EP0018930A1 - Retractable pouring units - Google Patents

Retractable pouring units Download PDF

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Publication number
EP0018930A1
EP0018930A1 EP19800420048 EP80420048A EP0018930A1 EP 0018930 A1 EP0018930 A1 EP 0018930A1 EP 19800420048 EP19800420048 EP 19800420048 EP 80420048 A EP80420048 A EP 80420048A EP 0018930 A1 EP0018930 A1 EP 0018930A1
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EP
European Patent Office
Prior art keywords
base
pourer
skirt
rings
annular
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP19800420048
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German (de)
French (fr)
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EP0018930B1 (en
Inventor
Pierre Babiol
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societe Nouvelle de Bouchons Plastiques SNBP
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Societe Nouvelle de Bouchons Plastiques SNBP
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Publication of EP0018930A1 publication Critical patent/EP0018930A1/en
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Publication of EP0018930B1 publication Critical patent/EP0018930B1/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D47/00—Closures with filling and discharging, or with discharging, devices
    • B65D47/04—Closures with discharging devices other than pumps
    • B65D47/06—Closures with discharging devices other than pumps with pouring spouts or tubes; with discharge nozzles or passages
    • B65D47/061—Closures with discharging devices other than pumps with pouring spouts or tubes; with discharge nozzles or passages with telescopic, retractable or reversible spouts, tubes or nozzles

Definitions

  • the present invention relates to improvements made to the retractable pouring assemblies used in particular although not exclusively on cans so as to facilitate the flow of their contents without harming their possibility of stacking.
  • the pourers in question When the pourers in question are associated with a metal canister such as a canister of vehicle oil, they generally comprise three elements: a base snapped into an opening at the top of the container, a tubular pourer capable of sliding in leaktight relation to to the base in order to project from the container against an appropriate stop, and a plug associated with the free end of the pourer.
  • the improvements which are the subject of the present invention aim to allow the production of a pourer of the genus in question which responds better than so far to the various wishes of the practice.
  • a retractable pouring assembly according to the invention associated above the container 1 made in the form of a metal container.
  • This pourer is more particularly arranged in an opening 1b made in the center of a boss lc from the above-mentioned top.
  • the pouring assembly comprises a base 2, a tubular pourer 3 and a plug 4 forming the latter, these three elements being made of a suitable plastic material as will be explained better below.
  • the base 2 which is made of a material such as polyethylene comprises a central sleeve 5 extended radially by a flange 6 which has one end 6a turned downwards, a groove 7 being formed immediately below the underside of this flange .
  • the bottom of the sleeve 5 is provided with an edge 5a folded twice at 90 ° so as to constitute a thin central chimney 5b capable of cooperating in leaktight manner with the periphery of the tubular spout 3.
  • the part of the sleeve 5 situated above of the collar 6 is provided with a peripheral cord 8.
  • the base 2 is snapped elastically inside the opening lb determined in the boss lc from above the of the container 1.
  • the tubular pourer 3 also made of polyethylene comprises 1 its upper part a thread 9 while its base is surrounded by a peripheral flange 10.
  • the periphery of the spout 3 is provided with a bead 11 whose distance from the flange 10 is at play almost equal to the height of the chimney 5b .
  • the plug 4 preferably made of polypropylene, is provided with a skirt 12, the inner face of which is threaded, its bottom 4a which comprises an annular lip 13 disposed more in the center than the skirt 12, extending beyond the latter to carry a second skirt 14 coaxial with the first and the inner face of which is provided with two diametrically opposite rods 14a, 14b (fig. 3) extending over approximately a quarter of the circumference of the face considered.
  • the second skirt 14 is surrounded by two half-panels 15, 16 whose length is less than its half-circumference.
  • Each ring is made integral with the latter by means of two tenons 17.18, 19.20 located two by two opposite one another and beyond each of which each half-ring projects to form a foot 15a, 15b respectively 16a, 16b.
  • Each half-ring also has a central ear 15c, 16c facilitating gripping as will be explained better below.
  • the periphery of the skirt 14 is connected to the middle of each ring by a bridge 21, 22.
  • the pourer is assembled first by engaging the spout in the base 2 by its end which carries the thread 9, this operation being carried out from below by compared to the chimney 5b.
  • the plug 4 is then screwed in completely with respect to the thread 9.
  • the spout is retracted so that the plug comes to be placed as shown in FIG. 1 relative to the base 2.
  • a tamper-evident shutter (fig. 4) whose half-rings 15, 16 rest against the top of the flange 6.
  • the user grasps together the two ears 15c, 16c and acts on them to rotate the half-rings in the direction of the arrows Fl, F2 (fig.
  • the mixture is heated at 170 ° C for 8 hours; the pressure is initially established at 26 bars, then gradually drops to 10 bars at the end of the reaction. Cool to 120 ° C, degas, then pour slowly 30 g of water and heat for 2 hours at 140 ° C, then 2 hours at 150 ° C while distilling. at atmospheric pressure. After treatment, as in Example 1, the benzoxazolone is obtained with an R T of 70% and a T T of 96%.
  • Example 4 is repeated, but with 9.9 g of Cu 2 Cl 2 (instead of 19.8 g); benzoxazolone is thus obtained with a RT of 70.5% and a T_T of 80.5%.
  • the autoclave is closed and purged using NH 3 .
  • the mixture is heated at 170 ° C for 6 hours.
  • the pressure initially stabilizes at around 26 bars (relative pressure) and then gradually drops to around 10 bars at the end of the reaction.
  • Cool to 120 ° C. open the autoclave, and transfer the contents of the autoclave to a 250 cm 3 flask at atmospheric pressure fitted with a distillation system similar to that of Example 1. To this flask is added slowly 3 cm 3 of water; it is then heated for 2 hours. at 140 ° C and then 2 h. at 150 ° C by regularly adding water at the rate of 4.5 cm 3 / h throughout the distillation.
  • Benzoxazolone was also obtained in the presence of Fe C1 2 , NiCl 2 and Ni.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Closures For Containers (AREA)
  • Thermally Insulated Containers For Foods (AREA)

Abstract

1. Retractable pourer assembly to be associated to a receptacle (1) of the type comprising : - an annular base (2) shaped to be clipped in the opening (1b) of the receptacle ; - a tubular pourer (3) slidably extending through said base, said pourer comprising means (23) to limit its mouvement outwards and having on its lower portion an annular flange (11) cooperating with the base (2) in extended position of said pourer ; - a stopper (4) screwed on the thread (9) of the free end of the pourer (3) and having a second skirt (14) whose inner face is provided with an annular ring (14a, 14b) clipping beneath a bead (8) of the base, the periphery of the second skirt (14) of the stopper (4) being associated to two half-rings (15, 16) whose ends or feet (15a, 15b, 16a, 16b) rest upon an annular collar (6) of the base (2) when said half-rings are pivoted about the lugs (17, 18, 19, 20) constituting pivot means.

Description

La présente invention est relative à des perfectionnements apportés aux ensembles verseurs escamotables utilisés notamment bien que non exclusivement sur des bidons de manière à faciliter l'écoulement de leur contenu sans nuire à leur possibilité d'empilage.The present invention relates to improvements made to the retractable pouring assemblies used in particular although not exclusively on cans so as to facilitate the flow of their contents without harming their possibility of stacking.

Lorsque les verseurs en question sont associés à un bidon métallique tel qu'un bidon d'huile pour véhicule, ils comprennent généralement trois éléments : une embase encliquetée dans une ouverture du dessus du récipient, un verseur tubulaire propre à coulisser de manière étanche par rapport à l'embase afin de venir en saillie par rapport au récipient contre une butée appropriée, et un bouchon associé à l'extrémité libre du verseur.When the pourers in question are associated with a metal canister such as a canister of vehicle oil, they generally comprise three elements: a base snapped into an opening at the top of the container, a tubular pourer capable of sliding in leaktight relation to to the base in order to project from the container against an appropriate stop, and a plug associated with the free end of the pourer.

Les perfectionnements qui font l'objet de la présente invention visent à permettre la réalisation d'un verseur du genre en question qui réponde mieux que jusqu'à présent au divers desiderata de la pratique.The improvements which are the subject of the present invention aim to allow the production of a pourer of the genus in question which responds better than so far to the various wishes of the practice.

A cet effet le bouchon comporte une seconde jupe extérieure dont la face intérieure est pourvue de deux joncs séparés situés en vis-à-vis et qui s'encliquettent sous un cordon de l'embase tandis que la face extérieure de ladite jupe est associée à deux demi-anneaux constituant chacun levier destiné à assurer l'arrachage du bouchon par rapport au cordon précité de l'embase. Le dessin annexé, donné à titre d'exemple, permettra de mieux comprendre l'invention, les caractéristiques qu'elle présente et les avantages qu'elle est susceptible de procurer :

  • Fig. 1 est une vue en coupe d'un ensemble verseur établi conformément à l'invention représenté en position effacée par rapport au-dessus d'un récipient.
  • Fig. 2 est une vue semblable à celle de fig. 1, mais illustrant le verseur à sa position sortie.
  • Fig. 3 montre le bouchon de fermeture du bec verseur en vue par dessous.
  • Fig. 4 est une vue partielle extérieure du dispositif suivant l'invention.
  • Fig. 5 illustre la manière dont le bouchon est dégagé de l'embase.
  • Fig. 6 est une vue par dessous du bec verseur selon l'invention suivant la flèche F (fig. 1).
To this end, the stopper has a second outer skirt, the inner face of which is provided with two separate rods located opposite and which snap under a bead of the base while the outer face of said skirt is associated with two half-rings each constituting a lever intended to ensure the tearing of the plug with respect to the aforementioned cord of the base. The appended drawing, given by way of example, will allow a better understanding of the invention, the characteristics which it presents and the advantages which it is capable of providing:
  • Fig. 1 is a sectional view of a pouring assembly established in accordance with the invention shown in the erased position relative to the top of a container.
  • Fig. 2 is a view similar to that of FIG. 1, but illustrating the pourer in its extended position.
  • Fig. 3 shows the closure cap of the spout seen from below.
  • Fig. 4 is a partial exterior view of the device according to the invention.
  • Fig. 5 illustrates the manner in which the plug is released from the base.
  • Fig. 6 is a view from below of the pouring spout according to the invention according to arrow F (FIG. 1).

0n a représenté en fig. 1 un ensemble verseur escamotable suivant l'invention associé au-dessus la d'un récipient 1 réalisé sous la forme d'un bidon métallique. Ce verseur est plus particulièrement disposé dans une ouverture lb pratiquée au centre d'un bossage lc du dessus précité.0n is shown in fig. 1 a retractable pouring assembly according to the invention associated above the container 1 made in the form of a metal container. This pourer is more particularly arranged in an opening 1b made in the center of a boss lc from the above-mentioned top.

L'ensemble verseur comprend une embase 2, un verseur tubulaire 3 et un bouchon 4 formant ce dernier, ces trois éléments étant réalisés en une matière plastique appropriée comme on l'expliquera mieux plus loin.The pouring assembly comprises a base 2, a tubular pourer 3 and a plug 4 forming the latter, these three elements being made of a suitable plastic material as will be explained better below.

L'embase 2 qui est réalisée en une matière telle que le polyéthylène comprend un manchon central 5 prolongé radialement par une collerette 6 qui comporte une extrémité 6a retournée vers le bas, une gorge 7 étant pratiquée immédiatement en dessous de la face inférieure de cette collerette. Le bas du manchon 5 est pourvu d'un bord 5a rabattu deux fois à 90° de manière à constituer une cheminée centrale mince 5b propre à coopérer de manière étanche avec la périphérie du bec tubulaire 3. La partie du manchon 5 située au-dessus de la collerette 6 est pourvue d'un cordon périphérique 8.The base 2 which is made of a material such as polyethylene comprises a central sleeve 5 extended radially by a flange 6 which has one end 6a turned downwards, a groove 7 being formed immediately below the underside of this flange . The bottom of the sleeve 5 is provided with an edge 5a folded twice at 90 ° so as to constitute a thin central chimney 5b capable of cooperating in leaktight manner with the periphery of the tubular spout 3. The part of the sleeve 5 situated above of the collar 6 is provided with a peripheral cord 8.

Comme représenté en fig. 2 l'embase 2 est encliquetée élastiquement à l'intérieur de l'ouverture lb déterminée dans le bossage lc du dessus la du récipient 1.As shown in fig. 2 the base 2 is snapped elastically inside the opening lb determined in the boss lc from above the of the container 1.

Le verseur tubulaire 3 réalisé aussi en polyéthylène comporte 1 sa partie supérieure un filetage 9 tandis que sa base est entourée par une bride périphérique 10. Le pourtour du bec 3 est pourvu d'un bourrelet 11 dont la distance à la bride 10 est au jeu près égale à la hauteur de la cheminée 5b.The tubular pourer 3 also made of polyethylene comprises 1 its upper part a thread 9 while its base is surrounded by a peripheral flange 10. The periphery of the spout 3 is provided with a bead 11 whose distance from the flange 10 is at play almost equal to the height of the chimney 5b .

Le bouchon 4 réalisé préférablement en polypropylène est pourvu d'une jupe 12 dont la face intérieure est filetée, son fond 4a qui comporte une lèvre annulaire 13 disposée plus au centre que la jupe 12, se prolongeant au-delà de celle-ci pour porter une seconde jupe 14 coaxiale à la première et dont la face intérieure est pourvue de deux joncs diamétralement opposés 14a, 14b (fig. 3) s'étendant sur environ le quart de la circonférence de la face considérée. La seconde jupe 14 est entourée de deux demi-panneaux 15, 16 dont la longueur est inférieure à sa demi-circonférence. Chaque anneau est rendu solidaire de cette dernière par l'intermédiaire de deux tenons 17.18, 19.20 situés deux à deux en vis-à-vis l'un de l'autre et au-delà de chacun desquels chaque demi-anneau dépasse pour former un pied 15a, 15b respectivement 16a, 16b. Chaque demi-anneau comporte encore une oreille centrale 15c, 16c facilitant la préhension comme on l'expliquera mieux plus loin. Enfin le pourtour de la jupe 14 est relié au milieu de chaque anneau par un pontet 21, 22.The plug 4, preferably made of polypropylene, is provided with a skirt 12, the inner face of which is threaded, its bottom 4a which comprises an annular lip 13 disposed more in the center than the skirt 12, extending beyond the latter to carry a second skirt 14 coaxial with the first and the inner face of which is provided with two diametrically opposite rods 14a, 14b (fig. 3) extending over approximately a quarter of the circumference of the face considered. The second skirt 14 is surrounded by two half-panels 15, 16 whose length is less than its half-circumference. Each ring is made integral with the latter by means of two tenons 17.18, 19.20 located two by two opposite one another and beyond each of which each half-ring projects to form a foot 15a, 15b respectively 16a, 16b. Each half-ring also has a central ear 15c, 16c facilitating gripping as will be explained better below. Finally, the periphery of the skirt 14 is connected to the middle of each ring by a bridge 21, 22.

En vue de son montage par rapport au récipient 1 l'assemblage du verseur s'effectue tout d'abord en engageant le bec dans l'embase 2 par son extrémité qui porte le filetage 9, cette opération s'effectuant à partir du dessous par rapport à la cheminée 5b. Le bouchon 4 est ensuite vissé à fond par rapport au filetage 9. Enfin le bec est escamoté de manière que le bouchon vienne se placer comme représenté en fig. 1 par rapport à l'embase 2. On a affaire à ce moment à un obturateur inviolable (fig. 4) dont les demi- anneaux 15, 16 reposent contre le dessus de la collerette 6. Lors du premier emploi, l'utilisateur saisit ensemble les deux oreilles 15c, 16c et agit sur elles pour faire pivoter les demi-anneaux dans le sens des flèches Fl, F2 (fig. 5) autour des pontets ce qui provoque d'abord la rupture des pontets d'inviolabilité 21, 22 puis la mise en contact de l'extrémité des pieds 15a, 15b, 16a, 16b avec le dessus de la collerette 6. Par suite de la qualité de la matière constituant le bouchon et de la dimension des tenons 17, 18, 19, 20 le soulèvement des anneaux au-delà de leur position correspondant au contact des pieds avec le dessus de la collerette 6 provoque le dégagement du bouchon par rapport aux joncs 14a, 14b par effet de levier de sorte que le bouchon se dégage de l'embase 2. Si l'utilisateur tire encore plus les deux demi-anneaux vers le haut il provoque la sortie du bec 3 jusqu'à ce que sa bride 10 vienne en contact avec le bord rabattu inférieur 5a de ladite embase (fig. 2). A ce moment le bec est axialement verrouillé entre le bourrelet 11 et la bride 10. Comme celle-ci comporte des saillies radiales 23 orientées vers l'extérieur (fig. 6), la rotation du bouchon encore solidaire angulairement du bec 3 amène ces saillies contre des butées 24 ménagées sous le bord inférieur de l'embase (flèche F3), ainsi le dévissage du bouchon peut s'effectuer facilement puisque le bec 3 devient fixe.In view of its mounting relative to the container 1, the pourer is assembled first by engaging the spout in the base 2 by its end which carries the thread 9, this operation being carried out from below by compared to the chimney 5b. The plug 4 is then screwed in completely with respect to the thread 9. Finally, the spout is retracted so that the plug comes to be placed as shown in FIG. 1 relative to the base 2. We are dealing at this time with a tamper-evident shutter (fig. 4) whose half-rings 15, 16 rest against the top of the flange 6. During the first use, the user grasps together the two ears 15c, 16c and acts on them to rotate the half-rings in the direction of the arrows Fl, F2 (fig. 5) around the bridges which firstly causes the tamper-evident bridges 21, 22 to break then bringing the ends of the feet 15a, 15b, 16a, 16b into contact with the above the collar 6. Owing to the quality of the material constituting the stopper and the size of the studs 17, 18, 19, 20 the lifting of the rings beyond their position corresponding to the contact of the feet with the top of the flange 6 causes the plug to be released relative to the rods 14a, 14b by leverage so that the plug is released from the base 2. If the user pulls the two half-rings even more upwards, it causes the outlet of the spout 3 until its flange 10 comes into contact with the lower folded edge 5a of said base (fig. 2). At this moment the spout is axially locked between the bead 11 and the flange 10. As the latter has radial projections 23 facing outwards (fig. 6), the rotation of the plug still angularly integral with the spout 3 brings these projections against stops 24 formed under the lower edge of the base (arrow F3), thus unscrewing the plug can be carried out easily since the spout 3 becomes fixed.

Après déversement du contenu du récipient lorsqu'on revisse le bouchon 4 sur le bec 3 celui-ci tourne dans le sens de la flèche F4 de manière que les saillies quittent les butées sur lesquelles elles sont en appui pour venir contre leurs voisines. On peut donc ainsi visser à fond le bouchon. Pour escamoter le bec il suffit d'appuyer sur le bouchon en direction du bas : la cheminée 5b se déforme légèrement au passage du bourrelet 11, enfin les joncs 14a, 14b viennent s'encliqueter sous le cordon 8 de l'embase. On notera qu'on prévoit avantageusement quatre saillies 23 et quatre butées 24.After the contents of the container have been spilled when the cap 4 is screwed back onto the spout 3, the latter rotates in the direction of the arrow F4 so that the projections leave the stops on which they are bearing to come against their neighbors. It is thus possible to screw the cap fully. To retract the spout, simply press the plug in the direction of the bottom: the chimney 5b deforms slightly when the bead 11 passes, finally the rods 14a, 14b snap under the cord 8 of the base. It will be noted that advantageously four projections 23 and four stops 24 are provided.

On notera la présence dans le fond du bouchon d'une seconde lèvre 26 (fig. 2) qui vient coopérer avec la périphérie intérieure du débouché 5c en vue d'assurer l'étanchéité lors du rebouchage aussi bien par rapport à l'intérieur de l'embase qu'à l'extérieur.Note the presence in the bottom of the cap of a second lip 26 (fig. 2) which comes to cooperate with the inner periphery of the outlet 5c in order to ensure sealing during the filling as well with respect to the interior of the base only outside.

On observe en fig. 6 la présence d'un croisillon 26 à l'intérieur du bec 3, son centre étant destiné à recevoir le point d'injection de l'élément en question.We observe in fig. 6 the presence of a spider 26 inside the spout 3, its center being intended to receive the point of injection of the element in question.

Il doit d'ailleurs être entendu que la description qui précède n'a été donnée qu'à titre d'exemple et qu'elle ne limite nullement le domaine de l'invention dont on ne sortirait pas en remplaçant les détails d'exécution décrits par tous autres équivalents.
de réactifs suivantes :

  • - 385,5 g d'orthochlorophénol
  • - 270 g d'urée
  • - 29,7 g de Cu2Cl2
It should moreover be understood that the above description has been given only by way of example and that it in no way limits the field of the invention from which one would not depart by replacing the execution details described by all other equivalents.
of the following reagents:
  • - 385.5 g of orthochlorophenol
  • - 270 g of urea
  • - 29.7 g of Cu 2 Cl 2

Au cours de la réaction, il se consomme 93 g de NH3. On obtient la benzoxazolone avec un R T de 67 % et un T T de 93,5 %.During the reaction, 93 g of NH 3 are consumed. Benzoxazolone is obtained with a RT of 67% and a TT of 93.5%.

Exemple 4Example 4

Dans un autoclave de 1,5 1, on charge :

  • - 257 g d'orthochlorophénol
  • - 300 g d'urée
  • - 19,8 g de Cu2Cl2
  • - 68,1 g de NH 3
In a 1.5 l autoclave, we load:
  • - 257 g of orthochlorophenol
  • - 300 g of urea
  • - 19.8 g of Cu 2 Cl 2
  • - 68.1 g of N H 3

On chauffe à 170° C pendant 8 heures ; la pression s'établit initialement à 26 bars, puis descend progressivement jusqu'à 10 bars en fin de réaction. On refroidit à 120°C, dégaze, puis on coule lentement 30 g d'eau et chauffe 2 heures à 140°C, puis 2 heures à 150°C tout en distillant. à pression atmosphérique. Après traitement, comme à l'exemple 1, on obtient la benzoxazolone avec un R T de 70 % et un T T de 96 %.The mixture is heated at 170 ° C for 8 hours; the pressure is initially established at 26 bars, then gradually drops to 10 bars at the end of the reaction. Cool to 120 ° C, degas, then pour slowly 30 g of water and heat for 2 hours at 140 ° C, then 2 hours at 150 ° C while distilling. at atmospheric pressure. After treatment, as in Example 1, the benzoxazolone is obtained with an R T of 70% and a T T of 96%.

Exemple 5Example 5

On reproduit l'exemple 4, mais avec 9,9'g de Cu2Cl2 (au lieu de 19,8 g) ; on'obtient ainsi la benzoxazolone avec un R T de 70,5 % et un T_T de 80,5 %.Example 4 is repeated, but with 9.9 g of Cu 2 Cl 2 (instead of 19.8 g); benzoxazolone is thus obtained with a RT of 70.5% and a T_T of 80.5%.

Exemple 6Example 6

Dans un autoclave en acier inoxydable de 1 1 muni d'un système d'agitation, on charge :

  • - 102,8 g d'orthochlorophénol
  • - 240 g d'urée
  • - 7,92 g de Cu2Cl2
In a 1 1 stainless steel autoclave equipped with a stirring system, the following are loaded:
  • - 102.8 g of orthochlorophenol
  • - 240 g of urea
  • - 7.92 g of Cu 2 Cl 2

On ferme l'autoclave,purge à l'aide de NH3 et on charge 51 g de NH3. On chauffe à 170°C pendant 8 heures. La pression se stabilise initialement à 38 bars (pression relative) puis descend progressivement jusqu'à 24 bars en fin de réaction. ce que le jonc (11) vient se placer au-dessus de la lèvre d'étanchéité ou cheminée (5b) de l'embase (2).

  • 6. Ensemble verseur suivant l'une quelconque des revendications 1 à 5, caractérisé en ce que le verseur (3) comporte des moyens (23, 24) de l'immobiliser angulairement en position sortie par rapport à l'embase (2).
  • 7. Ensemble verseur suivant la revendication 6, caractérisé en ce que les moyens d'immobilisation angulaire sont constitués par au moins un tenon (23) qui dépasse radialement au-delà de la périphérie de la bride (10) du verseur tubulaire (3) et par une butée (24) solidaire de l'embase (2) et contre laquelle le tenon (23) vient porter lorsqu'on visse ou qu'on dévisse le bouchon.
  • 8. Ensemble verseur suivant la revendication 7, caractérisé en ce qu'on prévoit quatre tenons (23) et quatre butées (24).
The autoclave is closed, purged using NH 3 and 51 g of NH 3 are charged. It is heated to 170 ° C for 8 hours. The pressure initially stabilizes at 38 bars (relative pressure) then gradually decreases to 24 bars at the end of the reaction. what the rod (11) is placed above the sealing lip or chimney (5b) of the base (2).
  • 6. pourer assembly according to any one of claims 1 to 5, characterized in that the pourer (3) comprises means (23, 24) to immobilize it angularly in the extended position relative to the base (2).
  • 7. Pouring assembly according to claim 6, characterized in that the angular immobilization means consist of at least one stud (23) which protrudes radially beyond the periphery of the flange (10) of the tubular pourer (3) and by a stop (24) integral with the base (2) and against which the lug (23) comes to bear when the screw is screwed on or unscrewed.
  • 8. Pouring assembly according to claim 7, characterized in that four pins (23) and four stops (24) are provided.

On purge à l'azote et chauffe 8 heures à 170°C. L'atmosphère sous pression d'ammoniac est ainsi obtenue par décomposition de l'urée en présence d'eau. Cette pression s'établit à 40 bars et se maintient à cette valeur. On refroidit, dégaze l'autoclave, on chauffe tout en distillant à pression atmosphérique 2 heures à 130°C puis 2 heures à 150°C. Après traitements habituels, on obtient la benzoxazolone avec un R T de 57,5 % et un T T de 95 %.It is purged with nitrogen and heated for 8 hours at 170 ° C. The atmosphere under ammonia pressure is thus obtained by decomposition of urea in the presence of water. This pressure is established at 40 bars and is maintained at this value. Cooled, degassed the autoclave, heated while distilling at atmospheric pressure for 2 hours at 130 ° C. then 2 hours at 150 ° C. After usual treatments, benzoxazolone is obtained with an R T of 57.5% and a T T of 95%.

Exemple 10Example 10

Dans un autoclave de 140cm3 revêtu intérieurement de poly- tétrafluoroéthylène, on charge :

  • - 24 g d'orthochlorophénol
  • - 28 g d'urée
  • - 2,5 g de CuC12
  • - 6,35 g de NH3.
In an autoclave of 140 cm 3 coated on the inside with polytetrafluoroethylene, we load:
  • - 24 g of orthochlorophenol
  • - 28 g of urea
  • - 2.5 g of CuC1 2
  • - 6.35 g of NH 3 .

On ferme l'autoclave, purge à l'aide de NH3. On chauffe à 170°C pendant 6 heures. La pression se stabilise initialement à environ 26 bars (pression relative) puis descend progressivement jusqu'à environ 10 bars en fin de réaction. On refroidit à 120°C, ouvre l'autoclave, et transfère le contenu de l'autoclave dans un ballon de 250cm3 sous pression atmosphérique muni d'un système de distillation semblable à celui de l'exemple 1. Dans ce ballon on ajoute lentement 3 cm3 d'eau ; on chauffe alors 2 h. à 14O°C puis 2 h. à 150°C en ajoutant régulièrement de l'eau à raison de 4,5 cm3/h tout au long de la distillation. On refroidit à nouveau à 120°C, ajoute 80 cm3 d'eau, refroidit à 20°C, ajoute 15cm3 d'une solution aqueuse d'acide sulfurique 6 N, ajoute 50 cm3 d'acétate d'éthyle. On décante et sépare la phase aqueuse qu'on lave à l'aide d'acétate d'éthyle. Dans la phase organique on obtient de la benzoxazolone avec un RT de 30 % et un T T de 80 %.The autoclave is closed and purged using NH 3 . The mixture is heated at 170 ° C for 6 hours. The pressure initially stabilizes at around 26 bars (relative pressure) and then gradually drops to around 10 bars at the end of the reaction. Cool to 120 ° C., open the autoclave, and transfer the contents of the autoclave to a 250 cm 3 flask at atmospheric pressure fitted with a distillation system similar to that of Example 1. To this flask is added slowly 3 cm 3 of water; it is then heated for 2 hours. at 140 ° C and then 2 h. at 150 ° C by regularly adding water at the rate of 4.5 cm 3 / h throughout the distillation. Cool again to 120 ° C, add 80 cm 3 of water, cool to 20 ° C, add 15 cm 3 of a 6N aqueous sulfuric acid solution, add 50 cm 3 of ethyl acetate. The aqueous phase is decanted and separated, which is washed with ethyl acetate. In the organic phase, benzoxazolone is obtained with a RT of 30% and a TT of 80%.

On a également obtenu la benzoxazolone en présence de Fe C12, NiCl2 et Ni.Benzoxazolone was also obtained in the presence of Fe C1 2 , NiCl 2 and Ni.

Claims (1)

1.1.
EP19800420048 1979-04-27 1980-04-25 Retractable pouring units Expired EP0018930B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR7911672A FR2454974A1 (en) 1979-04-27 1979-04-27 IMPROVEMENTS ON RETRACTABLE POURING ASSEMBLIES
FR7911672 1979-04-27

Publications (2)

Publication Number Publication Date
EP0018930A1 true EP0018930A1 (en) 1980-11-12
EP0018930B1 EP0018930B1 (en) 1983-06-22

Family

ID=9225211

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19800420048 Expired EP0018930B1 (en) 1979-04-27 1980-04-25 Retractable pouring units

Country Status (3)

Country Link
EP (1) EP0018930B1 (en)
DE (1) DE3063845D1 (en)
FR (1) FR2454974A1 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60182352U (en) * 1984-05-14 1985-12-03 青山　恵一 Can lid structure
US4632282A (en) * 1984-03-02 1986-12-30 Hirohisa Nagashima Spout assembly
DE4041831A1 (en) * 1990-12-24 1992-07-02 Stolz Heinrich Gmbh Closure for filling openings closed by screw cap - is pressed axially from above onto filler pipe
AT403568B (en) * 1996-03-26 1998-03-25 Gebro Broschek Gmbh ATTACHMENT OF A DISPENSING HEAD TO A BOTTLE CONTAINING A DISINFECTANT LIQUID, AND INTERMEDIATE PIECE FOR SUCH A FASTENING
WO2014197959A1 (en) * 2013-06-11 2014-12-18 Brasilata S/A Embalagens Metálicas Closure device for cans

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2502721A1 (en) * 1981-03-30 1982-10-01 Aerosol Inventions Dev Sleeve seal for fitting in neck of bottle - has cylindrical sleeve with open top hat cross section giving one plane and two cylindrical sealing faces
AU577050B2 (en) * 1983-06-27 1988-09-15 Van Leer S.A. (Proprietary) Limited Combined closure and pouring spout
FR2580259B1 (en) * 1985-04-15 1988-01-08 Shell Francaise Sa PORTABLE BOTTLE DOSER

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE640364A (en) * 1962-11-26 1964-03-16
FR1473766A (en) * 1966-04-05 1967-03-17 Leer Ind Ltd Van Closing device for drums or similar containers
FR2142571A1 (en) * 1971-06-21 1973-02-02 Rieke Corp
FR2239391A1 (en) * 1973-08-01 1975-02-28 Rieke Corp
FR2295890A1 (en) * 1974-12-28 1976-07-23 Stolz Heinrich CLOSURE FOR TANK SAMPLING HOLES
FR2358335A1 (en) * 1976-07-12 1978-02-10 Stolz Heinrich CLOSING DEVICE FOR THE SAMPLING ORIFICE OF A CONTAINER
US4076151A (en) * 1975-02-19 1978-02-28 Polyproducts Corporation Combined sealing and pouring spout assembly
FR2413283A1 (en) * 1977-12-30 1979-07-27 Astra Plastique Closure, for oil cans - has different hand screw threading pourer and lid and fixed ring acting as seal
NL7907330A (en) * 1978-10-02 1980-04-08 American Flange & Mfg VAT CLOSURE.

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE640364A (en) * 1962-11-26 1964-03-16
FR1473766A (en) * 1966-04-05 1967-03-17 Leer Ind Ltd Van Closing device for drums or similar containers
FR2142571A1 (en) * 1971-06-21 1973-02-02 Rieke Corp
FR2239391A1 (en) * 1973-08-01 1975-02-28 Rieke Corp
FR2295890A1 (en) * 1974-12-28 1976-07-23 Stolz Heinrich CLOSURE FOR TANK SAMPLING HOLES
US4076151A (en) * 1975-02-19 1978-02-28 Polyproducts Corporation Combined sealing and pouring spout assembly
FR2358335A1 (en) * 1976-07-12 1978-02-10 Stolz Heinrich CLOSING DEVICE FOR THE SAMPLING ORIFICE OF A CONTAINER
FR2413283A1 (en) * 1977-12-30 1979-07-27 Astra Plastique Closure, for oil cans - has different hand screw threading pourer and lid and fixed ring acting as seal
NL7907330A (en) * 1978-10-02 1980-04-08 American Flange & Mfg VAT CLOSURE.
DE2940119A1 (en) * 1978-10-02 1980-04-10 American Flange & Mfg Nestable foundry arrangement
GB2032878A (en) * 1978-10-02 1980-05-14 American Flange & Mfg Collapsible pouring spouts

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4632282A (en) * 1984-03-02 1986-12-30 Hirohisa Nagashima Spout assembly
JPS60182352U (en) * 1984-05-14 1985-12-03 青山　恵一 Can lid structure
DE4041831A1 (en) * 1990-12-24 1992-07-02 Stolz Heinrich Gmbh Closure for filling openings closed by screw cap - is pressed axially from above onto filler pipe
AT403568B (en) * 1996-03-26 1998-03-25 Gebro Broschek Gmbh ATTACHMENT OF A DISPENSING HEAD TO A BOTTLE CONTAINING A DISINFECTANT LIQUID, AND INTERMEDIATE PIECE FOR SUCH A FASTENING
WO2014197959A1 (en) * 2013-06-11 2014-12-18 Brasilata S/A Embalagens Metálicas Closure device for cans

Also Published As

Publication number Publication date
FR2454974A1 (en) 1980-11-21
EP0018930B1 (en) 1983-06-22
DE3063845D1 (en) 1983-07-28
FR2454974B1 (en) 1983-12-16

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