EP0164637A1 - Hochtemperaturschmierstoff für die spanlose Heissumformung von Metallen - Google Patents
Hochtemperaturschmierstoff für die spanlose Heissumformung von Metallen Download PDFInfo
- Publication number
- EP0164637A1 EP0164637A1 EP85106532A EP85106532A EP0164637A1 EP 0164637 A1 EP0164637 A1 EP 0164637A1 EP 85106532 A EP85106532 A EP 85106532A EP 85106532 A EP85106532 A EP 85106532A EP 0164637 A1 EP0164637 A1 EP 0164637A1
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- EP
- European Patent Office
- Prior art keywords
- temperature lubricant
- lubricant
- lubricant according
- temperature
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/12—Polysaccharides, e.g. cellulose, biopolymers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/028—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/241—Manufacturing joint-less pipes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/242—Hot working
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/243—Cold working
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/247—Stainless steel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/015—Dispersions of solid lubricants
- C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating
Definitions
- the invention relates to a high-temperature lubricant for the non-cutting hot forming of metals, containing a solid lubricant and a residue-free decomposing organic product.
- DE-OS 24 30 249 describes a high-temperature lubricant for the hot forming of metals on the basis of a phosphate-borate glass, an additive that burns the lubrication and a propellant that triggers a residue-free, decomposing organic product.
- the addition of alkali phosphate borate melt products results in a product that has another disadvantage of poor wetting shows properties on hot surfaces.
- the silica in turn has a bad influence on the lubrication behavior and the service life of the tools.
- the object of the present invention was to propose a high-temperature lubricant which does not have the disadvantages mentioned and which leads to closed and fully effective lubricating films at temperatures above 600.degree.
- the object is achieved with a high-temperature lubricant according to claim 1.
- the inorganic additive suitably consists of a mixture of 0.2 to 25% by weight of boron compound, 0.2 to 98.8% by weight of polyphosphate and 1 to 99.6% by weight of alkali silicate.
- the polyphosphate is used in insoluble or poorly soluble form.
- Madrell's salts or Kurrol's salts are preferably used as polyphosphates. These are compounds of the type (Na PO 3 ) n with n greater than 6 D is 50,000, preferably 6 to 10,000.
- the boron compound can be used in soluble and preferably in poorly soluble or insoluble form.
- borax boric acid
- B 2 0 3 KB 5 O 8 4H 2 O or zinc borate
- zinc borate can be used as the boron compound.
- the alkali silicate used is preferably a sodium water glass or potassium water glass with an SiO 2 content between 21 and 47%.
- insoluble or sparingly soluble compound which is preferably mentioned is particularly advantageous with regard to the wetting of hot surfaces and in particular the uniform layer thickness of the high-temperature lubricant on the tool and / or workpiece surfaces at temperatures above 350 ° C. and in particular at 600 ° C. and above .
- the quantitative ratios of the individual components can be 1 to 90% by weight for the solid lubricant, 1 to 50% by weight for the organic product which decomposes without heat, 1 to 80% by weight for the inorganic additive according to the invention and 0 for the organic stabilizer. 2 to 80% by weight.
- the organic product which decomposes without residues is used in lubricants for use at temperatures of up to 350 ° C. in amounts of at most 50% by weight, and decreases linearly for temperatures of 600 ° C. and above to a maximum of 5% by weight , used.
- Typical lubricants for use at temperatures of 350 ° C. can therefore contain 40 to 90% by weight solid lubricant, 10 to 50% by weight organic product, 0.2 to 5% by weight inorganic Additive and 0.2 to 5% by weight of organic stabilizing agent.
- the composition is expediently 10 to 90% by weight solid lubricant, 1 to 15% by weight organic product, 10 to 80% by weight inorganic additive and 0.2 to 4% by weight of organic stabilizing agent.
- Graphite, M O S 2 (molybdenum disulfide), CaF 2 or BN can be used as the solid lubricant.
- graphite leads to particularly good results. From the range of graphites, those with high purity, for example over 96%, and an average grain size of not more than 300 micrometers are preferred. The best results can be achieved with a graphite of 99.5% purity and an average grain size of 100 micrometers.
- the organic products which decompose without leaving any heat are, for example, alkylene homopolymers or copolymers.
- alkylene homopolymers or copolymers include the homo- and copolymers of aryl alkenes, a, ⁇ -unsaturated acids and esters, ⁇ , ⁇ -unsaturated acids and esters, alkenes (monoolefins, diolefins etc.), vinyl esters, vinyl alcohols, unsaturated dibasic acids and esters (dicarboxylic acids and -ester), alkyl esters and acyclic acids and esters understood.
- the Alkylenhomopolymer or copolymer can be polyethylene, P o l y-methyl methacrylate, polystyrene, polybutadiene, polyvinyl acetate, polyvinyl propionate, a copolymer of methyl methacrylate and styrene, a copolymer of Methylenmethacrylat and alpha methyl styrene, polydiallyl phthalate, polypropylene, a copolymer of styrene and butadiene, polymethylmethacrylate, a copolymer of vinyl acetate and dibutyl maleate, a copolymer of vinyl acetate and ethylene and polyisobutylene.
- These polymers can be used alone or as a mixture with one another.
- the high-temperature lubricant can also contain a number of other additives. This includes microbiologically active components and wetting agents.
- silicic acid which is usually in the form of highly disperse silicon oxide and which must be used as a stabilizer in compositions which contain polyphosphates, is particularly advantageous in the case of lubricants according to the invention.
- the silica itself is undesirable because it has a bad influence on the lubrication behavior and on the service life of the tools.
- Erfindungsgeäss should be present as 5-56 GEV% aqueous dispersion of the high-temperature lubricant for G e-consumption.
- the dispersion expediently has a viscosity of 500 to 15000 cp at 10 to 30 ° C.
- the organic stabilizer contained in the high-temperature lubricant may be sufficient to achieve the viscosity of the dispersion.
- suitable thickeners e.g. water-soluble polysaccharides, alkyl celluloses, polyvinyl alcohols, polyarylates, polyvinyl pyrrolidone, optionally minerals, such as clays.
- the high-temperature lubricant is usually used in the form of an aqueous dispersion.
- the aqueous dispersion can be applied to the tool and / or the workpiece to be machined, which can have temperatures of 100 to over 900 ° C. When the hot surfaces are touched, the water evaporates and a film of uniform layer thickness forms.
- the high-temperature lubricant can also be used in powder be used form.
- the tool and / or the workpiece is powdered or rolled or drawn through the lubricant.
- the lubricants according to the invention are particularly suitable for use at temperatures around 600 ° C. and above.
- the high temperature stability of the lubricants and in particular the stability of the lubricating film was essentially achieved through the high proportion of inorganic additives.
- the high-temperature lubricant according to the invention is therefore suitable, for example, for the lubrication of tools, e.g. Mandrel, mandrel bar or die, and workpieces, for example blanks or tubes, for hot forming in so-called “multiple pipe mills", continuous lines, mitral mills, Assel lines, push bench systems, bar presses or upsetting presses.
- tools e.g. Mandrel, mandrel bar or die
- workpieces for example blanks or tubes
- the high-temperature lubricant had a viscosity of 1900 C ps, measured at 20 ° C according to Epprecht with a Rheomat 15 of the Contraves.
- the present formulation showed the most favorable properties at relatively low application temperatures of 20 to 250 ° C in contours or consist streets.
- the above-mentioned formulation was sprayed onto tools (e.g. mandrels) using a spray device.
- the coefficient of friction was 0.037.
- a high temperature lubricant was prepared as a 70 wt% aqueous dispersion.
- the lubricating constituents corresponded to the formulation according to Example 1, but 5% by weight zinc borate was used instead of the borax.
- the high temperature lubricant had a viscosity of 2600 Cps at 20 ° C.
- the lubricant led to an improvement in the water resistance of the applied layer and better adhesion at operating temperatures of 20 to 250 ° C.
- the coefficient of friction was 0.030.
- the lubricant was sprayed onto the tool at tool temperatures of 400 to 900 ° C, forming a uniform film of lubricant. In the course of machining the workpiece, a uniform course of the current consumption of the roll stands could be observed, which suggests favorable friction behavior.
- the coefficient of friction was 0.043.
- the coefficient of friction was 0.030.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH2651/84A CH660023A5 (de) | 1984-05-30 | 1984-05-30 | Hochtemperaturschmierstoff fuer die spanlose heissumformung von metallen. |
CH2651/84 | 1984-05-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0164637A1 true EP0164637A1 (de) | 1985-12-18 |
Family
ID=4238541
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP85106532A Withdrawn EP0164637A1 (de) | 1984-05-30 | 1985-05-28 | Hochtemperaturschmierstoff für die spanlose Heissumformung von Metallen |
Country Status (11)
Country | Link |
---|---|
EP (1) | EP0164637A1 (ro) |
JP (1) | JPS612797A (ro) |
CN (1) | CN85103499A (ro) |
CH (1) | CH660023A5 (ro) |
CS (1) | CS251787B2 (ro) |
DD (1) | DD233379A5 (ro) |
HU (1) | HUT38121A (ro) |
PL (1) | PL142820B1 (ro) |
RO (1) | RO92319B (ro) |
SU (1) | SU1395145A3 (ro) |
ZA (1) | ZA853630B (ro) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0240825A2 (de) * | 1986-04-04 | 1987-10-14 | Lonza Ag | Schmierstoffsystem für Blech- und Profilwalzwerke |
US5042209A (en) * | 1988-01-19 | 1991-08-27 | Lonza Ltd. | Process for charging a carrier gas stream with a free-flowing material and process for operating the device |
US5099667A (en) * | 1989-06-16 | 1992-03-31 | Lonza Ltd. | System for suspending and applying solid lubricants to tools or work pieces |
WO1992007050A1 (en) * | 1990-10-19 | 1992-04-30 | United Technologies Corporation | Rheologically controlled glass lubricant for hot metal working |
US5205488A (en) * | 1990-03-26 | 1993-04-27 | Lonza Ltd. | Process and device for spraying a liquid intermittently, especially a lubricant suspension to be sprayed under high pressure |
US5242506A (en) * | 1990-10-19 | 1993-09-07 | United Technologies Corporation | Rheologically controlled glass lubricant for hot metal working |
US5271854A (en) * | 1986-09-23 | 1993-12-21 | Lonza Ltd. | High temperature lubricant containing carboxylated styrene-butadiene latex |
EP0612830A1 (en) * | 1992-12-28 | 1994-08-31 | Desilube Technology, Inc. | Improved thermally and oxidatively stable solid lubricants |
WO1998000483A1 (de) * | 1996-07-02 | 1998-01-08 | Chemische Fabrik Budenheim Rudolf A. Oetker | Schmiermittel und dessen verwendung |
WO2008043656A3 (de) * | 2006-10-09 | 2008-07-10 | Chem Fab Budenheim Kg | Graphithaltiger hochtemperaturschmierstoff für edel- und kohlenstoffstähle |
EP2105490A1 (de) | 2008-03-29 | 2009-09-30 | Stefan Graichen | Hochtemperaturschmiermittel, insbesondere mindestens einen Oxidationskatalysator enthaltendes Gesenkschmiermittel |
CN103242936A (zh) * | 2013-04-26 | 2013-08-14 | 河南师范大学 | 一种固体切削液及其制备方法 |
WO2014195166A1 (en) * | 2013-06-07 | 2014-12-11 | Hydro Aluminium Rolled Products Gmbh | Coating of a metal sheet or strip |
DE102010015596B4 (de) | 2009-04-22 | 2018-07-19 | GM Global Technology Operations LLC (n. d. Ges. d. Staates Delaware) | Verfahren zum Verbessern der tribologischen Eigenschaften und zur Verbesserung der Haftung eines Trockenschmiermittelfilms an warmformendem Material |
US10995297B2 (en) | 2013-03-21 | 2021-05-04 | Chemische Fabrik Budenheim Kg | Composition for protection from scale and as lubricant for hot processing metals |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07107157B2 (ja) * | 1986-02-07 | 1995-11-15 | 新日鐵化学株式会社 | 高温用潤滑剤組成物 |
JPH0230312A (ja) * | 1988-04-18 | 1990-01-31 | Kawasaki Steel Corp | 継目無鋼管の熱間圧延方法 |
JPH0230311A (ja) * | 1988-04-18 | 1990-01-31 | Kawasaki Steel Corp | 継目無鋼管の傾斜圧延方法 |
JPH07122069B2 (ja) * | 1989-06-09 | 1995-12-25 | 住友金属工業株式会社 | 熱間潤滑剤 |
ZA963198B (en) * | 1995-05-16 | 1996-10-25 | Timcal Ltd | Lubricant composition for use on workpieces in the hot forming of metals |
KR100660676B1 (ko) | 2002-04-04 | 2006-12-21 | 니프로 가부시키가이샤 | 약액 용기 |
US8283296B2 (en) * | 2006-10-11 | 2012-10-09 | Henkel Ag & Co., Kgaa | Lubricant for hot forging applications |
CN101811173A (zh) * | 2010-04-28 | 2010-08-25 | 启东尤希路化学工业有限公司 | 无石墨高性能环境友好型热锻加工液 |
CN102093927A (zh) * | 2010-12-03 | 2011-06-15 | 无锡润鹏复合新材料有限公司 | 石墨-氧化物复合型热轧无缝钢管用固体润滑剂及其制备方法 |
ES2928160T3 (es) * | 2014-03-28 | 2022-11-15 | Nihon Parkerizing | Agente de recubrimiento lubricante acuoso que tiene resistencia a la corrosión y trabajabilidad excelentes, y material metálico |
CA3172826A1 (en) * | 2020-03-16 | 2021-09-23 | Chemische Fabrik Budenheim Kg | Composition for lubricating and/or descaling in hot processing of metals |
CN114703011B (zh) * | 2021-11-11 | 2023-07-14 | 西峡县三胜新材料有限公司 | 一种顶管机高温芯棒用无机盐基高温润滑剂的制备及应用方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2270319A1 (ro) * | 1974-05-08 | 1975-12-05 | Lonza Ag | |
DE2430249A1 (de) * | 1974-06-24 | 1976-02-19 | Budenheim Rud A Oetker Chemie | Hochtemperaturschmierstoff fuer die heissumformung von metallen |
-
1984
- 1984-05-30 CH CH2651/84A patent/CH660023A5/de not_active IP Right Cessation
-
1985
- 1985-04-29 CN CN198585103499A patent/CN85103499A/zh active Pending
- 1985-05-14 ZA ZA853630A patent/ZA853630B/xx unknown
- 1985-05-20 RO RO118967A patent/RO92319B/ro unknown
- 1985-05-24 DD DD85276675A patent/DD233379A5/de unknown
- 1985-05-28 EP EP85106532A patent/EP0164637A1/de not_active Withdrawn
- 1985-05-28 PL PL1985253665A patent/PL142820B1/pl unknown
- 1985-05-28 SU SU853900950A patent/SU1395145A3/ru active
- 1985-05-29 HU HU852061A patent/HUT38121A/hu unknown
- 1985-05-29 CS CS853862A patent/CS251787B2/cs unknown
- 1985-05-29 JP JP60114449A patent/JPS612797A/ja active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2270319A1 (ro) * | 1974-05-08 | 1975-12-05 | Lonza Ag | |
DE2430249A1 (de) * | 1974-06-24 | 1976-02-19 | Budenheim Rud A Oetker Chemie | Hochtemperaturschmierstoff fuer die heissumformung von metallen |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0240825A2 (de) * | 1986-04-04 | 1987-10-14 | Lonza Ag | Schmierstoffsystem für Blech- und Profilwalzwerke |
EP0240825A3 (de) * | 1986-04-04 | 1988-08-24 | Lonza Ag | Schmierstoffsystem für Blech- und Profilwalzwerke |
US5271854A (en) * | 1986-09-23 | 1993-12-21 | Lonza Ltd. | High temperature lubricant containing carboxylated styrene-butadiene latex |
US5042209A (en) * | 1988-01-19 | 1991-08-27 | Lonza Ltd. | Process for charging a carrier gas stream with a free-flowing material and process for operating the device |
US5099667A (en) * | 1989-06-16 | 1992-03-31 | Lonza Ltd. | System for suspending and applying solid lubricants to tools or work pieces |
US5205488A (en) * | 1990-03-26 | 1993-04-27 | Lonza Ltd. | Process and device for spraying a liquid intermittently, especially a lubricant suspension to be sprayed under high pressure |
WO1992007050A1 (en) * | 1990-10-19 | 1992-04-30 | United Technologies Corporation | Rheologically controlled glass lubricant for hot metal working |
US5242506A (en) * | 1990-10-19 | 1993-09-07 | United Technologies Corporation | Rheologically controlled glass lubricant for hot metal working |
EP0612830A1 (en) * | 1992-12-28 | 1994-08-31 | Desilube Technology, Inc. | Improved thermally and oxidatively stable solid lubricants |
US6177386B1 (en) | 1996-07-02 | 2001-01-23 | Chemische Fabrik Budenheim Rudolf A. Oetker | Lubricant and use thereof |
WO1998000483A1 (de) * | 1996-07-02 | 1998-01-08 | Chemische Fabrik Budenheim Rudolf A. Oetker | Schmiermittel und dessen verwendung |
WO2008043656A3 (de) * | 2006-10-09 | 2008-07-10 | Chem Fab Budenheim Kg | Graphithaltiger hochtemperaturschmierstoff für edel- und kohlenstoffstähle |
US8440597B2 (en) | 2006-10-09 | 2013-05-14 | Chemische Fabril Budenheim KG | Graphite-containing high-temperature lubricant for high-grade steels and carbon steels |
CN101535459B (zh) * | 2006-10-09 | 2013-09-25 | 化学制造布敦海姆两合公司 | 用于高级钢和碳钢的含石墨的高温润滑剂 |
EP2105490A1 (de) | 2008-03-29 | 2009-09-30 | Stefan Graichen | Hochtemperaturschmiermittel, insbesondere mindestens einen Oxidationskatalysator enthaltendes Gesenkschmiermittel |
DE102008016348A1 (de) | 2008-03-29 | 2009-10-15 | Stefan Graichen | Hochtemperaturschmiermittel, insbesondere Gesenkschmiermittel, enthaltend mindestens einen Oxidationskatalysator |
DE102010015596B4 (de) | 2009-04-22 | 2018-07-19 | GM Global Technology Operations LLC (n. d. Ges. d. Staates Delaware) | Verfahren zum Verbessern der tribologischen Eigenschaften und zur Verbesserung der Haftung eines Trockenschmiermittelfilms an warmformendem Material |
US10995297B2 (en) | 2013-03-21 | 2021-05-04 | Chemische Fabrik Budenheim Kg | Composition for protection from scale and as lubricant for hot processing metals |
CN103242936A (zh) * | 2013-04-26 | 2013-08-14 | 河南师范大学 | 一种固体切削液及其制备方法 |
WO2014195166A1 (en) * | 2013-06-07 | 2014-12-11 | Hydro Aluminium Rolled Products Gmbh | Coating of a metal sheet or strip |
US20160075903A1 (en) * | 2013-06-07 | 2016-03-17 | Hydro Aluminium Rolled Products Gmbh | Coating of a metal sheet or strip |
Also Published As
Publication number | Publication date |
---|---|
ZA853630B (en) | 1985-12-24 |
HUT38121A (en) | 1986-04-28 |
RO92319B (ro) | 1987-12-01 |
CN85103499A (zh) | 1986-10-29 |
SU1395145A3 (ru) | 1988-05-07 |
CS251787B2 (en) | 1987-08-13 |
DD233379A5 (de) | 1986-02-26 |
RO92319A (ro) | 1987-11-30 |
JPS612797A (ja) | 1986-01-08 |
PL142820B1 (en) | 1987-12-31 |
CH660023A5 (de) | 1987-03-13 |
CS386285A2 (en) | 1986-12-18 |
PL253665A1 (en) | 1986-02-25 |
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