EA028721B1 - Способ получения маточной смеси на основе углеродных нанонаполнителей и сверхпластификатора и ее применение в неорганических отверждаемых системах - Google Patents
Способ получения маточной смеси на основе углеродных нанонаполнителей и сверхпластификатора и ее применение в неорганических отверждаемых системах Download PDFInfo
- Publication number
- EA028721B1 EA028721B1 EA201491576A EA201491576A EA028721B1 EA 028721 B1 EA028721 B1 EA 028721B1 EA 201491576 A EA201491576 A EA 201491576A EA 201491576 A EA201491576 A EA 201491576A EA 028721 B1 EA028721 B1 EA 028721B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- masterbatch
- cement
- carbon
- superplasticizer
- nanofillers
- Prior art date
Links
- 239000008030 superplasticizer Substances 0.000 title claims abstract description 58
- 239000000203 mixture Substances 0.000 title claims abstract description 40
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 100
- 239000004568 cement Substances 0.000 claims abstract description 64
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 34
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 34
- 239000000463 material Substances 0.000 claims abstract description 19
- 239000007788 liquid Substances 0.000 claims abstract description 12
- 238000010276 construction Methods 0.000 claims abstract description 10
- -1 plasters Substances 0.000 claims abstract description 10
- 238000005553 drilling Methods 0.000 claims abstract description 9
- 239000000919 ceramic Substances 0.000 claims abstract description 5
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 70
- 229910052799 carbon Inorganic materials 0.000 claims description 57
- 238000000034 method Methods 0.000 claims description 44
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 239000002270 dispersing agent Substances 0.000 claims description 18
- 229910021389 graphene Inorganic materials 0.000 claims description 13
- 239000007787 solid Substances 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 12
- 239000002131 composite material Substances 0.000 claims description 10
- 239000011398 Portland cement Substances 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 8
- 239000000194 fatty acid Substances 0.000 claims description 8
- 229930195729 fatty acid Natural products 0.000 claims description 8
- 239000002202 Polyethylene glycol Substances 0.000 claims description 7
- 239000002134 carbon nanofiber Substances 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 7
- 150000004665 fatty acids Chemical class 0.000 claims description 7
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 7
- 235000011837 pasties Nutrition 0.000 claims description 7
- 229920001223 polyethylene glycol Polymers 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- 229920000570 polyether Polymers 0.000 claims description 6
- 230000002787 reinforcement Effects 0.000 claims description 6
- 239000012763 reinforcing filler Substances 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 239000004570 mortar (masonry) Substances 0.000 claims description 5
- 229920005646 polycarboxylate Polymers 0.000 claims description 5
- 239000004576 sand Substances 0.000 claims description 5
- 229920000877 Melamine resin Polymers 0.000 claims description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 4
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 4
- 238000006068 polycondensation reaction Methods 0.000 claims description 4
- 229920001732 Lignosulfonate Polymers 0.000 claims description 3
- 229920001400 block copolymer Polymers 0.000 claims description 3
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 3
- 238000009792 diffusion process Methods 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 239000002557 mineral fiber Substances 0.000 claims description 3
- 239000002736 nonionic surfactant Substances 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 2
- 229930006000 Sucrose Natural products 0.000 claims description 2
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 2
- 229910052925 anhydrite Inorganic materials 0.000 claims description 2
- 239000011324 bead Substances 0.000 claims description 2
- 239000011400 blast furnace cement Substances 0.000 claims description 2
- 239000010440 gypsum Substances 0.000 claims description 2
- 229910052602 gypsum Inorganic materials 0.000 claims description 2
- 239000004571 lime Substances 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920000417 polynaphthalene Polymers 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 239000002893 slag Substances 0.000 claims description 2
- 239000010454 slate Substances 0.000 claims description 2
- 239000005720 sucrose Substances 0.000 claims description 2
- 150000003871 sulfonates Chemical class 0.000 claims description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
- 239000011852 carbon nanoparticle Substances 0.000 claims 1
- 150000003077 polyols Chemical class 0.000 claims 1
- 239000000600 sorbitol Substances 0.000 claims 1
- 150000004760 silicates Chemical class 0.000 abstract description 3
- 238000003780 insertion Methods 0.000 abstract 1
- 230000037431 insertion Effects 0.000 abstract 1
- 230000003014 reinforcing effect Effects 0.000 abstract 1
- 239000004567 concrete Substances 0.000 description 30
- 239000006185 dispersion Substances 0.000 description 23
- 239000002071 nanotube Substances 0.000 description 20
- 238000002360 preparation method Methods 0.000 description 10
- 239000000047 product Substances 0.000 description 8
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 6
- 238000005452 bending Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 230000035882 stress Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 238000005229 chemical vapour deposition Methods 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000007970 homogeneous dispersion Substances 0.000 description 3
- 230000036571 hydration Effects 0.000 description 3
- 238000006703 hydration reaction Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 229920005596 polymer binder Polymers 0.000 description 3
- 239000002491 polymer binding agent Substances 0.000 description 3
- 239000005708 Sodium hypochlorite Substances 0.000 description 2
- 229920006243 acrylic copolymer Polymers 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
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- 239000000428 dust Substances 0.000 description 2
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- 238000005187 foaming Methods 0.000 description 2
- 238000007306 functionalization reaction Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
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- 238000002347 injection Methods 0.000 description 2
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- 239000003129 oil well Substances 0.000 description 2
- 239000011505 plaster Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- 241000272525 Anas platyrhynchos Species 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000010441 alabaster Substances 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000003254 anti-foaming effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
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- 229910052802 copper Inorganic materials 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
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- 239000002079 double walled nanotube Substances 0.000 description 1
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- 238000001914 filtration Methods 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000011381 foam concrete Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000003827 glycol group Chemical group 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- FIGIUNNQWAGNTO-UHFFFAOYSA-N methanesulfonic acid;naphthalene Chemical compound CS(O)(=O)=O.C1=CC=CC2=CC=CC=C21 FIGIUNNQWAGNTO-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000002074 nanoribbon Substances 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 150000003385 sodium Chemical class 0.000 description 1
- 229920005552 sodium lignosulfonate Polymers 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 1
- 238000000527 sonication Methods 0.000 description 1
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/02—Alcohols; Phenols; Ethers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/38—Fibrous materials; Whiskers
- C04B14/386—Carbon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/04—Carboxylic acids; Salts, anhydrides or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/08—Fats; Fatty oils; Ester type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/03—Specific additives for general use in well-drilling compositions
- C09K8/035—Organic additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
- C08K3/045—Fullerenes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Nanotechnology (AREA)
- Civil Engineering (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1261229 | 2012-11-26 | ||
| FR1261229A FR2998573B1 (fr) | 2012-11-26 | 2012-11-26 | Melange maitre a base de nanocharges carbonees et de superplastifiant, et son utilisation dans des systemes inorganiques durcissables |
| PCT/FR2013/052838 WO2014080144A1 (fr) | 2012-11-26 | 2013-11-25 | Procede de preparation d'un melange maitre a base de nanocharges carbonees et de superplastifiant, et son utilisation dans des systemes inorganiques durcissables |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA201491576A1 EA201491576A1 (ru) | 2014-11-28 |
| EA028721B1 true EA028721B1 (ru) | 2017-12-29 |
Family
ID=47741071
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA201491576A EA028721B1 (ru) | 2012-11-26 | 2013-11-25 | Способ получения маточной смеси на основе углеродных нанонаполнителей и сверхпластификатора и ее применение в неорганических отверждаемых системах |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US9850363B2 (enExample) |
| EP (1) | EP2922801B1 (enExample) |
| JP (1) | JP6318164B2 (enExample) |
| KR (1) | KR102123136B1 (enExample) |
| CN (1) | CN104684863B (enExample) |
| EA (1) | EA028721B1 (enExample) |
| FR (1) | FR2998573B1 (enExample) |
| UA (1) | UA110883C2 (enExample) |
| WO (1) | WO2014080144A1 (enExample) |
| ZA (1) | ZA201501892B (enExample) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013062951A1 (en) | 2011-10-27 | 2013-05-02 | Garmor, Inc. | Composite graphene structures |
| WO2014138587A1 (en) | 2013-03-08 | 2014-09-12 | Garmor, Inc. | Graphene entrainment in a host |
| KR101910924B1 (ko) | 2013-03-08 | 2018-10-23 | 유니버시티 오브 센트럴 플로리다 리서치 파운데이션, 인코포레이티드 | 산업용 대규모 산화 그래핀 제조 |
| US9828290B2 (en) | 2014-08-18 | 2017-11-28 | Garmor Inc. | Graphite oxide entrainment in cement and asphalt composite |
| US12195340B2 (en) | 2015-03-13 | 2025-01-14 | University Of Central Florida Research Foundation, Inc. | Uniform dispersing of graphene nanoparticles in a host |
| US10351711B2 (en) | 2015-03-23 | 2019-07-16 | Garmor Inc. | Engineered composite structure using graphene oxide |
| WO2016167981A1 (en) | 2015-04-13 | 2016-10-20 | Garmor Inc. | Graphite oxide reinforced fiber in hosts such as concrete or asphalt |
| US11038182B2 (en) | 2015-09-21 | 2021-06-15 | Garmor Inc. | Low-cost, high-performance composite bipolar plate |
| CN106542787B (zh) * | 2016-10-13 | 2019-07-02 | 武汉轻工大学 | 具备压阻效应的石墨烯纳米片改性水泥基材料及制备方法 |
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| WO2009099640A1 (en) * | 2008-02-08 | 2009-08-13 | Northwestern University | Highly-dispersed carbon nanotube-reinforced cement-based materials |
| FR2969143A1 (fr) * | 2010-12-21 | 2012-06-22 | Arkema France | Procede d'introduction de nanocharges carbonees dans un systeme inorganique durcissable |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2014080144A1 (fr) | 2014-05-30 |
| EP2922801B1 (fr) | 2020-11-04 |
| EA201491576A1 (ru) | 2014-11-28 |
| UA110883C2 (uk) | 2016-02-25 |
| EP2922801A1 (fr) | 2015-09-30 |
| US10208180B2 (en) | 2019-02-19 |
| JP6318164B2 (ja) | 2018-04-25 |
| JP2015536899A (ja) | 2015-12-24 |
| US20180148561A1 (en) | 2018-05-31 |
| CN104684863A (zh) | 2015-06-03 |
| KR20150088314A (ko) | 2015-07-31 |
| FR2998573B1 (fr) | 2015-09-04 |
| US20150240047A1 (en) | 2015-08-27 |
| ZA201501892B (en) | 2016-10-26 |
| FR2998573A1 (fr) | 2014-05-30 |
| US9850363B2 (en) | 2017-12-26 |
| CN104684863B (zh) | 2017-08-15 |
| KR102123136B1 (ko) | 2020-06-15 |
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