EA200300977A1 - Способ получения водорода и его применение - Google Patents

Способ получения водорода и его применение

Info

Publication number
EA200300977A1
EA200300977A1 EA200300977A EA200300977A EA200300977A1 EA 200300977 A1 EA200300977 A1 EA 200300977A1 EA 200300977 A EA200300977 A EA 200300977A EA 200300977 A EA200300977 A EA 200300977A EA 200300977 A1 EA200300977 A1 EA 200300977A1
Authority
EA
Eurasian Patent Office
Prior art keywords
metal
metals
hydrogen
iron
water vapor
Prior art date
Application number
EA200300977A
Other languages
English (en)
Other versions
EA005832B1 (ru
Inventor
Бойд Р. Дэвис
Дж. Келли Киндиг
Роберт Р. Одл
Томас Э. Уэйэнд
Original Assignee
Элкемикс Корпорейшн
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/800,769 external-priority patent/US6682714B2/en
Priority claimed from US09/800,434 external-priority patent/US6620398B2/en
Priority claimed from US09/800,421 external-priority patent/US7232472B2/en
Priority claimed from US09/800,423 external-priority patent/US20020139049A1/en
Priority claimed from US10/085,436 external-priority patent/US6663681B2/en
Application filed by Элкемикс Корпорейшн filed Critical Элкемикс Корпорейшн
Publication of EA200300977A1 publication Critical patent/EA200300977A1/ru
Publication of EA005832B1 publication Critical patent/EA005832B1/ru

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/10—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with metals
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/025—Preparation or purification of gas mixtures for ammonia synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/10—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with metals
    • C01B3/105—Cyclic methods
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/05—Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/14—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot liquids, e.g. molten metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/12—Applying additives during coking
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1687—Integration of gasification processes with another plant or parts within the plant with steam generation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)

Abstract

Описывается способ получения газообразного водорода. Водород получают восстановлением водяного пара с использованием пары металл/оксид металла для удаления кислорода из воды. Водяной пар вводят в контакт с расплавленной смесью металлов, причем смесь металлов содержит первый химически активный металл, такой как железо, растворенный в металле-разбавителе, таком как олово. Химически активный металл окисляется до оксида металла, причем образуется газообразный водород, а затем оксид металла можно восстановить обратно до металла для дальнейшего получения водорода без существенного перемещения металла или оксида металла во второй реактор. Реактор (400) имеет огнеупорные боковые стенки (402), приспособленные для содержания расплавленной смеси (404) металлов. Когда водяной пар вводят через фурму (408), железо в смеси (404) металлов окисляется до оксида железа. Оксид железа поднимается и накапливается в слое (406) шлака. Газообразный продукт (416), содержащий водород, смешанный с водяным паром, удаляют через выпускной канал (410).Международная заявка была опубликована вместе с отчетом о международном поиске.
EA200300977A 2001-03-06 2002-03-05 Способ получения водорода EA005832B1 (ru)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US09/800,769 US6682714B2 (en) 2001-03-06 2001-03-06 Method for the production of hydrogen gas
US09/800,434 US6620398B2 (en) 2001-03-06 2001-03-06 Method for the production of ammonia
US09/800,421 US7232472B2 (en) 2001-03-06 2001-03-06 Method for the treatment of coal
US09/800,423 US20020139049A1 (en) 2001-03-06 2001-03-06 Method for the production of a methane-containing gas
US10/085,436 US6663681B2 (en) 2001-03-06 2002-02-28 Method for the production of hydrogen and applications thereof
PCT/US2002/006549 WO2002070403A1 (en) 2001-03-06 2002-03-05 Method for the production of hydrogen and applications thereof

Publications (2)

Publication Number Publication Date
EA200300977A1 true EA200300977A1 (ru) 2004-04-29
EA005832B1 EA005832B1 (ru) 2005-06-30

Family

ID=27505809

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200300977A EA005832B1 (ru) 2001-03-06 2002-03-05 Способ получения водорода

Country Status (9)

Country Link
EP (1) EP1373131A4 (ru)
JP (1) JP2004529056A (ru)
CN (1) CN1254433C (ru)
AU (1) AU2002254101B2 (ru)
CA (1) CA2440137A1 (ru)
EA (1) EA005832B1 (ru)
MX (1) MXPA03008037A (ru)
PL (1) PL364600A1 (ru)
WO (1) WO2002070403A1 (ru)

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EP1462170A1 (en) * 2003-03-28 2004-09-29 European Community Gas-phase chemical reactions using a molten metal catalyst
US20050042150A1 (en) * 2003-08-19 2005-02-24 Linnard Griffin Apparatus and method for the production of hydrogen
MX2007016201A (es) * 2006-04-28 2008-03-11 Tata Steel Ltd Montaje para la fabricacion de gas de hidrogeno por descomposicion termoquimica de agua utilizando la escoria de la planta de acero y materiales residuales.
JP4949795B2 (ja) * 2006-10-10 2012-06-13 ウチヤ・サーモスタット株式会社 水素発生媒体の製造方法
DE102008021562B4 (de) * 2008-04-30 2012-06-21 Voestalpine Stahl Gmbh Verfahren zur Herstellung von Wasserstoffgas mit Hilfe von Hüttenreststoffen und Verwendung von Hüttenreststoffen
CN101665240A (zh) * 2008-09-03 2010-03-10 李�杰 工业法制氢气及装置
JP5373410B2 (ja) 2009-01-09 2013-12-18 トヨタ自動車株式会社 アンモニア合成方法
CN103112821A (zh) * 2013-01-15 2013-05-22 上海交通大学 一种碱性硫化氢溶液催化铁水热还原水产氢的方法
KR101529692B1 (ko) * 2013-09-05 2015-07-01 한국과학기술연구원 물과 메탄을 연속적으로 분해하여 수소를 제조하는 방법
CN106220461B (zh) * 2016-07-19 2018-11-30 青岛科技大学 一种基于煤化学链气化直接制备甲烷的装置及方法
CN109790016A (zh) * 2016-09-25 2019-05-21 皮特·斯摩卡 一种发电燃料生产系统
GB201811785D0 (en) * 2018-07-19 2018-09-05 Univ Surrey A continuous process for sustainable production of hydrogen
RU2701936C1 (ru) * 2018-12-13 2019-10-02 Владимир Владимирович Сербиненко Способ непрерывного производства ценных химических продуктов и энергии из углеродсодержащего сырья
MY192817A (en) * 2019-04-22 2022-09-12 Univ Kebangsaan Malaysia A catalyst composition and method of making thereof for pure hydrogen production
CN111252735B (zh) * 2020-03-19 2023-04-07 上海交通大学 复合金属协同水热分解水制备氢气的方法
WO2024069211A1 (en) * 2022-09-28 2024-04-04 Volvo Truck Corporation Oxidization reactor for hydrogen fuel cell vehicle

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US4072514A (en) * 1971-04-20 1978-02-07 Suzuki Masahiro Magnesium composites and mixtures for hydrogen generation and method for manufacture thereof
US4216199A (en) * 1975-03-21 1980-08-05 Erickson Donald C Hydrogen production from carbonaceous fuels using intermediate oxidation-reduction
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Also Published As

Publication number Publication date
WO2002070403A1 (en) 2002-09-12
JP2004529056A (ja) 2004-09-24
EP1373131A1 (en) 2004-01-02
AU2002254101B2 (en) 2008-03-20
CA2440137A1 (en) 2002-09-12
MXPA03008037A (es) 2004-10-15
PL364600A1 (en) 2004-12-13
EA005832B1 (ru) 2005-06-30
EP1373131A4 (en) 2007-10-03
CN1505591A (zh) 2004-06-16
CN1254433C (zh) 2006-05-03

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Legal Events

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MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KZ KG MD TJ TM RU