EA201171319A1 - Полиметаллический катализатор гидроконверсии и способ его получения - Google Patents

Полиметаллический катализатор гидроконверсии и способ его получения

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Publication number
EA201171319A1
EA201171319A1 EA201171319A EA201171319A EA201171319A1 EA 201171319 A1 EA201171319 A1 EA 201171319A1 EA 201171319 A EA201171319 A EA 201171319A EA 201171319 A EA201171319 A EA 201171319A EA 201171319 A1 EA201171319 A1 EA 201171319A1
Authority
EA
Eurasian Patent Office
Prior art keywords
catalyst
range
catalyst precursor
volumetric shrinkage
sulfiding
Prior art date
Application number
EA201171319A
Other languages
English (en)
Other versions
EA021708B1 (ru
Inventor
Александр И. Куперман
Теодорус Маэсен
Дэннис Дайкстра
Сой Укунг
Даррен Фонг
Original Assignee
Шеврон Ю.Эс.Эй. Инк.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/432,721 external-priority patent/US7964525B2/en
Priority claimed from US12/432,727 external-priority patent/US8058203B2/en
Priority claimed from US12/432,728 external-priority patent/US7964526B2/en
Priority claimed from US12/432,730 external-priority patent/US8080492B2/en
Priority claimed from US12/432,719 external-priority patent/US7964524B2/en
Priority claimed from US12/432,723 external-priority patent/US7931799B2/en
Application filed by Шеврон Ю.Эс.Эй. Инк. filed Critical Шеврон Ю.Эс.Эй. Инк.
Publication of EA201171319A1 publication Critical patent/EA201171319A1/ru
Publication of EA021708B1 publication Critical patent/EA021708B1/ru

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • C07F15/045—Nickel compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • C10G49/04—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing nickel, cobalt, chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Предложены катализатор с низкой объемной усадкой и способ получения стойкого катализатора с низкой объемной усадкой. Катализатор получают сульфидированием предшественника катализатора, содержащего по меньшей мере одно соединение металла группы VIB; по меньшей мере одно соединение металла-промотора, выбранное из групп VIII, IIB, IIA, IVA и их сочетаний и имеющее степень окисления либо +2, либо +4; возможно, по меньшей мере один лигандообразующий агент; возможно, по меньшей мере, один разбавитель. В одном примере осуществления предшественник катализатора сначала подвергают формованию, а затем термической обработке до температуры в диапазоне от 50 до 200°С в течение времени от 15 мин до 12 ч, причем предшественник катализатора имеет низкую (менее 12%) объемную усадку после нагревания до температуры не менее 100°С в течение по меньшей мере 30 мин, например, при сульфидировании или в реакторе гидроочистки. В одном примере осуществления предшественник катализатора имеет мономодальное распределение по объему пор, по меньшей мере 90% пор являются макропорами, и суммарный объем пор составляет не менее 0,08 г/см. В другом примере осуществления катализатор пригоден для гидроочистки тяжелого дистиллята, имеющего температуру кипения в диапазоне от 343 до 454°С, средний молекулярный вес Mn в диапазоне от 300 до 400 и средний молекулярный диаметр в диапазоне от 0,9 до 1,7 нм.
EA201171319A 2009-04-29 2010-04-08 Полиметаллический катализатор гидроконверсии и способ его получения EA021708B1 (ru)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US12/432,721 US7964525B2 (en) 2009-04-29 2009-04-29 Hydroconversion multi-metallic catalyst and method for making thereof
US12/432,727 US8058203B2 (en) 2009-04-29 2009-04-29 Hydroconversion multi-metallic catalyst and method for making thereof
US12/432,728 US7964526B2 (en) 2009-04-29 2009-04-29 Hydroconversion multi-metallic catalyst and method for making thereof
US12/432,730 US8080492B2 (en) 2009-04-29 2009-04-29 Hydroconversion multi-metallic catalyst and method for making thereof
US12/432,719 US7964524B2 (en) 2009-04-29 2009-04-29 Hydroconversion multi-metallic catalyst and method for making thereof
US12/432,723 US7931799B2 (en) 2009-04-29 2009-04-29 Hydroconversion multi-metallic catalyst and method for making thereof
PCT/US2010/030326 WO2010126689A2 (en) 2009-04-29 2010-04-08 Hydroconversion multi-metallic catalyst and method for making thereof

Publications (2)

Publication Number Publication Date
EA201171319A1 true EA201171319A1 (ru) 2012-04-30
EA021708B1 EA021708B1 (ru) 2015-08-31

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Family Applications (3)

Application Number Title Priority Date Filing Date
EA201171319A EA021708B1 (ru) 2009-04-29 2010-04-08 Полиметаллический катализатор гидроконверсии и способ его получения
EA201171320A EA020644B1 (ru) 2009-04-29 2010-04-08 Полиметаллический катализатор для гидропереработки и способ его получения
EA201171321A EA020199B1 (ru) 2009-04-29 2010-04-08 Полиметаллический катализатор гидроконверсии и способ его получения

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EA201171320A EA020644B1 (ru) 2009-04-29 2010-04-08 Полиметаллический катализатор для гидропереработки и способ его получения
EA201171321A EA020199B1 (ru) 2009-04-29 2010-04-08 Полиметаллический катализатор гидроконверсии и способ его получения

Country Status (9)

Country Link
EP (3) EP2424663B1 (ru)
JP (3) JP5759452B2 (ru)
KR (2) KR101722491B1 (ru)
CN (3) CN102413932B (ru)
AU (3) AU2010241966B2 (ru)
CA (3) CA2760413C (ru)
EA (3) EA021708B1 (ru)
SG (3) SG175405A1 (ru)
WO (3) WO2010126690A2 (ru)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017106125A1 (en) * 2015-12-15 2017-06-22 Uop Llc Crystalline bis-ammonia transition metal molybdotungstate

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EA021708B1 (ru) * 2009-04-29 2015-08-31 Шеврон Ю.Эс.Эй. Инк. Полиметаллический катализатор гидроконверсии и способ его получения
AU2011326682B2 (en) * 2010-11-11 2016-07-14 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
EP2654948A4 (en) * 2010-12-20 2015-02-11 Chevron Usa Inc HYDROPROCESSING CATALYSTS AND MANUFACTURING METHOD THEREFOR
JP6097224B2 (ja) * 2010-12-30 2017-03-15 シェブロン ユー．エス．エー． インコーポレイテッド 水素化処理触媒を作製するための方法
US10400181B2 (en) * 2015-12-15 2019-09-03 Uop Llc Crystalline bis-ammonia metal molybdate
US10233398B2 (en) * 2015-12-15 2019-03-19 Uop Llc Crystalline transition metal oxy-hydroxide molybdotungstate
IT201600077340A1 (it) * 2016-07-22 2018-01-22 Eni Spa Catalizzatori di idrotrattamento e procedimento di preparazione di detti catalizzatori.
US9919987B1 (en) * 2016-11-22 2018-03-20 Chevron U.S.A. Inc. Naphthene ring opening over self-supported multi-metallic catalysts
FR3058909B1 (fr) * 2016-11-24 2018-11-16 Arkema France Sels d'acide sulfonique pour la preparation de catalyseur metallique
JP6924288B2 (ja) 2017-10-18 2021-08-25 ヒンドゥスタン ペトロリアム コーポレーション リミテッド 重油のアップグレード用触媒
US10995013B2 (en) * 2017-12-20 2021-05-04 Uop Llc Mixed transition metal tungstate
US11033883B2 (en) * 2018-06-26 2021-06-15 Uop Llc Transition metal molybdotungstate material
US10737249B2 (en) * 2018-06-26 2020-08-11 Uop Llc Crystalline transition metal molybdotungstate
CN109759087B (zh) * 2019-01-16 2022-02-08 安徽大学 一种NiS/MgAl-LDH光催化剂及其制备方法和应用
CN109985639A (zh) * 2019-04-17 2019-07-09 河南师范大学 一种用原位构建的Pt/ZnS-rGO光催化剂及其制备氢气的方法

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2238851A (en) 1938-07-16 1941-04-15 Standard Catalytic Co Thermal treatment of carbonaceous materials
US5841013A (en) 1994-05-17 1998-11-24 Exxon Research And Engineering Company Aromatics hydrogenation with a new class of metal oxides
US5866501A (en) * 1996-02-23 1999-02-02 Pradhan; Vivek R. Dispersed anion-modified iron oxide catalysts for hydroconversion processes
US6030915A (en) 1996-03-11 2000-02-29 Akzo Nobel N.V. Process for preparing a large pore hydroprocessing catalyst
US7288182B1 (en) * 1997-07-15 2007-10-30 Exxonmobil Research And Engineering Company Hydroprocessing using bulk Group VIII/Group VIB catalysts
US6162350A (en) * 1997-07-15 2000-12-19 Exxon Research And Engineering Company Hydroprocessing using bulk Group VIII/Group VIB catalysts (HEN-9901)
US6156695A (en) 1997-07-15 2000-12-05 Exxon Research And Engineering Company Nickel molybdotungstate hydrotreating catalysts
FR2775200B1 (fr) * 1998-02-20 2000-04-28 Inst Francais Du Petrole Catalyseur comprenant une zeolithe nu-88, un element du groupe vb et son utilisation en hydroconversion de charges petrolieres hydrocarbonees
CN1309476C (zh) * 1999-01-15 2007-04-11 阿尔伯麦尔荷兰公司 新型混合金属催化剂及其用途
DE60134140D1 (de) 2000-07-12 2008-07-03 Albemarle Netherlands Bv Verfahren zur herstellung eines ein additiv enthaltenden mischmetallkatalysators
JP5201496B2 (ja) * 2000-07-12 2013-06-05 アルベマーレ ネザーランズ ビー．ブイ． 添加剤に基く混合金属触媒を調製する方法
US7790652B2 (en) * 2003-09-17 2010-09-07 Shell Oil Company Process and catalyst for the hydroconversion of a heavy hydrocarbon feedstock
RU2387480C2 (ru) * 2004-09-08 2010-04-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Композиция катализатора гидрокрекинга
FR2874837B1 (fr) * 2004-09-08 2007-02-23 Inst Francais Du Petrole Catalyseur dope et procede ameliore de traitement de charges hydrocarbonees
EP1791639A1 (en) * 2004-09-22 2007-06-06 Exxonmobil Research And Engineering Company BULK Ni-Mo-W CATALYSTS MADE FROM PRECURSORS CONTAINING AN ORGANIC AGENT
ES2511771T3 (es) * 2005-10-26 2014-10-23 Albemarle Netherlands B.V. Catalizador para hidroprocesamiento a granel que comprende un metal del grupo VIII y el metal del grupo VIB molibdeno
WO2007070394A2 (en) * 2005-12-14 2007-06-21 Advanced Refining Technologies Llc Method of making hydroprocessing catalyst
CN101516500A (zh) * 2006-08-03 2009-08-26 国际壳牌研究有限公司 含有钼和第ⅷ族金属的催化剂及其用于加氢脱硫氢馏分油的用途
US7951746B2 (en) * 2006-10-11 2011-05-31 Exxonmobil Research And Engineering Company Bulk group VIII/group VIB metal catalysts and method of preparing same
AU2008318836B2 (en) 2007-10-31 2013-04-04 Chevron U.S.A. Inc. Hydroconversion processes employing multi-metallic catalysts and method for making thereof
CA2703137C (en) * 2007-10-31 2016-05-24 Chevron U.S.A. Inc. Hydroprocessing bulk catalyst and uses thereof
EA021708B1 (ru) * 2009-04-29 2015-08-31 Шеврон Ю.Эс.Эй. Инк. Полиметаллический катализатор гидроконверсии и способ его получения

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017106125A1 (en) * 2015-12-15 2017-06-22 Uop Llc Crystalline bis-ammonia transition metal molybdotungstate
RU2699797C1 (ru) * 2015-12-15 2019-09-11 Юоп Ллк Кристаллический бис-аммиачный молибдовольфрамат переходного металла

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