EP0062550B1 - Procédé de traitements thermochimiques de métaux par bombardement ionique - Google Patents

Procédé de traitements thermochimiques de métaux par bombardement ionique Download PDF

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Publication number
EP0062550B1
EP0062550B1 EP82400407A EP82400407A EP0062550B1 EP 0062550 B1 EP0062550 B1 EP 0062550B1 EP 82400407 A EP82400407 A EP 82400407A EP 82400407 A EP82400407 A EP 82400407A EP 0062550 B1 EP0062550 B1 EP 0062550B1
Authority
EP
European Patent Office
Prior art keywords
plasma
treatment
pieces
anode
cathode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP82400407A
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German (de)
English (en)
French (fr)
Other versions
EP0062550A1 (fr
Inventor
Roger Speri
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Innovatique SA
Original Assignee
Innovatique SA
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Filing date
Publication date
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Application filed by Innovatique SA filed Critical Innovatique SA
Priority to AT82400407T priority Critical patent/ATE37907T1/de
Publication of EP0062550A1 publication Critical patent/EP0062550A1/fr
Application granted granted Critical
Publication of EP0062550B1 publication Critical patent/EP0062550B1/fr
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/36Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases using ionised gases, e.g. ionitriding

Definitions

  • the present invention relates to a process for thermochemical treatment of metals such as nitriding, carbonitriding, carburizing, metallic deposits under vacuum, etc. by ion bombardment.
  • the treatment medium can be obtained by passing a stream of ammonia gas over the parts, which, when decomposed, releases active nitrogen atoms.
  • the treatment temperature which is of the order of 570 ° C. is then obtained by placing the parts in an electric oven.
  • the parts to be treated are placed in an enclosure containing a gas (NH 3 , molecular nitrogen, H 2 CH 4 ) at low pressure (0.1 to 10 torr).
  • a gas NH 3 , molecular nitrogen, H 2 CH 4
  • This enclosure is equipped with an anode and a cathode, connected to a high voltage electric current generator (between 300 and 1500 V).
  • the cathode is designed so as to support the parts to be treated which are therefore brought to the cathode.
  • the treatment is obtained by creating, between the cathode and the anode, a luminescent discharge which is maintained at the limit of the arc regime.
  • a plasma is created around the part to be treated, composed of nitrogen ions which in fact constitutes the treatment medium.
  • Another solution envisaged, for example in FR A 2 379 615 and USA 3 108 900, in order to obtain an operation free from the risk of arcing, consists in using, instead of direct current, high voltage current pulses. , but whose total energy is maintained at a predetermined value, so that it is not possible to reach, in the voltage / current discharge curve, the zone corresponding to the arc regime.
  • the invention proposes to make the 2 treatment parameters, namely the production of the treatment medium, that is to say plasma, and the heating to the treatment temperature of the parts completely independent. .
  • a cold plasma is continuously obtained, that is to say a plasma in which the heat energy dissipated during the dissociation remains at a very low level and cannot affect the temperature characteristics of the treatment in progress, in the case of a thermochemical treatment.
  • This method also makes it possible to eliminate the temperature heterogeneities as a function of the parameters linked to the parts such as the shape, the state, the hollow cathode phenomena during the rise in temperature, the dimensions of different parts, etc.
  • the installation for implementing the method involves an oven having a structure similar to that of a conventional heat or thermochemical treatment oven with a rarefied atmosphere, this oven comprising its own heating means, by convection, by radiation, coherent or not, or by induction, its own regulation means, a generator of process gas and current passages passing through the wall of the furnace and connected to the electrodes (anodes-cathodes) used for generating the plasma.
  • the supply of these electrodes can be ensured from the three-phase or single-phase industrial network by means of a generator comprising a controlled rectifier making it possible to obtain a variable DC voltage between 0 and the mains voltage, an inverter making it possible to transform this direct voltage in particular alternating voltage with variable amplitude and duty cycle, then rectified to obtain monopolar pulses at high voltage of the order of 300 to 1500 V and at high frequency of the order of 100 Hz to 10 K Hertz which supply the oven.
  • a generator comprising a controlled rectifier making it possible to obtain a variable DC voltage between 0 and the mains voltage, an inverter making it possible to transform this direct voltage in particular alternating voltage with variable amplitude and duty cycle, then rectified to obtain monopolar pulses at high voltage of the order of 300 to 1500 V and at high frequency of the order of 100 Hz to 10 K Hertz which supply the oven.
  • the two types of heating can be used independently, alternately or even simultaneously during the treatment (heating means specific to the oven and operation in hot plasma mode).

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
  • Plasma Technology (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Physical Vapour Deposition (AREA)
  • Chemical Vapour Deposition (AREA)
EP82400407A 1981-03-13 1982-03-09 Procédé de traitements thermochimiques de métaux par bombardement ionique Expired EP0062550B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT82400407T ATE37907T1 (de) 1981-03-13 1982-03-09 Verfahren fuer die thermochemischen behandlungen von metallen durch ionenbeschuss.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8105107 1981-03-13
FR8105107A FR2501727A1 (fr) 1981-03-13 1981-03-13 Procede de traitements thermochimiques de metaux par bombardement ionique

Publications (2)

Publication Number Publication Date
EP0062550A1 EP0062550A1 (fr) 1982-10-13
EP0062550B1 true EP0062550B1 (fr) 1988-10-12

Family

ID=9256233

Family Applications (1)

Application Number Title Priority Date Filing Date
EP82400407A Expired EP0062550B1 (fr) 1981-03-13 1982-03-09 Procédé de traitements thermochimiques de métaux par bombardement ionique

Country Status (6)

Country Link
US (2) US4490190A (enrdf_load_stackoverflow)
EP (1) EP0062550B1 (enrdf_load_stackoverflow)
JP (1) JPS57210971A (enrdf_load_stackoverflow)
AT (1) ATE37907T1 (enrdf_load_stackoverflow)
DE (1) DE3279106D1 (enrdf_load_stackoverflow)
FR (1) FR2501727A1 (enrdf_load_stackoverflow)

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DE4238993C1 (enrdf_load_stackoverflow) * 1992-01-20 1993-07-01 Leybold Durferrit Gmbh, 5000 Koeln, De

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US8187377B2 (en) 2002-10-04 2012-05-29 Silicon Genesis Corporation Non-contact etch annealing of strained layers
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JP4257157B2 (ja) * 2003-06-13 2009-04-22 本田技研工業株式会社 窒化処理方法及び装置
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Also Published As

Publication number Publication date
FR2501727B1 (enrdf_load_stackoverflow) 1983-06-03
JPS57210971A (en) 1982-12-24
DE3279106D1 (en) 1988-11-17
EP0062550A1 (fr) 1982-10-13
ATE37907T1 (de) 1988-10-15
US4672170A (en) 1987-06-09
FR2501727A1 (fr) 1982-09-17
US4490190A (en) 1984-12-25

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