EA200600430A1 - Способ получения углеводородов из диоксида углерода - Google Patents

Способ получения углеводородов из диоксида углерода

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Publication number
EA200600430A1
EA200600430A1 EA200600430A EA200600430A EA200600430A1 EA 200600430 A1 EA200600430 A1 EA 200600430A1 EA 200600430 A EA200600430 A EA 200600430A EA 200600430 A EA200600430 A EA 200600430A EA 200600430 A1 EA200600430 A1 EA 200600430A1
Authority
EA
Eurasian Patent Office
Prior art keywords
sub
carbon dioxide
hydrocarbons
sup
fuels
Prior art date
Application number
EA200600430A
Other languages
English (en)
Other versions
EA008700B1 (ru
Inventor
Чавдар Ангелов Ангелов
Original Assignee
Чавдар Ангелов Ангелов
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Чавдар Ангелов Ангелов filed Critical Чавдар Ангелов Ангелов
Publication of EA200600430A1 publication Critical patent/EA200600430A1/ru
Publication of EA008700B1 publication Critical patent/EA008700B1/ru

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/12—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon dioxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/50—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon dioxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/85—Chromium, molybdenum or tungsten
    • C07C2523/88—Molybdenum
    • C07C2523/881—Molybdenum and iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C07C2527/16—Phosphorus; Compounds thereof containing oxygen
    • C07C2527/167—Phosphates or other compounds comprising the anion (PnO3n+1)(n+2)-

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

Способ относится к области производства топлив и сырья для производства химической продукции. Он является экономически эффективным способом получения углеводородов из диоксида углерода в промышленных условиях с повышением выхода углеводородов, в том числе и жидких C-С, являющихся основными компонентами моторных топлив. Способ включает стадию получения диоксида углерода путем его адсорбции этаноламином из дымовых газов с последующей десорбцией и смешением с Нв объемном соотношении, равном 4, с последующим компримированием до давления 35-50 атм, нагревом до 300-350°С и пропусканием через катализатор с объемной скоростью 1500 h. Катализатор содержит в мас.%: Fe 40-45%, Мо 1,0-2,5%, K 1,0-1,5%, а в качестве носителя используют комбинацию алюминия, циркония, их оксидов и фосфатов. Есть возможность подвергнуть газообразные углеводороды, получаемые в процессе гидрирования диоксида углерода, каталитической ароматизации. Есть возможность газовую смесь Ни СОи катализатор в процессе гидрирования диоксида углерода на первой стадии подвергнуть воздействию модулированными высокочастотными полями в частотном диапазоне от 1 до 50 МГц с частотой модуляции в диапазоне от 1 до 200 кГц, а на второй стадии подвергнуть воздействию плазмой одноэлектродных высокочастотных разрядов в верхней и средней частях реактора.
EA200600430A 2005-07-29 2006-03-16 Способ получения углеводородов из диоксида углерода EA008700B1 (ru)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BG109246A BG109246A (bg) 2005-07-29 2005-07-29 Метод за получаване на въглеводороди от въглероден диоксид

Publications (2)

Publication Number Publication Date
EA200600430A1 true EA200600430A1 (ru) 2007-02-27
EA008700B1 EA008700B1 (ru) 2007-06-29

Family

ID=35614577

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200600430A EA008700B1 (ru) 2005-07-29 2006-03-16 Способ получения углеводородов из диоксида углерода

Country Status (7)

Country Link
EP (1) EP1960496B1 (ru)
AT (1) ATE461987T1 (ru)
BG (1) BG109246A (ru)
DE (1) DE602006013187D1 (ru)
EA (1) EA008700B1 (ru)
UA (1) UA78656C2 (ru)
WO (1) WO2007012150A1 (ru)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2115098A2 (en) 2007-02-09 2009-11-11 Dale R. Lutz Reliable carbon-neutral power generation system
US9557057B2 (en) 2007-02-09 2017-01-31 Dale Robert Lutz Reliable carbon-neutral power generation system
CN107837818B (zh) * 2016-09-19 2020-06-09 中国科学院大连化学物理研究所 一种二氧化碳加氢直接制取汽油馏分烃的方法
CN109626486B (zh) * 2018-12-29 2020-07-28 西安交通大学 一种耦合处理高浓度有机废水和重金属废水的方法
CN114455585B (zh) * 2022-02-16 2024-01-16 青海师范大学 一种吸附空气中二氧化碳的方法
CN117019151B (zh) * 2023-07-05 2024-04-12 珠海市福沺能源科技有限公司 一种二氧化碳加氢的空腔微球催化剂及其制备方法和应用

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB709645A (en) * 1951-06-30 1954-06-02 Rheinpreussen Ag A process for the conversion of carbon dioxide with hydrogen
JPS6023330A (ja) * 1983-07-15 1985-02-05 Daido Sanso Kk 炭化水素の製造方法
US5140049A (en) * 1985-10-25 1992-08-18 Exxon Research And Engineering Co. Method for producing olefins from H2 and CO2 using an iron carbide based catalyst
DE4220865A1 (de) * 1991-08-15 1993-02-18 Asea Brown Boveri Verfahren und vorrichtung zur hydrierung von kohlendioxid
DE69233766D1 (de) * 1991-10-09 2009-09-03 Kansai Electric Power Co Rückgewinnung von Kohlendioxid aus Verbrennungsabgas
RU2089533C1 (ru) * 1994-07-04 1997-09-10 Конструкторско-технологический институт каталитических и адсорбционных процессов на цеолитах "Цеосит" СО РАН Способ получения углеводородов бензиновых фракций
KR0169188B1 (ko) * 1995-07-31 1999-03-20 강박광 탄화수소의 제조방법
CN1260823A (zh) * 1997-06-18 2000-07-19 埃克森化学专利公司 用改性的分子筛将合成气转化成低碳烯烃的方法
KR100351625B1 (ko) * 1999-11-11 2002-09-11 한국화학연구원 탄화수소 제조용 촉매
RU2205171C1 (ru) * 2001-10-16 2003-05-27 Королева Наталия Владиславовна Способ получения длинноцепочечных углеводородов из co и h2 в жидкой фазе
DE10156975A1 (de) * 2001-11-20 2003-06-05 Stefan Geyer Verfahren zur Herstellung von Kohlenwasserstoffen

Also Published As

Publication number Publication date
UA78656C2 (en) 2007-04-10
ATE461987T1 (de) 2010-04-15
EP1960496B1 (en) 2010-03-24
EA008700B1 (ru) 2007-06-29
DE602006013187D1 (de) 2010-05-06
BG109246A (bg) 2005-11-30
EP1960496A1 (en) 2008-08-27
WO2007012150A1 (en) 2007-02-01

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