EP0176848A2 - Etoffe non tissée - Google Patents

Etoffe non tissée Download PDF

Info

Publication number
EP0176848A2
EP0176848A2 EP85111673A EP85111673A EP0176848A2 EP 0176848 A2 EP0176848 A2 EP 0176848A2 EP 85111673 A EP85111673 A EP 85111673A EP 85111673 A EP85111673 A EP 85111673A EP 0176848 A2 EP0176848 A2 EP 0176848A2
Authority
EP
European Patent Office
Prior art keywords
solid particles
binder
nonwoven
nonwoven fabric
fibers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP85111673A
Other languages
German (de)
English (en)
Other versions
EP0176848A3 (fr
Inventor
Peter Dr. Heidel
Franz Kaulich
Heinz Dr. Artus
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of EP0176848A2 publication Critical patent/EP0176848A2/fr
Publication of EP0176848A3 publication Critical patent/EP0176848A3/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/12Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with filaments or yarns secured together by chemical or thermo-activatable bonding agents, e.g. adhesives, applied or incorporated in liquid or solid form
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005Synthetic yarns or filaments
    • D04H3/009Condensation or reaction polymers
    • D04H3/011Polyesters
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H5/00Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
    • D04H5/02Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by mechanical methods, e.g. needling
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H5/00Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
    • D04H5/04Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by applying or incorporating chemical or thermo-activatable bonding agents in solid or liquid form
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24273Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
    • Y10T428/24322Composite web or sheet

Definitions

  • the present invention relates to a nonwoven fabric which consists predominantly of synthetic fibers and is provided with a layer of inert fibrous solid particles, and which is suitable for use as a carrier web in roofing membranes which are resistant to flying flames and radiant heat.
  • roofing sheets are usually coated on one or both sides with bitumen, but can also have a coating of elastomers or plastomers.
  • laminates such as those e.g. are described in DE-PS 28 27 136, used as a carrier web.
  • a laminate of a synthetic fiber fleece and a mineral fiber fleece from DE-GM 77 39 489 is known as a carrier web for roofing membranes.
  • the two non-woven layers made of synthetic and mineral fiber material are bonded to one another there by binding or gluing.
  • Thermoplastic and crosslinking thermosets are used for this.
  • Such carrier sheets lead to roofing and sealing sheets with sufficiently high processing stability Bituminizing and laying. Their dimensional stability even allows single-layer installation on the roof. The fire behavior of these roofing membranes according to DIN 4102 / Part 7 is significantly improved by the mineral fiber layer.
  • the coating compound e-at the processing temperatures of the B and the roofing membrane behaves even inert, however, forms a substantially closed, preferably foam-like layer at higher temperatures.
  • nonwoven fabric according to the invention. Surprisingly, it was found that the fire behavior of nonwovens made from fibers or filaments consolidated with a binder or from roofing membranes produced therefrom is significantly improved if the nonwoven contains a layer of inert fibrous solid particles distributed in the binder.
  • Inert means that the solid particles are resistant to the attack of heat and fire, i.e. are not or hardly inflammable.
  • Fibrous solid particles are to be understood as those whose spatial extent is at least one dimension large compared to the effective opening width of the fleece layer, as described for geotextiles in volume 56 (1983) of the communications of the Franzius Institute for Hydraulic and Coastal Engineering at the University of Hanover , Page 379 to 381 is defined.
  • fibrous solid particles examples include mineral fibers, in particular so-called short-cut fibers, such as are used for the production of wet nonwovens, and by cutting or grinding mineral wool, glass fibers or ceramic Fibers are made. These mineral fibers usually have diameters between 5 and 50 ⁇ m, their length can be between 50 ⁇ m and 18 mm. In practice, however, the upper limit of the longitudinal expansion of the fibrous solid particles is determined by their dispersibility in the dissolved or emulsified binder.
  • shaped structures made of inert materials can also be used as fibrous solid particles, provided that their spatial extent in at least one dimension is large compared to the effective opening width of the nonwoven layer and insofar as they can be dispersed in the binder.
  • flameproofed cellulose fibers or other fibers can also be used as inert fibrous solid particles, which impart non-flammable properties to the nonwoven fabric according to the invention which are not exhibited by single-material nonwovens, e.g. Coloring or dyeability, better adhesion to coatings, hydrophilicity or hydrophobicity, electrical conductivity or antistatic effects (metal fibers), or different shrinkage properties to create curling effects. .
  • Binders are often used in the form of aqueous dispersions or aqueous solutions for the consolidation of nonwovens.
  • Known binders in the form of aqueous dispersions are homopolymers, copolymers or terpolymers made from acrylic acid esters, acrylic acid amides, acrylonitrile, butadiene and styrene.
  • binders are particularly suitable for the production of the nonwoven fabric according to the invention Basis of water-soluble urea-formaldehyde, melamine-formaldehyde, phenol-formaldehyde condensates or water-dispersed polymers of vinylidene chloride and vinyl chloride, which are used alone or in a mixture.
  • the binders can be made according to various, e.g. described in "Vliesstoff", G. Thieme Verlag Stuttgart, New York, edited by J. Lünenschand and W. Albrecht 1982, pages 177 to 199.
  • the most common method is padding in a trough followed by a pair of squeeze rollers. Water is removed from the binder by the action of heat and the binder-filament bond is formed.
  • the nonwoven fabric to be consolidated with these binders can consist of fibers or filaments made from the known synthetic polymers.
  • the inert fibrous solid particles are preferably added to the aqueous binder liquor and kept in suspension by stirring. Sedimentation of the solid particles can also be done by adding a thickener, e.g. based on soluble cellulose derivatives.
  • the binder with the inert fibrous solid particles dispersed therein is applied from one side to the nonwoven made of fibers or filaments made of synthetic Polymers applied.
  • a layer-like accumulation of the inert fibrous solid particles first forms, which during the subsequent evaporation of the water introduced into the nonwoven with the aqueous binder suspension and the hardening of the binder is firmly embedded in this binder together with the solidified nonwoven made of fibers or filaments forms the nonwoven according to the invention.
  • the size restriction of the inert fibrous solid particles to those with a spatial extent in at least one dimension that is large compared to the effective opening width of the nonwoven layer is crucial, since this largely prevents penetration into the underlying nonwoven layer.
  • the proportion of inert fibrous solid particles in the nonwoven fabric according to the invention can be between 30 and 200 g / m 2 , that of the other fibers and filaments can be 50 to 350 g / m 2 .
  • the proportion of the inert fibrous solid particles in the total weight of the nonwoven according to the invention should be between 10 and 50%, preferably between 20 and 30%.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Nonwoven Fabrics (AREA)
  • Building Environments (AREA)
  • Laminated Bodies (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
EP85111673A 1984-09-28 1985-09-16 Etoffe non tissée Withdrawn EP0176848A3 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3435640 1984-09-28
DE19843435640 DE3435640A1 (de) 1984-09-28 1984-09-28 Vliesstoff

Publications (2)

Publication Number Publication Date
EP0176848A2 true EP0176848A2 (fr) 1986-04-09
EP0176848A3 EP0176848A3 (fr) 1989-04-26

Family

ID=6246604

Family Applications (1)

Application Number Title Priority Date Filing Date
EP85111673A Withdrawn EP0176848A3 (fr) 1984-09-28 1985-09-16 Etoffe non tissée

Country Status (8)

Country Link
US (1) US4657801A (fr)
EP (1) EP0176848A3 (fr)
JP (1) JPS6183383A (fr)
AU (1) AU4797485A (fr)
DE (1) DE3435640A1 (fr)
FI (1) FI853680L (fr)
NO (1) NO853810L (fr)
ZA (1) ZA857468B (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0379100A1 (fr) * 1989-01-17 1990-07-25 Hoechst Aktiengesellschaft Nappe de support résistant à la flamme pour nappes de bitume et procédé pour sa fabrication
WO1993007202A1 (fr) * 1991-10-07 1993-04-15 Desmepol B.V. Utilisation d'un materiau sous forme de mat fibreux aiguillete et non tisse

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE9207367U1 (fr) * 1992-05-30 1992-09-10 Hoechst Ag, 6230 Frankfurt, De

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2365650A1 (fr) * 1976-09-23 1978-04-21 Rohm & Haas Etoffe non tissee contenant un liant
FR2390530A1 (fr) * 1977-05-14 1978-12-08 Hoechst Ag Procede de fabrication d'un non-tisse en filaments de polyesters

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2827136C2 (de) * 1978-06-21 1982-05-19 Hoechst Ag, 6000 Frankfurt Bituminierte Dachbahn
DE3226041A1 (de) * 1982-07-12 1984-01-12 Didier-Werke Ag, 6200 Wiesbaden Verfahren zur herstellung von genadelten fasernblankets aus mineralischen, insbesondere feuerfesten, fasern und nach dem verfahren hergestellte faserblankets

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2365650A1 (fr) * 1976-09-23 1978-04-21 Rohm & Haas Etoffe non tissee contenant un liant
FR2390530A1 (fr) * 1977-05-14 1978-12-08 Hoechst Ag Procede de fabrication d'un non-tisse en filaments de polyesters

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0379100A1 (fr) * 1989-01-17 1990-07-25 Hoechst Aktiengesellschaft Nappe de support résistant à la flamme pour nappes de bitume et procédé pour sa fabrication
WO1993007202A1 (fr) * 1991-10-07 1993-04-15 Desmepol B.V. Utilisation d'un materiau sous forme de mat fibreux aiguillete et non tisse

Also Published As

Publication number Publication date
FI853680L (fi) 1986-03-29
AU4797485A (en) 1986-04-10
US4657801A (en) 1987-04-14
EP0176848A3 (fr) 1989-04-26
JPS6183383A (ja) 1986-04-26
DE3435640A1 (de) 1986-04-10
FI853680A0 (fi) 1985-09-25
ZA857468B (en) 1986-05-28
NO853810L (no) 1986-04-01

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Inventor name: ARTUS, HEINZ, DR.

Inventor name: KAULICH, FRANZ

Inventor name: HEIDEL, PETER, DR.