EA201791445A1 - Способы получения олигомеров олефина - Google Patents

Способы получения олигомеров олефина

Info

Publication number
EA201791445A1
EA201791445A1 EA201791445A EA201791445A EA201791445A1 EA 201791445 A1 EA201791445 A1 EA 201791445A1 EA 201791445 A EA201791445 A EA 201791445A EA 201791445 A EA201791445 A EA 201791445A EA 201791445 A1 EA201791445 A1 EA 201791445A1
Authority
EA
Eurasian Patent Office
Prior art keywords
olefin
methods
olegomers
obtaining
composition
Prior art date
Application number
EA201791445A
Other languages
English (en)
Other versions
EA033241B1 (ru
Inventor
Тимур Михайлович ЗИЛЬБЕРШТЕЙН
Денис Алексеевич Ленев
Original Assignee
Публичное акционерное общество "СИБУР Холдинг"
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Публичное акционерное общество "СИБУР Холдинг" filed Critical Публичное акционерное общество "СИБУР Холдинг"
Publication of EA201791445A1 publication Critical patent/EA201791445A1/ru
Publication of EA033241B1 publication Critical patent/EA033241B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/04—Ethylene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/107—Alkenes with six carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
    • C07C2531/34—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24 of chromium, molybdenum or tungsten

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Предлагаются способы получения олигомеров олефина. Способы могут включать получение композиции, которая включает алкилалюминиевое соединение, соединение хрома и углеводородный растворитель. Углеводородный растворитель может включать н-ундекан, C-C-алкановое соединение, имеющее одно разветвление, или соответствующую смесь. Способы могут дополнительно включать введение в контакт олефина с композицией для образования олигомеров олефина. Олефин может включать этилен, и олигомеры олефина могут включать 1-гексен.
EA201791445A 2014-12-23 2014-12-23 Способы получения олигомеров олефина EA033241B1 (ru)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/RU2014/000974 WO2016105228A1 (en) 2014-12-23 2014-12-23 Methods of preparing oligomers of an olefin

Publications (2)

Publication Number Publication Date
EA201791445A1 true EA201791445A1 (ru) 2017-10-31
EA033241B1 EA033241B1 (ru) 2019-09-30

Family

ID=53801142

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201791445A EA033241B1 (ru) 2014-12-23 2014-12-23 Способы получения олигомеров олефина

Country Status (12)

Country Link
US (1) US10099970B2 (ru)
EP (1) EP3237363B1 (ru)
JP (1) JP6594429B2 (ru)
KR (1) KR102121038B1 (ru)
CN (1) CN107207384B (ru)
CA (1) CA2971698C (ru)
DK (1) DK3237363T3 (ru)
EA (1) EA033241B1 (ru)
HR (1) HRP20190950T1 (ru)
MX (1) MX2017008376A (ru)
WO (1) WO2016105228A1 (ru)
ZA (1) ZA201704088B (ru)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016105227A1 (en) 2014-12-23 2016-06-30 Public Joint Stock Company "Sibur Holding" Methods of preparing oligomers of an olefin
WO2016105226A1 (en) 2014-12-23 2016-06-30 Public Joint Stock Company "Sibur Holding" Methods of precipitating polymer and deactivated organometallic catalyst in an olefin oligomerization reaction
EA201990746A1 (ru) * 2016-11-14 2019-10-31 Каталитическая система, используемая в процессе олигомеризации олефинов и способ олигомеризации олефинов
WO2018116173A1 (en) * 2016-12-19 2018-06-28 Sabic Global Technologies B.V. Method of treating a hydrocarbon stream
KR102581907B1 (ko) * 2018-01-02 2023-09-22 에스케이이노베이션 주식회사 파라핀을 제조하는 방법
FR3112969B1 (fr) * 2020-07-30 2022-08-05 Ifp Energies Now Nouvelle composition catalytique a base de chrome et procede associe pour la trimerisation de l’ethylene en hexene-1

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FR1308672A (fr) 1961-09-26 1962-11-09 Ethyl Corp Procédé de fabrication d'hydrocarbures normalement liquides du type des alphaoléfines
JPS5017442B1 (ru) * 1968-06-19 1975-06-20
JPH06157654A (ja) * 1992-11-24 1994-06-07 Mitsubishi Kasei Corp α−オレフィンの低重合方法
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US5543375A (en) 1994-02-18 1996-08-06 Phillips Petroleum Company Olefin production
JP3766170B2 (ja) * 1996-03-14 2006-04-12 三菱化学株式会社 α−オレフィン低重合体の製造方法
WO1997033924A1 (fr) 1996-03-14 1997-09-18 Mitsubishi Chemical Corporation PROCEDE DE PRODUCTION D'OLIGOMERS D'α-OLEFINES
JP3881418B2 (ja) * 1996-03-15 2007-02-14 三菱化学株式会社 α−オレフィン低重合体の製造方法
US20020182124A1 (en) 1997-10-14 2002-12-05 William M. Woodard Olefin production process
JP2002172327A (ja) * 2000-12-05 2002-06-18 Tosoh Corp エチレンの三量化触媒及びこの触媒を用いたエチレンの三量化方法
BRPI0316870B1 (pt) * 2002-12-20 2019-10-08 Sasol Technology (Pty) Ltd. Trimerização de olefinas
US9272961B2 (en) 2006-12-27 2016-03-01 Mitsubishi Chemical Corporation Production method of polyolefin, polyolefin and 1-hexene for linear low density polyethylene production raw material
RU2430116C1 (ru) * 2010-01-29 2011-09-27 Закрытое Акционерное Общество "Сибур Холдинг" Способ полимеризации и сополимеризации олефиновых олигомеров
US8658750B2 (en) * 2010-03-09 2014-02-25 Exxonmobil Chemical Patents Inc. System and method for selective trimerization
CN102781884B (zh) * 2010-03-26 2015-11-25 三菱化学株式会社 α-烯烃低聚物的制造方法
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WO2016105226A1 (en) 2014-12-23 2016-06-30 Public Joint Stock Company "Sibur Holding" Methods of precipitating polymer and deactivated organometallic catalyst in an olefin oligomerization reaction
WO2016105227A1 (en) 2014-12-23 2016-06-30 Public Joint Stock Company "Sibur Holding" Methods of preparing oligomers of an olefin

Also Published As

Publication number Publication date
ZA201704088B (en) 2018-11-28
KR102121038B1 (ko) 2020-06-09
CN107207384A (zh) 2017-09-26
KR20170097746A (ko) 2017-08-28
CN107207384B (zh) 2021-03-23
DK3237363T3 (da) 2019-06-24
CA2971698A1 (en) 2016-06-30
EP3237363A1 (en) 2017-11-01
HRP20190950T1 (hr) 2019-08-23
EP3237363B1 (en) 2019-05-01
MX2017008376A (es) 2018-04-11
CA2971698C (en) 2019-08-13
WO2016105228A1 (en) 2016-06-30
US10099970B2 (en) 2018-10-16
JP6594429B2 (ja) 2019-10-23
EA033241B1 (ru) 2019-09-30
JP2018501267A (ja) 2018-01-18
US20170355652A1 (en) 2017-12-14

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