EP0161667B1 - Procédé de traitement de surfaces métalliques - Google Patents

Procédé de traitement de surfaces métalliques Download PDF

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Publication number
EP0161667B1
EP0161667B1 EP85105917A EP85105917A EP0161667B1 EP 0161667 B1 EP0161667 B1 EP 0161667B1 EP 85105917 A EP85105917 A EP 85105917A EP 85105917 A EP85105917 A EP 85105917A EP 0161667 B1 EP0161667 B1 EP 0161667B1
Authority
EP
European Patent Office
Prior art keywords
treatment
solution
ppm
contact
fluoride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP85105917A
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German (de)
English (en)
Other versions
EP0161667A1 (fr
Inventor
Peter King
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel Corp
Original Assignee
Parker Chemical Co
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Filing date
Publication date
Application filed by Parker Chemical Co filed Critical Parker Chemical Co
Priority to AT85105917T priority Critical patent/ATE38254T1/de
Publication of EP0161667A1 publication Critical patent/EP0161667A1/fr
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Publication of EP0161667B1 publication Critical patent/EP0161667B1/fr
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides

Definitions

  • the invention relates to a method for the corrosion-protective treatment of metal surfaces made of iron and steel with fluoride-containing solutions.
  • containers made from low-carbon steel sheet - usually referred to as black sheet - are usually manufactured by pre-forming, deep drawing and smoothing.
  • Such containers have a desirable light gray glossy surface which, after a coating treatment with a clear organic varnish or printing on the outer surface, make them suitable as attractive packaging.
  • the process sequence in the manufacture of black plate containers usually consists in unwinding the black plate strip provided with a protective oil layer from the coil, in applying drawing lubricants, in a first preliminary deformation into a cup and in deep drawing and smoothing to form the final shape.
  • drawing lubricants such as water or aqueous emulsions that facilitate the deep-drawing process are usually used in the drawing and smoothing process.
  • the containers are then cut smooth in a trimmer and cleaned in a multi-stage washing process. Lubricants, protective oils, cooling lubricants and other contaminants are removed first in a cleaner with a low concentration and then in a cleaner with a higher concentration.
  • the containers are then passed through one or more water rinse stages, whereupon they are completely dried in a drying oven.
  • the outer surface is first provided with a basecoat or a decorative print and after drying with an outer layer of can lacquer. After it has hardened, it is coated internally with subsequent hardening. If the opacity of the selected paint is low, the container finally obtained must retain the shiny, light gray metallic appearance - as far as visible through the paint.
  • the object of the invention is to provide a method by means of which the aforementioned problems can be remedied. It should be able to be integrated as an integrable component in the multi-stage cleaning or rinsing process and retain the desirable light gray shiny metal surface at least until the final protection by painting or another type of surface treatment is guaranteed.
  • the object is achieved by designing the method of the type mentioned at the outset in accordance with the invention in such a way that the metal surface is brought into contact with a solution which contains 10 to 5000 ppm aluminum ions, 10 to 200 ppm fluoride ions and up to 1000 ppm ions of at least one of the Contains metals titanium, zirconium and / or hafnium and which has a pH of 2 to 5.5.
  • the aluminum can be introduced into the solution intended for carrying out the process according to the invention in the form of any soluble and compatible aluminum salt.
  • Suitable salts are e.g. Aluminum fluoride, but especially aluminum sulfate hydrate.
  • the aluminum concentration may be above the solubility limit. Concentrations in the range of 25 to 250 ppm are preferred.
  • the fluoride can be introduced into the aqueous treatment solution as a simple fluorine compound, such as hydrofluoric acid, as a simple or bifluoride salt of alkali or ammonium.
  • a simple fluorine compound such as hydrofluoric acid
  • complex fluorides e.g. As boron, silicon, aluminum, zircon, hafnium and / or titanium can be used.
  • a maximum fluoride concentration of 150 ppm is preferred.
  • the fluoride concentration generally depends on the amount of aluminum present in the solution, the nature of the metal surface to be treated, the temperature of the treatment solution and the duration of the treatment.
  • the ions of at least one of the metals titanium, zirconium and hafnium can be introduced into the solution in the form of any compound which is soluble in the acidic aqueous medium, unless disturbing bath constituents are added.
  • Suitable compounds are, for example, potassium fluorotitanate, titanium zirconium fluoride, fluozirconic acid, ammonium or alkali fluorozirconates, zirconium fluoride, zirconium sulfate and hafnium oxide and hafnium acids and salts, for example: hafnium nitrate, fluoride or chloride.
  • Alkali fluorozirconate, in particular potassium fluorozirconate (K 2 ZrF 6 ) is preferably used, especially since zirconium and fluorine are introduced at the same time.
  • the concentration of ions of at least one of the metals titanium, zirconium and hafnium can range up to 1000 ppm, those in the range from 40 to 320 ppm are preferred. The most common concentration in the working bath is around 80 ppm.
  • the solution holds hydrogen ions in such an amount that a pH of 2 to 5.5 results.
  • pH values above 5.5 no visible treatment or coating formation is obtained and consequently no corrosion protection is created.
  • the pH to be set depends on the duration of the treatment, the bath temperature and, for example, the spray pressure, but also on the concentration of the other bath components.
  • a pH value of 4.0 to 4.5 can achieve particularly favorable results.
  • the aqueous treatment solution is usually obtained from a concentrate by dilution with water. Both batch and supplement concentrate contain about 1 to 25, preferably 2.5 to 10, g / 1 aluminum, 0.1 to 5 g / l fluoride and up to 10 g / 1 titanium, zirconium and / or hafnium.
  • the pH of the concentrate is usually in the range from 0 to 4.
  • the aqueous acidic treatment solution is applied to the surface of iron or steel at a temperature of 26.7 to 82 ° C, preferably 32.2 to 54 ° C.
  • the treatment time can be 2 seconds to 5 minutes, preferably 5 seconds to 1 minute.
  • the contact of the metal surface with the solution can take place in dipping, flooding and in particular in spraying.
  • the spray treatment is also advantageous because the conventional washing treatment into which the process according to the invention can be integrated, in particular because of the shape of the containers to be treated and the necessary thorough contact with the solution, is generally designed as a spray process anyway.
  • the process according to the invention can be carried out in the second stage of a three-stage washing process, in the third stage of a five-stage washing process or in the fourth stage of a six-stage washing process.
  • the fourth stage is used to rinse with water in the fifth stage and with deionized water in the sixth stage before drying takes place in a convection oven.
  • the duration of the contact between the metal surface and the treatment solution is largely determined by the operation of the existing system. When setting the treatment temperature, too, you will usually follow the treatment temperatures otherwise prevailing in the system.
  • the pH was approximately 0.7.
  • the treatment solution was obtained by adding 3 of the aforementioned concentrate to 140 l of water.
  • the pH was adjusted to 3.8 to 4.5.
  • the treatment of a black sheet container was carried out in a five-stage washing plant with the stages of alkaline cleaning, water rinsing, treatment with the above-mentioned treatment solution for a period of 1 min, water rinsing and rinsing with demineralized water.
  • the container treated in this way with a remainder of water in the curved bottom was then dried at 163 ° C. No rust was visible on the surface of the container.
  • a continuous treatment line for black tin cans with the same treatment steps as above was stopped for half an hour. Thereafter, the cans in level 2 showed signs of rust, whereas the cans in levels 1, 3, 4 and 5 showed no visible rust.
  • black tin cans were subjected to the alkaline cleaning, water rinsing, and contacting with an aqueous solution which contained 200 ppm aluminum, 75 ppm HBF 4 , 80 ppm zirconium and had a pH of 4.4, Water rinsing, rinsing treated with deionized water.
  • the individual treatment tanks were of practically the same length, so that the treatment times were practically the same at 40 seconds each.
  • the temperature of the solution applied in the third stage was 49 ° C.
  • Black tin cans were treated according to the procedure according to Example 2, with the exception that the pH of the aqueous acidic solution of stage 3 was set to 3.5. After the final rinsing treatment, the cans were dried in an oven at 193 ° C. for 3 minutes. The cans showed a brown-golden discoloration, which is intolerable if only a final treatment with a clear varnish is provided.
  • Black tin cans were again treated according to the procedure in Example 2, with the exception that the pH of the acidic treatment solution was set to 5.5 in stage 3. After drying in the oven, the cans were shiny and without significant discoloration. Only some of the cans showed local discolouration on the floor curvature, the edges and contact surfaces of two neighboring cans. Some cans that had been removed from the system before the oven dried and therefore remained damp showed rust very quickly.
  • Example 1 According to the scheme of Example 1, a number of treatment solutions were prepared, which differed in the content of titanium, zirconium, hafnium. Finally, a solution was prepared as a control solution that contained only fluoride and was free of aluminum, zirconium, titanium and hafnium. In the first-mentioned solutions, the zircon was introduced as potassium fluorozirconate, the hafnium as hafnium dioxide (Hf0 2 ) and the titanium as hexafluorotitanic acid. In a procedure similar to Example 1, black tin cans were treated in a 19 liter spray tank for 1 min at 49 ° C.
  • All treatment solutions had a pH of 4.3 and a fluoride content of 100 ppm (introduced as HBF 4 ).
  • the aluminum and titanium, zirconium and / or hafnium content (in ppm) of the solution and the results obtained are shown in the table below.
  • the appearance of the can jacket and the base of the can after drying in the oven were used for evaluation.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Metallurgy (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Compounds Of Iron (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Saccharide Compounds (AREA)
  • Coating With Molten Metal (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Claims (8)

1. Procédé de traitement anticorrosion de surfaces métalliques de fer ou d'acier avec des solutions contenant du fluorure, caractérisé en ce que l'on met les surfaces métalliques en contact avec une solution qui contient 10 à 5000 ppm d'ions aluminium, 10 à 200 ppm d'ions fluorure et jusqu'à 1000 ppm d'ions d'au moins un des métaux titane, zirconium et/ou hafnium et qui présente un pH de 2 à 5,5.
2. Procédé selon la revendication 1, caractérisé en ce que l'on met les surfaces métalliques en contact avec une solution qui contient 25 à 250 ppm d'ions aluminium.
3. Procédé selon la revendication 1 ou 2, caractérisé en ce que l'on met les surfaces métalliques en contact avec une solution qui contient au maximum 150 ppm d'ions fluorure.
4. Procédé selon la revendication 1, 2, ou 3, caractérisé en ce que l'on met les surfaces métalliques en contact avec une solution qui contient 40 à 320 ppm d'ions d'au moins un des métaux titane, zirconium, hafnium.
5. Procédé selon une ou plusieurs des revendications 1 à 4, caractérisé en que l'on met les solutions métalliques en contact avec la solution à une température de 26,7 à 82°C.
6. Procédé selon la revendication 5, caractérisé en ce que l'on met les surfaces métalliques en contact avec la solution à une température de 32,2 à 54°C.
7. Procédé selon une ou plusieurs des revendications 1 à 6, caractérisé en ce que l'on met les surfaces métalliques en contact avec la solution pendant une durée de 2 secondes à 5 minutes.
8. Procédé selon la revendication 7, caractérisé en ce que l'on met les surfaces métalliques en contact avec la solution pendant une durée de 5 secondes à 1 minute.
EP85105917A 1984-05-18 1985-05-14 Procédé de traitement de surfaces métalliques Expired EP0161667B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT85105917T ATE38254T1 (de) 1984-05-18 1985-05-14 Verfahren zur behandlung von metalloberflaechen.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/611,663 US4496404A (en) 1984-05-18 1984-05-18 Composition and process for treatment of ferrous substrates
US611663 1984-05-18

Publications (2)

Publication Number Publication Date
EP0161667A1 EP0161667A1 (fr) 1985-11-21
EP0161667B1 true EP0161667B1 (fr) 1988-10-26

Family

ID=24449936

Family Applications (1)

Application Number Title Priority Date Filing Date
EP85105917A Expired EP0161667B1 (fr) 1984-05-18 1985-05-14 Procédé de traitement de surfaces métalliques

Country Status (13)

Country Link
US (1) US4496404A (fr)
EP (1) EP0161667B1 (fr)
JP (1) JPS60255986A (fr)
AT (1) ATE38254T1 (fr)
AU (1) AU576574B2 (fr)
BR (1) BR8502349A (fr)
CA (1) CA1264538A (fr)
DE (2) DE3565863D1 (fr)
ES (1) ES8603589A1 (fr)
GB (1) GB2158845B (fr)
MX (1) MX164560B (fr)
NZ (1) NZ212007A (fr)
ZA (1) ZA853561B (fr)

Families Citing this family (17)

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Publication number Priority date Publication date Assignee Title
JP2541269B2 (ja) * 1987-08-27 1996-10-09 日本板硝子株式会社 酸化物薄膜の製造方法
DE3829154A1 (de) * 1988-08-27 1990-03-01 Collardin Gmbh Gerhard Chromfreies verfahren zur vorbehandlung von metallischen oberflaechen vor einer beschichtung mit organischen materialien
US5073196A (en) * 1989-05-18 1991-12-17 Henkel Corporation Non-accelerated iron phosphating
DE4017186A1 (de) * 1990-05-29 1991-12-05 Metallgesellschaft Ag Erzeugung von konversionsueberzuegen auf zink- oder zinklegierungsoberflaechen
DE4017187A1 (de) * 1990-05-29 1991-12-05 Metallgesellschaft Ag Verfahren zur nachspuelung von konversionsschichten
DE3924984A1 (de) * 1989-07-28 1991-01-31 Metallgesellschaft Ag Verfahren zur passivierenden nachspuelung von phosphatschichten
US5294266A (en) * 1989-07-28 1994-03-15 Metallgesellschaft Aktiengesellschaft Process for a passivating postrinsing of conversion layers
BE1005464A3 (fr) * 1990-11-03 1993-08-03 Glaverbel Objets reflechissants et leur procede de fabrication.
BR9206419A (pt) * 1991-08-30 1995-04-04 Henkel Corp Processo para a produção de um revestimento de conversão protetor.
US5281282A (en) * 1992-04-01 1994-01-25 Henkel Corporation Composition and process for treating metal
RU2125118C1 (ru) * 1992-04-01 1999-01-20 Хенкель Корпорейшн Способ получения композиции и способ обработки ею металла, его вариант
DE19510825A1 (de) * 1995-03-24 1996-09-26 Henkel Kgaa Korrosionsschützender Reiniger für verzinnten Stahl
US5641542A (en) * 1995-10-11 1997-06-24 Betzdearborn Inc. Chromium-free aluminum treatment
US5840772A (en) * 1996-09-18 1998-11-24 Ppg Industries, Inc. Methods of recycling and compositions used therein
JP4099307B2 (ja) * 2000-04-20 2008-06-11 日本ペイント株式会社 アルミニウム用ノンクロム防錆処理剤、防錆処理方法および防錆処理されたアルミニウム製品
KR100466418B1 (ko) * 2000-11-25 2005-01-13 주식회사 포스코 내유화변색성, 내식성 및 도장성이 우수한 주석도금강판및 그 제조방법
US7611588B2 (en) * 2004-11-30 2009-11-03 Ecolab Inc. Methods and compositions for removing metal oxides

Family Cites Families (11)

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Publication number Priority date Publication date Assignee Title
GB947658A (en) * 1960-07-25 1964-01-22 Polychrome Corp Planographic printing plate and method for preparing same
US3160506A (en) * 1962-10-19 1964-12-08 Polychrome Corp Planographic printing plate and method for preparing same
US3539403A (en) * 1966-12-07 1970-11-10 Collardin Gmbh Gerhard Solutions for the deposition of protective layers on zinc surfaces and process therefor
US3539402A (en) * 1967-02-16 1970-11-10 Collardin Gmbh Gerhard Solutions for the deposition of protective surface layers on iron and zinc and process therefor
DE1933013C3 (de) * 1969-06-28 1978-09-21 Gerhard Collardin Gmbh, 5000 Koeln Verfahren zur Erzeugung von Schutzschichten auf Aluminium, Eisen und Zink mittels komplexe Fluoride enthaltender Lösungen
US4017334A (en) * 1973-10-04 1977-04-12 Oxy Metal Industries Corporation Process for treating aluminum cans
FR2417537A1 (fr) * 1978-02-21 1979-09-14 Parker Ste Continentale Composition a base d'hafnium pour inhiber la corrosion des metaux
US4273592A (en) * 1979-12-26 1981-06-16 Amchem Products, Inc. Coating solution for metal surfaces
US4370177A (en) * 1980-07-03 1983-01-25 Amchem Products, Inc. Coating solution for metal surfaces
DE3105508A1 (de) * 1981-02-14 1982-09-02 Metallgesellschaft Ag, 6000 Frankfurt Beiz- und entrostungspaste fuer metalle
US4457790A (en) * 1983-05-09 1984-07-03 Parker Chemical Company Treatment of metal with group IV B metal ion and derivative of polyalkenylphenol

Also Published As

Publication number Publication date
MX164560B (es) 1992-08-26
ES543711A0 (es) 1986-01-01
AU4223085A (en) 1985-11-21
NZ212007A (en) 1988-09-29
AU576574B2 (en) 1988-09-01
JPS60255986A (ja) 1985-12-17
ES8603589A1 (es) 1986-01-01
GB8512285D0 (en) 1985-06-19
ZA853561B (en) 1985-12-24
DE3565863D1 (en) 1988-12-01
GB2158845A (en) 1985-11-20
EP0161667A1 (fr) 1985-11-21
BR8502349A (pt) 1986-01-21
ATE38254T1 (de) 1988-11-15
US4496404A (en) 1985-01-29
GB2158845B (en) 1987-11-04
DE3517280A1 (de) 1985-11-28
CA1264538A (fr) 1990-01-23

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