EA199900820A1 - Способ разложения циклоалкилгидроперосида - Google Patents

Способ разложения циклоалкилгидроперосида

Info

Publication number
EA199900820A1
EA199900820A1 EA199900820A EA199900820A EA199900820A1 EA 199900820 A1 EA199900820 A1 EA 199900820A1 EA 199900820 A EA199900820 A EA 199900820A EA 199900820 A EA199900820 A EA 199900820A EA 199900820 A1 EA199900820 A1 EA 199900820A1
Authority
EA
Eurasian Patent Office
Prior art keywords
mpa
parameter
decomposition
solubility parameter
hansen
Prior art date
Application number
EA199900820A
Other languages
English (en)
Inventor
Ибалдус Франсискус Крагтен
Хенрикус Анна Христиан Баур
Original Assignee
Дсм Н.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Дсм Н.В. filed Critical Дсм Н.В.
Publication of EA199900820A1 publication Critical patent/EA199900820A1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/14—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom belonging to a ring other than a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Способ разложения смеси, содержащей циклоалкилгидропероксид, при этом указанная смесь включает органическую фазу и водную фазу, где в процессе разложения присутствует, по меньшей мере, одно соединение, которое соответствует следующим параметрам: А > -0,5 и В > -1,0 (1), при этом А и В являются зависимыми от T, ρ, η, ε, δ, δ, δ, δ, μ и Е, где Tявляется нормальной температурой кипения (°С), ρ является плотностью, измеренной при 25°С (кг/м), ηявляется показателем преломления (-), εявляется относительной диэлектрической постоянной (-), δявляется параметром растворимости Хансена (Hansen) для дисперсии (МПа), δявляется параметром растворимости Хансена для полярности (МПа), δявляется параметром растворимости Хансена для водородных мостиковых связей (МПа), δ является параметром растворимости Скетчарда-Гильдебранта (Scatchard-Hildebrant)(МПа), μ является дипольным моментом (Debey) и Еявляется донорно/акцепторной характеристикой по Льюису (Lewis) (ккал/мол).Международная заявка была опубликована вместе с отчетом о международном поиске.
EA199900820A 1997-03-12 1998-03-06 Способ разложения циклоалкилгидроперосида EA199900820A1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
BE9700217A BE1011041A3 (nl) 1997-03-12 1997-03-12 Werkwijze voor het ontleden van cycloalkylhydroperoxide.
PCT/NL1998/000134 WO1998040340A1 (en) 1997-03-12 1998-03-06 Process for decomposing cycloalkylhydroperoxide

Publications (1)

Publication Number Publication Date
EA199900820A1 true EA199900820A1 (ru) 2000-04-24

Family

ID=3890399

Family Applications (1)

Application Number Title Priority Date Filing Date
EA199900820A EA199900820A1 (ru) 1997-03-12 1998-03-06 Способ разложения циклоалкилгидроперосида

Country Status (17)

Country Link
US (1) US5959153A (ru)
EP (1) EP1019355A1 (ru)
JP (1) JP2001519780A (ru)
KR (1) KR20000076089A (ru)
CN (1) CN1255114A (ru)
AU (1) AU6639298A (ru)
BE (1) BE1011041A3 (ru)
BR (1) BR9808852A (ru)
CA (1) CA2283175A1 (ru)
CO (1) CO5060437A1 (ru)
CZ (1) CZ321599A3 (ru)
EA (1) EA199900820A1 (ru)
GE (1) GEP20002296B (ru)
ID (1) ID23162A (ru)
PL (1) PL335618A1 (ru)
SK (1) SK123799A3 (ru)
WO (1) WO1998040340A1 (ru)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1445268B1 (en) * 2001-11-16 2008-05-21 Asahi Organic Chemicals Industry Co., Ltd. Process for the production of phenolic novolaks

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2675407A (en) * 1952-04-10 1954-04-13 Standard Oil Dev Co Air oxidation of cycloalkanes
SU178370A1 (ru) * 1965-04-15 1966-01-22
DE2127520A1 (de) * 1971-06-03 1972-12-14 Badische Anilin- & Soda-Fabrik Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Cycloalkanol- und Cycloalkanon-Gemischen
NL7802125A (nl) * 1978-02-25 1979-08-28 Stamicarbon Werkwijze voor het bereiden van cycloalkanolen en cycloalkanonen.
US4160000A (en) * 1978-03-13 1979-07-03 Phillips Petroleum Company Extraction of hydroperoxides
US4328372A (en) * 1979-06-27 1982-05-04 Phillips Petroleum Company Recovery of cyclohexanone from cyclohexylbenzene hydroperoxide acid cleavage product
NL8201695A (nl) * 1982-04-23 1983-11-16 Stamicarbon Werkwijze voor de bereiding van cyclohexanol en cyclohexanon.
DE4104419A1 (de) * 1991-02-14 1992-08-20 Basf Ag Kreislaufverfahren zur herstellung von cyclohexenoxid sowie cyclohexanol und cyclohexanon
US5206441A (en) * 1992-04-06 1993-04-27 E. I. Du Pont De Nemours And Company High rate process for preparation of cyclohexanol and cyclohexanone
BE1007904A3 (nl) * 1993-12-23 1995-11-14 Dsm Nv Werkwijze voor de bereiding van een alkanol en/of een alkanon.
BE1009662A3 (nl) * 1995-10-13 1997-06-03 Dsm Nv Werkwijze voor het ontleden van cycloalkylhydroperoxide.

Also Published As

Publication number Publication date
CO5060437A1 (es) 2001-07-30
GEP20002296B (en) 2000-11-25
AU6639298A (en) 1998-09-29
CZ321599A3 (cs) 1999-12-15
US5959153A (en) 1999-09-28
BE1011041A3 (nl) 1999-04-06
CN1255114A (zh) 2000-05-31
JP2001519780A (ja) 2001-10-23
BR9808852A (pt) 2002-07-23
ID23162A (id) 2000-03-23
SK123799A3 (en) 2000-05-16
KR20000076089A (ko) 2000-12-26
EP1019355A1 (en) 2000-07-19
CA2283175A1 (en) 1998-09-17
WO1998040340A1 (en) 1998-09-17
PL335618A1 (en) 2000-05-08

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