GB1444702A - Xylene isomerization - Google Patents
Xylene isomerizationInfo
- Publication number
- GB1444702A GB1444702A GB3166374A GB3166374A GB1444702A GB 1444702 A GB1444702 A GB 1444702A GB 3166374 A GB3166374 A GB 3166374A GB 3166374 A GB3166374 A GB 3166374A GB 1444702 A GB1444702 A GB 1444702A
- Authority
- GB
- United Kingdom
- Prior art keywords
- xylenes
- xylene isomerization
- isomerize
- composited
- ethylbenzene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7034—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
- C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2729—Changing the branching point of an open chain or the point of substitution on a ring
- C07C5/2732—Catalytic processes
- C07C5/2737—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
1444702 Isomerizing xylenes MOBIL OIL CORP 17 July 1974 [13 Sept 1973] 31663/74 Heading C5E C 8 aromatic mixtures are contacted in liquid phase at 500-660 F. in the absence of added H 2 with zeolites ZSM-5, 8, 11, 12 or 21 in acid form to isomerize the xylenes and convert at least some of the ethylbenzene to compounds readily separable by distillation from C 8 aromatics. The zeolite may contain metal cations as well as hydrogen cations and may be composited with a binder, e.g. alumina.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US00397038A US3856871A (en) | 1973-09-13 | 1973-09-13 | Xylene isomerization |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1444702A true GB1444702A (en) | 1976-08-04 |
Family
ID=23569629
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3166374A Expired GB1444702A (en) | 1973-09-13 | 1974-07-17 | Xylene isomerization |
Country Status (18)
Country | Link |
---|---|
US (1) | US3856871A (en) |
JP (1) | JPS5341657B2 (en) |
AR (1) | AR224491A1 (en) |
BE (1) | BE819848A (en) |
CA (1) | CA1026384A (en) |
CS (1) | CS189668B2 (en) |
DD (1) | DD113741B3 (en) |
DE (1) | DE2441516C3 (en) |
ES (1) | ES428167A1 (en) |
FR (1) | FR2243919B1 (en) |
GB (1) | GB1444702A (en) |
IN (1) | IN142292B (en) |
IT (1) | IT1021337B (en) |
NL (1) | NL173846C (en) |
PL (1) | PL94144B1 (en) |
RO (1) | RO71348A (en) |
SU (1) | SU890971A3 (en) |
ZA (1) | ZA743917B (en) |
Families Citing this family (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4101596A (en) * | 1977-01-10 | 1978-07-18 | Mobil Oil Company | Low pressure xylene isomerization |
US4101595A (en) * | 1977-05-02 | 1978-07-18 | Mobil Oil Corporation | Conversion of ethyl benzene to para xylene |
US4163028A (en) * | 1977-07-22 | 1979-07-31 | Mobil Oil Corporation | Xylene isomerization |
US4159283A (en) * | 1978-04-07 | 1979-06-26 | Mobil Oil Corporation | Isomerization process |
US4245130A (en) * | 1978-06-02 | 1981-01-13 | The British Petroleum Company Limited | Isomerization of alkyl aromatics using a gallium containing aluminosilicate catalyst |
US4159282A (en) * | 1978-06-09 | 1979-06-26 | Mobil Oil Corporation | Xylene isomerization |
USRE31782E (en) * | 1978-06-09 | 1984-12-25 | Mobil Oil Corporation | Xylene isomerization |
US4218573A (en) * | 1978-06-12 | 1980-08-19 | Mobil Oil Corporation | Xylene isomerization |
US4188282A (en) * | 1978-06-12 | 1980-02-12 | Mobile Oil Corporation | Manufacture of benzene, toluene and xylene |
US4224141A (en) * | 1979-05-21 | 1980-09-23 | Mobil Oil Corporation | Manufacture of aromatic compounds |
US4236996A (en) * | 1979-05-25 | 1980-12-02 | Mobil Oil Corporation | Xylene isomerization |
US4283584A (en) * | 1980-04-14 | 1981-08-11 | Mobil Oil Corporation | Manufacture of aromatic compounds |
US4409413A (en) * | 1980-06-23 | 1983-10-11 | Toray Industries, Incorporated | Conversion of xylenes containing ethyl benzene |
EP0054385B1 (en) | 1980-12-12 | 1985-08-14 | Exxon Research And Engineering Company | Xylene isomerization |
ATE15613T1 (en) * | 1980-12-12 | 1985-10-15 | Exxon Research Engineering Co | ZEOLITE COMPOSITION. |
NZ199280A (en) * | 1980-12-17 | 1985-05-31 | Ici Plc | Isomerisation of hydrocarbons using catalytic zeolite designated nu-5 |
DE3261680D1 (en) * | 1981-05-20 | 1985-02-07 | Ici Plc | Process for the isomerization of alkylbenzenes |
JPS63196528A (en) * | 1985-09-13 | 1988-08-15 | ユ−オ−ピ− インコ−ポレイテツド | Manufacture of xylene by use of both isomerizing/transalkylating zone |
US5043512A (en) * | 1988-10-06 | 1991-08-27 | Mobil Oil Corp. | Alkylaromatic isomerization process |
US6518472B1 (en) | 1996-08-05 | 2003-02-11 | Bp Corporation North America Inc. | Stabilized dual bed xylene isomerization catalyst system |
US5763714A (en) * | 1997-01-08 | 1998-06-09 | Catalytic Distillation Technologies | Process and apparatus for the production and recovery of p-xylene |
US5866736A (en) * | 1997-10-14 | 1999-02-02 | Catalytic Distillation Technologies | Process for the production of alkyl benzene |
TWI263630B (en) * | 2003-07-08 | 2006-10-11 | Toray Industries | Conversion catalyst for ethylbenzene containing xylenes and process for converting ethylbenzene containing xylenes by using catalyst |
US6872866B1 (en) | 2003-12-15 | 2005-03-29 | Uop Llc | Liquid phase process for C8 alkylaromatic isomerization |
CN100512954C (en) * | 2003-12-30 | 2009-07-15 | 环球油品公司 | Process and bimetallic catalyst for c* alkyl aromatic isomerization |
US20050143614A1 (en) * | 2003-12-30 | 2005-06-30 | Leon-Escamilla E. A. | Process and catalyst for C8 alkylaromatic isomerization |
US20050143615A1 (en) * | 2003-12-30 | 2005-06-30 | Bogdan Paula L. | Process and bimetallic catalyst for C8 alkylaromatic isomerization |
CN102858722B (en) | 2010-04-21 | 2015-04-01 | 埃克森美孚化学专利公司 | Xylenes isomerization process and catalyst therefor |
US8569559B2 (en) * | 2010-06-25 | 2013-10-29 | Exxonmobil Chemical Patents Inc. | Paraxylene production process and apparatus |
MX358764B (en) | 2012-04-20 | 2018-09-03 | Coca Cola Co | Methods of preparing para-xylene from biomass. |
ES2809484T3 (en) | 2015-08-18 | 2021-03-04 | Bp Corp North America Inc | Process for the manufacture of disilicate ZSM-5 catalysts for xylene isomerization |
CN110088068B (en) | 2016-12-21 | 2022-12-06 | 环球油品有限责任公司 | Compositions of matter and structures of zeolite UZM-55 and use in isomerization of aromatic molecules |
SG11202100544QA (en) | 2018-07-20 | 2021-02-25 | Scg Chemicals Co Ltd | Process for the separation of ethylbenzene from other c8 aromatic compounds |
US10975006B2 (en) | 2018-07-20 | 2021-04-13 | Scg Chemicals Co., Ltd. | Integrated processes for para-xylene production |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2795630A (en) * | 1954-08-26 | 1957-06-11 | Standard Oil Co | Preparation of trialkylbenzenes |
US3281483A (en) * | 1963-08-15 | 1966-10-25 | Shell Oil Co | Disproportionation of alkyl aromatic hydrocarbons in the presence of hydrogen mordenite |
US3790471A (en) * | 1969-10-10 | 1974-02-05 | Mobil Oil Corp | Conversion with zsm-5 family of crystalline aluminosilicate zeolites |
US3646236A (en) * | 1970-03-27 | 1972-02-29 | Engelhard Min & Chem | Disproportionation of toluene with a platinum-rhenium-solid oxide catalyst |
US3691247A (en) * | 1970-09-28 | 1972-09-12 | Phillips Petroleum Co | Selectively removing monoalkylbenzenes from mixtures thereof with dialkylbenzenes |
US3751504A (en) * | 1972-05-12 | 1973-08-07 | Mobil Oil Corp | Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation |
US3756942A (en) * | 1972-05-17 | 1973-09-04 | Mobil Oil Corp | Process for the production of aromatic compounds |
US3761389A (en) * | 1972-08-28 | 1973-09-25 | Mobil Oil Corp | Process of converting aliphatics to aromatics |
-
1973
- 1973-09-13 US US00397038A patent/US3856871A/en not_active Expired - Lifetime
-
1974
- 1974-05-23 CA CA200,640A patent/CA1026384A/en not_active Expired
- 1974-06-10 IN IN1261/CAL/74A patent/IN142292B/en unknown
- 1974-06-18 ZA ZA00743917A patent/ZA743917B/en unknown
- 1974-06-19 FR FR7421256A patent/FR2243919B1/fr not_active Expired
- 1974-06-20 JP JP6972974A patent/JPS5341657B2/ja not_active Expired
- 1974-07-11 ES ES428167A patent/ES428167A1/en not_active Expired
- 1974-07-17 GB GB3166374A patent/GB1444702A/en not_active Expired
- 1974-07-24 SU SU742049507A patent/SU890971A3/en active
- 1974-08-13 RO RO7479759A patent/RO71348A/en unknown
- 1974-08-30 DE DE2441516A patent/DE2441516C3/en not_active Expired
- 1974-09-11 NL NLAANVRAGE7412093,A patent/NL173846C/en not_active IP Right Cessation
- 1974-09-12 IT IT27243/74A patent/IT1021337B/en active
- 1974-09-12 BE BE148467A patent/BE819848A/en not_active IP Right Cessation
- 1974-09-12 DD DD74181056A patent/DD113741B3/en unknown
- 1974-09-12 CS CS746283A patent/CS189668B2/en unknown
- 1974-09-13 PL PL1974174095A patent/PL94144B1/pl unknown
- 1974-09-13 AR AR255604A patent/AR224491A1/en active
Also Published As
Publication number | Publication date |
---|---|
NL173846B (en) | 1983-10-17 |
DD113741B3 (en) | 1986-06-11 |
NL173846C (en) | 1984-03-16 |
CS189668B2 (en) | 1979-04-30 |
RO71348A (en) | 1982-02-01 |
DD113741A5 (en) | 1975-06-20 |
PL94144B1 (en) | 1977-07-30 |
CA1026384A (en) | 1978-02-14 |
DE2441516A1 (en) | 1975-03-20 |
BE819848A (en) | 1975-03-12 |
SU890971A3 (en) | 1981-12-15 |
IN142292B (en) | 1977-06-18 |
IT1021337B (en) | 1978-01-30 |
JPS5341657B2 (en) | 1978-11-06 |
FR2243919B1 (en) | 1979-08-03 |
US3856871A (en) | 1974-12-24 |
DE2441516C3 (en) | 1979-12-13 |
ES428167A1 (en) | 1976-07-16 |
NL7412093A (en) | 1975-03-17 |
ZA743917B (en) | 1976-01-28 |
JPS5053335A (en) | 1975-05-12 |
AR224491A1 (en) | 1981-12-15 |
DE2441516B2 (en) | 1979-04-26 |
FR2243919A1 (en) | 1975-04-11 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |