EP0088980B1 - Vorrichtung und Giessform zum Stranggiessen von dünnwandigen giesseisernen Röhren - Google Patents

Vorrichtung und Giessform zum Stranggiessen von dünnwandigen giesseisernen Röhren Download PDF

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Publication number
EP0088980B1
EP0088980B1 EP83102221A EP83102221A EP0088980B1 EP 0088980 B1 EP0088980 B1 EP 0088980B1 EP 83102221 A EP83102221 A EP 83102221A EP 83102221 A EP83102221 A EP 83102221A EP 0088980 B1 EP0088980 B1 EP 0088980B1
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EP
European Patent Office
Prior art keywords
die
lip
continuous casting
ring
installation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP83102221A
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English (en)
French (fr)
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EP0088980A1 (de
Inventor
Rio Bellocci
Yves Gourmel
Michel Pierrel
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Pont a Mousson SA
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Pont a Mousson SA
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Publication date
Application filed by Pont a Mousson SA filed Critical Pont a Mousson SA
Priority to AT83102221T priority Critical patent/ATE19363T1/de
Publication of EP0088980A1 publication Critical patent/EP0088980A1/de
Application granted granted Critical
Publication of EP0088980B1 publication Critical patent/EP0088980B1/de
Expired legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/006—Continuous casting of metals, i.e. casting in indefinite lengths of tubes

Definitions

  • the present invention relates to a vertical downward continuous casting installation with tubular die for obtaining a thin cast iron tube, that is to say a tube whose thickness / diameter ratio is low, less than 10%, the thickness itself not exceeding 5 mm.
  • a continuous casting installation of such a tube comprises, according to a previous patent filed in France on January 27, 1978 under No. 7 802 277 and published under No. 2,415,501, below a casting basin provided with '' a lower orifice, a substantially cylindrical die which is surrounded by a cooling jacket and delimits, with a core which crosses the basin, a tubular space for pouring the tube, an extractor device pulling the solidified tube step by step as measure of its formation.
  • the problem is therefore to remove these incrustation rings by modifying the die head of the continuous casting installation while maintaining perfect homogeneity and continuity of the die inner wall between this head and the body.
  • the present invention relates to a continuous casting installation with a die according to claim 1, which solves this problem.
  • Patent FR-A-2 415 501 describes a continuous casting installation with a tubular die which has all the characteristics of the first part of claim 1.
  • the die comprises a composite head with a narrow annular lip surrounded by an insulating ring which fills the space between the lip and the internal wall of the casting opening of the installation.
  • This arrangement significantly reduces the cooling flow, transfers it above said composite die head, and prevents any start of solidification on the internal wall of said composite head.
  • the invention is applied to an installation for continuous vertical downward casting of a thin-walled tube, made of cast iron, T, the thickness / diameter ratio of which is low, that is to say less than 10%, the thickness itself not exceeding 5 mm and possibly being of the order of 3 mm.
  • FIG. 1 part of the casting basin 1 supplying the die of the invention, in liquid iron F.
  • the casting basin 1 is contained in a metal case or casing 2 internally coated with a thick refractory lining 3, for example of silico-aluminous type, and it has at its lower part, which is, moreover, the only one shown in FIG. 1, a vertical pouring orifice 4, of cylindrical shape and axis XX, inside which is mounted the upper end or head of the die 6, as well as a core 8 which defines with this die a tubular space casting 10.
  • the core 8 which is made of graphite and is coaxial with the pouring orifice, passes right through the pouring basin 1 and is suspended at its upper part, bearing on the body 2, by known means, not shown, for example those described in patent FR No. 2,415,501.
  • this core 8 is hollow and internally comprises a heating device, for example an inductor 12 in the form of coil, copper, helically wound and internally cooled by water, or a heating resistor.
  • the die 6 is also made of graphite. It is tubular and coaxial with the core 8, that is to say with an axis XX, and it surrounds the core 8 by delimiting with it the narrow tubular space 10 whose width corresponds to the thickness of the wall of the tube T to flow.
  • the die 6, the height of which is for example 25 cm for the casting of a cast iron tube T, with an external diameter of 170 mm and a thickness of 5 mm, is supported at its lower end by a flange 9 suspended from the body 2 of the casting basin by tie rods 14.
  • the flange 9 also supports a cooling jacket 15, coaxial with the die 6 and the core 8, which is in close contact with the outer wall of this die between the body 2 of the tapping basin, that is to say the outlet from the pouring orifice 4, and the flange 9.
  • This cooling jacket 15 is shown diagrammatically in the form of a water circulation sleeve with pipes 16 and 13 for entering and leaving the water , but it is obvious that it can comprise, in accordance with patent FR 2 415 501, between the water circulation sleeve and the die 6, a coolant metal jacket with low melting point in order to ensure contact better thermal and, therefore, a perfect evacuation of calories.
  • the installation further comprises a device for extracting, or extracting, the cast T-tube, consisting for example of two pairs of rollers 18 and 20 with horizontal axes, applied to the outer wall of the cast T-tube, symmetrically with respect to axis XX. Two of these rollers, located on the same side of the axis XX, are connected by a transmission chain 19 and driven in rotation, step by step, that is to say with stopping times, by a gear unit 21.
  • the exit of the solidified tube T from the tubular space 10 is carried out step by step.
  • the casting installation is provided with a die 6 which comprises at its upper part a composite head 17 extending a hollow cylindrical body 7 which may be of constant wall thickness, said head 17 being adjusted in the orifice 4.
  • the composite head 17 has a thin or narrow annular lip 22, connected by a wide rounded 23, with the thick body 7, but in one piece with it, in graphite.
  • This connection takes place exactly at the mouth of the pouring orifice 4, that is to say in the plane of the contact P (drawn in phantom) between the outer face of the metal case 2 and the upper end of the cooling jacket 15. Consequently, over its entire height, the thin annular lip 22 has, inside the pouring orifice 4, a thickness substantially less than that of the body 7 of the die 6, at the outside this orifice. At its upper part, the lip 22 has a thickness which is a fraction of that of the cooled part 7 of the die 6.
  • the lip 22 is frustoconical but, as its conicity is very small, it is almost over its entire height that its thickness is a fraction of that of the cooled body 7.
  • the lip 22 has a thickness at most equal to 1/3 of the thickness of the body 7, just before the rounded from its connection with this body, and an axial dimension at least equal to the thickness of the body 7 of the die and currently equal to 1.5 times this thickness.
  • the lip 22 is surrounded by a refractory ring 24, for example made of silico-aluminex material, having good thermal insulation characteristics.
  • the ring 24 is adjusted on the lip 22 of which it matches the external profile and constitutes, with this lip, the composite head 17 of the die 6.
  • the shape and the width of the ring 24 allow this head to be adjusted on the internal wall of the orifice 4 and thus of authorizing the flow of the liquid iron only between the lip 22 and the core 8.
  • the thin annular lip has its upper end in direct contact with the liquid iron F contained in the casting basin 1 and is connected with the thick body 7 of the die 6, just at the upper limit of the energetic cooling of this die 6 through the cooling jacket 15.
  • the horizontal and flat upper edge 25 of the ring 24, which is flush with the upper end of the lip 22, is also in contact with the liquid iron F of the basin 1.
  • its lower edge is in contact with the cylindrical body 7 and with the rounding 23 connecting the lip to this body in the plane P.
  • Cooling can only come from the cooling jacket 15.
  • a cooling flow passes through the conductive graphite of the lip 22 and of the body 7, but cannot pass through the refractory material of the ring 24.
  • the flow of cooling created between the liquid iron and the cooling jacket follow the paths indicated by the arrow lines f 1 in dotted lines and f 2 in broken lines in FIG. 2.
  • a good heat conductor has, on the one hand a small cross-section which offers a small section for the passage of calories, and on the other hand a significant length or height which slows down the heat flow f 1 accordingly , while the ring 24, which is made of refractory silico-aluminous material (conductivity coefficient: 0.5 to 3 kCal / h / m 2 / ° C), opposes the passage of calories and must therefore be bypassed.
  • the liquid iron contained in the annular space 10, inside the lip 22 and the orifice casting 4, above the plane P is relatively little cooled. We can even consider that it undergoes practically no cooling.
  • the lip 22 is not only in one piece with the body 7, but also its internal surface is exactly in the extension of the internal cylindrical wall 26 of this body 7 (and therefore carries the same reference numeral 26 ), so that the die has a continuous wall over its entire height and in particular between the hot zone located in the pouring orifice 4, above the plane P, and the zone cooled by the casing 11, below the plane P.
  • This graphite wall continuity 26 offered to liquid cast iron is particularly advantageous since it exists at the start of the casting and is maintained during this, while the graphite die 6 heats up in contact with the cast iron liquid and therefore expands uniformly.
  • a die 36 of the prior art comprises a head 37 of frustoconical shape which , to the right of the body 2, has the same width as the body of the die and thins in the direction of the casting basin.
  • the thickness of solidified cast iron FS can reach half the width of the annular space 10 and even the whole of this space, until it is blocked. Below the plane P, the cooling of the liquid iron is much more vigorous since the path of the flow of calories f 2 to the cooling jacket 15 is much more direct, much shorter.
  • the plane P of separation between these two cooling zones therefore marks a clear difference in thickness of solidified cast iron, which at 28 presents a breakthrough at each extraction pass.
  • the composite head 17 of the die 6 of FIGS. 1 and 2 remains hot and avoids the cooling of the cast iron in this zone of the die, so that no solidification begins above the plane P. It is only below the plane P that solidification begins. The aforementioned serious defect is therefore avoided.
  • the head 17 of the die is robust, offers no mechanical fragility because the ring 24 protects and externally strengthens the thinned lip 22, and thus ensures the continuity of the thickness of the die, including in the zone contained inside the pouring orifice 4.
  • FIGS. 1 and 2 are particularly advantageous, it is possible to produce in other ways a composite hot head of die comprising, on the one hand a graphite part of small section, providing a continuity of cylindrical wall to the flow of the cast iron in the annular space 10 and offering a small section for the passage of calories in the direction of the cooling jacket 15, and on the other hand an insulating refractory part, for example silico-aluminous.
  • the limit between the composite head and the body 7 of the die must remain the horizontal plane P, the body 7 having the same height as the envelope 15.
  • the die head comprises, above the plane P, two thin concentric annular lips, respectively outer 32 and inner 22.
  • the lips 22 and 32 are made of graphite since they are the continuity of the thick tubular body 7 of the die.
  • the outer surface of the outer lip 32 is cylindrical to be applied exactly against the wall of the pouring orifice, while the facing surfaces of the two lips are slightly frustoconical and are separated by an insulating refractory ring 34, made of silico material -aluminous, in close contact with each of them, which of course is flush with their upper ends, in the same horizontal plane.
  • the refractory lining extends above the head and is connected with the internal wall of the internal lip 22.
  • the refractory ring 34 constitutes an obstacle preventing the passage of calories while ensuring mechanical reinforcement of the hot die head.
  • the composite die head comprises, above the plane P, a lip 42, the hollowed out external face 43 of which is concave in an obviously semitoric profile, which forms an upper rim or widening 44 joining the internal wall of the orifice. casting and a housing for a refractory ring, silico-aluminous, 45 with semi-toroidal conjugate profile and cylindrical external profile adjusted to the cylindrical internal profile of the pouring orifice 4.
  • the flange 44 occupies the same annular width as the body 7 located below the plane P. But this upper rim 44 of large width, in contact with the liquid iron contained in the casting basin 1, is substantially thinned.
  • the semi-toric refractory ring 45 located just below, so that the flow f i of heat entrainment towards the cooling jacket 15 cannot spread over the entire annular width of this upper rim nor go directly towards the cooling jacket 15.
  • the flow i 1 must bypass the refractory ring 45 and cross a narrow annular section ab, between the refractory ring 45 and the tubular space 10 Therefore, the entrainment of calories by the flow f i is weak.
  • the hollowed out outer surface of the lip and the refractory ring may have a rectangular recess profile.
  • Fig. 5 shows an embodiment of this type.
  • a graphite composite head has a thin internal lip 46, the hollowed out outer surface of which delimits two housings of rectangular section, which are filled by two refractory rings 48 and 49, concentric and of the same cylindrical shape (rectangular profile nearly).
  • the two rings 48 and 49 are separated by a horizontal partition 50 made of graphite, formed by a circumferential fin of the lip 46 in contact with the refractory lining 3 and, consequently, not capable of providing a passage for calories.
  • a horizontal partition 50 made of graphite, formed by a circumferential fin of the lip 46 in contact with the refractory lining 3 and, consequently, not capable of providing a passage for calories.
  • the lip 46 has an upper rim or planar partition 52, which gives the graphite head a meridian profile at F.
  • the upper section of this meridian profile at F can be either covered with refractory lining 3, if the latter is connected by a rounding (in solid lines) with the internal wall of the graphite lip 46, or in contact with liquid cast iron if the rounded connection is made along the line in broken lines, in the extension of the peripheral edges of the partitions 50, 52.
  • the lip 46 can be devoid of an upper rim 52; the upper insulating ring 49 is then, at its upper part, in contact with the lining 3, which gives the graphite lip a T-meridian profile.
  • the passage section offered to the flow 1 1 for discharging calories to the cooling jacket 15 remains limited to the thinned vertical tubular lip 46 of the head.
  • the composite head may also include other arrangements of graphite lip and of ring opposing the passage of calories, depending on the installations.
  • the insulating ring 45 (fig. 4), 48, 49 (fig. 5)
  • the rings 45, 48, 49 can be made of alumina fibers while the ring 24 can be made of silico-alumina concrete, the latter being much less insulating than the alumina fibers.
  • the height of a lip 32, 42, 46 above the plane P, and its average radial width are similar to those of the lip 22 in FIGS. 1 and 2.
  • the invention has been described for a vertical downward continuous casting installation comprising a tubular die, it also applies to an upward continuous casting installation with tubular die, the die head becoming the "foot" of the die and being immersed in the cast iron bath located at the bottom of the installation; it also applies to a horizontal continuous casting installation (the X-X axis being horizontal) or to an inclined continuous casting installation (the X-X axis being oblique).

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Continuous Casting (AREA)
  • Molds, Cores, And Manufacturing Methods Thereof (AREA)
  • Metal Extraction Processes (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
  • Building Environments (AREA)
  • Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
  • Perforating, Stamping-Out Or Severing By Means Other Than Cutting (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Record Information Processing For Printing (AREA)
  • Mechanical Pencils And Projecting And Retracting Systems Therefor, And Multi-System Writing Instruments (AREA)
  • Holo Graphy (AREA)
  • Shaping Of Tube Ends By Bending Or Straightening (AREA)
  • Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
  • Manufacture Of Alloys Or Alloy Compounds (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Claims (9)

1. Einrichtung zum Stranggiessen mit einer Rohrförmigen Giessform und einem mit einer unteren Öffnung (4) versehenen Eingussbecken (1), einem unter dem Becken in der Verlängerung der Innenwandung der Giessöffnung (4) angeordneten Kühlmantel (15) für die Giessform und einem geheizten Kern (8), der mit der Giessform (6) einen geraden rohrförmigen Giessraum (10) begrenzt, wobei der Kern koaxial zur Giessöffnung (4) angeordnet ist und die Giessform einen dicken zylinderförmigen Körper (7), der von dem Kühlmantel (15) umgeben ist und einen in die Giessöffnung (4) ragenden Kopf (17) aufweist, mit einer geraden ringförmigen Lippe (22, 32, 42, 46), deren Innenfläche (26) die Innenfläche des Körpers (7) der Giessform stetig verlängert, wobei die Giessform mit der Lippe auf der Höhe der Berührungsebene (P) zwischen dem Becken und dem Kühlmantel verbunden ist, dadurch gekennzeichnet, dass der Kopf (17) der Giessform (6) zusammengesetzt ist und aufweist: mindestens einen Ring (24, 34, 45, 48, 49) aus einem isolierenden Material, der einen Wärmefluss verhindert, die Lippe (22, 32, 42, 46) umgibt und mit dem Körper (7) in Kontakt steht, dadurch, dass die Lippe (22, 32, 42, 46) über eine Abrundung mit dem Körper verbunden ist, und dadurch, dass der isolierende Ring (24, 34) den Raum zwischen der Lippe (22, 42, 46) und der Innenwand der Giessöffnung (4) ausfüllt.
2. Stranggiesseinrichtung mit Giessform nach Anspruch 1, gekennzeichnet, durch eine zweite äussere Lippe (32), die koaxial zur inneren Lippe (22) angeordnet ist und von dieser durch einen Ringraum getrennt ist und aussen zylinderförmig geformt ist, um gegen die Wandung der Giessöffnung anzuliegen, wobei der hitzebeständige Ring (34) den Raum zwischen den beiden Lippen füllt.
3. Stranggiesseinrichtung mit Giessform nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass die Lippe (42, 46) einen oberen Rand (44, 52) und aussen eine Ausnehmung aufweist, bestehend aus mindestens einer ringförmigen Höhlung als Sitz für einen isolierenden Ring (45, 48, 49).
4. Stranggiesseinrichtung mit Giessform nach Anspruch 3, dadurch gekennzeichnet, dass die ausgenommene Aussenfläche (43) der Lippe (42) konkav und semitorisch ausgebildet ist.
5. Stranggiesseinrichtung mit Giessform nach Anspruch 3, dadurch gekennzeichnet, dass die Lippe (46) eine sich seitlich erstreckende Rippe (50) aufweist, die eine Trennwand zwischen zwei konzentrischen übereinander angeordneten Ringen (48, 49) bildet.
6. Stranggiesseinrichtung mit Giessform nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass die radiale Breite der Lippe (22, 46) etwa ein Drittel der radialen Breite des Körpers (7) der Giessform beträgt.
7. Stranggiesseinrichtung mit Giessform nach Anspruch 3, dadurch gekennzeichnet, dass der Ring (48, 49) aus einem isolierenden Material wie z.B. Aluminiumoxidfasern besteht.
8. Stranggiesseinrichtung mit Giessform nach Anspruch 1, dadurch gekennzeichnet, dass die Lippe (22, 32, 42, 46) eine axiale Höhe aufweist, die mindestens gleich der Dicke des Körpers (7) ist und vorzugsweise eineinhalb mal so gross wie diese Dicke ist.
9. Stranggiesseinrichtung mit Giessform nach Anspruch 1, dadurch gekennzeichnet, dass der isolierende Ring (24, 34) über dem oberen Ende der Lippe (22, 32) übersteht.
EP83102221A 1982-03-12 1983-03-07 Vorrichtung und Giessform zum Stranggiessen von dünnwandigen giesseisernen Röhren Expired EP0088980B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT83102221T ATE19363T1 (de) 1982-03-12 1983-03-07 Vorrichtung und giessform zum stranggiessen von duennwandigen giesseisernen roehren.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8204195A FR2523006A1 (fr) 1982-03-12 1982-03-12 Filiere tubulaire pour la coulee continue d'un tube, a paroi mince, en fonte
FR8204195 1982-03-12

Publications (2)

Publication Number Publication Date
EP0088980A1 EP0088980A1 (de) 1983-09-21
EP0088980B1 true EP0088980B1 (de) 1986-04-23

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EP83102221A Expired EP0088980B1 (de) 1982-03-12 1983-03-07 Vorrichtung und Giessform zum Stranggiessen von dünnwandigen giesseisernen Röhren

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Country Link
US (1) US4506723A (de)
EP (1) EP0088980B1 (de)
JP (1) JPS58168456A (de)
KR (1) KR880002066B1 (de)
AT (1) ATE19363T1 (de)
AU (1) AU554716B2 (de)
BE (1) BE896139A (de)
BR (1) BR8301236A (de)
CA (1) CA1201868A (de)
CH (1) CH654503A5 (de)
CZ (1) CZ279230B6 (de)
DD (1) DD208564A5 (de)
DE (1) DE3363143D1 (de)
EG (1) EG15354A (de)
ES (1) ES520523A0 (de)
FR (1) FR2523006A1 (de)
GB (1) GB2116466B (de)
HR (1) HRP930747B1 (de)
IN (1) IN158610B (de)
IT (2) IT1159367B (de)
MX (1) MX159487A (de)
PL (1) PL135939B1 (de)
RO (1) RO86288B (de)
SE (1) SE8301221L (de)
SI (1) SI8310507A8 (de)
SK (1) SK278292B6 (de)
SU (1) SU1215607A3 (de)
UA (1) UA6078A1 (de)
YU (1) YU44096B (de)

Families Citing this family (11)

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Publication number Priority date Publication date Assignee Title
JPS59215251A (ja) * 1983-05-23 1984-12-05 Kuroki Kogyosho:Kk 金属パイプの連続鋳造方法
FR2557820B1 (fr) * 1984-01-10 1987-05-07 Pont A Mousson Dispositif d'alimentation en metal liquide pour installation de coulee continue verticale d'un tube metallique, notamment en fonte
GB8401976D0 (en) * 1984-01-25 1984-02-29 Imi Refiners Ltd Casting apparatus
JPS61135452A (ja) * 1984-12-06 1986-06-23 Nippon Light Metal Co Ltd 中空ビレットの連続鋳造装置
FR2573683B1 (fr) * 1984-11-26 1987-01-02 Pont A Mousson Installation d'alimentation en metal liquide avec controle de temperature du metal liquide pour la coulee continue d'un tuyau en fonte
JP2692142B2 (ja) * 1988-06-10 1997-12-17 石川島播磨重工業株式会社 半凝固金属スラリー製造装置
FR2751250B1 (fr) * 1996-07-17 1998-08-21 Pont A Mousson Dispositif de bridage d'une table de coulee d'une machine de coulee continue verticale de pieces, en particulier de tubes, en fonte
DE19918228C2 (de) * 1999-04-22 2002-08-14 Daimler Chrysler Ag Verfahren zum Herstellen von Rohlingen für Zylinderlaufbüchsen
AU2006319755A1 (en) * 2005-11-30 2007-06-07 Advanced Intellectual Holdings Pty Ltd Apparatus for laying elongate elements
EP2336094A1 (de) 2009-12-21 2011-06-22 Mapei S.p.A. Starke Weichmacher für Beton- und Zementmaterialien und Herstellungsverfahren dafür
BR102017015433B1 (pt) * 2017-07-18 2023-04-18 Tupy S.A. Sistema para a produção de um componente de ferro por lingotamento contínuo

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1480828A (fr) * 1966-03-16 1967-05-12 Anaconda American Brass Co Appareil et procédé de coulée continue de tubes métalliques
GB1235112A (en) * 1967-06-19 1971-06-09 Consolidus Ltd Improvements relating to continuous casting apparatus
FR2415501A1 (fr) * 1978-01-27 1979-08-24 Pont A Mousson Procede et installation pour la coulee continue de produits tubulaires

Also Published As

Publication number Publication date
JPS6238065B2 (de) 1987-08-15
GB2116466A (en) 1983-09-28
SE8301221D0 (sv) 1983-03-07
YU44096B (en) 1990-02-28
DE3363143D1 (en) 1986-05-28
KR840003965A (ko) 1984-10-06
IT8353050V0 (it) 1983-03-11
GB2116466B (en) 1986-04-03
CZ279230B6 (cs) 1995-02-15
SK278292B6 (en) 1996-08-07
FR2523006B1 (de) 1984-04-27
FR2523006A1 (fr) 1983-09-16
YU50783A (en) 1985-12-31
SE8301221L (sv) 1983-09-13
MX159487A (es) 1989-06-16
ES8401347A1 (es) 1983-12-16
IT8367275A0 (it) 1983-03-11
BE896139A (fr) 1983-09-12
BR8301236A (pt) 1983-11-22
KR880002066B1 (ko) 1988-10-14
EP0088980A1 (de) 1983-09-21
UA6078A1 (uk) 1994-12-29
HRP930747B1 (en) 1996-04-30
RO86288B (ro) 1985-03-31
SI8310507A8 (en) 1995-04-30
ATE19363T1 (de) 1986-05-15
RO86288A (ro) 1985-03-15
CA1201868A (en) 1986-03-18
AU1193783A (en) 1983-09-15
PL135939B1 (en) 1986-01-31
EG15354A (en) 1986-06-30
IT1159367B (it) 1987-02-25
GB8303711D0 (en) 1983-03-16
DD208564A5 (de) 1984-04-04
ES520523A0 (es) 1983-12-16
CH654503A5 (fr) 1986-02-28
JPS58168456A (ja) 1983-10-04
AU554716B2 (en) 1986-08-28
SU1215607A3 (ru) 1986-02-28
US4506723A (en) 1985-03-26
IN158610B (de) 1986-12-20
PL240969A1 (en) 1983-11-07

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