EP0195499A1 - Herstellung von Stahlwerkstücken mittels Gasnitrieren - Google Patents

Herstellung von Stahlwerkstücken mittels Gasnitrieren Download PDF

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Publication number
EP0195499A1
EP0195499A1 EP86300661A EP86300661A EP0195499A1 EP 0195499 A1 EP0195499 A1 EP 0195499A1 EP 86300661 A EP86300661 A EP 86300661A EP 86300661 A EP86300661 A EP 86300661A EP 0195499 A1 EP0195499 A1 EP 0195499A1
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EP
European Patent Office
Prior art keywords
component
steel
surface layer
nitrogen
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP86300661A
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English (en)
French (fr)
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EP0195499B1 (de
Inventor
Cyril Dawes
Donald Frederick Tranter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SENIOR HEAT TREATMENT Ltd
Original Assignee
Lucas Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Lucas Industries Ltd filed Critical Lucas Industries Ltd
Publication of EP0195499A1 publication Critical patent/EP0195499A1/de
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Publication of EP0195499B1 publication Critical patent/EP0195499B1/de
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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/34—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases more than one element being applied in more than one step
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
    • C23C8/24—Nitriding
    • C23C8/26—Nitriding of ferrous surfaces

Definitions

  • the invention relates to a method of making a steel component having predetermined properties, in particular a permutation of low weight, corrosion resistance and tribological properties and, according to need, yield strength, black colour and other properties.
  • the invention also includes the component itself.
  • intertitial free steel is of increased formability which makes it a candidate for use in making components.
  • Such steel is prone to brittleness when subjected to nitriding.
  • This invention is based on the realisation that, under certain nitriding processes, such a steel may be treated to secure the benefits of nitriding without inducing brittleness.
  • a method of making a non-brittle component of interstitial-free steel comprising heating the component in a gaseous atmosphere containing a nitrogen donor, the concentration of the donor being sufficient to provide the component with both an epsilon iron nitride surface layer and a layer of nitrides of trace alloying elements, particularly titanium, below the surface layer, the heat treatment being performed at a temperature of from about 500°C to about 740°C and for a period of from about 30 minutes to about four hours.
  • the conditions of the nitriding are arranged to cause the formation of an epsilon iron nitride surface layer and beneath it a layer of a fine dispersion of nitrides of alloying elements in the interstitial-free steel.
  • the conditions are determined by the proportion of the nitrogen donor, typically ammonia, in the gaseous atmosphere and the temperature and time of the treatment. If the proportion of the nitrogen donor is less than 15% of the atmosphere, dependent on treatment temperature, the nitrogen will diffuse through the component and the required epsilon iron nitride surface layer will not be formed and the required tribological and corrosion resistance properties will not be achieved.
  • the concentration of ammonia be at least 20%, preferably 50%, or more by volume, of the atmosphere.
  • the atmosphere is a mixture of ammonia and another gas
  • the atmosphere be a 20:80 or 50:50 by volume mixture of ammonia and an endothermic gas mixture of carbon monoxide, carbon dioxide, nitrogen and hydrogen.
  • the nitriding step is carried out at elevated temperature. This must be at least 500°C; if the temperature is less than this, the nitriding step will take too long to be practical on an economic scale. The temperature should not exceed 740°C otherwise the component will have inadequate strength and will be prone to distortion.
  • the nitriding step will require to be performed for a period which is industrially acceptable and will of course form a layer of the required properties. This period will typically range from about 30 minutes (or less depending on the equipment used) up to about four hours; preferably the period is about one hour.
  • interstitial-free steel This is a steel which has been vacuum degassed so that it has virtually no soluble carbon or nitrogen. Typically it contains small amounts of titanium, aluminium and columbium. It has an average plastic strain ratio of 2.0.
  • the nitriding of an interstitial-free steel causes ferrite strengthening and nitride precipitation of the trace alloying elements. This results in the development of increased depth of hardness with increasing treatment time and improved resistance to tempering. It was to be expected that brittleness would also be induced but by this invention surprisingly this does not happen.
  • the steel has an epsilon iron nitride surface layer which may range from about 10 to about 50 micrometres in thickness.
  • a layer of nitrided alloying elements, particularly titanium is a layer of nitrided alloying elements, particularly titanium. The innermost portion of the component is free of nitrided elements, and we believe that as a consequence of these layers at the periphery of the component but not within its centre, the component will not be brittle.
  • the invention provides a method of making a component of a steel by nitriding the component to form an epsilon iron nitride surface layer, optionally followed by the formation of an oxide rich layer and quenching characterised in that the component is formed of an interstitial-free steel which is nitrided in a gaseous atmosphere containing a nitrogen donor in sufficient quantity to form the epsilon iron nitride surface layer and an underlying layer of nitrides of the alloying elements of the interstitial-free steel, the innermost portion of the component being substantially free of nitrides whereby the component has corrosion resistance and tribological properties without brittleness.
  • the steel component is preferably from about 0.5 mm to about 3 mm thick, dependent on the properties required of the component. With an increase in component thickness, in the method the concentration of nitrogen donor should be increased together with the temperature and/or treatment time.
  • the component may be subjected to oxidation and/or quenching.
  • the oxidation step may be performed following nitriding while the component is still at high temperature by exposing the component to air or other oxidising atmosphere for at least two seconds.
  • the oxide layer formed is preferably from about 0.2 micrometre to about 1 micrometre, preferably about 0.5 micrometre.
  • Quenching is preferably performed in an oil/water emulsion following nitriding and/or oxidation.
  • the quenching tends to darken the colour of the component so that an aesthetically pleasing black finish is obtained.
  • a non-brittle steel component formed of interstitial-free steel having a thickness of at least 0.5 mm, an epsilon iron nitride surface layer thereon, nitrides of alloying elements in the steel underlying the surface layer.
  • a component having a thickness of 1.5 mm and a yield strength of 800 MPa can be used as a car bumper armature since it will resist impact forces in a low speed collision.
  • surface layer strength is required for example in a car seat slider up to 2 mm wall thickness, the product will have the required permutation of surface layer strength, corrosion resistance etc.
  • a series of components of 1.2 mm thick interstitial-free steel having the following composition C 0.018 S 0.012 Mn 0.21 P 0.01 and Ti 0.12 was subjected to nitriding, oxidising and quenching.
  • the nitriding atmosphere in the heat treatment furnace, treatment time and temperature were varied as shown in Table I.
  • the oxidation step was conducted by exposing the nitrided component to air for 15 seconds on removal from the heat treatment furnace, followed by quenching into a water- based emulsion quenchant at 80°C.
  • the quenchant was CASTROL VW553 in a ratio of 1 part quenchant : 6 parts water.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
EP86300661A 1985-02-20 1986-01-31 Herstellung von Stahlwerkstücken mittels Gasnitrieren Expired EP0195499B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8504349 1985-02-20
GB8504349A GB2173513B (en) 1985-02-25 1985-02-25 Making of steel component

Publications (2)

Publication Number Publication Date
EP0195499A1 true EP0195499A1 (de) 1986-09-24
EP0195499B1 EP0195499B1 (de) 1989-05-10

Family

ID=10574789

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86300661A Expired EP0195499B1 (de) 1985-02-20 1986-01-31 Herstellung von Stahlwerkstücken mittels Gasnitrieren

Country Status (5)

Country Link
US (1) US4710238A (de)
EP (1) EP0195499B1 (de)
JP (1) JPS61194169A (de)
DE (1) DE3663267D1 (de)
GB (1) GB2173513B (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0299625A2 (de) * 1987-07-17 1989-01-18 LUCAS INDUSTRIES public limited company Erzeugung von korrosionsbeständigen Stählen
EP0733720A1 (de) * 1995-03-22 1996-09-25 August Bilstein GmbH Oberflächenbehandelte Kolbenstange

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4756774A (en) * 1984-09-04 1988-07-12 Fox Steel Treating Co. Shallow case hardening and corrosion inhibition process
US5037491A (en) * 1986-02-28 1991-08-06 Fox Patrick L Shallow case hardening and corrosion inhibition process
DE3904776A1 (de) * 1989-02-17 1990-08-23 Ver Schmiedewerke Gmbh Verfahren zur herstellung eines hochfesten und zaehen metallischen schichtverbundwerkstoffes
CA2016843A1 (en) * 1990-05-15 1991-11-15 Michel J. Korwin Thermochemical treatment of machinery components for improved corrosion resistance
AU673144B2 (en) * 1991-10-24 1996-10-31 Grouputer Corporation Pty Ltd Group based computer use system
US5244375A (en) * 1991-12-19 1993-09-14 Formica Technology, Inc. Plasma ion nitrided stainless steel press plates and applications for same
JP3970323B2 (ja) * 1996-06-05 2007-09-05 デュラセル、インコーポレーテッド リチウム化リチウム酸化マンガンスピネルの改良された製造法
TWI403413B (zh) * 2009-04-27 2013-08-01 Univ Tatung 親疏水性可轉換複合膜及其製備方法
KR101704849B1 (ko) 2009-08-07 2017-02-08 스와겔로크 컴패니 저진공 하에서의 저온 침탄
CA2861180A1 (en) 2012-01-20 2013-07-25 Swagelok Company Concurrent flow of activating gas in low temperature carburization
US9896757B2 (en) 2015-07-02 2018-02-20 Shultz Steel Company Galling and corrosion resistant inner diameter surface in aluminum caster roll shell steels

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1813808A1 (de) * 1967-12-11 1969-07-10 United States Steel Corp Verfahren und Herstellung von nitriertem Bandstahl
DE2135763A1 (de) * 1970-07-21 1972-01-27 Nissan Motor Verfahren zum Bilden einer Verbundschicht in der Oberfläche eisenhaltigen Metalls
FR2179879A1 (de) * 1972-04-13 1973-11-23 Midland Ross Corp
FR2286195A1 (fr) * 1974-09-24 1976-04-23 Armco Steel Corp Procede d'amelioration de la limite elastique des aciers lamines a froid ou emboutis
GB2027062A (en) * 1978-07-12 1980-02-13 Honda Motor Co Ltd Continuous process for brazing and nitriding

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3303063A (en) * 1964-06-15 1967-02-07 Gen Motors Corp Liquid nitriding process using urea
US4464207A (en) * 1978-08-14 1984-08-07 The Garrett Corporation Dispersion strengthened ferritic stainless steel
JPS55119119A (en) * 1979-02-09 1980-09-12 Nachi Fujikoshi Corp Hardening method for steel at low temperature
JPS5917167B2 (ja) * 1980-06-09 1984-04-19 株式会社不二越 鋼の焼入方法
US4496401A (en) * 1981-10-15 1985-01-29 Lucas Industries Corrosion resistant steel components and method of manufacture thereof
JPS6160874A (ja) * 1984-08-30 1986-03-28 Oyo Kagaku Kenkyusho 表面硬化鋼及び鋼の表面硬化法
JPS6160875A (ja) * 1984-08-31 1986-03-28 Hitachi Ltd タ−ビン材料の製造方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1813808A1 (de) * 1967-12-11 1969-07-10 United States Steel Corp Verfahren und Herstellung von nitriertem Bandstahl
DE2135763A1 (de) * 1970-07-21 1972-01-27 Nissan Motor Verfahren zum Bilden einer Verbundschicht in der Oberfläche eisenhaltigen Metalls
FR2179879A1 (de) * 1972-04-13 1973-11-23 Midland Ross Corp
FR2286195A1 (fr) * 1974-09-24 1976-04-23 Armco Steel Corp Procede d'amelioration de la limite elastique des aciers lamines a froid ou emboutis
GB2027062A (en) * 1978-07-12 1980-02-13 Honda Motor Co Ltd Continuous process for brazing and nitriding

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, vol. 67, 1967, page 8794, abstract no. 93222v, Columbus, Ohio, US; & HU - A - 153 760 (LASZLO GILLEMOT et al.) 22-06-1967 *
CHEMICAL ABSTRACTS, vol. 89, no. 24, December 1978, page 230, abstract no. 201418d, Columbus, Ohio, US; J. BIDLEN: "The effect of nitridation of low-carbon steel Kohal Extra on the coefficient of friction and abrasive wear resistance", & zb. VED. PR. VYS. SK. TECH. KOSICIACH 1974 (Pub. 1977), (2), 125-33 (Slo), KOHAL EXTRA *
HÄRTEREI - TECHNISCHE MITTEILUNGEN, vol. 29, no. 1, March 1974, pages 42-49, Munich, DE; J. WÜNNING: "Neues Verfahren und Anlagen zum Nitrieren mit -Verbindungsschicht" *
PATENTS ABSTRACTS OF JAPAN, vol. 8, no. 56, (C-214)[1493], 14th March 1984; & JP - A - 58 213 866 (MITSUBISHI JUKOGYO K.K.) 12-12-1983 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0299625A2 (de) * 1987-07-17 1989-01-18 LUCAS INDUSTRIES public limited company Erzeugung von korrosionsbeständigen Stählen
EP0299625A3 (en) * 1987-07-17 1990-02-28 Lucas Industries Public Limited Company Manufacture of corrosion resistant steel components
EP0733720A1 (de) * 1995-03-22 1996-09-25 August Bilstein GmbH Oberflächenbehandelte Kolbenstange

Also Published As

Publication number Publication date
JPS61194169A (ja) 1986-08-28
US4710238A (en) 1987-12-01
EP0195499B1 (de) 1989-05-10
DE3663267D1 (en) 1989-06-15
GB2173513B (en) 1989-06-14
GB2173513A (en) 1986-10-15
GB8504349D0 (en) 1985-03-20

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