EP0122949A1 - Fil fascié ayant l'aspect d'un filé, résistant à la chaleur, et procédé pour le fabriquer - Google Patents

Fil fascié ayant l'aspect d'un filé, résistant à la chaleur, et procédé pour le fabriquer Download PDF

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Publication number
EP0122949A1
EP0122949A1 EP83103913A EP83103913A EP0122949A1 EP 0122949 A1 EP0122949 A1 EP 0122949A1 EP 83103913 A EP83103913 A EP 83103913A EP 83103913 A EP83103913 A EP 83103913A EP 0122949 A1 EP0122949 A1 EP 0122949A1
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Prior art keywords
yarn
tow
fiber
less
poly
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EP83103913A
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German (de)
English (en)
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EP0122949B1 (fr
Inventor
Yoshiyuki Sasaki
Mitsuo Matsumoto
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Teijin Ltd
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Teijin Ltd
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Priority to DE8383103913T priority Critical patent/DE3372385D1/de
Priority to EP19830103913 priority patent/EP0122949B1/fr
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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01H—SPINNING OR TWISTING
    • D01H1/00—Spinning or twisting machines in which the product is wound-up continuously
    • D01H1/11—Spinning by false-twisting
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01G—PRELIMINARY TREATMENT OF FIBRES, e.g. FOR SPINNING
    • D01G1/00—Severing continuous filaments or long fibres, e.g. stapling
    • D01G1/06—Converting tows to slivers or yarns, e.g. in direct spinning
    • D01G1/08—Converting tows to slivers or yarns, e.g. in direct spinning by stretching or abrading
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D02G3/047—Blended or other yarns or threads containing components made from different materials including aramid fibres

Definitions

  • the present invention relates to a spun-like fasciated yarn having good heat durability maintaining excellent mechanical strength and less creep deformation even under a high temperature condition exceeding 300°C.
  • wholly aromatic polyamide fibers such as poly-para-phenyleneterephthalamide or poly-meta-phenyleneisophthalamide which is on the market under the trade name "Kevlar®” from Du Pont de Nemours and Co. of USA or "Cornex®” from Teijin Limited of Japan, has superior mechanical strength and high modulus as well as good heat durability and anti-erosive properties. Due to the above-mentioned advantages, they are widely utilized in the industrial field.
  • a bag filter is one of the suitable usages of the wholly aromatic polyamide fibers because the bag filter has to often be exposed to a'high temperature and erosive atmosphere.
  • a fabric woven from the spun yarn of such a fiber is expected to be more advantageous than a filament yarn fabric because of a better filtration ability caused by a relatively looser structure and a larger thickness of the spun yarn than of the filament yarn.
  • a resultant spun yarn cannot satisfactorily be applied to the aforesaid object due to the reasons explained below.
  • the fiber can be formed only by the dry spinning or wet spinning of a solution in which the polymer is dissolved by a suitable solvent. Under such conditions, it is more advantageous to have a thicker tow for staple fibers than to have a plurality of thinner filament yarns. Since the tow for staple fibers has a very large thickness of, for example, from several dozen thousand denier to several hundred thousand denier, a higher draw ratio is hardly attainable.
  • the tows thus obtained are cut into staple fibers after being crimped and, thereafter, are subjected to a conventional complicated spinning process comprising scutching, carding, drawing, doubling, twisting, etc.
  • a conventional complicated spinning process comprising scutching, carding, drawing, doubling, twisting, etc.
  • the fibers in the spun yarn are considerably disoriented and deformed. This causes, along with the crimps thereof, a greater elongation and lower strength of the yarn.
  • the wholly aromatic polyamide fiber lacks a spinna- bilty due to its hardness and rigidity, the abovesaid tendency is accelerated. Accordingly, the spun yarn has an undesirable creep deformation, especially in a high temperature atmosphere, compared to a filament yarn. This is the reason why the conventional spun yarn of the wholly aromatic polyamide fibers is unsatisfactory in the above-mentioned object.
  • the present inventors have studied a long time to obtain a spun yarn having none of the drawbacks mentioned above, and succeeded in accomplishing the present invention which provides an excellent spun yarn having a higher mechanical strength and-a desirable anti-creep property under a high temperature condition relative.to those of a filament yarn. Before, it was believed that filament yarn was superior to spun yarn regarding the above-mentioned items due to the continuity thereof. However, the yarn according to the present invention contradicts this belief.
  • the object of the present invention is attainable by a fasciated yarn consisting of staple fibers of a wholly aromatic polyamide polymer prepared by the stretch--breaking of a tow; comprising a core portion and a plurality of wrap fiber groups wrapped around the core portion, the yarn being characterized in that the staple fiber has a mean fiber length within a.range of from 150 mm to 600 mm, a crimpability of less than 5%, and a mean degree of parallelism (6) of less than 3°, and that the number of the wrap fiber groups is within the range of from 0.5 to 20 per 1 cm in length of said yarn, and a method for producing a fasciated yarn consisting of staple fibers of a wholly aromatic polyamide polymer comprising the following steps of: stretch-breaking a tow of filaments into a bundle of staple fibers taking care not to disturb the parallelism thereof, each filament of said tow having a crimpability of less than 5%; and subjecting said bundle of staple fibers, omitting the crimping
  • a yarn according to the present invention is a fasciated yarn of the same type as those disclosed in USP No. 3,079,746 by F. C. Field, Jr. and No. 4,265,082 by Y. Sasaki et al. That is, the yarn comprises a core portion 1 having substantially no twist consisting of staple fibers and a plurality of wrap fiber groups 2 wrapped around the core portion.
  • the staple fibers composing the core portion 1 have to be substantially, parallel to an axis of the yarn. Distortion of the core portion fibers is represented as a mean degree of parallelism 6 and has to be less than 3° thereof according to the invention. That is, the mean degree of parallelism ⁇ is an inclination of the staple fiber bundle composing the core portion relative to the axis of the yarn, a measurement being carried out according to the following steps:
  • the ⁇ exceeding 3° is not desirable, because the yarn shows an excess elongation corresponding to stress.
  • the staple fiber composing the core portion has preferably no crimps, if any, a crimpability thereof being at most 5%.
  • the crimpability means a value measured according to JIS 1074-65,'in which a single fiber of a length of 30 cm to be tested is loaded by a weight of 50 mg/d for 30 seconds and, thereafter, its length l 0 is measured, and the weight is replaced to a lighter one of 2 mg/d and, two minutes later, the length l 1 of the fiber is measured, the crimpability CR being calculated by the following equation (2),
  • the average value for 10 test pieces is representative of CR.
  • the staple fibers in the core portion have the CR exceeding 5%, because, in such a case, the yarn becomes bulky causing a lower tensile strength and a greater elongation, especially under a high temperature condition.
  • a mean fiber length L of the staple fiber is necessarily within the range of from 150 mm to 600 mm. If the fiber length L is less than 150 mm, the tensile strength does not reach 3 g/d and, while, if the fiber length L is more than 600 mm, the yarn structure is similar to that of a filament yarn which lacks the bulkiness common in spun yarn. Both of them are not unsuitable for the object of the present invention.
  • the staple fiber composing the wrap fiber group 2 originates from the same source as the core portion fiber. One end of the wrap fiber is embedded in the core portion 1, and the other end thereof is free, which wraps around the core portion 1 and binds it to retain a yarn structure.
  • the wrap fiber group fibers should have substantially the identical characteristics of the core portion fibers.
  • a number of wrap fiber groups N must be within the range of from 0.5 to 20 per 1 cm in length of the yarn in the mean value. If the number N is less than 0.5, the fasciate action to the core portion is too weak to have a compact structure thereof, whereby yarn breakage may occur during a post operation such as weaving or knitting. On the other hand, wrap fiber groups of more than 20 per 1 cm in length naturally cause the decrease of the core portion fibers as well as the mean degree of parallelism ⁇ exceeding 3°, both of which result in undesirable low mechanical properties of the yarn.
  • the staple fibers composing the fasciated yarn according to the present invention consist of wholly aromatic polyamide polymer fibers.
  • the wholly aromatic polyamide polymers herein-described include not only in a narrow sense such as the aforesaid poly-para-phenyleneterephthalamide or poly-meta-phenyleneisophthalamide but also aromatic polyether amides having linkages defined below, in a wide sense.
  • aromatic polyether amide fiber means a fiber composed of polymers which consist of the recurring units of the following formulas
  • aromatic carbocyclic rests with bonding chains extending coaxially there may be mentioned, for example, 1,4-phenylene and 1,4-naphthylene rests.
  • aromatic carboxylic rests with bonding chains extending parallel to the axis there may be mentioned, for example, 1,5-napthylene and 2,6-naphthylene.
  • the so-joined aromatic rests include, for example,
  • alkyl rests containing net more than 5 carbon atoms there may be mentioned a methyl, an ethyl, a propyl, a butyl, a pentyl rest, and the like. Of these rests, methyl is preferable.
  • the hydrogen atoms bonded to the carbon atoms may be substituted.
  • substituents there may be mentioned halogen atoms (e.g., chlorine, bromine, and fluorine atoms), lower alkyl rests (e.g., methyl, ethyl, iso--propyl, and n-propyl rests), lower alkoxy rests (e.g., methoxy and ethoxy rests), a cyano rest, an acetyl rest, and a nitro rest.
  • halogen atoms e.g., chlorine, bromine, and fluorine atoms
  • lower alkyl rests e.g., methyl, ethyl, iso--propyl, and n-propyl rests
  • lower alkoxy rests e.g., methoxy and ethoxy rests
  • cyano rest e.g., methoxy and ethoxy rests
  • Fibers spinning from these polymers are well-known to have surprisingly excellent properties even in a high temperature atmosphere exceeding 300°C.
  • a fiber bundle used for the present inventive method is prepared by the so-called "stretch-breaking" of a filament tow.
  • the fiber bundle thus prepared has to be fasciated while keeping a parallel orientation thereof.
  • the orientation of the staple fiber in the resultant yarn cannot be completely parallelized and, in addition to this, the crimp of the staple fiber, which is necessary to enhance the spinnability thereof, causes an undesirable creep elongation of the yarn relative to a filament yarn.
  • the stretch-breaking is also effective for the micro--structure of the fiber. That is, since each filament is drawn to the utmost extent by the stretching force to break a filament, the degree of molecular orientation in the micro-structure of the fiber can be greatly improved, thereby the staple fiber thus obtained has superior mechanical properties to those of the original filament.
  • Fig. 2 illustrates an embodiment of the apparatus utilized for practicing the method according to the invention. If the amount of the oil and/or water is too small, the tow may become charged with electricity which causes disturbance of the fiber parallelism or wrapping of the fibers around a metallic surface of the stretch rollers due to repulsion of the composing filaments.
  • a suitable amount should be within a range of from 0.05% to 0.30% for the oil and of-less than 7% for the water relative to the weight of the tow. More specifically, for the water, the more preferable range is different to respective wholly aromatic polyamide fibers due to their intrinsic water absorptions; that is, less than 6% for poly-para-phenylene terephthalamide, and less than 3% for aromatic polyether amide.
  • the mean fiber length of the staple fiber stretch--broken from the tow depends on a distance between the feed rollers 5 and the stretch rollers 6 as well as a draw ratio therebetween.
  • the fiber bundle 4' thus stretch-broken is collectively guided to the stretch rollers 6 by a trumpet shaped chute 7 provided upstream of the former, and is thereby drafted to a predetermined thickness sliver.
  • the fiber bundle 4' is introduced into an aspirator 8 provided downstream of the stretch roller 6 along with a suction flow. Downstream of the aspirator 8 is arranged an air nozzle 9 within which the fiber bundle 4', introduced therein in a ribbon form, is false-twisted by a vortex, so that edge porton fibers thereof entangle around a core portion thereof to form a resultant fasciated yarn.
  • the structure of the air nozzle 9 is disclosed, for example, in the above-mentioned USP No. 3,079,746.
  • a feed ratio of the stretch rollers 6 relative to draw-off rollers 10 provided downstream of the former has to be less than +4% preferably less than +1% including a 0% or minus feed ratio.
  • the core portion 1 of the resultant yarn is partially twisted in an S or Z direction which causes the mean degree of parallelism to be more than 3° and the number of the wrap fiber groups to be more than 20 per 1 cm in length, both of which are not desirable as described before.
  • the resultant fasciated yarn is continuously wound on a cheese 11.
  • the yarn thus obtained has, as it is, excellent properties suitable for attaining the objects of the present invention. However, the properties can be improved more by heat treatment carried out after the yarn forming.
  • This heat treatment may be exercised continuously subsequent to the false-twist operation, as illustrated in Fig. 3, by a heat roller 12, to a surface of which the yarn has made contact several times, or separately to the spinning process, may be carried out by an autoclave in which the cheese 11 of the yarn is steamed.
  • the temperature of the heat treatment is preferably more than 200°C and, thereby, the residual shrinkage and creep deformation of the yarn, especially in a high temperature atmosphere, can be improved to be suitable for usage under such conditions.
  • a filament tow of 4400 d/3000 f consisting of poly-para-phenyleneterephthalamide fibers was processed by the apparatus shown in Fig. 2.
  • the tow had an oil content and a water content of 0.25% and 4.0%, respectively, by weight, and a fiber composing the tow had no crimps at all.
  • the distance and the draw ratio between the feed rollers 2 and the stretch rollers 6 were adjusted to 750 mm and 25 times, respectively.
  • the tow was stretch--broken to a staple fiber bundle having a mean fiber length L of 312 mm and, finally, was formed into a fasciated yarn of 30 S (cotton count) according to the present invention.
  • Air pressures utilized for the aspirator 8 and the air nozzle 9 were 3 kg/cm 2 and 5 kg/cm 2 , respectively.
  • a filament tow of 3000 d/2000 f consisting of aromatic polyetheramide fibers having no crimps, consisting of 25 mol% of para-phenylenediamine, 25 mol% of 3.4'-diaminodiphenylether, and 50 mol% of terephthalic acid was processed by the apparatus shown in Fig. 2.
  • the tow had an oil and water content of 0.1% and 1.6%, respectively, by weight.
  • the distance and the draw ratio between the feed rollers 2 and the stretch rollers 6 were adjusted to 750 mm and 20 times, respectively.
  • the tow was stretch--broken to a staple fiber bundle having a mean fiber length L of 290 mm and, finally, was formed into a fasciated yarn of 35 S (cotton count) according to the present invention.
  • Air pressures utilized for the aspirator 8 and the air nozzle 9 were the same as Example 1.
  • a filament tow of 7000 d/3500 f consisting of poly-meta-phenyleneisophthalamide fibers having no crimps was processed as the same manner described in Examples 1 and 2.
  • the distance and the draw ratio between the feed rollers 2 and the stretch rollers 6 were adjusted to 600 mm and 26 times, respectively.
  • the tow was stretch--broken to a staple fiber bundle having a mean fiber length L of 230 mm and, finally, was formed into a fasciated yarn of 20 S (cotton count) according to the present invention.
  • Air pressures utilized for the aspirator 8 and the air nozzle 9 were 4 kg/cm 2 , respectively.
  • the tow processings were carried out on the same tow utilized in Example 3 under the same conditions as Examples 1 and 2, except that the roller distances were adjusted to 280 mm and 1800 mm, respectively, thereby obtaining two comparative yarns having mean fiber lengths L of 103 mm and 710 mm, respectively.
  • Example 3 The same filament tow as utilized in Example 3 was crimped, prior to the stretch-breaking operation, to have a crimpability CR of 10% by a stuffer box system without heating.
  • the tow was processed under the same conditions as Example 3, thereby obtaining a comparative yarn of excess crimpability.
  • Example 3 The same filament tow as utilized in Example 3 was processed under the same conditions as Example 3 except that the feed ratio between the two pairs of rollers 6 and 10 was adjusted to +7.%, thereby obtaining a comparative yarn of the mean degree of parallelism 6 of 4°.
  • Tow processings were carried out with the same tow as utilized in Example 3 under the same conditions thereof, except that the feed ratios between the two pairs of rollers 6 and 10, and the air pressure of the aspirator 8 and the air nozzle 9 were adjusted to the following sets of values: (1) feed ratio -2%, air pressure 2 kg/cm 2 respectively,' and (2) feed ratio +8%, air pressure 6 kg/cm 2 respectively, thereby obtaining two comparative yarns having the number of wrap fiber groups N of 0.42/cm and 23.0/cm, respectively.
  • a filament tow of 7000 d/6000 f consisting of poly-meta-phenyleneisophthale amide fibers having no crimps was processed by the apparatus shown in Fig. 2.
  • the distance and the draw ratio between the feed rollers 2 and the stretch rollers 6 were adjusted to 600 mm and 26 times, respectively.
  • the tow was stretch--broken to a staple fiber bundle having a mean fiber length L of 230 mm and, finally, was formed into a fasciated yarn A of 20 S (cotton count) by adjusting the air pressures of the aspirator and the air nozzle to 4 kg/cm 2 and 5 kg/cm 2 , respectively.
  • Example 4 the same tow as described in Example 4, was cut to form staple fibers of 2 inch lengths after crimps were imparted by a stuffer box system, and the staple fibers were spun to become a spun yarn B as a comparative example by means of a conventional cotton spinning system.
  • the yarn A according to the present invention shows a different stress-strain curve from that of the comparative yarn B.
  • the yarn according to the present invention can be utilized for a bag filter, because of its excellent mechanical strength and creep durability in a high temperature condition. Further, the yarn is suitable for a reinforcing member embedded in a mold material such as rubber because the yarn is rich in fluffs and in inter--fiber porosity which enhance the anchoring effect in the mold material.
  • the yarn also can be preferably utilized for sewing thread due to its heat radiation ability which serves to suppress the temperature elevation of a sewing needle even at a high sewing speed.
  • a fasciated yarn of 20 S (cotton count)having a mean fiber length of 230 mm was prepared from a filament tow of 7000 d/1000 f consisting of poly-meta-phenyleneisophthalamide fibers by utilizing the apparatus shown in Fig. 2.
  • a bag filter C according to the present invention was manufactured from a satin made of the abovesaid yarn. Densities of the warp and weft were 73 ends/in and 57 picks/in, respectively.
  • a fasciated yarn of 3.6 S (cotton count) was produced, according to the present invention, from a filament tow of 150,000 d consisting of the same aromatic polyether amide fiber as utilized in Example 2 by means of the apparatus shown in Fig. 2, thereby being knit in a tubular braid.
  • the braid was layered in a hose structure as an inner reinforcement 52 along with an inner rubber layer 51, a polyester filament fabric 53, and an outer rubber layer 54.
  • Three hoses to be tested were filled with brake oil and were left in the atmosphere at a temperature of 150°C for 100, 200, and 500 hours, respectively. Each burst test was carried out on one of the hoses at each time period.
  • a hose to be tested was subjected to repeated bending motions caused by a pulley, on which the hose was mounted.
  • the pulley had a diameter 15 times of the hose width and was rotated reciprocally at a rate of 10 m/sec. After 2000 revolutions under a tension of 5 kg/cm, the breaking strength of the hose was measured.
  • Two hoses to be tested were immersed into a solution of 20% sulfuric acid at 90°C and a solution of 10% caustic soda at 95°C, respectively, for 100 hours.
  • the same fasciated yarn of 3.6 S (cotton count) as obtained in Example 6 was two-plied with an S twist of 10 t/10 cm to form a cord according to the present invention.
  • the cord was immersed into a first bath, which was followed by drying at 150°C for 1 minute and baking at 240°C for 1 minute. Then, the cord was immersed into a second bath which was followed by drying at 150°C for 1 minute and baking at 240°C for 1 minute, thereby obtaining a cohesive cord for a timing belt.
  • Formulas of the first and second baths are as follows:
  • a two-plied cohesive cord to be tested was embedded in a rubber layer of 1 cm width composing a timing belt, so that the cord was directed perpendicular to the longitudinal direction of the belt. Then the belt was vulcanized under a temperature of 160°C for 20 minutes. A force was measured, which is necessary to pull out the cord from the structure of the vulcanized belt, at a rate of 200 cm/min.
  • a cord to be tested was treated in an autoclave filled with steam of 150°C (6 kg/cm 2 ) for 100 hours.
  • the strength retaining ratios were calculated from the breaking strengths of the treated cord and the untreated one.
  • a cord to be tested was subjected to repeated elongations of 6% and compressions of 18%, caused by a Goodrich type disc tester, for 100 hours or 200 hours.
  • the strength retaining ratios were calculated from the breaking strengths of the treated cord and the untreated one.
  • the same fasciated yarn of 3.6 S (cotton count) as obtained in Example 6 was two-plied with a primary twist of 109 t/m and, then, the resultant yarn was three-plied with a final twist of 227 t/m to form a cord.
  • the cord was incorporated into a V-belt as shown in Fig. 4, in which reference numerals 41 and 45 designate cotton fabrics, respectively; 42 and 44 chloroprene rubber layers, respectively; and 43 the cord consisting of the invented yarns.
  • the V-belt to be tested was subjected to repeated bendings caused by a pulley, on which the V-belt was mountted.
  • the pulley had a diameter 15 times of the V-belt width and was rotated at a rate of 10 m/sec. After 10 9 revolutions in the atmosphere having a temperature of 16°C and an RH of 65% under a tension of 5 kg/cm, the breaking strength of the V-belt was measured and the strength retaining ratio was calculated relative to the untreated one.
  • a creep tester provided by K.K. IWAMOTO SEISAKUSHO was utilized.
  • V-belt to be tested was subjected to repeated bendings under conditions of 40°C temperature and 100% RH by the same device as utilized for testing the wearability. After 10 9 revolutions under a tension of 1 kg/cm, the dimensions of the V-belt were measured and compared to the original ones.
  • V-belts to be tested were immersed into aqueous solutions of 20% sulfuric acid at 95°C, and 10% caustic soda at 95°C, respectively, for 100 hours.
  • the same fasciated yarn of 3.6 S (cotton count) as obtained in Example 6 was chopped to a plurality of pieces of 5 mm in length.
  • the chopped pieces were mixed with a heat durable rubber composition described in Table 6 with a weight ratio of 2.0:100, and the mixed composition was extruded through a slit to form a mold A in a sheet form of 3 mm in thickness.
  • the mold A was processed, according to the following steps, to have a test piece: preparing two sheets of the above-said rubber composition not containing the chopped pieces, having thicknesses of 5 mm and 2 mm, respectively; interposing a canvas woven from a polyester yarn between the prepared two sheets to form a layered sample of 30 mm in width; peeling the rubber sheet of 5 mm in thickness along a 100 mm length and complementing a separately prepared rubber sheet of 2 mm in thickness of the same composition and the mold A of 3 mm in thickness in a layered manner to have a sample; and vulcanizing the sample under a pressure of 50 kg/cm 2 to make a finished test piece.
  • test piece was subjected to repeated bendings of 60 Hz by means of a hot pulley of 125°C surface temperature and a 75 mm diameter under a tension of 55 kg, and the time required to cause a crack on a surface of the test piece was measured.
  • a mold B was prepared by utilizing a filament yarn of 1500 d/1000 f consisting of the same aromatic polyether amide fibers as the yarn utilized in the mold A, and another test piece was obtained in accordance with the same manner as described above and subjected to the cracking test.
  • a filament tow of 3000 denier consisting of the same aromatic polyether amide fibers as utilized in Example 2 was processed by the apparatus shown in Fig. 2 to form a fasciated yarn A of 53 S (cotton count) according to the present invention.
  • the yarn A was two-plied with a primary twist of S 700 t/m and the resultant yarn was three-plied with a final twist of Z 450 t/m, thereby obtaining a sewing thread.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
EP19830103913 1983-04-21 1983-04-21 Fil fascié ayant l'aspect d'un filé, résistant à la chaleur, et procédé pour le fabriquer Expired EP0122949B1 (fr)

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Application Number Priority Date Filing Date Title
DE8383103913T DE3372385D1 (en) 1983-04-21 1983-04-21 Heat-durable spun-like fasciated yarn and method for producing the same
EP19830103913 EP0122949B1 (fr) 1983-04-21 1983-04-21 Fil fascié ayant l'aspect d'un filé, résistant à la chaleur, et procédé pour le fabriquer

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Application Number Priority Date Filing Date Title
EP19830103913 EP0122949B1 (fr) 1983-04-21 1983-04-21 Fil fascié ayant l'aspect d'un filé, résistant à la chaleur, et procédé pour le fabriquer

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EP0122949A1 true EP0122949A1 (fr) 1984-10-31
EP0122949B1 EP0122949B1 (fr) 1987-07-08

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Cited By (7)

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Publication number Priority date Publication date Assignee Title
WO1994009195A1 (fr) * 1992-10-14 1994-04-28 Wool Research Organisation Of New Zealand Incorporated Fil multi-composants a fort volume
WO2000077283A2 (fr) * 1999-06-14 2000-12-21 E.I. Du Pont De Nemours And Company Procede et produit de rupture par etirage
EP1522614A1 (fr) * 2003-10-06 2005-04-13 Schärer Schweiter Mettler AG Dispositif pour produire des filés de fibres synthétiques
EP1522613A1 (fr) * 2003-10-06 2005-04-13 Schärer Schweiter Mettler AG Dispositif pour produire des filés de fibres synthétiques
US7083853B2 (en) 1999-06-14 2006-08-01 E. I. Du Pont De Nemours And Company Stretch break method and product
US7100246B1 (en) 1999-06-14 2006-09-05 E. I. Du Pont De Nemours And Company Stretch break method and product
US7581376B2 (en) 2004-02-27 2009-09-01 E.I. Du Pont De Nemours And Company Spun yarn, and method and apparatus for the manufacture thereof

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Publication number Priority date Publication date Assignee Title
US2784458A (en) * 1949-07-08 1957-03-12 Deering Milliken Res Corp Process and apparatus for converting continuous filamentary material into filaments of staple length
US3079746A (en) * 1961-10-23 1963-03-05 Du Pont Fasciated yarn, process and apparatus for producing the same
US4118921A (en) * 1976-10-06 1978-10-10 E. I. Du Pont De Nemours And Company Yarn of entangled fibers
US4265082A (en) * 1978-10-20 1981-05-05 Teijin Limited Spun-like yarn and a process for manufacturing the same

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
US2784458A (en) * 1949-07-08 1957-03-12 Deering Milliken Res Corp Process and apparatus for converting continuous filamentary material into filaments of staple length
US3079746A (en) * 1961-10-23 1963-03-05 Du Pont Fasciated yarn, process and apparatus for producing the same
US4118921A (en) * 1976-10-06 1978-10-10 E. I. Du Pont De Nemours And Company Yarn of entangled fibers
US4265082A (en) * 1978-10-20 1981-05-05 Teijin Limited Spun-like yarn and a process for manufacturing the same

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Title
CHEMIEFASERN/TEXTILINDUSTRIE, vol. 30, no. 9, September 1980, page 678, Frankfurt am Main, DE. *

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994009195A1 (fr) * 1992-10-14 1994-04-28 Wool Research Organisation Of New Zealand Incorporated Fil multi-composants a fort volume
GB2286605A (en) * 1992-10-14 1995-08-23 Wool Res Organisation High bulk,multi-component yarn
GB2286605B (en) * 1992-10-14 1996-12-04 Wool Res Organisation High bulk,multi-component yarn
US7267871B2 (en) 1999-06-14 2007-09-11 E. I. Du Pont De Nemours And Company Stretch break method and product
WO2000077283A3 (fr) * 1999-06-14 2002-08-29 Du Pont Procede et produit de rupture par etirage
US7083853B2 (en) 1999-06-14 2006-08-01 E. I. Du Pont De Nemours And Company Stretch break method and product
US7100246B1 (en) 1999-06-14 2006-09-05 E. I. Du Pont De Nemours And Company Stretch break method and product
WO2000077283A2 (fr) * 1999-06-14 2000-12-21 E.I. Du Pont De Nemours And Company Procede et produit de rupture par etirage
CN100392163C (zh) * 1999-06-14 2008-06-04 纳幕尔杜邦公司 拉断法和产品
US7454816B2 (en) 1999-06-14 2008-11-25 E.I. Du Pont De Nemours And Company Stretch break method, apparatus and product
EP1522614A1 (fr) * 2003-10-06 2005-04-13 Schärer Schweiter Mettler AG Dispositif pour produire des filés de fibres synthétiques
EP1522613A1 (fr) * 2003-10-06 2005-04-13 Schärer Schweiter Mettler AG Dispositif pour produire des filés de fibres synthétiques
US7581376B2 (en) 2004-02-27 2009-09-01 E.I. Du Pont De Nemours And Company Spun yarn, and method and apparatus for the manufacture thereof

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DE3372385D1 (en) 1987-08-13

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