EA199801062A1 - Способ изомеризации алкилароматических углеводородов - Google Patents

Способ изомеризации алкилароматических углеводородов

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Publication number
EA199801062A1
EA199801062A1 EA199801062A EA199801062A EA199801062A1 EA 199801062 A1 EA199801062 A1 EA 199801062A1 EA 199801062 A EA199801062 A EA 199801062A EA 199801062 A EA199801062 A EA 199801062A EA 199801062 A1 EA199801062 A1 EA 199801062A1
Authority
EA
Eurasian Patent Office
Prior art keywords
zeolite
isomerization
aromatic hydrocarbons
alkyl aromatic
crystals
Prior art date
Application number
EA199801062A
Other languages
English (en)
Other versions
EA001597B1 (ru
Inventor
Гари Д. Мор
Иоганнес П. Вердуийн
Original Assignee
Эксон Кемикэл Пейтентс Инк.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Эксон Кемикэл Пейтентс Инк. filed Critical Эксон Кемикэл Пейтентс Инк.
Publication of EA199801062A1 publication Critical patent/EA199801062A1/ru
Publication of EA001597B1 publication Critical patent/EA001597B1/ru

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/861—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only halogen as hetero-atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/865—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an ether
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/868—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains sulfur as hetero-atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/87—Gallosilicates; Aluminogallosilicates; Galloborosilicates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/03—Catalysts comprising molecular sieves not having base-exchange properties
    • C07C2529/035—Crystalline silica polymorphs, e.g. silicalites
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/80—Mixtures of different zeolites
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

В заявке описан способ изомеризации сырья, включающего алкилароматические углеводороды, например одноядерные алкилароматические углеводороды и/или двуядерные алкилароматические углеводороды. Этот способ осуществляют посредством контактирования сырья в конверсионных условиях со связанным цеолитом цеолитным катализатором, который включает первые кристаллы первого цеолита с промежуточными размерами пор, и связующее вещество, которое содержит вторые кристаллы второго цеолита. Способ находит конкретное применение при изомеризации сырья, содержащего этилбензол и менее чем равновесные количества ксилолов с этилбензолом, а его осуществление позволяет получать продукт, содержащий более чем равновесные количества параксилола, с низкими потерями ароматических соединений, в частности потерями ксилолов.Международная заявка была опубликована вместе с отчетом о международном поиске.
EA199801062A 1996-05-29 1997-05-29 Способ изомеризации алкилароматических углеводородов EA001597B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US1855096P 1996-05-29 1996-05-29
PCT/US1997/009574 WO1997045385A1 (en) 1996-05-29 1997-05-29 Process for isomerization of alkylaromatic hydrocarbons

Publications (2)

Publication Number Publication Date
EA199801062A1 true EA199801062A1 (ru) 1999-06-24
EA001597B1 EA001597B1 (ru) 2001-06-25

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EA199801062A EA001597B1 (ru) 1996-05-29 1997-05-29 Способ изомеризации алкилароматических углеводородов

Country Status (13)

Country Link
US (1) US6008425A (ru)
EP (1) EP0918737A1 (ru)
JP (1) JP2000511195A (ru)
KR (1) KR20000016072A (ru)
CN (1) CN1084718C (ru)
AU (1) AU737957B2 (ru)
BR (1) BR9709419A (ru)
CA (1) CA2256512A1 (ru)
EA (1) EA001597B1 (ru)
ID (1) ID18446A (ru)
TW (1) TW408094B (ru)
WO (1) WO1997045385A1 (ru)
ZA (1) ZA974711B (ru)

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JP4067122B2 (ja) 1996-05-29 2008-03-26 エクソンモービル・ケミカル・パテンツ・インク 芳香族変換方法及びこの方法に有用なゼオライト触媒
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AU1623799A (en) * 1997-12-03 1999-06-16 Exxon Chemical Patents Inc. Preparation of zeolite bound by mfi structure type zeolite and use thereof
US6383967B1 (en) * 1997-12-08 2002-05-07 Uop Llc Selective aromatics disproportionation/transalkylation catalyst
ATE244600T1 (de) 1999-05-20 2003-07-15 Exxonmobil Chem Patents Inc Kohlenwasserstoffumwandlungsverfahren und hierbei anwendbarer katalysator
EP1061046B1 (en) 1999-06-18 2007-09-26 Nippon Shokubai Co., Ltd. Molding of binderless zeolite, method for its production and its use
US7148391B1 (en) * 2002-11-14 2006-12-12 Exxonmobil Chemical Patents Inc. Heavy aromatics processing
US7247762B2 (en) * 2003-09-12 2007-07-24 Exxonmobil Chemical Patents Inc. Process for xylene isomerization and ethylbenzene conversion
US6872866B1 (en) * 2003-12-15 2005-03-29 Uop Llc Liquid phase process for C8 alkylaromatic isomerization
FR2895283B1 (fr) * 2005-12-22 2008-02-01 Inst Francais Du Petrole Catalyseur comprenant une zeolithe euo, une zeolithe 10mr et une zeolithe 12mr et son utilisation en isomerisation des composes c8 aromatiques
US8546287B2 (en) 2010-05-31 2013-10-01 Fina Technology, Inc. Rhenium promoted catalyst
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SG11201804523QA (en) * 2015-12-11 2018-06-28 Shell Int Research Catalyst composition and isomerisation process
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CN112570005B (zh) * 2019-09-30 2023-08-04 中国石油化工股份有限公司 一种调控反应体系中金属加氢活性的方法及其应用

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Also Published As

Publication number Publication date
TW408094B (en) 2000-10-11
CA2256512A1 (en) 1997-12-04
CN1223629A (zh) 1999-07-21
JP2000511195A (ja) 2000-08-29
EA001597B1 (ru) 2001-06-25
CN1084718C (zh) 2002-05-15
ZA974711B (en) 1998-10-09
BR9709419A (pt) 1999-08-10
AU3227997A (en) 1998-01-05
EP0918737A1 (en) 1999-06-02
WO1997045385A1 (en) 1997-12-04
US6008425A (en) 1999-12-28
AU737957B2 (en) 2001-09-06
ID18446A (id) 1998-04-09
KR20000016072A (ko) 2000-03-25

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