EP0025157B1 - Verfahren zur Luftwäsche in Klimaanlagen - Google Patents
Verfahren zur Luftwäsche in Klimaanlagen Download PDFInfo
- Publication number
- EP0025157B1 EP0025157B1 EP80105021A EP80105021A EP0025157B1 EP 0025157 B1 EP0025157 B1 EP 0025157B1 EP 80105021 A EP80105021 A EP 80105021A EP 80105021 A EP80105021 A EP 80105021A EP 0025157 B1 EP0025157 B1 EP 0025157B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- air
- ozone
- water
- fluid
- spray
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000005406 washing Methods 0.000 title claims abstract description 5
- 238000004378 air conditioning Methods 0.000 title claims description 8
- 238000000034 method Methods 0.000 title claims description 5
- 238000009434 installation Methods 0.000 title claims 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000007921 spray Substances 0.000 claims abstract description 16
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 4
- 150000002367 halogens Chemical class 0.000 claims abstract description 4
- 238000005507 spraying Methods 0.000 claims description 2
- 239000003595 mist Substances 0.000 claims 1
- 239000012530 fluid Substances 0.000 abstract 7
- 125000004122 cyclic group Chemical group 0.000 abstract 3
- 239000012535 impurity Substances 0.000 abstract 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 6
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 6
- 229910052794 bromium Inorganic materials 0.000 description 6
- 238000004659 sterilization and disinfection Methods 0.000 description 6
- SISAYUDTHCIGLM-UHFFFAOYSA-N bromine dioxide Chemical compound O=Br=O SISAYUDTHCIGLM-UHFFFAOYSA-N 0.000 description 4
- JGJLWPGRMCADHB-UHFFFAOYSA-N hypobromite Chemical compound Br[O-] JGJLWPGRMCADHB-UHFFFAOYSA-N 0.000 description 4
- 244000052616 bacterial pathogen Species 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000009423 ventilation Methods 0.000 description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000005201 scrubbing Methods 0.000 description 2
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 206010016275 Fear Diseases 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000011001 backwashing Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 150000002927 oxygen compounds Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000036642 wellbeing Effects 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F3/00—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems
- F24F3/12—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling
- F24F3/14—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by humidification; by dehumidification
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
- F24F8/10—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering
- F24F8/117—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering using wet filtering
- F24F8/133—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering using wet filtering by direct contact with liquid, e.g. with sprayed liquid
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F6/00—Air-humidification, e.g. cooling by humidification
- F24F6/12—Air-humidification, e.g. cooling by humidification by forming water dispersions in the air
- F24F6/14—Air-humidification, e.g. cooling by humidification by forming water dispersions in the air using nozzles
- F24F2006/146—Air-humidification, e.g. cooling by humidification by forming water dispersions in the air using nozzles using pressurised water for spraying
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
- F24F8/20—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation
- F24F8/24—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation using sterilising media
- F24F8/26—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation using sterilising media using ozone
Definitions
- the invention relates to a method for air washing in air conditioning systems using a spray chamber through which the air is passed and in which a spray is generated by spraying and collecting a supply of scrubber water.
- Such an air wash e.g. known from US-A No. 3065043, causes humidification of the air and flushing out dust particles.
- air-conditioned rooms with a particularly high number of germs e.g. in hospitals, however, there is the additional problem of air disinfection, which has so far not been solved satisfactorily.
- chemical disinfectants to the circulating spray water, it is known that extremely high numbers of colonies are found in these spray chambers.
- disinfectants have their own problems, especially odor problems in the common rooms. Furthermore, bacterial growth in the ventilation ducts of air conditioning systems and the consequent re-germination of the air could not be prevented.
- Air disinfection with ozone fails due to the control problem of adding only as much ozone as can be reduced by the undesirable organic substances present in the air at the moment. It is important to avoid excess ozone in the air we breathe under all circumstances, as this is toxic.
- the maximum workplace concentration (MAK value) specified in the relevant regulations of the health authorities is 0.1 ppm ozone.
- the invention is based on the object of proposing an air disinfection method which can be used in air conditioning systems and which has no annoying or harmful side effects and, in particular in rooms with high demands on air hygiene, substantially improves the previous situation.
- This object is achieved according to the invention in an air washing process of the type described in the introduction in that the scrubber water is treated with ozone in a circulating circuit and contains a halogen which reacts with ozone.
- Air disinfection takes place in two stages or can be seen under two aspects.
- germs as well as other undesirable water constituents are washed out of the air, get into the ozone treatment unit with the water and there are literally burned by contact with concentrated ozone and then filtered out.
- the bromine (hypobromite or bromine dioxide) activated by ozone creates a germ-free environment in the washer and, as has been shown, also in the ventilation ducts of the air conditioning system. Bacterial colonies no longer occur there.
- the permanent disinfection of the second type does not only take place in the spray water.
- active oxygen is rather given to the air flow during air humidification, which results in a considerable reduction in the number of bacteria in the air-conditioned rooms and the well-being of the patients, e.g. during long-term operations or in intensive care units, influenced very favorably.
- the bromine content of the spray water is not consumed.
- the oxidation processes and the reduction processes linked to disinfection are reversible and the corresponding bromine states form a balance. This can be measured by measuring the redox potential and can also be controlled by influencing the amount of ozone accordingly.
- the invention In addition to the reliable killing of all germs and viruses in the conditioned air, the invention also has the advantage that the maintenance and cleaning effort for the laundry chambers can be sustainably reduced.
- a spray chamber 1 is switched into the collecting duct of an air conditioning system and the air flow passes through it in the direction of the arrow.
- spray nozzles 2 and in the right part baffle plates 3 are indicated schematically.
- a circulation pump 5 sucks off the scrubbing water at the bottom of the spray chamber and conveys it to the spray nozzles 2.
- Another circulation circuit runs from the water supply 4 back to the water supply 4 via a circulation pump 6 and an ozone treatment unit 7.
- the ozone treatment unit 7 consists of a container which is partially filled with fine filter gravel and has a filter star 9 at the outlet.
- an ozone generator 10 Arranged on the inside of the container lid is an ozone generator 10, which is fed from the outside with dried compressed air and high voltage.
- the ozone gas exits through a check valve 11 on the underside of the ozone generator.
- the check valve 11 is surrounded by a mixer chamber 12, which connects to the ozone generator 10 at the bottom and Contains baffles.
- the water supply line is inserted through the lid of the container and connected to the bottom of the mixer chamber 12. In the mixer chamber, the water entering through the feed line is mixed intensively with the ozone-containing gas emerging from the check valve 11, after which it leaves the mixer chamber again in the radial direction.
- the spray water contains a nutrient-free complexing agent to avoid limescale deposits.
- the filter is backwashed with the help of facilities not shown, using the scrubbing water.
- This backwashing water discharged into the sewer is then replaced by fresh water, the rinsed substances being replenished by adding an appropriate amount of hydrobromic acid and complexing agents.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Central Air Conditioning (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
- Treating Waste Gases (AREA)
- Separation Of Particles Using Liquids (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT80105021T ATE2633T1 (de) | 1979-08-29 | 1980-08-23 | Verfahren zur luftwaesche in klimaanlagen. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19792934846 DE2934846A1 (de) | 1979-08-29 | 1979-08-29 | Verfahren zur luftwaesche in klimaanlagen |
DE2934846 | 1979-08-29 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0025157A1 EP0025157A1 (de) | 1981-03-18 |
EP0025157B1 true EP0025157B1 (de) | 1983-02-23 |
Family
ID=6079535
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP80105021A Expired EP0025157B1 (de) | 1979-08-29 | 1980-08-23 | Verfahren zur Luftwäsche in Klimaanlagen |
Country Status (5)
Country | Link |
---|---|
US (1) | US4410339A (enrdf_load_stackoverflow) |
EP (1) | EP0025157B1 (enrdf_load_stackoverflow) |
JP (1) | JPS5659141A (enrdf_load_stackoverflow) |
AT (1) | ATE2633T1 (enrdf_load_stackoverflow) |
DE (1) | DE2934846A1 (enrdf_load_stackoverflow) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60500851A (ja) * | 1983-02-18 | 1985-06-06 | クザルノ,ヤヌ−シユ | 空気清浄装置 |
JPS6058228A (ja) * | 1983-09-09 | 1985-04-04 | Senichi Masuda | 空気清浄装置 |
US4601886A (en) * | 1984-05-24 | 1986-07-22 | Hudgins Richard G | Air treatment apparatus |
JPS6261615A (ja) * | 1985-09-10 | 1987-03-18 | Fuji Electric Co Ltd | 気体の除塵・除菌装置 |
US5017351A (en) * | 1988-02-11 | 1991-05-21 | Rafson Harold J | Process for removing volatile organic compounds from air streams |
JPH02135110A (ja) * | 1988-11-16 | 1990-05-24 | Daiei Sangyo Kk | 汚濁空気・汚濁水の浄化処理装置 |
DE4408303A1 (de) * | 1993-09-14 | 1995-03-16 | Hatz Walter | Verfahren und Einrichtung zum Entkeimen von Luftwäschern in Klimaanlagen |
US5878912A (en) | 1995-12-26 | 1999-03-09 | Stein; Myron | Duct disinfecting method and apparatus |
RU2138321C1 (ru) * | 1998-08-25 | 1999-09-27 | Меньщиков Владимир Михайлович | Устройство для отсоса и очистки воздуха |
SE9903177L (sv) * | 1999-09-08 | 2001-05-08 | Otre Ab | Apparat och metod för behandling av luft |
US6503547B1 (en) * | 1999-11-18 | 2003-01-07 | Grupo Interozone | Method for diffusing ozone in a closed environment |
GB9927617D0 (en) * | 1999-11-24 | 2000-01-19 | Ump Co Ltd | Biocide air delivery systems |
US6743279B2 (en) * | 2002-05-17 | 2004-06-01 | Airborne Contaminant Systems, Llc | Air purification device for air handling units |
US7105039B2 (en) * | 2003-02-26 | 2006-09-12 | Scott Decker | Ozone remediation apparatus and methods |
WO2017143599A1 (zh) * | 2016-02-27 | 2017-08-31 | 孙华 | 空气净化方法及系统 |
DE202018005053U1 (de) * | 2018-11-01 | 2020-02-05 | Peter Mittelsdorf | Luftreinigungsvorrichtung |
CN113074501A (zh) * | 2020-01-06 | 2021-07-06 | 青岛海尔电冰箱有限公司 | 用于冰箱的除农残装置以及冰箱 |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2090466A (en) * | 1935-03-30 | 1937-08-17 | Francis R Bichowsky | Means for humidifying and drying air |
DE715595C (de) * | 1936-12-08 | 1942-01-03 | Henri Bernard Beer | Verfahren und Vorrichtung zur Reinigung und Sterilisierung von Luft mittels Ozon |
US2207774A (en) * | 1938-12-07 | 1940-07-16 | Tubize Chatillon Corp | Gas conditioning |
US2405553A (en) * | 1941-06-07 | 1946-08-13 | Donald K Allison | Means and method of ozonizing liquids |
US2606150A (en) * | 1948-04-08 | 1952-08-05 | Air Reduction | Dispersion of gaseous treating agents in liquids |
US2771416A (en) * | 1950-03-06 | 1956-11-20 | Edmund J Ryan | Water purification |
US2874032A (en) * | 1955-10-04 | 1959-02-17 | Borg Warner | Dissolver |
FR1176463A (fr) * | 1957-06-03 | 1959-04-10 | Dispositif pour l'enrichissement de l'air de salles communes, de salles de spectacles et de tous lieux publics | |
US3065043A (en) * | 1958-05-23 | 1962-11-20 | Midland Ross Corp | Air purification |
DE1256862B (de) * | 1958-12-20 | 1967-12-21 | Otto Heinz Brandi Dipl Ing | Luftwaescher fuer Klimaanlagen |
US3366441A (en) * | 1964-02-10 | 1968-01-30 | Ultra Dynamics Corp | Ultraviolet system for control of algae and slime within humidity control and similar systems |
US3805481A (en) * | 1964-04-23 | 1974-04-23 | E Armstrong | Apparatus for and process of treating liquids with a gas |
US3326747A (en) * | 1965-05-17 | 1967-06-20 | Sol B Wiczer | Disinfecting solution and method |
US3445001A (en) * | 1967-06-02 | 1969-05-20 | Ozonator Corp | Water purifier |
DE2301127A1 (de) * | 1970-06-19 | 1974-07-18 | Plafog Planungs Und Forschungs | Verfahren zur langzeitdesinfektion von wasser |
DE2060895A1 (de) * | 1970-12-10 | 1972-06-15 | Sheikh Morris I | Luftsterilisationsverfahren |
DE2156571C3 (de) * | 1971-11-15 | 1981-07-30 | Hans-Ulrich Ing.(Grad.) 6200 Wiesbaden Klein | Verwendung eines Filterbettes in Vorrichtung zur komplexen Wasseraufbereitung mit Ozon |
DE2332058A1 (de) * | 1973-06-23 | 1975-01-16 | Demag Ag | Verfahren zur entkeimung von in abfuellbehaeltern oder flaschen abzufuellendem trinkwasser |
DE2450731A1 (de) * | 1974-10-25 | 1976-04-29 | Hydro Elektrik Gmbh | Verfahren zur wasseraufbereitung mit ozon |
DE2632298A1 (de) * | 1976-07-17 | 1978-01-19 | Heinz Hoelter | Verfahren zur reinigung von rohgasen, vorzugsweise kraftwerksabgasen, durch einsatz von saeuren und oder salzen der halogengruppe |
JPS5393170A (en) * | 1977-01-28 | 1978-08-15 | Asahi Glass Co Ltd | Deodorizing method for exhaust gas or waste liquid |
JPS6048219B2 (ja) * | 1978-01-24 | 1985-10-25 | 三菱電機株式会社 | 低級アルデヒド類を含む気体の浄化方法 |
JPS5561920A (en) * | 1978-11-01 | 1980-05-10 | Mitsubishi Electric Corp | Deodorizing method |
-
1979
- 1979-08-29 DE DE19792934846 patent/DE2934846A1/de active Granted
-
1980
- 1980-08-23 AT AT80105021T patent/ATE2633T1/de not_active IP Right Cessation
- 1980-08-23 EP EP80105021A patent/EP0025157B1/de not_active Expired
- 1980-08-29 JP JP11852580A patent/JPS5659141A/ja active Pending
-
1981
- 1981-11-09 US US06/319,383 patent/US4410339A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0025157A1 (de) | 1981-03-18 |
ATE2633T1 (de) | 1983-03-15 |
DE2934846A1 (de) | 1981-03-19 |
JPS5659141A (en) | 1981-05-22 |
DE2934846C2 (enrdf_load_stackoverflow) | 1990-10-31 |
US4410339A (en) | 1983-10-18 |
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