EP0062550B1 - Procédé de traitements thermochimiques de métaux par bombardement ionique - Google Patents
Procédé de traitements thermochimiques de métaux par bombardement ionique Download PDFInfo
- Publication number
- EP0062550B1 EP0062550B1 EP82400407A EP82400407A EP0062550B1 EP 0062550 B1 EP0062550 B1 EP 0062550B1 EP 82400407 A EP82400407 A EP 82400407A EP 82400407 A EP82400407 A EP 82400407A EP 0062550 B1 EP0062550 B1 EP 0062550B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- plasma
- treatment
- pieces
- anode
- cathode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000011282 treatment Methods 0.000 title claims abstract description 33
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 4
- 239000002184 metal Substances 0.000 title claims abstract description 4
- 150000002739 metals Chemical class 0.000 title claims abstract description 4
- 238000000034 method Methods 0.000 title claims description 11
- 238000010849 ion bombardment Methods 0.000 title claims description 5
- 230000005495 cold plasma Effects 0.000 claims abstract description 5
- 238000010438 heat treatment Methods 0.000 claims description 15
- 238000001816 cooling Methods 0.000 claims description 2
- 238000005121 nitriding Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- -1 nitriding Chemical class 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005256 carbonitriding Methods 0.000 description 1
- 238000005255 carburizing Methods 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 235000020004 porter Nutrition 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/36—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases using ionised gases, e.g. ionitriding
Definitions
- the present invention relates to a process for thermochemical treatment of metals such as nitriding, carbonitriding, carburizing, metallic deposits under vacuum, etc. by ion bombardment.
- the treatment medium can be obtained by passing a stream of ammonia gas over the parts, which, when decomposed, releases active nitrogen atoms.
- the treatment temperature which is of the order of 570 ° C. is then obtained by placing the parts in an electric oven.
- the parts to be treated are placed in an enclosure containing a gas (NH 3 , molecular nitrogen, H 2 CH 4 ) at low pressure (0.1 to 10 torr).
- a gas NH 3 , molecular nitrogen, H 2 CH 4
- This enclosure is equipped with an anode and a cathode, connected to a high voltage electric current generator (between 300 and 1500 V).
- the cathode is designed so as to support the parts to be treated which are therefore brought to the cathode.
- the treatment is obtained by creating, between the cathode and the anode, a luminescent discharge which is maintained at the limit of the arc regime.
- a plasma is created around the part to be treated, composed of nitrogen ions which in fact constitutes the treatment medium.
- Another solution envisaged, for example in FR A 2 379 615 and USA 3 108 900, in order to obtain an operation free from the risk of arcing, consists in using, instead of direct current, high voltage current pulses. , but whose total energy is maintained at a predetermined value, so that it is not possible to reach, in the voltage / current discharge curve, the zone corresponding to the arc regime.
- the invention proposes to make the 2 treatment parameters, namely the production of the treatment medium, that is to say plasma, and the heating to the treatment temperature of the parts completely independent. .
- a cold plasma is continuously obtained, that is to say a plasma in which the heat energy dissipated during the dissociation remains at a very low level and cannot affect the temperature characteristics of the treatment in progress, in the case of a thermochemical treatment.
- This method also makes it possible to eliminate the temperature heterogeneities as a function of the parameters linked to the parts such as the shape, the state, the hollow cathode phenomena during the rise in temperature, the dimensions of different parts, etc.
- the installation for implementing the method involves an oven having a structure similar to that of a conventional heat or thermochemical treatment oven with a rarefied atmosphere, this oven comprising its own heating means, by convection, by radiation, coherent or not, or by induction, its own regulation means, a generator of process gas and current passages passing through the wall of the furnace and connected to the electrodes (anodes-cathodes) used for generating the plasma.
- the supply of these electrodes can be ensured from the three-phase or single-phase industrial network by means of a generator comprising a controlled rectifier making it possible to obtain a variable DC voltage between 0 and the mains voltage, an inverter making it possible to transform this direct voltage in particular alternating voltage with variable amplitude and duty cycle, then rectified to obtain monopolar pulses at high voltage of the order of 300 to 1500 V and at high frequency of the order of 100 Hz to 10 K Hertz which supply the oven.
- a generator comprising a controlled rectifier making it possible to obtain a variable DC voltage between 0 and the mains voltage, an inverter making it possible to transform this direct voltage in particular alternating voltage with variable amplitude and duty cycle, then rectified to obtain monopolar pulses at high voltage of the order of 300 to 1500 V and at high frequency of the order of 100 Hz to 10 K Hertz which supply the oven.
- the two types of heating can be used independently, alternately or even simultaneously during the treatment (heating means specific to the oven and operation in hot plasma mode).
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
- Plasma Technology (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Physical Vapour Deposition (AREA)
- Chemical Vapour Deposition (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT82400407T ATE37907T1 (de) | 1981-03-13 | 1982-03-09 | Verfahren fuer die thermochemischen behandlungen von metallen durch ionenbeschuss. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8105107 | 1981-03-13 | ||
FR8105107A FR2501727A1 (fr) | 1981-03-13 | 1981-03-13 | Procede de traitements thermochimiques de metaux par bombardement ionique |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0062550A1 EP0062550A1 (fr) | 1982-10-13 |
EP0062550B1 true EP0062550B1 (fr) | 1988-10-12 |
Family
ID=9256233
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP82400407A Expired EP0062550B1 (fr) | 1981-03-13 | 1982-03-09 | Procédé de traitements thermochimiques de métaux par bombardement ionique |
Country Status (6)
Country | Link |
---|---|
US (2) | US4490190A (enrdf_load_stackoverflow) |
EP (1) | EP0062550B1 (enrdf_load_stackoverflow) |
JP (1) | JPS57210971A (enrdf_load_stackoverflow) |
AT (1) | ATE37907T1 (enrdf_load_stackoverflow) |
DE (1) | DE3279106D1 (enrdf_load_stackoverflow) |
FR (1) | FR2501727A1 (enrdf_load_stackoverflow) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4238993C1 (enrdf_load_stackoverflow) * | 1992-01-20 | 1993-07-01 | Leybold Durferrit Gmbh, 5000 Koeln, De |
Families Citing this family (60)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3322341A1 (de) * | 1983-06-22 | 1985-01-03 | Siegfried Dr.-Ing. 5135 Selfkant Strämke | Verfahren und vorrichtung zur oberflaechenbehandlung von werkstuecken durch glimmentladung |
US4700315A (en) * | 1983-08-29 | 1987-10-13 | Wellman Thermal Systems Corporation | Method and apparatus for controlling the glow discharge process |
US4568396A (en) * | 1984-10-03 | 1986-02-04 | The United States Of America As Represented By The Secretary Of The Navy | Wear improvement in titanium alloys by ion implantation |
FR2587729B1 (fr) * | 1985-09-24 | 1988-12-23 | Centre Nat Rech Scient | Procede et dispositif de traitement chimique, notamment de traitement thermochimique et de depot chimique dans un plasma homogene de grand volume |
US4693760A (en) * | 1986-05-12 | 1987-09-15 | Spire Corporation | Ion implanation of titanium workpieces without surface discoloration |
CH671407A5 (enrdf_load_stackoverflow) * | 1986-06-13 | 1989-08-31 | Balzers Hochvakuum | |
JPS6333553A (ja) * | 1986-07-24 | 1988-02-13 | Masanobu Nunogaki | プラズマ源窒化法 |
GB8625912D0 (en) * | 1986-10-29 | 1986-12-03 | Electricity Council | Thermochemical treatment |
DE3700633C2 (de) * | 1987-01-12 | 1997-02-20 | Reinar Dr Gruen | Verfahren und Vorrichtung zum schonenden Beschichten elektrisch leitender Gegenstände mittels Plasma |
US4764394A (en) * | 1987-01-20 | 1988-08-16 | Wisconsin Alumni Research Foundation | Method and apparatus for plasma source ion implantation |
US4777109A (en) * | 1987-05-11 | 1988-10-11 | Robert Gumbinner | RF plasma treated photosensitive lithographic printing plates |
US4853046A (en) * | 1987-09-04 | 1989-08-01 | Surface Combustion, Inc. | Ion carburizing |
US5127967A (en) * | 1987-09-04 | 1992-07-07 | Surface Combustion, Inc. | Ion carburizing |
US4872922A (en) * | 1988-03-11 | 1989-10-10 | Spire Corporation | Method and apparatus for the ion implantation of spherical surfaces |
US5025365A (en) * | 1988-11-14 | 1991-06-18 | Unisys Corporation | Hardware implemented cache coherency protocol with duplicated distributed directories for high-performance multiprocessors |
US4968006A (en) * | 1989-07-21 | 1990-11-06 | Spire Corporation | Ion implantation of spherical surfaces |
US5079032A (en) * | 1989-07-21 | 1992-01-07 | Spire Corporation | Ion implantation of spherical surfaces |
US5152795A (en) * | 1990-04-25 | 1992-10-06 | Spire Corporation | Surgical implants and method |
US5123924A (en) * | 1990-04-25 | 1992-06-23 | Spire Corporation | Surgical implants and method |
US5226975A (en) * | 1991-03-20 | 1993-07-13 | Cummins Engine Company, Inc. | Plasma nitride chromium plated coating method |
FR2679258B1 (fr) * | 1991-07-16 | 1993-11-19 | Centre Stephanois Recherc Meca | Procede de traitement de pieces en metal ferreux pour ameliorer simultanement leur resistance a la corrosion et leurs proprietes de friction. |
FR2681472B1 (fr) | 1991-09-18 | 1993-10-29 | Commissariat Energie Atomique | Procede de fabrication de films minces de materiau semiconducteur. |
CH689767A5 (de) | 1992-03-24 | 1999-10-15 | Balzers Hochvakuum | Verfahren zur Werkstueckbehandlung in einer Vakuumatmosphaere und Vakuumbehandlungsanlage. |
FR2689976B1 (fr) * | 1992-04-14 | 1995-06-30 | Innovatique Sa | Procede et dispositif pour la determination et le controle de la composition du melange gazeux reactif utilise au cours d'un traitement thermochimique sous atmosphere rarefiee. |
US5868878A (en) * | 1993-08-27 | 1999-02-09 | Hughes Electronics Corporation | Heat treatment by plasma electron heating and solid/gas jet cooling |
DE4427902C1 (de) * | 1994-08-06 | 1995-03-30 | Leybold Durferrit Gmbh | Verfahren zum Aufkohlen von Bauteilen aus kohlungsfähigen Werkstoffen mittels einer impulsförmig betriebenen Plasmaentladung |
FR2748851B1 (fr) * | 1996-05-15 | 1998-08-07 | Commissariat Energie Atomique | Procede de realisation d'une couche mince de materiau semiconducteur |
US6033974A (en) | 1997-05-12 | 2000-03-07 | Silicon Genesis Corporation | Method for controlled cleaving process |
US6291313B1 (en) | 1997-05-12 | 2001-09-18 | Silicon Genesis Corporation | Method and device for controlled cleaving process |
US6245161B1 (en) | 1997-05-12 | 2001-06-12 | Silicon Genesis Corporation | Economical silicon-on-silicon hybrid wafer assembly |
US20070122997A1 (en) | 1998-02-19 | 2007-05-31 | Silicon Genesis Corporation | Controlled process and resulting device |
US6027988A (en) * | 1997-05-28 | 2000-02-22 | The Regents Of The University Of California | Method of separating films from bulk substrates by plasma immersion ion implantation |
US6548382B1 (en) | 1997-07-18 | 2003-04-15 | Silicon Genesis Corporation | Gettering technique for wafers made using a controlled cleaving process |
FR2773261B1 (fr) | 1997-12-30 | 2000-01-28 | Commissariat Energie Atomique | Procede pour le transfert d'un film mince comportant une etape de creation d'inclusions |
JPH11316919A (ja) | 1998-04-30 | 1999-11-16 | Hitachi Ltd | スピントンネル磁気抵抗効果型磁気ヘッド |
US6291326B1 (en) | 1998-06-23 | 2001-09-18 | Silicon Genesis Corporation | Pre-semiconductor process implant and post-process film separation |
JP2003506883A (ja) | 1999-08-10 | 2003-02-18 | シリコン ジェネシス コーポレイション | 低打ち込みドーズ量を用いて多層基板を製造するための劈開プロセス |
US6263941B1 (en) | 1999-08-10 | 2001-07-24 | Silicon Genesis Corporation | Nozzle for cleaving substrates |
US6221740B1 (en) | 1999-08-10 | 2001-04-24 | Silicon Genesis Corporation | Substrate cleaving tool and method |
US6500732B1 (en) | 1999-08-10 | 2002-12-31 | Silicon Genesis Corporation | Cleaving process to fabricate multilayered substrates using low implantation doses |
FR2823599B1 (fr) | 2001-04-13 | 2004-12-17 | Commissariat Energie Atomique | Substrat demomtable a tenue mecanique controlee et procede de realisation |
RU2208064C1 (ru) * | 2001-11-19 | 2003-07-10 | Уфимский государственный авиационный технический университет | Способ электронно-ионного азотирования крупногабаритных изделий в низкотемпературной газоразрядной плазме и устройство для его осуществления |
US8187377B2 (en) | 2002-10-04 | 2012-05-29 | Silicon Genesis Corporation | Non-contact etch annealing of strained layers |
FR2848336B1 (fr) | 2002-12-09 | 2005-10-28 | Commissariat Energie Atomique | Procede de realisation d'une structure contrainte destinee a etre dissociee |
JP4257157B2 (ja) * | 2003-06-13 | 2009-04-22 | 本田技研工業株式会社 | 窒化処理方法及び装置 |
FR2856844B1 (fr) | 2003-06-24 | 2006-02-17 | Commissariat Energie Atomique | Circuit integre sur puce de hautes performances |
FR2857953B1 (fr) | 2003-07-21 | 2006-01-13 | Commissariat Energie Atomique | Structure empilee, et procede pour la fabriquer |
FR2861497B1 (fr) | 2003-10-28 | 2006-02-10 | Soitec Silicon On Insulator | Procede de transfert catastrophique d'une couche fine apres co-implantation |
FR2889887B1 (fr) | 2005-08-16 | 2007-11-09 | Commissariat Energie Atomique | Procede de report d'une couche mince sur un support |
US9362439B2 (en) | 2008-05-07 | 2016-06-07 | Silicon Genesis Corporation | Layer transfer of films utilizing controlled shear region |
US8293619B2 (en) | 2008-08-28 | 2012-10-23 | Silicon Genesis Corporation | Layer transfer of films utilizing controlled propagation |
US8993410B2 (en) | 2006-09-08 | 2015-03-31 | Silicon Genesis Corporation | Substrate cleaving under controlled stress conditions |
US7811900B2 (en) | 2006-09-08 | 2010-10-12 | Silicon Genesis Corporation | Method and structure for fabricating solar cells using a thick layer transfer process |
FR2910179B1 (fr) | 2006-12-19 | 2009-03-13 | Commissariat Energie Atomique | PROCEDE DE FABRICATION DE COUCHES MINCES DE GaN PAR IMPLANTATION ET RECYCLAGE D'UN SUBSTRAT DE DEPART |
FR2925221B1 (fr) | 2007-12-17 | 2010-02-19 | Commissariat Energie Atomique | Procede de transfert d'une couche mince |
US8330126B2 (en) | 2008-08-25 | 2012-12-11 | Silicon Genesis Corporation | Race track configuration and method for wafering silicon solar substrates |
US8329557B2 (en) | 2009-05-13 | 2012-12-11 | Silicon Genesis Corporation | Techniques for forming thin films by implantation with reduced channeling |
US20100294751A1 (en) * | 2009-05-22 | 2010-11-25 | Innovative Engineering & Product Development, Inc. | Variable frequency heating controller |
FR2947098A1 (fr) | 2009-06-18 | 2010-12-24 | Commissariat Energie Atomique | Procede de transfert d'une couche mince sur un substrat cible ayant un coefficient de dilatation thermique different de celui de la couche mince |
BR102014026134B1 (pt) * | 2014-10-20 | 2022-09-27 | Universidade Federal De Santa Catarina | Processo e reator de plasma para tratamento termoquímico de superfície de peças metálicas |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL91406C (enrdf_load_stackoverflow) * | 1950-08-03 | |||
US3228809A (en) * | 1953-12-09 | 1966-01-11 | Berghaus Elektrophysik Anst | Method of regulating an electric glow discharge and discharge vessel therefor |
US3108900A (en) * | 1959-04-13 | 1963-10-29 | Cornelius A Papp | Apparatus and process for producing coatings on metals |
US3190772A (en) * | 1960-02-10 | 1965-06-22 | Berghaus Bernhard | Method of hardening work in an electric glow discharge |
GB1255321A (en) * | 1968-03-11 | 1971-12-01 | Lucas Industries Ltd | Surface diffusion processes using electrical glow discharges |
FR2324755A1 (fr) * | 1975-09-19 | 1977-04-15 | Anvar | Dispositif de pulverisation cathodique de grande vitesse de depot |
FR2332336A1 (fr) * | 1975-11-21 | 1977-06-17 | Vide & Traitement Sa | Procede et four pour la realisation de traitements de metaux par bombardement ionique |
FR2332337A1 (fr) * | 1975-11-21 | 1977-06-17 | Vide & Traitement Sa | Four de traitement thermique ou thermochimique par bombardement ionique |
CH611938A5 (enrdf_load_stackoverflow) * | 1976-05-19 | 1979-06-29 | Battelle Memorial Institute | |
FR2379615A1 (fr) * | 1977-02-08 | 1978-09-01 | Vide & Traitement Sa | Procede de traitement thermochimique de metaux |
JPS5429845A (en) * | 1977-08-10 | 1979-03-06 | Kawasaki Heavy Ind Ltd | Ion nitriding treatment method |
US4331856A (en) * | 1978-10-06 | 1982-05-25 | Wellman Thermal Systems Corporation | Control system and method of controlling ion nitriding apparatus |
US4253907A (en) * | 1979-03-28 | 1981-03-03 | Western Electric Company, Inc. | Anisotropic plasma etching |
JPS5813625B2 (ja) * | 1979-12-12 | 1983-03-15 | 超エル・エス・アイ技術研究組合 | ガスプラズマ食刻法 |
US4297387A (en) * | 1980-06-04 | 1981-10-27 | Battelle Development Corporation | Cubic boron nitride preparation |
US4342631A (en) * | 1980-06-16 | 1982-08-03 | Illinois Tool Works Inc. | Gasless ion plating process and apparatus |
-
1981
- 1981-03-13 FR FR8105107A patent/FR2501727A1/fr active Granted
-
1982
- 1982-03-08 US US06/355,880 patent/US4490190A/en not_active Expired - Fee Related
- 1982-03-09 EP EP82400407A patent/EP0062550B1/fr not_active Expired
- 1982-03-09 DE DE8282400407T patent/DE3279106D1/de not_active Expired
- 1982-03-09 AT AT82400407T patent/ATE37907T1/de not_active IP Right Cessation
- 1982-03-12 JP JP57039264A patent/JPS57210971A/ja active Pending
-
1984
- 1984-10-04 US US06/657,791 patent/US4672170A/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4238993C1 (enrdf_load_stackoverflow) * | 1992-01-20 | 1993-07-01 | Leybold Durferrit Gmbh, 5000 Koeln, De |
Also Published As
Publication number | Publication date |
---|---|
FR2501727B1 (enrdf_load_stackoverflow) | 1983-06-03 |
JPS57210971A (en) | 1982-12-24 |
DE3279106D1 (en) | 1988-11-17 |
EP0062550A1 (fr) | 1982-10-13 |
ATE37907T1 (de) | 1988-10-15 |
US4672170A (en) | 1987-06-09 |
FR2501727A1 (fr) | 1982-09-17 |
US4490190A (en) | 1984-12-25 |
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