EP0120709A2 - Procédé permettant d'obtenir des motifs très contrastés sur des matières textiles et produits en résultant - Google Patents

Procédé permettant d'obtenir des motifs très contrastés sur des matières textiles et produits en résultant Download PDF

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Publication number
EP0120709A2
EP0120709A2 EP84302105A EP84302105A EP0120709A2 EP 0120709 A2 EP0120709 A2 EP 0120709A2 EP 84302105 A EP84302105 A EP 84302105A EP 84302105 A EP84302105 A EP 84302105A EP 0120709 A2 EP0120709 A2 EP 0120709A2
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EP
European Patent Office
Prior art keywords
yarns
areas
pattern
dye
solvent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP84302105A
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German (de)
English (en)
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EP0120709A3 (en
EP0120709B1 (fr
Inventor
Robert Charles Arnott
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Milliken Research Corp
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Milliken Research Corp
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Publication of EP0120709A2 publication Critical patent/EP0120709A2/fr
Publication of EP0120709A3 publication Critical patent/EP0120709A3/en
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Publication of EP0120709B1 publication Critical patent/EP0120709B1/fr
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C23/00—Making patterns or designs on fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B11/00—Treatment of selected parts of textile materials, e.g. partial dyeing
    • D06B11/0079—Local modifications of the ability of the textile material to receive the treating materials, (e.g. its dyeability)
    • D06B11/0089—Local modifications of the ability of the textile material to receive the treating materials, (e.g. its dyeability) the textile material being a surface

Definitions

  • This invention relates to a process for generating patterns exhibiting high visual contrast on textile substrates, and novel products which may be produced thereby. More specifically, one embodiment of this invention relates to a process wherein individual constituent fibers in an area on the surface of a textile substrate defining a pattern are thermally conditioned or treated to permit relatively rapid extraction of dye from those fibers by a solvent, while adjacent fibers which have not been so thermally conditioned or treated resist such rapid dye extraction, thereby resulting in fabrics wherein, following the controlled exposure to a suitable solvent, the heat-treated pattern areas contain visually less dye than adjacent, solvent exposed pattern-complementary areas.
  • Processes for generating patterns on the surface of textile substrates are well known in the art. Such processes may or may not require the pattern-wise application of dye to achieve a pattern, or even a dye-defined pattern, on the substrate surface.
  • processes which do not require the pattern-wise application of dye are included processes wherein heat, for example, from a heated embossing roll or in the form of impinging heated fluid streams, is directed onto the substrate surface in a pattern configuration prior to a dyeing step.
  • the thermally treated portions of the surface accept dye to a different (generally greater) degree than do the untreated portions, thereby usually resulting in pattern areas having higher, visually contrasting aye concentrations.
  • Other processes rely on a variety of physical effects to define or establish patterned areas on the substrate surface. For example, some processes rely on physical compression and perhaps heat setting of individual fibers to imprint the surface and thereby define a pattern. Other systems may rely on fiber entanglement to yield visually distinct areas on the substrate surface.
  • This technique can produce patterns which are quite detailed and which, under some circumstances, can achieve rather high levels of visual contrast between pattern and pattern-complementary (i.e., background) areas, even though not requiring the pattern-wise application of dye.
  • the substrate is, for example, a pile fabric and the pile yarns have been heated sufficiently to induce substantial thermally-induced longitudinal shrinkage among the individual pile yarns.
  • the resulting sculptured or surface contoured effect can result in dramatic contrast levels between pattern and pattern-complementary areas, provided the surface is appropriately illuminated.
  • the degree of contrast is often heavily dependent upon the type and direction of the incident illumination.
  • patterning may be achieved -using the pattern-wise application of heat or other conditioning agent, rather than the pattern-wise application of dye, to individual yarns on the substrate surface, and wherein the degree of visual contrast between pattern and pattern-complementary areas on the substrate surface may be controllably varied from relatively low to relatively high values, ano wherein the perceived contrast is not significantly dependent upon the nature of the illumination.
  • the process of this invention involves the treating or conditioning, by physical or other means, of individual yarns in the pattern areas of the substrate to permit the subsequent selective extraction of dye in treated yarns processed in a controlled solvent-based extraction step, which extraction step has substantially no visible effect on adjacent, untreated yarns forming the pattern-complementary areas of the substrate.
  • the dye may be applied to the yarns either prior to or following the treating or conditioning step.
  • the role played by the treating or conditioning agent in this invention may be thought of as being somewhat similar to that of a catalyst, in the sense that the chosen solvent extracts dye with much greater speed from the treated yarns than from the untreated yarns.
  • the chosen solvents useful in the practice of this invention will, given sufficient exposure, extract dye from untreated areas as well as treated areas, and perhaps to the same extent, but will not do so at the same rate.
  • Figure 1 depicts a pile fabric, comprised of thermoplastic and non-thermoplastic yarns, in which heat conditioning has caused thermal deformation, in the form of longitudinal shrinkage, to individual thermoplastic pile yarns; dye has then been selectively extracted from those thermally deformed fibers.
  • Figure 2 depicts a pile fabric in which heat conditioning has caused thermal deformation, in the form of longitudinal shrinkage, to tufts or groups of thermoplastic pile yarns; dye has then been selectively extracted from those thermally deformed yarn groups.
  • Figure 3 depicts a flat knitted fabric comprised of thermoplastic yarns wherein heat conditioning has caused thermal deformation, in the form of melting and/or fusing of individual yarns; dye is selectively extracted from the deformed region of the fabric.
  • Figure 4 depicts a textile substrate in which dye has been selectively extracted from the heat-treated diamond-shaped areas, in accordance with the teachings of this invention.
  • a textile fabric comprised of polyester (e.g., polyethylene teraphthalate) yarns which have been conventionally dyed with a disperse dye is impinged with heated streams of fluid, for example, air, in a pattern-wise configuration by an apparatus similar to that disclosed in commonly assigned U. S. Patent Application Serial Number 253,135, referenced above.
  • This apparatus is discussed herein as merely one example of an apparatus which may be used to practice this invention; commonly assigned U. S. Patent No. 4,364,156, also incorporated by reference herein, further defines a manifold which may prove advantageous when used in conjunction with the apparatus of U. S. Patent Application Serial No. 253,135.
  • any means by which appropriate amounts of heat may be suitably applied in a pattern-wise configuration to the yarns comprising the surface of the textile substrate to be patterned may be employed.
  • a laser beam of suitable power and intensity, directed onto or over the substrate surface in a pattern configuration, may be used instead of heated air streams.
  • thermal energy tends to induce a decrease in the internal orientation of at least portions of individual, untensioned yarns in those pattern areas where the maximum rate of solvent extraction of dye is desired.
  • the decrease in orientation is thought to promote the entry of the solvent into the yarn interior, perhaps by generating voids between adjacent constituent molecules, and thereby accellerate the dye extraction process.
  • thermal conditioning may tend to cause radial migration of dye molecules from the yarn interior toward the yarn surface which, contributes to the observed accellerated rate of dye extraction by the solvent in thermally treated yarns.
  • thermoplastic yarns are accompanied by thermal deformation or distortion of the yarns, e.g., softening, longitudinal shrinking, melting, or fusing of individual yarns.
  • thermal deformation or distortion of the yarns e.g., softening, longitudinal shrinking, melting, or fusing of individual yarns.
  • conditioned polymeric yarns have increased voids between adjacent polymer molecules within the fibers comprising the yarns, as compared to unconditioned yarns of the same type, thereby enhancing the migration rate of solvent molecules into and out of the yarns.
  • a package of yarn 20/2 T-811W Bright DACRON (DACRON is a trademark of DuPont), manufactured by Milliken & Company from DuPont polyethylene terephthalate fiber, was dyed in a laboratory package dye machine using Eastman Polyester Blue GLF (Color Index Name Disperse Blue 27). Lengths of this yarn were heat treated by immersion for 5 seconds in a fluidized bed, Model SBS-2 distributed by Fisher Scientific Company of Pittsburg, Pennsylvania, over a range from 300°F. to 500°F., in increments of 25°F. Measurements of length before and after heat treatment allowed calculation of the percent shrinkage at each temperature.
  • Standard lengths were then solvent extracted by immersing them in 5 ml of methylene chloride at room temperature for one minute and then removing the yarn from the solvent.
  • the UV-Visible spectra of these extracts were then recorded to yield the absorbence attributed to the blue dye at a wavelength of between 592 and 595 millimicrons, thereby giving an indication of the amount of dye extract by the solvent.
  • the rate of dye extraction generally increases after brief thermal conditioning at temperatures above about 300 0 F., and increases dramatically after brief thermal conditioning at temperatures extending from about 425°F. to somewhere between about 475°F. and 500°F., i.e., a temperature just below the melting point of the unconstrained yarn.
  • somewhat higher temperatures i.e., 500°F. or above, may be employed to generate increased shrinkage and increased dye extraction rates.
  • the fabric is then exposed for a controlled period of time to a solvent which, during that time period, selectively extracts dye from the heat treated areas only, and which has relatively little or substantially no effect upon those portions of the fabric surface which have not been heat treated in accordance with the teachings of this invention.
  • a solvent which, during that time period, selectively extracts dye from the heat treated areas only, and which has relatively little or substantially no effect upon those portions of the fabric surface which have not been heat treated in accordance with the teachings of this invention.
  • the heat treated fabric be immediately exposed to the solvent, or be stored under any particular set of conditions following the pattern-wise heat treatment of the fabric.
  • Solvents which have been used with fabrics containing polyester yarns which were dyed using disperse dyes include hot perchloroethylene and 1,1,1-trichtoroethane.
  • Other solvents which may be found to be satisfactory may be found in Table II of the technical article "Interactions of Nonaqueous Solvents with Textile Fibers - Part I: Effects of Solvents on the Mechanical Properties of a Polyester Yarn" by A. S. Ribnick, H.-D. Weigmann, and L.
  • a preferred solvent for polyester yarn/disperse dye combinations is methylene chloride, which may be used at room temperature and which is capable of extracting substantial quantities of disperse dye from pattern-wise heat treated polyester relatively quickly.
  • polyester-containing fabric which has been heat treated in a pattern-wise configuration may be immersed in a bath of methylene chloride at room temperature and agitated for a short period of time to assure proper circulation of the solvent in the vicinity of the yarns comprising the patterned areas of the fabric.
  • the methylene chloride solvent can, in a matter of 30 to 60 seconds or less, extract substantially all the visible dye from those pattern areas of the fabric which have been heavily heat treated.
  • the solvent will extract visably less dye from pattern areas, or portirons of individual yarns, which have been less heavily treated, i.e., exposed to lower temperatures, and will extract substantially no dye from those areas or yarns, or portions of yarns, which have not been heat treated.
  • Using warm or hot methylene chloride solvent produces the same selective extraction effects, but within a substantially shortened time period virtually complete dye extraction may be achieved in heavily patterned areas in a matter of a few seconds. It must be remembered that if solvent exposure time is not monitored carefully, complete dye extraction will occur in lightly treated or non-treated areas as well.
  • Means other than immersion may be used to bring the fabric into contact with the solvent if desired, e.g., the solvent may be sprayed on the fabric. It is also contemplated that, following application of the solvent, physical agitation of the yarns, to wash dye saturated solvent from the surface may be used to facilitate the extraction process. Means for halting solvent action may vary. Most simpley, of course, the solvent may be washed or otherwise removed from the substrate surface after the desired "residence time" or exposure time has passed.
  • the chosen solvent be one which is not readily flammable, and of course should be one which is neither grossly toxic to humans nor destructive to the yarns used. It is believed that suitable solvents should be selected from those solvents having a hildebrand solubility parameter ( ) which is appropriate to the yarn of interest. It has been found, for example, that for yarns consisting essentially of polyethylene teraphthalate ( 10.7), workable solvents should have hildebrand solubility parameter values within the range of about 8 to about 14. Solvents having values closest to 10.7 do not necessarily result in maximum dye extraction rates and are not necessarily preferred over other solvents having more extreme values.
  • Solvents having values substantially higher or lower than 10.7 may interact quite well with different portions of the polyethylene teraphthalate molecule and produce high dye extraction rates. It has been found that suitable solvents having solubility parameter values between about 9 and about 10, and also between about.11.5 to about 13, often work quite well; suitable solvents from the former group tend to interact well with the aromatic portion of the polyethylene teraphthalate molecule, while solvents from the latter group tend to interact well with the aliphatic portion of that molecule.
  • the fabric was then treated with streams of hot air from the heated air device described hereinabove to generate a sculptured pile fabric having a pin dot array of depressed, thermally shrunken yarns.
  • the fabric speed in the device was 6.5 ypm; the manifold air temperature was about 670°F.
  • the coloration in the sculptured prior to exposure to the solvent areas was slightly darker than in the background area, where the pile remained substantially erect.
  • the patterned fabric was immersed in a bath of methylene chloride at 23°C.
  • a 44 gauge double needle bar raschel knit polyester pile fabric, identified by Milliken & Company as Style 6590 having a weight of approximately 9 oz./yd. 2 was dyed with a disperse dye to give a uniform deep blue color.
  • This fabric was treated with streams of hot air using the device disclosed above to yield a dot array of thermally shrunken pile.
  • the fabric speed in the device was 25 ypm; the manifold air temperature was about 820°F.
  • a raschel knit pile fabric of 100% polyester, identified by Milliken & Company as Style 180 having a weight of approximately 5 oz./yd. 2 was dyed to a uniform green color with disperse dye.
  • the fabric was treated with streams of hot air in pattern configuration using the above-referenced device.
  • the fabric speed in the device was 7 ypm; the manifold air temperature was about 700°F.
  • a sculptured image was obtained which was difficult to read at all angles of light.
  • the fabric was then dipped in methylene chloride at 23°C. for 30 seconds, removed and dried with a stream of cool air to yield a highly contrasting design of white against a green background that was much more readable than the untreated patterned fabric.
  • a 100% polyester knit fabric (interlock) manufactured by Milliken & Company and identified as Style 2651 having a weight of 3.0 oz.yd. 2 was eyed to a deep blue shade using disperse dye and imaged by computer controlled streams of heated air using the above-referenced device.
  • the fabric speed in the device was 3.75 ypm; the manifold air temperature was about 820°F.
  • Prior to exposure to the solvent the image was darker in the heated area.
  • methylene chloride at 23°C. for 30 seconds and air dried, the imaged area became lighter.
  • a woven fabric containing an intimate blend of polyester and cotton in the ratio 65/35 manufactured by Milliken & Company and identified as Style 2602, weighing approximately 4.75 oz./yd. was union dyed to a navy blue shade.
  • the fabric was imaged with hot air streams to yield a diamond pattern with flowers in the center, using the above-referenced device.
  • the fabric speed in the device was 6 ypm; the manifold air temperature was about 700°F.
  • On the dark navy fabric there was only slight contrast between the imaged and the unimaged areas.
  • a napped woven fabric containing a disperse-dyeable polyester yarn in the filling direction and a cationic-dyeable polyester yarn in the warp direction was woven in such a way that, after cross-dyeing, napping created a sculptured effect consisting of square-shaped non-pile areas, approximately 0.1 inches per side, which appeared black (cationic dye) in a field of grey (dispersed dyed nap).
  • the fabric was manufactured by Milliken & Company and identified as Style 8317 having a weight of approximately 10 oz./yd. 2 .
  • the fabric was imaged with a stream of hot air using the above-referenced device.
  • the fabric speed in the device was 6.75 ypm; the manifold air temperature was about 670°F.
  • the fabric was immersed in methylene chloride at 23°C. for 1 minute, then dried.
  • the resulting pattern showed a highly contrasting white pattern area, and a black pin dot on a grey background.
  • the resulting effect was multicolor and showed good contrast with the cationic dye removed to a much lesser extent, if at all, by the solvent extraction process.
  • a woven polyester fabric having both cationic-dyeable polyester yarn and disperse-dyeable polyester yarn, identified as Style 8327 having a weight of 9.5 oz./yd. 2 was cross-dyed and then patterned with a stream of heated air at 760°F. in the above-referenced device. Fabric speed was 6.75 ypm. The patterned fabric was then dipped in methylene chloride for 1 minute at 23°C. After 1 minute the sample was removed and dried. It showed strong contrast where the hot air had impinged, giving very light diagonal blue line pattern against a field of medium-to-dark blue yarns.
  • Example 1 The fabric of Example 1 was similarly treated with hot air. The treated fabric was then immersed for 5 seconds in a bath of methylene chloride heated to 35°C. The results after removal from the solvent and drying were substantially identical to those achieved in Example 1.
  • Example 1 The procedures of Example 1 were followed, except that acetone heated to 53°C. was substituted for methylene chloride. The results were similar to those achieved in Example 1.
  • Example 1 The procedures of Example 1 were followed, except that 1,1,1-trichtoroethane at 70°C. was substituted for the methylene chloride. The results were similar to those achieved in Example 1.
  • Example 1 The procedures of Example 1 were followed, except that perchloroethylene at 95°C. was substituted for the methylene chloride, and the exposure time was extended to 5 minutes. The results were similar to those achieved in Example 1.
  • Example 1 The procedures of Example 1 were followed, except that ethanol at 73°C. was substituted for the methylene chloride, and the exposure time was extended to 5 minutes. A very slight change in the visual dye concentration was observed in the treated areas.
  • Example 1 The procedures of Example 1 were followed, except that the heat treatment with hot air streams was done prior to conventional dyeing.
  • the resulting fabric contained dark brown dots on a medium brown field. Exposure of the patterned fabric to methylene chloride for one minute at 23°C. results in a noticeable visual lightening of the dot areas. Further exposure, for a total exposure time of 5 minutes, resulted in a fabric exhibiting light beige dots on a medium brown field.
EP84302105A 1983-03-28 1984-03-28 Procédé permettant d'obtenir des motifs très contrastés sur des matières textiles et produits en résultant Expired EP0120709B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US47941083A 1983-03-28 1983-03-28
US479410 1983-03-28

Publications (3)

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EP0120709A2 true EP0120709A2 (fr) 1984-10-03
EP0120709A3 EP0120709A3 (en) 1985-05-29
EP0120709B1 EP0120709B1 (fr) 1988-09-07

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EP84302105A Expired EP0120709B1 (fr) 1983-03-28 1984-03-28 Procédé permettant d'obtenir des motifs très contrastés sur des matières textiles et produits en résultant

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EP (1) EP0120709B1 (fr)
JP (1) JPH0823114B2 (fr)
AU (1) AU578604B2 (fr)
BE (1) BE899263A (fr)
CA (1) CA1225840A (fr)
CH (1) CH669493GA3 (fr)
DE (1) DE3411486C2 (fr)
DK (1) DK166885B1 (fr)
FR (1) FR2543588B1 (fr)
GB (1) GB2138031B (fr)
IE (1) IE55089B1 (fr)
LU (1) LU85274A1 (fr)
MX (1) MX158723A (fr)
NL (1) NL190420C (fr)
NZ (1) NZ207630A (fr)
SE (1) SE466502B (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1176240A2 (fr) * 2000-07-20 2002-01-30 Malden Mills Industries, Inc. Etoffes à faces de couleurs contrastants et/ou de contours différents
US7183231B2 (en) 2001-11-07 2007-02-27 The Procter & Gamble Company Textured materials and method of manufacturing textured materials
CN112626668A (zh) * 2021-01-04 2021-04-09 方连明 一种富硒布料及其制备方法和应用

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1343752A (fr) * 1962-10-12 1963-11-22 Traitements Chimiques Des Text Procédé de teinture de matières textiles
US3648488A (en) * 1970-10-08 1972-03-14 Gaf Corp Apparatus for producing heat induced effects on flexible substrates
US3751284A (en) * 1971-07-02 1973-08-07 United Merchants & Mfg Tone-on-tone resin bonded pigmenting of flock printed fabric with low temperature air drying
FR2238799A1 (fr) * 1973-07-24 1975-02-21 Bayer Ag
FR2254667A1 (en) * 1973-12-17 1975-07-11 Hoechst Ag Fabric colour shading process - uses combination of reactive dyestuff and thermal surface treatment
FR2283987A1 (fr) * 1974-09-05 1976-04-02 Hoechst Ag Production d'effets de rongeage irreguliers
FR2289667A1 (fr) * 1974-10-31 1976-05-28 Girmes Werke Ag Procede de production d'effets colores de dessins sur des etoffes a poils et etoffe ainsi realisee
FR2323799A1 (fr) * 1973-12-21 1977-04-08 Stotz & Co Ag Surface textile a zones de moindre rigidite
US4147507A (en) * 1974-10-31 1979-04-03 Girmes-Werke Ag Production of colored patterns on nap fabrics
FR2456807A1 (fr) * 1979-05-14 1980-12-12 Estampados Estil Sa Procede d'impression par rongeage de matieres textiles teintes au bleu indigo
EP0059029A1 (fr) * 1981-01-23 1982-09-01 Milliken Research Corporation Appareil pour créer des effets visuels de surface sur des matériaux en déplacement
FR2507218A1 (fr) * 1981-06-05 1982-12-10 Temauri Masson Rosine Procede d'impression de tissu par irradiation localisee de colorants d'impression

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU498410B2 (en) * 1974-04-26 1979-03-15 Wira Fabrics
US4499637A (en) * 1979-12-14 1985-02-19 Milliken Research Corporation Method for the production of materials having visual surface effects
JPS5925907U (ja) * 1982-08-06 1984-02-17 積水樹脂株式会社 電線防護カバ−
AU572311B2 (en) * 1984-07-03 1988-05-05 Taylor, D.P. Patterning fabrics

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1343752A (fr) * 1962-10-12 1963-11-22 Traitements Chimiques Des Text Procédé de teinture de matières textiles
US3648488A (en) * 1970-10-08 1972-03-14 Gaf Corp Apparatus for producing heat induced effects on flexible substrates
US3751284A (en) * 1971-07-02 1973-08-07 United Merchants & Mfg Tone-on-tone resin bonded pigmenting of flock printed fabric with low temperature air drying
FR2238799A1 (fr) * 1973-07-24 1975-02-21 Bayer Ag
FR2254667A1 (en) * 1973-12-17 1975-07-11 Hoechst Ag Fabric colour shading process - uses combination of reactive dyestuff and thermal surface treatment
FR2323799A1 (fr) * 1973-12-21 1977-04-08 Stotz & Co Ag Surface textile a zones de moindre rigidite
FR2283987A1 (fr) * 1974-09-05 1976-04-02 Hoechst Ag Production d'effets de rongeage irreguliers
FR2289667A1 (fr) * 1974-10-31 1976-05-28 Girmes Werke Ag Procede de production d'effets colores de dessins sur des etoffes a poils et etoffe ainsi realisee
US4147507A (en) * 1974-10-31 1979-04-03 Girmes-Werke Ag Production of colored patterns on nap fabrics
FR2456807A1 (fr) * 1979-05-14 1980-12-12 Estampados Estil Sa Procede d'impression par rongeage de matieres textiles teintes au bleu indigo
EP0059029A1 (fr) * 1981-01-23 1982-09-01 Milliken Research Corporation Appareil pour créer des effets visuels de surface sur des matériaux en déplacement
FR2507218A1 (fr) * 1981-06-05 1982-12-10 Temauri Masson Rosine Procede d'impression de tissu par irradiation localisee de colorants d'impression

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1176240A2 (fr) * 2000-07-20 2002-01-30 Malden Mills Industries, Inc. Etoffes à faces de couleurs contrastants et/ou de contours différents
EP1176240A3 (fr) * 2000-07-20 2002-06-05 Malden Mills Industries, Inc. Etoffes à faces de couleurs contrastants et/ou de contours différents
US6685749B1 (en) 2000-07-20 2004-02-03 Malden Mills Industries, Inc. Fabrics with surfaces of contrasting colors and/or different contour
US7183231B2 (en) 2001-11-07 2007-02-27 The Procter & Gamble Company Textured materials and method of manufacturing textured materials
CN112626668A (zh) * 2021-01-04 2021-04-09 方连明 一种富硒布料及其制备方法和应用

Also Published As

Publication number Publication date
DK169184D0 (da) 1984-03-27
LU85274A1 (fr) 1984-11-14
FR2543588B1 (fr) 1986-07-25
JPH0823114B2 (ja) 1996-03-06
NL190420C (nl) 1994-02-16
CA1225840A (fr) 1987-08-25
BE899263A (fr) 1984-07-16
IE840768L (en) 1984-09-28
MX158723A (es) 1989-03-03
NL190420B (nl) 1993-09-16
SE466502B (sv) 1992-02-24
NZ207630A (en) 1988-02-29
NL8400934A (nl) 1984-10-16
SE8401658L (sv) 1984-09-29
EP0120709A3 (en) 1985-05-29
AU2608584A (en) 1984-10-04
GB2138031B (en) 1986-04-09
FR2543588A1 (fr) 1984-10-05
DE3411486C2 (de) 1996-04-18
AU578604B2 (en) 1988-11-03
CH669493GA3 (fr) 1989-03-31
SE8401658D0 (sv) 1984-03-26
DE3411486A1 (de) 1984-10-04
IE55089B1 (en) 1990-05-23
DK169184A (da) 1984-09-29
DK166885B1 (da) 1993-07-26
JPS602741A (ja) 1985-01-09
EP0120709B1 (fr) 1988-09-07
GB2138031A (en) 1984-10-17
GB8407920D0 (en) 1984-05-02

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