain times.
- the present invention offers a solution to this problem in the form of an agent consisting of: 0.5-10% by weight of surfactant from the group of addition compounds of ethylene oxide with alcohols or alkylphenols, alkylbenzenesulfonates, alkylsulfates, alkanesulfonates, fatty acid ester sulfonates and mixtures thereof, 0.1 - 4.5% by weight of alkali-soluble, non-metal-crosslinked polymer compound with a minimum film-forming temperature between 0 and 70 ° C, 0.01 - 5% by weight of alkaline complexing agents, 0-3% by weight of alkalizing agent, 0 - 40% by weight of water-miscible organic solvent, 0 - 5 wt .-% additives and Rest of water.
- surfactant from the group of addition compounds of ethylene oxide with alcohols or alkylphenols, alkylbenzenesulfonates, alkylsulfates, alkanesulfonates,
- This agent is used in such a way that a preferably one to three percent solution of the agent is first prepared by dilution with water which is then applied to the surfaces to be cleaned with the help of wipers, sponges or similar aids and partly removed from the surface with the dirt. After this treatment, the surface is not rinsed off, so that the remaining cleaning agent solution can dry out to form an evenly protective film. Because of this application method, such agents are also referred to as wiping agents.
- the agent according to the invention is distinguished by an optimal cleaning action against a large number of soiling and at the same time forms a resistant film which forms excellent protection against re-soiling. In contrast to other agents, this film is completely transparent and allows the color and structure of the treated surfaces to appear unchanged without additional gloss. When the agent is used again, the film dissolves, making the cleaning process easier. There is no annoying film addition.
- the agent according to the invention is preferably suitable for the caring cleaning of floors and delivers excellent results on stone, sealed parquet, tiles, linoleum and plastic floors.
- Use on high-gloss floor coverings is particularly advantageous because the film formed does not reduce the gloss due to its high transparency.
- An agent of the following composition is preferably used.
- surfactant from the group of addition compounds of ethylene oxide with alcohols or alkylphenols, Alkylbenzenesulfonates, alkylsulfates, alkanesulfonates, fatty acid ester sulfonates and mixtures thereof, 0.2-2.9% by weight of alkali-soluble, non-metal-crosslinked polymer compound with a minimum film-forming temperature between 0 and 70 ° C, 0.05 - 3% by weight of alkaline complexing agents, 0.05-2% by weight of alkalizing agent, 0-20% by weight of water-miscible organic solvent, 0.05 - 2 wt .-% additives and Rest of water.
- the water-soluble, non-hardness-sensitive surfactants from the group of addition compounds of ethylene oxide with alcohols or alkylphenols, alkylbenzenesulfonates, alkylsulfates, alkanesulfonates, fatty acid ester sulfonates and mixtures thereof are suitable for the agents according to the invention.
- the amounts used are 0.5 to 10% by weight, preferably 1 to 6% by weight, based on the undiluted medium.
- Nonionic and anionic surfactants are preferably used together.
- the nonionic surfactants mentioned are addition compounds of 4-40, preferably 8-20, moles of ethylene oxide (EO) with 1 mole of an aliphatic alcohol or alkylphenol with 10-20 C atoms.
- EO ethylene oxide
- the aliphatic alcohols can be branched or unsaturated and have primary and / or secondary hydroxyl groups.
- nonionic surfactants are nonylphenol + 13 EO, internal C15-C17 alkanediol + 9 EO, C14 / C15 oxo alcohol + 11 EO, coconut alcohol + 7 EO, tallow alcohol + 14 EO.
- Adducts of 8-20 mol EO with fatty alcohols with 12-18 C atoms are preferably used as nonionic surfactants.
- anionic surfactants come from the classes of sulfonates and sulfates and are used consistently as salts, preferably as sodium salts.
- the surfactants of the sulfonate type are the alkylbenzenesulfonates with C 9-15 -alkyl groups, the esters of alpha-sulfofatty acids, e.g. B.
- Suitable sulfate-type surfactants are the sulfuric acid monoesters of primary alcohols natural and synthetic origin, ie from fatty alcohols, such as. B. coconut fatty alcohols, tallow fatty alcohols, oleyl alcohol, or the C10-C20 oxo alcohols, and those of secondary alcohols of these chain lengths.
- Alkylbenzenesulfonates and alkanesulfonates are preferably used as anionic surfactants.
- nonionic and anionic surfactants good to very good cleaning results are achieved throughout, but in many cases it is possible, without loss of cleaning performance, to use a smaller proportion, ie up to about 50%, of these surfactants by other types, such as ethylene oxide adducts Polypropylene oxide or to replace fatty acid amides or olefin sulfonates, sulfosuccinates and alkyl ether sulfates.
- all polymer compounds soluble in water in the alkaline range are suitable, provided they are not metal-crosslinked and have a minimum film-forming temperature between 0 and 70 ° C. These are generally copolymers of at least three different monomers.
- the solubility is at least 0.1%, preferably 0.2%, at a pH between 8 and 10.5, in particular between 8.5 and 9.5.
- the polymers used preferably contain, as the most important constituent, an acrylate copolymer of 1 to 30 parts by weight, based on the copolymer of monomers containing carboxylic acid groups, 30 to 70 parts by weight of monomers which form homopolymers with glass transition temperatures below 20 ° C., preferably esters of acrylic acid with C1-C8 alcohols and / or methacrylic acid with C4 to C8 alcohols and 30 to 70 parts by weight of Comono mers that form homopolymers with glass transition temperatures above room temperature, preferably methacrylic acid esters of C1 to C3 alcohols or styrene.
- an acrylate copolymer of 1 to 30 parts by weight, based on the copolymer of monomers containing carboxylic acid groups, 30 to 70 parts by weight of monomers which form homopolymers with glass transition temperatures below 20 ° C., preferably esters of acrylic acid with C1-C8 alcohols and / or methacrylic acid with C4 to C8 alcohols
- ethylenically unsaturated carboxylic acids can be used; acrylic acid and methacrylic acid are primarily suitable.
- esters of acrylic acid with C1-C8 alcohols are esters of acrylic acid with C1-C8 alcohols and esters of methacrylic acid with C4-C8 alcohols.
- the methyl, ethyl, propyl, butyl or 2-ethylhexyl ester of acrylic acid can be used here, as can the butyl, hexyl or 2-ethylhexyl ester of methacrylic acid.
- Comonomers whose homopolymers have glass transition temperatures above room temperature are esters of methacrylic acid with C1-C3 alcohols, such as methyl methacrylate or ethyl methacrylate.
- a particularly important comonomer whose homopolymer has a glass transition temperature above room temperature is styrene.
- Copolymers of acrylic acid and / or methacrylic acid with styrene, acrylic acid esters and / or methacrylic acid esters are preferably used.
- the copolymers of acrylic acid or methacrylic acid with different acrylic and / or methacrylic acid esters and / or styrene are particularly preferred, for example copolymers of methyl acrylate, ethyl acrylate, methacrylic acid and styrene.
- the respective ratios of comonomers whose homopolymers have glass transition temperatures below room temperature and monomers whose homopolymers have glass transition temperatures above room temperature must be set so that the film-forming temperature of the polymer dispersion is in the range between 0 and 70 ° C.
- the general knowledge of polymer chemistry applies.
- the film formation temperatures mentioned relate to the plasticizer-free system, i. H. on the polymers without further additives.
- the polymers are preferably soluble in water only in the alkaline range, while they remain undissolved in the acidic range.
- Corresponding products are often offered by the trade in emulsified form.
- 0.1 to 4.5% by weight of the polymers, calculated as pure polymer, are used in the agents according to the invention.
- Preferred contents are 0.2 to 2.9% by weight, in particular 0.2 to 1.0% by weight.
- Suitable for the agents according to the invention are water-soluble, preferably low molecular weight complexing agents (builders) which are able to prevent disturbances due to the water hardness when the agents are used.
- Pentasodium triphosphate, trisodium citrate, sodium gluconate, tetrasodium ethylenediaminetetraacetate (EDTA-Na) and trisodium nitrilotriacetate (NTA-Na) are particularly suitable.
- EDTA-Na and / or sodium gluconate are preferably used.
- the amounts are 0.01 to 5% by weight, preferably 0.05 to 3% by weight and in particular not more than 1% by weight, based on the total composition.
- the alkalizing agents together with the complexing agents serve to give the agents in the undiluted state a pH of 8 to 10.5, preferably 8.5 to 9.5. At these pH values, the polymers are at least partially in the salt form.
- the choice of these agents is not critical insofar as they are compatible with the other ingredients. For example, ammonia, alkanolamines, alkaline salts such as Na2CO3 or NaOH are suitable. Ammonia is preferably used.
- the alkalizing agents are used in amounts of up to 3% by weight, preferably 0.05 to 2% by weight.
- water-miscible organic solvents can be present, with solvents that are highly fat-dissolving preferred.
- solvents are lower mono- and dialcohols, ether alcohols, polyethers and amines. Typical representatives of these solvent groups are isopropanol, butyl glycol, dimethyl diglycol and methyl pyrrolidone.
- Lower ether alcohols for example mono- or diethylene glycol monoalkyl ethers having 1 to 4 carbon atoms in the alkyl group, are preferably used.
- the solvent content is not more than 40% by weight, preferably not more than 20% by weight and in particular between 0.5 and 10% by weight.
- customary substances can additionally achieve effects such as are particularly desired in floor cleaning, for example a pleasant smell or a disinfectant effect. Furthermore, they can serve the Stabilize means yourself and make them appealing.
- additives examples include inorganic neutral salts, dyes, fragrances, foam inhibitors and antimicrobial agents. It goes without saying that only those representatives of these substances who are compatible with the other constituents of the agents and do not impair the action of the agents are selected.
- the total amount of additives is not more than 5% by weight, preferably not more than 2% by weight and in particular between 0.05 and 0.5% by weight of the composition.
- Tables 1 and 2 below show the composition of five agents according to the invention and three agents of the prior art. The contents of the individual raw materials are given in percent by weight, based on the finished agent and anhydrous raw materials.
- Polymer 1 Primal® 644, polymer dispersion from Rohm and Haas, Philadelphia, USA
- Neocryl ® BT 20 polymer dispersion from Polyvinylchemie, Waalwijk, NL
- Polymer 3 Copolymer of 58% by weight methyl methacrylate 30% by weight ethyl acrylate 10% by weight acrylic acid 2 wt% styrene
- the cleaning effect of the wiping care products was determined with the help of a Gardner washability and abrasion tester, as described in the quality standards of the industrial association cleaning and care products e. V. (Seifen- ⁇ le-Fette-Wwachs, 108 , pages 526-528 (1982)).
- a white PVC film is soiled with soot and grease and, under standardized conditions, is wiped mechanically with a sponge soaked in the cleaning agent.
- the cleaning performance is measured by photoelectric determination of the reflectance.
- the care effect is shown, among other things, by the fact that a film from previous treatments with the same agent facilitates the detachment of subsequently applied soiling.
- test method specified above was therefore modified in such a way that the film was wiped with the wiping agent to be tested and then dried before the same stain was applied. After this The application of the soiling was then carried out in the same way as the cleaning performance:
- the wiping agents 1-5 according to the invention have an excellent cleaning performance both with respect to non-pretreated and to pretreated film. Soiling from pretreated film is removed even better than from the original film.
- the means 6 - 8 used for comparison show good cleaning performance either only on untreated film (6) or only on pretreated film (7, 8).
- the care effect of the agent 8 is quite comparable to that of the agents according to the invention, but unlike these, after multiple use leads to a film addition which adversely affects the natural appearance of the treated surfaces.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Physical Vapour Deposition (AREA)
- Polishing Bodies And Polishing Tools (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT86112626T ATE58751T1 (de) | 1985-09-20 | 1986-09-12 | Reinigungsmittel fuer harte oberflaechen. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3533531 | 1985-09-20 | ||
DE19853533531 DE3533531A1 (de) | 1985-09-20 | 1985-09-20 | Reinigungsmittel fuer harte oberflaechen |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0215451A2 true EP0215451A2 (fr) | 1987-03-25 |
EP0215451A3 EP0215451A3 (en) | 1988-05-18 |
EP0215451B1 EP0215451B1 (fr) | 1990-11-28 |
Family
ID=6281452
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP86112626A Expired - Lifetime EP0215451B1 (fr) | 1985-09-20 | 1986-09-12 | Produit de nettoyage pour surfaces dures |
Country Status (5)
Country | Link |
---|---|
US (1) | US4725319A (fr) |
EP (1) | EP0215451B1 (fr) |
JP (1) | JPH0823038B2 (fr) |
AT (1) | ATE58751T1 (fr) |
DE (2) | DE3533531A1 (fr) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
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EP0467472A2 (fr) * | 1990-07-16 | 1992-01-22 | Colgate-Palmolive Company | Composition liquide de nettoyage pour surfaces dures avec polymères antisalissantes |
WO1993020173A1 (fr) * | 1992-03-27 | 1993-10-14 | Henkel Kommanditgesellschaft Auf Aktien | Produits liquides de nettoyage de surfaces dures |
WO1993020174A1 (fr) * | 1992-03-27 | 1993-10-14 | Henkel Kommanditgesellschaft Auf Aktien | Produits liquides de nettoyage |
WO1994014943A1 (fr) * | 1992-12-22 | 1994-07-07 | Henkel-Ecolab Gmbh & Co. Ohg | Produit d'entretien neutre pour sols (ii) |
WO1994020594A1 (fr) * | 1993-03-10 | 1994-09-15 | Henkel-Ecolab Gmbh & Co. Ohg | Produits d'entretien pour sols |
WO1994020595A1 (fr) * | 1993-03-05 | 1994-09-15 | Henkel Kommanditgesellschaft Auf Aktien | Nettoyant pour sols |
WO1995010589A1 (fr) * | 1993-10-14 | 1995-04-20 | Henkel Kommanditgesellschaft Auf Aktien | Agent de nettoyage aqueux pour sols |
EP0790286A1 (fr) * | 1996-02-13 | 1997-08-20 | Unilever N.V. | Procédé et appareil pour le traitement de surfaces |
US5782991A (en) * | 1996-02-13 | 1998-07-21 | Diversey Lever, Inc. | Surface treating process |
WO1999018182A1 (fr) * | 1997-10-07 | 1999-04-15 | The Procter & Gamble Company | Composition detergente pour surfaces dures a tres faible contenu de polymere cisaillant-diluant |
DE10357389A1 (de) * | 2003-12-07 | 2005-07-07 | Benda, Jürgen Michael | Nicht mechanische Reinigung von Speckstein und/oder anderen Steinen anhand einer Kombination eines wässrigen und eines wasserfreien Reinigungsproduktes |
US6979371B1 (en) | 1997-10-07 | 2005-12-27 | The Procter & Gamble Company | Detergent composition for hard surfaces comprising hydrophilic shear-thinning polymer at very low level |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
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US5008030A (en) * | 1989-01-17 | 1991-04-16 | Colgate-Palmolive Co. | Acidic disinfectant all-purpose liquid cleaning composition |
JPH02274800A (ja) * | 1989-04-14 | 1990-11-08 | Manritsu:Kk | 床用洗浄剤 |
JP2796535B2 (ja) * | 1990-06-01 | 1998-09-10 | ライオン株式会社 | ゼオライト含有液体洗浄剤組成物 |
SE469058B (sv) * | 1991-10-10 | 1993-05-10 | Berol Nobel Ab | Anvaendning av en trietanolamininnehaallande produktblandning i kosmetiska produkter och rengoerande kompositioner |
DE69315534T2 (de) * | 1992-05-12 | 1998-06-18 | Eastman Kodak Co | Zusatz für eine wässrige photographische stabilisierungslösung |
US5837665A (en) * | 1996-05-02 | 1998-11-17 | Young; Robert | Spot cleaner for carpets |
WO1997042296A1 (fr) * | 1996-05-07 | 1997-11-13 | Kao Corporation | Composition detergente liquide pour surfaces dures et procede pour nettoyer une surface dure |
US5770548B1 (en) * | 1996-05-14 | 1999-06-29 | Johnson & Son Inc S C | Rinseable hard surface cleaner comprising silicate and hydrophobic acrylic polymer |
US5955413A (en) * | 1997-10-24 | 1999-09-21 | 3M Innovative Properties Company | Carpet cleaning and reapplication system based on methacrylic acid polymer, sequestrant, and anionic surfactant |
DE19751859A1 (de) * | 1997-11-22 | 1999-07-29 | Henkel Ecolab Gmbh & Co Ohg | Mittel zum Reinigen von harten Oberflächen |
CA2260607C (fr) | 1998-02-02 | 2007-01-23 | Playtex Products, Inc. | Compositions stables pour enlever les taches des tissus et des tapis |
DE19953457A1 (de) * | 1999-11-05 | 2001-05-23 | Rwe Dea Ag | Verfahren zur Reinigung von Oberflächen |
JP3464442B2 (ja) * | 2000-10-26 | 2003-11-10 | 三菱電機株式会社 | 電磁機器 |
US6635609B2 (en) | 2002-02-11 | 2003-10-21 | Johnsondiversey, Inc. | Surface maintenance composition |
US7780611B2 (en) * | 2003-05-01 | 2010-08-24 | Boston Scientific Scimed, Inc. | Medical instrument with controlled torque transmission |
US7331355B2 (en) * | 2003-10-30 | 2008-02-19 | The Procter & Gamble Company | Floor cleaning and gloss enhancing compositions |
US8211846B2 (en) | 2007-12-14 | 2012-07-03 | Lam Research Group | Materials for particle removal by single-phase and two-phase media |
US8206511B2 (en) * | 2009-10-06 | 2012-06-26 | Ecolab Usa Inc. | Daily cleaner with slip-resistant and gloss-enhancing properties |
US9920281B2 (en) | 2009-11-12 | 2018-03-20 | Ecolab Usa Inc. | Soil resistant surface treatment |
JP5894146B2 (ja) | 2010-05-20 | 2016-03-23 | エコラボ ユーエスエー インコーポレイティド | レオロジー改変された低発泡性液体抗菌組成物及びその使用方法 |
US8585829B2 (en) | 2010-12-13 | 2013-11-19 | Ecolab Usa Inc. | Soil resistant floor cleaner |
WO2013160092A1 (fr) | 2012-04-24 | 2013-10-31 | Unilever N.V. | Composition de traitement de surface dure |
EP3635084A1 (fr) * | 2017-05-11 | 2020-04-15 | Ecolab USA Inc. | Compositions et procédé de nettoyage ou de restauration de sol |
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NL6900307A (fr) * | 1969-01-08 | 1969-10-27 | ||
FR2294231A1 (fr) * | 1974-12-10 | 1976-07-09 | Procter & Gamble Europ | Composition d'entretien et de nettoyage des sols |
US4230605A (en) * | 1978-12-13 | 1980-10-28 | Armstrong Cork Company | Cleaning composition for no-wax vinyl composition floor covering |
EP0068359A1 (fr) * | 1981-06-30 | 1983-01-05 | S.C. Johnson & Son, Inc. | Produit d'entretien pour surfaces à base de fibres de verre et de céramique |
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BE759066A (fr) * | 1969-11-17 | 1971-05-17 | Atlantic Richfield Co | Compositions de shampooings |
US3716488A (en) * | 1970-09-04 | 1973-02-13 | Stevens & Co Inc J P | Textile fabric cleaning compositions |
US3723358A (en) * | 1971-02-22 | 1973-03-27 | Johnson & Son Inc S C | Fabric treating shampoo compositions |
US3901727A (en) * | 1971-03-08 | 1975-08-26 | Minnesota Mining & Mfg | Process and composition for cleaning and imparting water and oil repellency and stain resistance to a substrate |
US3723323A (en) * | 1971-04-22 | 1973-03-27 | Johnson & Son Inc S C | Fabric treating shampoo compositions |
US4002571A (en) * | 1972-03-08 | 1977-01-11 | S. C. Johnson & Son, Inc. | Cleaning compositions |
GB1430204A (en) * | 1973-09-18 | 1976-03-31 | Johnson & Son Inc S C | Aqueous cleaning composition |
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JPS5326804A (en) * | 1976-08-23 | 1978-03-13 | Aaru Buruu Moorisu | Liquid detergent for floor and its using method |
PH17613A (en) * | 1981-05-29 | 1984-10-05 | Unilever Nv | General-purpose cleaning composition |
DE3316876A1 (de) * | 1983-05-07 | 1984-11-08 | Henkel KGaA, 4000 Düsseldorf | Mittel zur entfernung filbildender polymerer schutzueberzuege |
US4537802A (en) * | 1984-08-31 | 1985-08-27 | Flanagan John J | Floor finishing, cleaning and burnishing compositions containing ucon polymers, and method of use |
US4609406A (en) * | 1984-09-05 | 1986-09-02 | Pennzoil Company | Rust conversion coatings |
US4565644A (en) * | 1985-01-04 | 1986-01-21 | Creative Products Resource Associates, Ltd. | Floor cleaning and waxing composition |
-
1985
- 1985-09-20 DE DE19853533531 patent/DE3533531A1/de not_active Withdrawn
-
1986
- 1986-09-09 US US06/905,713 patent/US4725319A/en not_active Expired - Lifetime
- 1986-09-12 DE DE8686112626T patent/DE3675861D1/de not_active Expired - Fee Related
- 1986-09-12 EP EP86112626A patent/EP0215451B1/fr not_active Expired - Lifetime
- 1986-09-12 AT AT86112626T patent/ATE58751T1/de not_active IP Right Cessation
- 1986-09-20 JP JP61223489A patent/JPH0823038B2/ja not_active Expired - Lifetime
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Publication number | Priority date | Publication date | Assignee | Title |
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NL6900307A (fr) * | 1969-01-08 | 1969-10-27 | ||
FR2294231A1 (fr) * | 1974-12-10 | 1976-07-09 | Procter & Gamble Europ | Composition d'entretien et de nettoyage des sols |
US4230605A (en) * | 1978-12-13 | 1980-10-28 | Armstrong Cork Company | Cleaning composition for no-wax vinyl composition floor covering |
EP0068359A1 (fr) * | 1981-06-30 | 1983-01-05 | S.C. Johnson & Son, Inc. | Produit d'entretien pour surfaces à base de fibres de verre et de céramique |
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GR910100312A (en) * | 1990-07-16 | 1992-08-26 | Colgate Palmolive Co | Liquid cleaning composition for rough surfaces |
EP0467472A3 (en) * | 1990-07-16 | 1993-06-02 | Colgate-Palmolive Company | Hard surface liquid cleaning composition with anti-soiling polymer |
EP0467472A2 (fr) * | 1990-07-16 | 1992-01-22 | Colgate-Palmolive Company | Composition liquide de nettoyage pour surfaces dures avec polymères antisalissantes |
WO1993020173A1 (fr) * | 1992-03-27 | 1993-10-14 | Henkel Kommanditgesellschaft Auf Aktien | Produits liquides de nettoyage de surfaces dures |
WO1993020174A1 (fr) * | 1992-03-27 | 1993-10-14 | Henkel Kommanditgesellschaft Auf Aktien | Produits liquides de nettoyage |
US5507971A (en) * | 1992-03-27 | 1996-04-16 | Henkel Kommanditgesellschaft Auf Aktien | Liquid cleaners for hard surfaces |
WO1994014943A1 (fr) * | 1992-12-22 | 1994-07-07 | Henkel-Ecolab Gmbh & Co. Ohg | Produit d'entretien neutre pour sols (ii) |
WO1994020595A1 (fr) * | 1993-03-05 | 1994-09-15 | Henkel Kommanditgesellschaft Auf Aktien | Nettoyant pour sols |
US5683975A (en) * | 1993-03-10 | 1997-11-04 | Henkel Ecolab Gmbh & Co Ohg | Floor wiping composition |
WO1994020594A1 (fr) * | 1993-03-10 | 1994-09-15 | Henkel-Ecolab Gmbh & Co. Ohg | Produits d'entretien pour sols |
WO1995010589A1 (fr) * | 1993-10-14 | 1995-04-20 | Henkel Kommanditgesellschaft Auf Aktien | Agent de nettoyage aqueux pour sols |
US5753604A (en) * | 1993-10-14 | 1998-05-19 | Henkel Kommanditgesellschaft Auf Aktien | Water-containing floor cleaning composition |
EP0790286A1 (fr) * | 1996-02-13 | 1997-08-20 | Unilever N.V. | Procédé et appareil pour le traitement de surfaces |
US5782991A (en) * | 1996-02-13 | 1998-07-21 | Diversey Lever, Inc. | Surface treating process |
WO1999018182A1 (fr) * | 1997-10-07 | 1999-04-15 | The Procter & Gamble Company | Composition detergente pour surfaces dures a tres faible contenu de polymere cisaillant-diluant |
US6979371B1 (en) | 1997-10-07 | 2005-12-27 | The Procter & Gamble Company | Detergent composition for hard surfaces comprising hydrophilic shear-thinning polymer at very low level |
DE10357389A1 (de) * | 2003-12-07 | 2005-07-07 | Benda, Jürgen Michael | Nicht mechanische Reinigung von Speckstein und/oder anderen Steinen anhand einer Kombination eines wässrigen und eines wasserfreien Reinigungsproduktes |
DE10357389B4 (de) * | 2003-12-07 | 2005-12-15 | Benda, Jürgen Michael | Verfahren zur Reinigung von Speckstein |
Also Published As
Publication number | Publication date |
---|---|
EP0215451B1 (fr) | 1990-11-28 |
US4725319A (en) | 1988-02-16 |
DE3675861D1 (de) | 1991-01-10 |
ATE58751T1 (de) | 1990-12-15 |
JPH0823038B2 (ja) | 1996-03-06 |
EP0215451A3 (en) | 1988-05-18 |
JPS6272800A (ja) | 1987-04-03 |
DE3533531A1 (de) | 1987-04-02 |
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