EP0088746A1 - Procédé de traitement thermique de rails - Google Patents
Procédé de traitement thermique de rails Download PDFInfo
- Publication number
- EP0088746A1 EP0088746A1 EP83890026A EP83890026A EP0088746A1 EP 0088746 A1 EP0088746 A1 EP 0088746A1 EP 83890026 A EP83890026 A EP 83890026A EP 83890026 A EP83890026 A EP 83890026A EP 0088746 A1 EP0088746 A1 EP 0088746A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- rail
- coolant
- temperature
- content
- coolant additive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 15
- 239000002826 coolant Substances 0.000 claims abstract description 49
- 239000000654 additive Substances 0.000 claims abstract description 27
- 230000000996 additive effect Effects 0.000 claims abstract description 27
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 21
- 239000011572 manganese Substances 0.000 claims abstract description 21
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 20
- 239000010959 steel Substances 0.000 claims abstract description 20
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 19
- 238000001816 cooling Methods 0.000 claims abstract description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 10
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 7
- 239000012535 impurity Substances 0.000 claims abstract description 5
- 229910052742 iron Inorganic materials 0.000 claims abstract description 5
- 238000010791 quenching Methods 0.000 claims abstract description 5
- 230000000171 quenching effect Effects 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims description 6
- 229920000151 polyglycol Polymers 0.000 claims description 6
- 239000010695 polyglycol Substances 0.000 claims description 6
- 229910001562 pearlite Inorganic materials 0.000 claims description 3
- 238000005096 rolling process Methods 0.000 claims description 3
- 229910001566 austenite Inorganic materials 0.000 claims description 2
- 230000009466 transformation Effects 0.000 claims description 2
- 230000000630 rising effect Effects 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 235000019362 perlite Nutrition 0.000 abstract 1
- 239000010451 perlite Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 description 9
- 239000000203 mixture Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 230000007423 decrease Effects 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910000734 martensite Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910000967 As alloy Inorganic materials 0.000 description 1
- 229910000914 Mn alloy Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 230000009191 jumping Effects 0.000 description 1
- 238000010583 slow cooling Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/04—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for rails
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/56—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
- C21D1/60—Aqueous agents
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/62—Quenching devices
- C21D1/63—Quenching devices for bath quenching
Definitions
- the invention relates to a method for the heat treatment of rails made of a steel containing C, Si and Mn as well as alloy elements by quenching the rail or at least the rail head by means of a cooling medium from a temperature lying in the austenite region to a temperature at which the pearlite transformation is complete, to achieve a fine pearlitic structure.
- the formation of the structure largely depends on the cooling conditions.
- the formation of martensite must be prevented in any case, since this causes the rail to become brittle. It has been found that optimal wear properties can be achieved with such rails if the cooling is carried out in such a way that a fine pearlitic structure is produced.
- the object of the invention is now to even out the fine pearlitic microstructure and thus to improve the wear properties of the rail or the rail head.
- the invention consists essentially in the fact that rails made of steel, the 0.65 to 0.85% C, max. 0.80% Si and 0.5 to 2.5% Mn, balance iron and unavoidable impurities, are treated in a cooling medium, the water with a known synthetic coolant additive, preferably polyglycol, in an amount of 20 to 60%, based on the total cooling medium, contains.
- This synthetic coolant additive forms a layer on the rail or the rail head, which reduces the cooling rate.
- Such a layer is uniform and is not adversely affected by scaling jumping off, so that uniform cooling conditions can be achieved in this way over the entire surface and over the entire length of the rail or the rail head.
- the synthetic coolant additive preferably polyglycol
- the synthetic coolant additive is used according to the invention in an amount of 20-60%, based on the total cooling medium.
- rail steels with 0.65% - 0.85% C, max. 0.80% Si and 0.5 - 2.5% Mn, balance iron and unavoidable impurities a uniform result in terms of wear resistance can be achieved.
- Polyglycol has proven itself particularly well in this regard.
- the cooling medium can also be sprayed onto the rail or the rail head. But the rail or at least the rail is useful Rail head immersed in the cooling medium in a manner known per se, since in this way the film of the synthetic coolant additive can be formed better and more uniformly.
- the heat treatment can take place in a manner known per se from the rolling heat, so that the rolling heat is utilized and subsequent heating, which is costly, is avoided.
- the cooling medium is preferably composed such that there is a cooling rate of 0.2-6 C / sec in the temperature range between 800 and 500 ° C. sets.
- the cooling rates which are required to achieve a fine pearlitic structure are known for the various compositions of the rail and are in the range 0.2-6 ° C./sec.
- a thicker film of the coolant additive forms on the rail or the rail head and the cooling rate becomes lower than with a lower synthetic coolant additive.
- Within the range of 0.2 - 6 ° C / sec. can be selected by choosing the amount of the coolant additive taking into account the composition of the rail steel within the above-mentioned limits of 0.65 - 0.85% C, max. 0.80% Si and 0.5-2.5% Mn the cooling rate can be varied.
- Fig. 1 shows a diagram and Fig. 2 shows a cross section through a rail head
- Fi g . 3 shows a diagram of the wear resistance as a function of the Vickers hardness
- FIG. 4 shows the dependence of the improvement of the wear resistance on the manganese and carbon content for a given proportion of the coolant additive.
- samples are determined at different distances from the surface b of the rail head along the so-called hardness track indicated by the arrow a on the cut surface.
- Fig. 1 the Vickers hardness HV 30 is plotted on the ordinate.
- the distances of the measurements from the surface or the running surface b of a rail head are plotted on the abscissa.
- Curve c shows a measurement in rails treated by the method according to the invention which have a fine pearlitic structure.
- Curve d shows the hardness curve along the hardness track a with a rail of similar composition, the head of which was quenched in hot water.
- FIG. 3 shows a diagram in which the wear resistance ⁇ , expressed in N / cm 2 , is plotted on the ordinate.
- the Vickers hardness HV 30 measured in the edge of the rail head, is shown on the abscissa.
- Curve e shows the course of wear resistance in comparison to Vickers hardness.
- the area e 1 is the area in which the wear resistance and the Vickers hardness are in the case of rails heat-treated by the method according to the invention.
- the known values which can be achieved by known methods, are considerably below the range e 1 .
- the areas e2, e3 and e 4 show the strength values achieved so far for different rail steel qualities, e3 and e 4 for different standard rail steel grades and e2 for a Cr-Mn rail steel.
- the manganese content in% by weight is plotted on the ordinate, starting at 1.1% by weight.
- the carbon content in% by weight begins on the abscissa applied with 0.65% by weight.
- the e-g a transmitted square in this graph f limits the range of steels with a carbon content of 0.7 - 0.75 wt% and a manganese g e-stop of 1.2 -. 1.3 wt.%.
- a proportion of 30% by volume of a polyglycol as coolant additive gives the best results.
- A corresponds to 30% by volume of a polyglycol in the coolant.
- the proportion of the coolant additive With increasing carbon content, the proportion of the coolant additive must be reduced to achieve the same results if the manganese content remains the same. Conversely, with the carbon content remaining constant and the manganese content increasing, the proportion of the coolant additive must be increased in order to again achieve the same results, the straight lines h and i representing the lower and the upper limit for the proportion of the coolant additive, namely 20% by volume and 50% by volume .%, reproduces. If the coolant additive in the steels mentioned falls below the lower limit of 20% by volume, the cooling rate would be too high, causing the tendency to warp in the rail head to increase to a great extent. Conversely, exceeding the upper limit of 50 vol.% Coolant additive for the steels in the specified range would result in increased deposit formation.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Articles (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT931/82 | 1982-03-09 | ||
AT0093182A AT375402B (de) | 1982-03-09 | 1982-03-09 | Verfahren zum waermebehandeln von schienen |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0088746A1 true EP0088746A1 (fr) | 1983-09-14 |
EP0088746B1 EP0088746B1 (fr) | 1987-04-15 |
Family
ID=3503141
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19830890026 Expired EP0088746B1 (fr) | 1982-03-09 | 1983-02-22 | Procédé de traitement thermique de rails |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0088746B1 (fr) |
JP (1) | JPS58221229A (fr) |
AT (1) | AT375402B (fr) |
CA (1) | CA1205729A (fr) |
DE (1) | DE3370972D1 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1994002652A1 (fr) * | 1992-07-15 | 1994-02-03 | Voest-Alpine Schienen Gmbh | Procede de traitement thermique de rails |
WO1997045562A1 (fr) * | 1996-05-24 | 1997-12-04 | Bwg Butzbacher Weichenbau Gmbh | Procede de production d'une superstructure de voie ferree et superstructure de voie ferree |
CZ299001B6 (cs) * | 2000-05-29 | 2008-04-02 | Voestalpine Schienen Gmbh | Zpusob a zarízení na kalení kolejnic nebo hlavy kolejnic |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62161917A (ja) * | 1986-01-09 | 1987-07-17 | Nippon Steel Corp | 耐摩耗性、耐損傷性にすぐれた端頭部熱処理レ−ルの製造法 |
JPS63203724A (ja) * | 1987-02-19 | 1988-08-23 | Nkk Corp | レ−ルの焼入方法 |
DE4003363C1 (en) * | 1990-02-05 | 1991-03-28 | Voest-Alpine Industrieanlagenbau Ges.M.B.H., Linz, At | Hardening rails from rolling temp. - using appts. with manipulator engaging rail from exit roller table with support arms positioned pivotably on each side |
AT401359B (de) * | 1991-04-05 | 1996-08-26 | Vae Ag | Verfahren zur herstellung eines herzstückes |
EP0685566B2 (fr) * | 1993-12-20 | 2013-06-05 | Nippon Steel & Sumitomo Metal Corporation | Rail a elevee resistance a l'abrasion et a haute tenacite, possedant une structure metallographique perlitique, et procede de production dudit rail |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1242660B (de) * | 1963-06-29 | 1967-06-22 | Union Carbide Corp | Abschreckmedium zum Abschrecken von waermebehandeltem Metall |
DE1802273A1 (de) * | 1968-01-18 | 1969-08-07 | Zentralinstitut Fuer Fertigung | Mittel zum Abschrecken von austenitisiertem Stahl oder anderen Eisenwerkstoffen zum Zweck des Haertens oder Verguetens |
DE2439338B1 (de) * | 1974-08-16 | 1975-10-23 | Fried. Krupp, Huettenwerke Ag, 4630 Bochum | Verfahren zur Wärmebehandlung von Schienen |
DE2630176A1 (de) * | 1975-07-03 | 1977-03-17 | Houghton & Co E F | Verfahren zum abschrecken zur hitzebehandlung von metallen |
DE2820784A1 (de) * | 1977-05-18 | 1978-11-23 | Centre Rech Metallurgique | Verfahren zur herstellung von schienen mit verbesserten eigenschaftswerten |
-
1982
- 1982-03-09 AT AT0093182A patent/AT375402B/de not_active IP Right Cessation
-
1983
- 1983-02-22 EP EP19830890026 patent/EP0088746B1/fr not_active Expired
- 1983-02-22 DE DE8383890026T patent/DE3370972D1/de not_active Expired
- 1983-03-07 CA CA000423018A patent/CA1205729A/fr not_active Expired
- 1983-03-09 JP JP3889983A patent/JPS58221229A/ja active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1242660B (de) * | 1963-06-29 | 1967-06-22 | Union Carbide Corp | Abschreckmedium zum Abschrecken von waermebehandeltem Metall |
DE1802273A1 (de) * | 1968-01-18 | 1969-08-07 | Zentralinstitut Fuer Fertigung | Mittel zum Abschrecken von austenitisiertem Stahl oder anderen Eisenwerkstoffen zum Zweck des Haertens oder Verguetens |
DE2439338B1 (de) * | 1974-08-16 | 1975-10-23 | Fried. Krupp, Huettenwerke Ag, 4630 Bochum | Verfahren zur Wärmebehandlung von Schienen |
DE2630176A1 (de) * | 1975-07-03 | 1977-03-17 | Houghton & Co E F | Verfahren zum abschrecken zur hitzebehandlung von metallen |
DE2820784A1 (de) * | 1977-05-18 | 1978-11-23 | Centre Rech Metallurgique | Verfahren zur herstellung von schienen mit verbesserten eigenschaftswerten |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1994002652A1 (fr) * | 1992-07-15 | 1994-02-03 | Voest-Alpine Schienen Gmbh | Procede de traitement thermique de rails |
US6406569B1 (en) | 1992-07-15 | 2002-06-18 | Voest-Alpine Schienen Gmbh | Procedure for the thermal treatment of rails |
US6547897B2 (en) | 1992-07-15 | 2003-04-15 | Voest-Alpine Schienen Gmbh | Procedure for the thermal treatment of rails |
WO1997045562A1 (fr) * | 1996-05-24 | 1997-12-04 | Bwg Butzbacher Weichenbau Gmbh | Procede de production d'une superstructure de voie ferree et superstructure de voie ferree |
CZ299001B6 (cs) * | 2000-05-29 | 2008-04-02 | Voestalpine Schienen Gmbh | Zpusob a zarízení na kalení kolejnic nebo hlavy kolejnic |
Also Published As
Publication number | Publication date |
---|---|
AT375402B (de) | 1984-08-10 |
CA1205729A (fr) | 1986-06-10 |
DE3370972D1 (en) | 1987-05-21 |
JPS58221229A (ja) | 1983-12-22 |
EP0088746B1 (fr) | 1987-04-15 |
ATA93182A (de) | 1983-12-15 |
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RIN2 | Information on inventor provided after grant (corrected) |
Inventor name: PRSKAWETZ, GEORG, DIPL.-ING. Inventor name: POINTNER, PETER, DIPL.-ING. Inventor name: MOSER, ALFRED, DR., DIPL.-ING. |