EP0036537A2 - Procédé de teinture de mélanges de fibres de polyester et de cellulose - Google Patents

Procédé de teinture de mélanges de fibres de polyester et de cellulose Download PDF

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Publication number
EP0036537A2
EP0036537A2 EP81101670A EP81101670A EP0036537A2 EP 0036537 A2 EP0036537 A2 EP 0036537A2 EP 81101670 A EP81101670 A EP 81101670A EP 81101670 A EP81101670 A EP 81101670A EP 0036537 A2 EP0036537 A2 EP 0036537A2
Authority
EP
European Patent Office
Prior art keywords
acid
dyeing
dye
polyester
dyestuff
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP81101670A
Other languages
German (de)
English (en)
Other versions
EP0036537B1 (fr
EP0036537A3 (en
Inventor
Dietrich Dr. Hildebrand
Udo Winfried Dr. Hendricks
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of EP0036537A2 publication Critical patent/EP0036537A2/fr
Publication of EP0036537A3 publication Critical patent/EP0036537A3/de
Application granted granted Critical
Publication of EP0036537B1 publication Critical patent/EP0036537B1/fr
Expired legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58Material containing hydroxyl groups
    • D06P3/60Natural or regenerated cellulose
    • D06P3/66Natural or regenerated cellulose using reactive dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82Textiles which contain different kinds of fibres
    • D06P3/8204Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8223Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups
    • D06P3/8238Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using different kinds of dye
    • D06P3/8252Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using different kinds of dye using dispersed and reactive dyes

Definitions

  • the invention relates to a process for single-bath, single-stage dyeing of fiber mixtures of cellulose and polyester fibers with reactive and disperse dyes by the pull-out process from electrolyte-containing dye baths, characterized in that a dye bath is used which contains a reactive dye with fluorotriazinyl and / or Fluoropyrimidinyl group and 0.1 - 5 g / 1 of an acid donor effective at dyeing temperature.
  • Suitable reactive dyes are, in particular, organic dyes from the anthraquinone, azo and phthalocanine series which have a monofluoro-s-triazinyl radical, in particular those which contain an ether or thioether group or in particular an optionally substituted amino group as further substituents on the triazine ring, or else fluoropyrimidine dyes especially those with Difluorchlorpyrimidinylrest.
  • Such dyes are described in large numbers, for example. in British Patents 1,169,254; 1,188,606; 1 526 840.
  • Water-soluble derivatives of organic or inorganic acids are used as acid donors, which release acidic groups specifically in the temperature range from 60 to 100 ° C and thus the pH value of the dye bath, which is initially neutral to weakly alkaline during the dyeing process, preferably up to pH in the acidic range Move 4-5.
  • Suitable acid donors are: alkali metal salts of halocarboxylic acids and their amides, such as sodium monochloroacetic acid, sodium dichloroacetic acid, sodium 3-chloropropionate, monochloroacetamide; Lactones such as butyrolactone; Halbester of sulfuric acid such as lauryl sulfate, hexadecyl sulfate and octadecyl sulfate or preferably 2-ethylhexyl sulfate, butyl sulfate, as well as the oxyethylated and oxypropylated Schwefelklasteder of alcohols, for example butylglycol sulfate, Butyldiglykolsulfat, further C 1 -C 4 alkyl esters of phosphoric acid or phosphorous acid, C 1 -C 4 alkyl esters of phosphonic and phosphinic acid, such as trimethyl phosphate, trie
  • polyester fiber components Commercially available carriers may be used for the dyeing of the polyester fiber components. Examples include trichlorobenzene, o-dichlorobenzene, methyl cresotate, butyl benzoate, o-phenylphenol, p-phenylphenol,
  • the carriers are used in the usual amounts for dyeing polyester fibers and are added to the dye bath after the dye and salt have been added.
  • the process is suitable for dyeing yarn and pieces on packers and packages, jet dyeing machines, reel runners and jiggers.
  • the process is generally carried out as follows:
  • the textile material is introduced into a dyebath which has a pH of about 7-10, preferably 7-9 and 0.01-10 g / 1 of a fluorotriazinyl and / or fluoropyrimidinyl reactive dye , 01-10 g / l of a conventional disperse dye, 10-200 g / l of a conventional electrolyte such as sodium sulfate or sodium chloride, 0.1-10 g / l of an acid donor and preferably 0.1-10 g / l of a buffer, in particular one Contains phosphate buffers for a pH range of 7-9, as well as other common auxiliaries, for example 1-8 g / l of a carrier.
  • the dye bath is inside heated from 30 - 40 ° C to 95 - 130 ° C for 1 - 2 hours and dyed at this temperature for 1/2 - 1 hour.
  • Suitable buffer systems are, for example, trisodium phosphate monosodium dihydrogen phosphate or disodium hydrogen phosphate.
  • the reactive dye is dyed in the alkaline range, preferably at pH 7.5-9 below 100 ° C.
  • 100 g of a knitted fabric consisting of 50 g polyester and 50 g cotton are treated on a HT jet dyeing machine with a 30 ° C. liquor, which consists of consists.
  • the liquor is brought to 130 ° C. in 100 minutes and kept at this temperature for 1 hour.
  • the liquor is brought to 130 ° C. in 100 minutes and kept at this temperature for 1 hour.
  • the liquor is brought to 130 ° C. in 55 minutes and kept at this temperature for 1 hour.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Coloring (AREA)
EP81101670A 1980-03-21 1981-03-07 Procédé de teinture de mélanges de fibres de polyester et de cellulose Expired EP0036537B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19803010979 DE3010979A1 (de) 1980-03-21 1980-03-21 Faerbeverfahren
DE3010979 1980-03-21

Publications (3)

Publication Number Publication Date
EP0036537A2 true EP0036537A2 (fr) 1981-09-30
EP0036537A3 EP0036537A3 (en) 1981-12-16
EP0036537B1 EP0036537B1 (fr) 1983-09-28

Family

ID=6097954

Family Applications (1)

Application Number Title Priority Date Filing Date
EP81101670A Expired EP0036537B1 (fr) 1980-03-21 1981-03-07 Procédé de teinture de mélanges de fibres de polyester et de cellulose

Country Status (3)

Country Link
EP (1) EP0036537B1 (fr)
JP (1) JPS5846594B2 (fr)
DE (2) DE3010979A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0062865A1 (fr) * 1981-04-14 1982-10-20 Bayer Ag Procédé de teinture
EP0597330A1 (fr) * 1992-11-10 1994-05-18 Bayer Ag Composition de colorants réactifs pour mélanges de fibres polyester/cellulose
CN102561071A (zh) * 2010-12-23 2012-07-11 福建凤竹纺织科技股份有限公司 一种涤棉织物的分散、活性一浴染色工艺

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5930971A (ja) * 1982-07-06 1984-02-18 日本化薬株式会社 セルロ−ス及びセルロ−ス含有繊維材料の捺染又はパジング染色法
JPS59106583A (ja) * 1982-12-13 1984-06-20 日本化学工業株式会社 ポリエステル/セルロ−ス混紡繊維品の染色方法
JPS6253376A (ja) * 1985-09-03 1987-03-09 Nippon Chem Ind Co Ltd:The 染料組成物
JPH0684593B2 (ja) * 1985-09-15 1994-10-26 一方社油脂工業株式会社 ポリエステル/セルロ−ス混紡・交織品の染色方法
JPS62230858A (ja) * 1985-12-27 1987-10-09 Nippon Chem Ind Co Ltd:The 染料組成物
TW330957B (en) * 1995-06-22 1998-05-01 Daistar Japan Kk Method of dyeing a blended fiber containing cellulose fibers and polyester fibers
CN104074069A (zh) * 2014-07-02 2014-10-01 浙江航民股份有限公司 染色用分散染料与活性染料的同浴剂

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1469750A1 (de) * 1965-12-31 1968-12-12 Hoechst Ag Verfahren zum Faerben von Fasermaterialien aus nativer oder regenerierter Cellulose mit Reaktivfarbstoffen oder von Gemischen aus diesen Cellulosefasern und Fasermaterialien aus hochmolekularen linearen Polyestern mit Reaktivfarbstoffen und Dispersionsfarbstoffen
DE1619464A1 (de) * 1966-02-23 1970-10-29 Hoechst Ag Verfahren zum Faerben von Cellulosefasern mit Reaktivfarbstoffen oder von Mischungen aus Cellulose- und Polyesterfasern mit Reaktiv- und Dispersionsfarbstoffen
DE2354728A1 (de) * 1972-11-06 1974-05-09 Sandoz Ag Verfahren zum faerben und fixieren von textilen materialien
US3910758A (en) * 1971-06-17 1975-10-07 Bayer Ag Dyeing wool with fluorine substituted pyrimidine containing azo reactive dyestuff
DE2834997B1 (de) * 1978-08-10 1980-01-03 Hoechst Ag Verfahren zum Faerben von synthetischen Polyamidfasern mit Reaktivfarbstoffen nach der Ausziehmethode
GB2027756A (en) * 1978-08-10 1980-02-27 Hoechst Ag Process for dyeing cellulose fibres with reactive dyes according to the batchwise exhaustion method
EP0017172A1 (fr) * 1979-04-05 1980-10-15 Bayer Ag Procédé de teinture de fibres cellulosiques et de mélanges fibreux contenant des fibres cellulosiques et de polyesters avec des colorants réactifs
EP0024332A1 (fr) * 1979-08-17 1981-03-04 Bayer Ag Teinture de mélanges de fibres de laine et de fibres cellulosiques

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1469750A1 (de) * 1965-12-31 1968-12-12 Hoechst Ag Verfahren zum Faerben von Fasermaterialien aus nativer oder regenerierter Cellulose mit Reaktivfarbstoffen oder von Gemischen aus diesen Cellulosefasern und Fasermaterialien aus hochmolekularen linearen Polyestern mit Reaktivfarbstoffen und Dispersionsfarbstoffen
DE1619464A1 (de) * 1966-02-23 1970-10-29 Hoechst Ag Verfahren zum Faerben von Cellulosefasern mit Reaktivfarbstoffen oder von Mischungen aus Cellulose- und Polyesterfasern mit Reaktiv- und Dispersionsfarbstoffen
US3910758A (en) * 1971-06-17 1975-10-07 Bayer Ag Dyeing wool with fluorine substituted pyrimidine containing azo reactive dyestuff
DE2354728A1 (de) * 1972-11-06 1974-05-09 Sandoz Ag Verfahren zum faerben und fixieren von textilen materialien
DE2834997B1 (de) * 1978-08-10 1980-01-03 Hoechst Ag Verfahren zum Faerben von synthetischen Polyamidfasern mit Reaktivfarbstoffen nach der Ausziehmethode
GB2027756A (en) * 1978-08-10 1980-02-27 Hoechst Ag Process for dyeing cellulose fibres with reactive dyes according to the batchwise exhaustion method
EP0017172A1 (fr) * 1979-04-05 1980-10-15 Bayer Ag Procédé de teinture de fibres cellulosiques et de mélanges fibreux contenant des fibres cellulosiques et de polyesters avec des colorants réactifs
EP0024332A1 (fr) * 1979-08-17 1981-03-04 Bayer Ag Teinture de mélanges de fibres de laine et de fibres cellulosiques

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, Band 90, Nr. 20, 14. Mai 1979, seite 53, zusammenfassung 153.370d Columbus Ohio (US) & Cellul. Chem. Technol. 1978, 12(6) 693-702 A. BENDAK et al. "New Processing Technique for Dyeing of Polyester/Cotton Blend" * Abstract * *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0062865A1 (fr) * 1981-04-14 1982-10-20 Bayer Ag Procédé de teinture
EP0597330A1 (fr) * 1992-11-10 1994-05-18 Bayer Ag Composition de colorants réactifs pour mélanges de fibres polyester/cellulose
CN102561071A (zh) * 2010-12-23 2012-07-11 福建凤竹纺织科技股份有限公司 一种涤棉织物的分散、活性一浴染色工艺

Also Published As

Publication number Publication date
EP0036537B1 (fr) 1983-09-28
JPS56144277A (en) 1981-11-10
DE3010979A1 (de) 1981-10-01
DE3160995D1 (en) 1983-11-03
EP0036537A3 (en) 1981-12-16
JPS5846594B2 (ja) 1983-10-17

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