EA200500780A1 - Получение углеводородов - Google Patents

Получение углеводородов

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Publication number
EA200500780A1
EA200500780A1 EA200500780A EA200500780A EA200500780A1 EA 200500780 A1 EA200500780 A1 EA 200500780A1 EA 200500780 A EA200500780 A EA 200500780A EA 200500780 A EA200500780 A EA 200500780A EA 200500780 A1 EA200500780 A1 EA 200500780A1
Authority
EA
Eurasian Patent Office
Prior art keywords
gas
reforming
steam
stream
hydrocarbons
Prior art date
Application number
EA200500780A
Other languages
English (en)
Other versions
EA006869B1 (ru
Inventor
Питер Эдвард Джеймс Эбботт
Мартин Фаулес
Original Assignee
Джонсон Мэтти Плс
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Джонсон Мэтти Плс filed Critical Джонсон Мэтти Плс
Publication of EA200500780A1 publication Critical patent/EA200500780A1/ru
Publication of EA006869B1 publication Critical patent/EA006869B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1247—Higher hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/146—At least two purification steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/146—At least two purification steps in series
    • C01B2203/147—Three or more purification steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Описан способ получения углеводородов, содержащий a) паровой реформинг вводимого углеводородного сырья (10) путем разделения сырья на первый (12) и второй (13) потоки, смешивания первого потока с паром (16), пропускания смеси первого потока и пара над катализатором, расположенным в нагреваемых трубках в теплообменной установке для реформинга (28) с образованием газа первичного реформинга (30), формирования потока подаваемого сырья в установку вторичного реформинга (40), содержащего газ первичного реформинга и второй углеводородный поток, частичного сжигания потока подаваемого сырья в установку вторичного реформинга кислородсодержащим газом (44) и приведения полученного газа после частичного сжигания к равновесию над катализатором вторичного реформинга и использования полученного газа вторичного реформинга (48) для нагрева трубок теплообменной установки для реформинга с образованием частично охлажденного газа после реформинга, b) дополнительное охлаждение частично охлажденного газа после реформинга ниже точки росы пара для конденсации воды и отделение конденсированной воды (56) с получением обезвоженного синтез-газа (58), c) синтез углеводородов из указанного обезвоженного синтез-газа по реакции Фишера-Тропша и выделение, по меньшей мере, некоторого количества синтезированных углеводородов для образования хвостового газа (70) и d) введение по меньшей мере части указанного хвостового газа в поток подаваемого сырья в установку вторичного реформинга перед его частичным сжиганием.Международная заявка была опубликована вместе с отчетом о международном поиске.
EA200500780A 2002-11-07 2003-10-23 Получение углеводородов EA006869B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB0225961.2A GB0225961D0 (en) 2002-11-07 2002-11-07 Production of hydrocarbons
PCT/GB2003/004622 WO2004041716A1 (en) 2002-11-07 2003-10-23 Production of hydrocarbons

Publications (2)

Publication Number Publication Date
EA200500780A1 true EA200500780A1 (ru) 2005-10-27
EA006869B1 EA006869B1 (ru) 2006-04-28

Family

ID=9947372

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200500780A EA006869B1 (ru) 2002-11-07 2003-10-23 Получение углеводородов

Country Status (14)

Country Link
US (1) US7314891B2 (ru)
EP (1) EP1560788B1 (ru)
JP (1) JP4422029B2 (ru)
AT (1) ATE320403T1 (ru)
AU (1) AU2003276396B2 (ru)
CA (1) CA2504596C (ru)
DE (1) DE60304064T2 (ru)
DK (1) DK1560788T3 (ru)
EA (1) EA006869B1 (ru)
GB (1) GB0225961D0 (ru)
MY (1) MY134407A (ru)
NO (1) NO336963B1 (ru)
WO (1) WO2004041716A1 (ru)
ZA (1) ZA200503477B (ru)

Cited By (1)

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RU2665691C2 (ru) * 2012-05-09 2018-09-04 Икспендер Энерджи Инк. Усовершенствованный способ фишера-тропша для составления углеводородного топлива с применением условий gtl

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DE102006023248C5 (de) 2006-05-18 2018-01-25 Air Liquide Global E&C Solutions Germany Gmbh Verfahren und Anlage zur Herstellung von Synthesegas
US7910629B2 (en) * 2006-10-20 2011-03-22 Exxonmobil Research And Engineering Company Light ends recovery process for a GTL plant
US8053481B2 (en) * 2006-11-08 2011-11-08 Wm Gtl, Inc. Low-pressure Fischer-Tropsch process
EP1927577A1 (en) * 2006-12-01 2008-06-04 Casale Chemicals S.A. Process for producing synthesis gas and related apparatus
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WO2009089456A2 (en) * 2008-01-09 2009-07-16 Rentech, Inc. Ethanol as a feedstock for a bctl facility
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GB201115929D0 (en) 2011-09-15 2011-10-26 Johnson Matthey Plc Improved hydrocarbon production process
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EP2676924A1 (en) 2012-06-21 2013-12-25 Haldor Topsoe A/S Process for Reforming Hydrocarbons
WO2014180888A1 (en) 2013-05-08 2014-11-13 Shell Internationale Research Maatschappij B.V. Process for the preparation of syngas
EA033831B1 (ru) * 2013-12-02 2019-11-29 Haldor Topsoe As Способ конверсии природного газа в углеводородные продукты и установка для осуществления способа
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WO2016083434A1 (en) * 2014-11-25 2016-06-02 Haldor Topsøe A/S A process for generation of synthesis gas by flue gas recycle
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US20190084833A1 (en) * 2016-02-03 2019-03-21 Epiphany Energy Corporation Production of liquid hydrocarbons, biofuels and uncontaminated co2 from gaseous feedstock
JP7017024B2 (ja) * 2016-02-29 2022-02-08 株式会社Ihi オレフィン製造システム、および、オレフィン製造方法
DE102016002728A1 (de) * 2016-03-08 2017-09-14 Linde Aktiengesellschaft Verfahren zur Erzeugung von Synthesegas
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2665691C2 (ru) * 2012-05-09 2018-09-04 Икспендер Энерджи Инк. Усовершенствованный способ фишера-тропша для составления углеводородного топлива с применением условий gtl

Also Published As

Publication number Publication date
DK1560788T3 (da) 2006-07-10
AU2003276396A1 (en) 2004-06-07
EP1560788B1 (en) 2006-03-15
NO336963B1 (no) 2015-12-07
MY134407A (en) 2007-12-31
CA2504596C (en) 2011-05-03
ATE320403T1 (de) 2006-04-15
EP1560788A1 (en) 2005-08-10
US20060135629A1 (en) 2006-06-22
CA2504596A1 (en) 2004-05-21
ZA200503477B (en) 2006-07-26
US7314891B2 (en) 2008-01-01
AU2003276396B2 (en) 2008-06-26
DE60304064T2 (de) 2006-11-09
EA006869B1 (ru) 2006-04-28
JP2006505646A (ja) 2006-02-16
WO2004041716A1 (en) 2004-05-21
DE60304064D1 (de) 2006-05-11
JP4422029B2 (ja) 2010-02-24
GB0225961D0 (en) 2002-12-11
NO20052354L (no) 2005-06-10

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