EA018648B1 - Предшественник катализатора и катализатор гидрирования углеводородного сырья, способ его получения, способ гидрирования - Google Patents
Предшественник катализатора и катализатор гидрирования углеводородного сырья, способ его получения, способ гидрирования Download PDFInfo
- Publication number
- EA018648B1 EA018648B1 EA201070545A EA201070545A EA018648B1 EA 018648 B1 EA018648 B1 EA 018648B1 EA 201070545 A EA201070545 A EA 201070545A EA 201070545 A EA201070545 A EA 201070545A EA 018648 B1 EA018648 B1 EA 018648B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- group
- metal
- catalyst
- catalyst precursor
- combinations
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 200
- 238000000034 method Methods 0.000 title claims abstract description 80
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 17
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 16
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 12
- 230000008569 process Effects 0.000 title description 57
- 239000012018 catalyst precursor Substances 0.000 claims abstract description 195
- 229910052751 metal Inorganic materials 0.000 claims abstract description 166
- 239000002184 metal Substances 0.000 claims abstract description 166
- 239000000203 mixture Substances 0.000 claims abstract description 96
- 238000005486 sulfidation Methods 0.000 claims abstract description 52
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000001301 oxygen Substances 0.000 claims abstract description 44
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 44
- 239000003446 ligand Substances 0.000 claims abstract description 42
- 230000003647 oxidation Effects 0.000 claims abstract description 16
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 16
- 238000006243 chemical reaction Methods 0.000 claims description 62
- 150000002739 metals Chemical class 0.000 claims description 53
- 150000001875 compounds Chemical class 0.000 claims description 50
- 238000005984 hydrogenation reaction Methods 0.000 claims description 49
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 45
- 239000001257 hydrogen Substances 0.000 claims description 43
- 229910052739 hydrogen Inorganic materials 0.000 claims description 43
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 38
- 239000002244 precipitate Substances 0.000 claims description 35
- 229910052717 sulfur Inorganic materials 0.000 claims description 33
- 239000011593 sulfur Substances 0.000 claims description 33
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical group [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 29
- 229910052750 molybdenum Inorganic materials 0.000 claims description 29
- 239000011733 molybdenum Substances 0.000 claims description 29
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 29
- 229910052721 tungsten Inorganic materials 0.000 claims description 29
- 239000010937 tungsten Substances 0.000 claims description 29
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 28
- 150000002736 metal compounds Chemical class 0.000 claims description 27
- -1 silica sol ions Chemical class 0.000 claims description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 25
- 239000002243 precursor Substances 0.000 claims description 24
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 23
- 239000011541 reaction mixture Substances 0.000 claims description 19
- 229910052783 alkali metal Inorganic materials 0.000 claims description 15
- 239000011701 zinc Substances 0.000 claims description 15
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 14
- 229910052725 zinc Inorganic materials 0.000 claims description 14
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 13
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 13
- 150000001340 alkali metals Chemical class 0.000 claims description 13
- 229910052749 magnesium Inorganic materials 0.000 claims description 13
- 239000011777 magnesium Substances 0.000 claims description 13
- 229910052718 tin Inorganic materials 0.000 claims description 13
- 239000000377 silicon dioxide Substances 0.000 claims description 12
- 229910052782 aluminium Inorganic materials 0.000 claims description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 11
- 230000015572 biosynthetic process Effects 0.000 claims description 11
- 150000001768 cations Chemical class 0.000 claims description 11
- 229910052759 nickel Inorganic materials 0.000 claims description 11
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 10
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 claims description 10
- 229910052710 silicon Inorganic materials 0.000 claims description 10
- 239000010703 silicon Substances 0.000 claims description 10
- 241000700159 Rattus Species 0.000 claims description 9
- 230000007935 neutral effect Effects 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 6
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 4
- 229910052793 cadmium Inorganic materials 0.000 claims description 4
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 4
- 238000000975 co-precipitation Methods 0.000 claims description 4
- 239000000499 gel Substances 0.000 claims description 4
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims description 4
- 235000019353 potassium silicate Nutrition 0.000 claims description 4
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 claims description 3
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical group [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 239000004111 Potassium silicate Substances 0.000 claims description 2
- 239000004115 Sodium Silicate Substances 0.000 claims description 2
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical group [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 2
- 239000000347 magnesium hydroxide Substances 0.000 claims description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 2
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-O oxonium Chemical compound [OH3+] XLYOFNOQVPJJNP-UHFFFAOYSA-O 0.000 claims description 2
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims description 2
- 229910052913 potassium silicate Inorganic materials 0.000 claims description 2
- KVOIJEARBNBHHP-UHFFFAOYSA-N potassium;oxido(oxo)alumane Chemical compound [K+].[O-][Al]=O KVOIJEARBNBHHP-UHFFFAOYSA-N 0.000 claims description 2
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 2
- 239000000243 solution Substances 0.000 description 95
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 60
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 44
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 39
- 239000000463 material Substances 0.000 description 37
- 239000003921 oil Substances 0.000 description 37
- 239000007789 gas Substances 0.000 description 35
- 239000002994 raw material Substances 0.000 description 31
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 30
- 229910052757 nitrogen Inorganic materials 0.000 description 30
- 239000003085 diluting agent Substances 0.000 description 25
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 24
- 238000009835 boiling Methods 0.000 description 22
- 230000003197 catalytic effect Effects 0.000 description 22
- 230000000694 effects Effects 0.000 description 20
- 239000011148 porous material Substances 0.000 description 18
- 239000000725 suspension Substances 0.000 description 18
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 17
- 239000007788 liquid Substances 0.000 description 17
- 239000003795 chemical substances by application Substances 0.000 description 15
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 15
- 239000000047 product Substances 0.000 description 15
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 15
- 238000004517 catalytic hydrocracking Methods 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 14
- 239000008367 deionised water Substances 0.000 description 14
- 229910021641 deionized water Inorganic materials 0.000 description 14
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 13
- 239000002253 acid Substances 0.000 description 13
- 239000007791 liquid phase Substances 0.000 description 13
- 229910052799 carbon Inorganic materials 0.000 description 12
- 239000002738 chelating agent Substances 0.000 description 12
- 239000012071 phase Substances 0.000 description 12
- 239000011135 tin Substances 0.000 description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 11
- 239000011230 binding agent Substances 0.000 description 11
- 229910017052 cobalt Inorganic materials 0.000 description 11
- 239000010941 cobalt Substances 0.000 description 11
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 11
- 239000011976 maleic acid Substances 0.000 description 11
- 239000000843 powder Substances 0.000 description 11
- 239000007787 solid Substances 0.000 description 11
- 238000000634 powder X-ray diffraction Methods 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 9
- 239000011651 chromium Substances 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 8
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 7
- QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 7
- 239000004927 clay Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 231100000252 nontoxic Toxicity 0.000 description 7
- 230000003000 nontoxic effect Effects 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 6
- UYJXRRSPUVSSMN-UHFFFAOYSA-P ammonium sulfide Chemical compound [NH4+].[NH4+].[S-2] UYJXRRSPUVSSMN-UHFFFAOYSA-P 0.000 description 6
- 239000002585 base Substances 0.000 description 6
- 150000007942 carboxylates Chemical class 0.000 description 6
- 229910052804 chromium Inorganic materials 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 238000001556 precipitation Methods 0.000 description 6
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical class [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 5
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 5
- 150000001342 alkaline earth metals Chemical class 0.000 description 5
- 239000000908 ammonium hydroxide Chemical class 0.000 description 5
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- 238000003786 synthesis reaction Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 150000001299 aldehydes Chemical class 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
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- 125000002587 enol group Chemical group 0.000 description 4
- 239000000295 fuel oil Substances 0.000 description 4
- HHLFWLYXYJOTON-UHFFFAOYSA-N glyoxylic acid Chemical compound OC(=O)C=O HHLFWLYXYJOTON-UHFFFAOYSA-N 0.000 description 4
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- 150000002576 ketones Chemical class 0.000 description 4
- 239000010687 lubricating oil Substances 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
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- 229910052720 vanadium Inorganic materials 0.000 description 4
- 229910001182 Mo alloy Inorganic materials 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
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- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
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- 230000000996 additive effect Effects 0.000 description 3
- HZVVJJIYJKGMFL-UHFFFAOYSA-N almasilate Chemical compound O.[Mg+2].[Al+3].[Al+3].O[Si](O)=O.O[Si](O)=O HZVVJJIYJKGMFL-UHFFFAOYSA-N 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 150000001805 chlorine compounds Chemical class 0.000 description 3
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- 150000002373 hemiacetals Chemical class 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 125000003099 maleoyl group Chemical group C(\C=C/C(=O)*)(=O)* 0.000 description 3
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- FAKFSJNVVCGEEI-UHFFFAOYSA-J tin(4+);disulfate Chemical compound [Sn+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O FAKFSJNVVCGEEI-UHFFFAOYSA-J 0.000 description 3
- 238000005292 vacuum distillation Methods 0.000 description 3
- XIOUDVJTOYVRTB-UHFFFAOYSA-N 1-(1-adamantyl)-3-aminothiourea Chemical compound C1C(C2)CC3CC2CC1(NC(=S)NN)C3 XIOUDVJTOYVRTB-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
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- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- 229920003091 Methocel™ Polymers 0.000 description 2
- HSHXDCVZWHOWCS-UHFFFAOYSA-N N'-hexadecylthiophene-2-carbohydrazide Chemical compound CCCCCCCCCCCCCCCCNNC(=O)c1cccs1 HSHXDCVZWHOWCS-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
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- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 235000011054 acetic acid Nutrition 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
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- 239000002283 diesel fuel Substances 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
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- 150000003657 tungsten Chemical class 0.000 description 1
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- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
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- 239000002351 wastewater Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- SRWMQSFFRFWREA-UHFFFAOYSA-M zinc formate Chemical compound [Zn+2].[O-]C=O SRWMQSFFRFWREA-UHFFFAOYSA-M 0.000 description 1
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 1
- 229940007718 zinc hydroxide Drugs 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- HJSYJHHRQVHHMQ-TYYBGVCCSA-L zinc;(e)-but-2-enedioate Chemical compound [Zn+2].[O-]C(=O)\C=C\C([O-])=O HJSYJHHRQVHHMQ-TYYBGVCCSA-L 0.000 description 1
- XAEWLETZEZXLHR-UHFFFAOYSA-N zinc;dioxido(dioxo)molybdenum Chemical compound [Zn+2].[O-][Mo]([O-])(=O)=O XAEWLETZEZXLHR-UHFFFAOYSA-N 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
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- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
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- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
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- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- B01J23/888—Tungsten
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- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
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- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
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- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/66—Tungsten
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
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Families Citing this family (109)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8206575B2 (en) | 2007-10-31 | 2012-06-26 | Chevron U.S.A. Inc. | Hydroconversion processes employing multi-metallic catalysts and method for making thereof |
| US8022259B2 (en) * | 2008-05-30 | 2011-09-20 | Uop Llc | Slurry hydroconversion of biorenewable feedstocks |
| CA2756424A1 (en) * | 2009-04-21 | 2010-10-28 | Sapphire Energy, Inc. | Methods of preparing oil compositions for fuel refining |
| SG175824A1 (en) * | 2009-04-29 | 2011-12-29 | Chevron Usa Inc | Hydroconversion multi-metallic catalyst and method for making thereof |
| US7931799B2 (en) | 2009-04-29 | 2011-04-26 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
| WO2010126689A2 (en) | 2009-04-29 | 2010-11-04 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
| US8080492B2 (en) | 2009-04-29 | 2011-12-20 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
| US7964526B2 (en) | 2009-04-29 | 2011-06-21 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
| US8058203B2 (en) | 2009-04-29 | 2011-11-15 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
| MX2012005688A (es) * | 2009-11-24 | 2012-06-13 | Chevron Usa Inc | Catalizador masico de hidroprocesamiento y metodos para su elaboracion. |
| JP5683604B2 (ja) * | 2009-12-18 | 2015-03-11 | エクソンモービル リサーチ アンド エンジニアリング カンパニーExxon Research And Engineering Company | 水素処理触媒およびそれらの製造 |
| CN103037968B (zh) | 2010-06-01 | 2016-08-24 | 埃克森美孚研究工程公司 | 加氢处理催化剂和它们的制备 |
| CN103052443B (zh) | 2010-08-13 | 2016-01-20 | 国际壳牌研究有限公司 | 用废催化剂细粉制备的加氢催化剂及其用途 |
| US8658558B2 (en) | 2010-11-11 | 2014-02-25 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
| CA2817523C (en) * | 2010-11-11 | 2018-12-04 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
| US8575061B2 (en) | 2010-11-11 | 2013-11-05 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
| US8575062B2 (en) | 2010-11-11 | 2013-11-05 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
| US9168519B2 (en) | 2010-11-11 | 2015-10-27 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
| US8586500B2 (en) | 2010-11-11 | 2013-11-19 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
| US9040446B2 (en) | 2010-12-30 | 2015-05-26 | Chevron U.S.A. Inc. | Hydroprocessing catalysts and methods for making thereof |
| ITMI20110510A1 (it) * | 2011-03-30 | 2012-10-01 | Eni Spa | Ossidi misti di metalli di transizione, catalizzatori di idrotrattamento da essi ottenuti, e processo di preparazione |
| US9035115B2 (en) | 2011-12-09 | 2015-05-19 | Chevron U.S.A. Inc. | Hydroconversion of renewable feedstocks |
| US8884077B2 (en) | 2011-12-09 | 2014-11-11 | Chevron U.S.A. Inc. | Hydroconversion of renewable feedstocks |
| US9266802B2 (en) * | 2011-12-09 | 2016-02-23 | Chevron U.S.A. Inc. | Hydroconversion of renewable feedstocks |
| US8704007B2 (en) | 2011-12-09 | 2014-04-22 | Chevron U.S.A. Inc. | Hydroconversion of renewable feedstocks |
| FR2984764B1 (fr) * | 2011-12-22 | 2014-01-17 | IFP Energies Nouvelles | Procede de preparation d'un catalyseur utilisable en hydrotraitement et hydroconversion |
| US9266098B2 (en) | 2012-09-05 | 2016-02-23 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalysts and method for making thereof |
| CN103657672B (zh) * | 2012-09-18 | 2016-05-18 | 中国科学院大连化学物理研究所 | 层状结构超深度加氢脱硫多金属本体催化剂及制备和应用 |
| US11633727B2 (en) | 2012-10-10 | 2023-04-25 | Albemarle Catalysts Company B.V. | Supported hydrotreating catalysts having enhanced activity |
| US11731118B2 (en) | 2012-10-10 | 2023-08-22 | Albemarle Catalysts Company B.V. | Supported hydrotreating catalysts having enhanced activity |
| US20140206915A1 (en) | 2013-01-18 | 2014-07-24 | Chevron U.S.A. Inc. | Paraffinic jet and diesel fuels and base oils from vegetable oils via a combination of hydrotreating, paraffin disproportionation and hydroisomerization |
| US10196575B2 (en) | 2013-11-15 | 2019-02-05 | Chevron U.S.A. Inc. | Lubricating base oil production |
| CN105586073B (zh) * | 2014-10-22 | 2018-06-01 | 中国石油化工股份有限公司 | 一种汽油选择性加氢脱硫催化剂预硫化方法 |
| US9938475B2 (en) * | 2014-10-28 | 2018-04-10 | Exxonmobil Research And Engineering Company | Catalyst configuration for increased hydrocracking activity |
| MY193473A (en) * | 2014-12-19 | 2022-10-14 | Shell Int Research | Method for preparing a catalyst |
| US10232357B2 (en) | 2015-12-15 | 2019-03-19 | Uop Llc | Crystalline ammonia transition metal molybdate |
| US10005812B2 (en) | 2015-12-15 | 2018-06-26 | Uop Llc | Transition metal molybdotungsten oxy-hydroxide |
| US10052616B2 (en) | 2015-12-15 | 2018-08-21 | Uop Llc | Crystalline ammonia transition metal molybdotungstate |
| US10400181B2 (en) | 2015-12-15 | 2019-09-03 | Uop Llc | Crystalline bis-ammonia metal molybdate |
| US10449523B2 (en) | 2015-12-15 | 2019-10-22 | Uop Llc | Crystalline bis-ammonia transition metal molybdotungstate |
| US10399063B2 (en) | 2015-12-15 | 2019-09-03 | Uop Llc | Mixed metal oxides |
| US10052614B2 (en) | 2015-12-15 | 2018-08-21 | Uop Llc | Mixed metal oxides |
| US10053637B2 (en) | 2015-12-15 | 2018-08-21 | Uop Llc | Transition metal tungsten oxy-hydroxide |
| US10399065B2 (en) | 2015-12-15 | 2019-09-03 | Uop Llc | Crystalline transition metal tungstate |
| US10322404B2 (en) | 2015-12-15 | 2019-06-18 | Uop Llc | Crystalline transition metal oxy-hydroxide molybdate |
| US10046315B2 (en) | 2015-12-15 | 2018-08-14 | Uop Llc | Crystalline transition metal molybdotungstate |
| US10233398B2 (en) * | 2015-12-15 | 2019-03-19 | Uop Llc | Crystalline transition metal oxy-hydroxide molybdotungstate |
| US10953389B2 (en) | 2016-02-01 | 2021-03-23 | Albemarle Europe Sprl | Nickel containing mixed metal-oxide/carbon bulk hydroprocessing catalysts and their applications |
| US10023813B2 (en) | 2016-06-23 | 2018-07-17 | King Fahd University Of Petroleum And Minerals | Process for selective deep hydrodesulfurization of a hydrocarbon feedstock using an unsupported nanocatalyst made by laser pyrolysis |
| CN107774277B (zh) * | 2016-08-29 | 2020-02-14 | 中国石油化工股份有限公司 | 一种制备加氢处理催化剂的方法 |
| US9919987B1 (en) * | 2016-11-22 | 2018-03-20 | Chevron U.S.A. Inc. | Naphthene ring opening over self-supported multi-metallic catalysts |
| JP2020514455A (ja) | 2016-12-21 | 2020-05-21 | サウジ アラビアン オイル カンパニーSaudi Arabian Oil Company | 水素化分解プロセスのための触媒充填の最適化方法 |
| US20180230389A1 (en) | 2017-02-12 | 2018-08-16 | Magēmā Technology, LLC | Multi-Stage Process and Device for Reducing Environmental Contaminates in Heavy Marine Fuel Oil |
| US11788017B2 (en) | 2017-02-12 | 2023-10-17 | Magëmã Technology LLC | Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil |
| US12281266B2 (en) | 2017-02-12 | 2025-04-22 | Magẽmã Technology LLC | Heavy marine fuel oil composition |
| US12559689B2 (en) | 2017-02-12 | 2026-02-24 | Magēmā Technology LLC | Multi-stage process and device for treatment heavy marine fuel and resultant composition and the removal of detrimental solids |
| US12025435B2 (en) | 2017-02-12 | 2024-07-02 | Magēmã Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil |
| US12071592B2 (en) | 2017-02-12 | 2024-08-27 | Magēmā Technology LLC | Multi-stage process and device utilizing structured catalyst beds and reactive distillation for the production of a low sulfur heavy marine fuel oil |
| US10604709B2 (en) | 2017-02-12 | 2020-03-31 | Magēmā Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials |
| CN110662822A (zh) * | 2017-06-07 | 2020-01-07 | 埃克森美孚研究工程公司 | 从原油生产柴油和基础油 |
| US10882030B2 (en) | 2017-08-25 | 2021-01-05 | Uop Llc | Crystalline transition metal tungstate |
| US10773245B2 (en) | 2017-08-25 | 2020-09-15 | Uop Llc | Crystalline transition metal molybdotungstate |
| US20190126227A1 (en) | 2017-10-30 | 2019-05-02 | Saudi Arabian Oil Company | Catalyst loading method to disperse heat in hydroconversion reactor |
| US20190128845A1 (en) | 2017-11-02 | 2019-05-02 | Ohio State Innovation Foundation | Imms method for petroleum feedstock evaluation |
| FR3074698B1 (fr) * | 2017-12-13 | 2019-12-27 | IFP Energies Nouvelles | Procede d'hydroconversion en slurry de charge hydrocarbonee lourde |
| FR3074699B1 (fr) * | 2017-12-13 | 2019-12-20 | IFP Energies Nouvelles | Procede d'hydroconversion de charge hydrocarbonee lourde en reacteur hybride |
| US10995013B2 (en) | 2017-12-20 | 2021-05-04 | Uop Llc | Mixed transition metal tungstate |
| US11034591B2 (en) | 2017-12-20 | 2021-06-15 | Uop Llc | Highly active quaternary metallic materials using short-chain alkyl quaternary ammonium compounds |
| US10843176B2 (en) | 2017-12-20 | 2020-11-24 | Uop Llc | Highly active quaternary metallic materials using short-chain alkyl quaternary ammonium compounds |
| US11078088B2 (en) | 2017-12-20 | 2021-08-03 | Uop Llc | Highly active multimetallic materials using short-chain alkyl quaternary ammonium compounds |
| US10875013B2 (en) | 2017-12-20 | 2020-12-29 | Uop Llc | Crystalline oxy-hydroxide transition metal molybdotungstate |
| US10822247B2 (en) | 2017-12-20 | 2020-11-03 | Uop Llc | Highly active trimetallic materials using short-chain alkyl quaternary ammonium compounds |
| US11117811B2 (en) | 2017-12-20 | 2021-09-14 | Uop Llc | Highly active quaternary metallic materials using short-chain alkyl quaternary ammonium compounds |
| US11007515B2 (en) | 2017-12-20 | 2021-05-18 | Uop Llc | Highly active trimetallic materials using short-chain alkyl quaternary ammonium compounds |
| CN108390026B (zh) * | 2018-01-22 | 2020-07-14 | 李慧 | 一种笼式正极材料及其制备方法和应用 |
| WO2019152268A1 (en) * | 2018-01-31 | 2019-08-08 | Advanced Refining Technologies Llc | Hydroprocessing catalyst for the reduction of metals and sulfur in heavy feeds |
| JP7011479B2 (ja) * | 2018-01-31 | 2022-01-26 | Eneos株式会社 | 炭化水素油の製造方法 |
| US10737248B2 (en) | 2018-06-26 | 2020-08-11 | Uop Llc | Crystalline transition metal tungstate |
| US10737249B2 (en) | 2018-06-26 | 2020-08-11 | Uop Llc | Crystalline transition metal molybdotungstate |
| US11033883B2 (en) | 2018-06-26 | 2021-06-15 | Uop Llc | Transition metal molybdotungstate material |
| US10682632B2 (en) | 2018-06-26 | 2020-06-16 | Uop Llc | Transition metal tungstate material |
| US10688479B2 (en) | 2018-06-26 | 2020-06-23 | Uop Llc | Crystalline transition metal tungstate |
| FR3083136A1 (fr) * | 2018-06-27 | 2020-01-03 | IFP Energies Nouvelles | Catalyseur a base d'un ester d'acide butenedioique et son utilisation dans un procede d'hydrotraitement et/ou d'hydrocraquage |
| FR3083135A1 (fr) * | 2018-06-27 | 2020-01-03 | IFP Energies Nouvelles | Catalyseur a base d’un ester d’acide pentanedioique ou d’acide hexanedioique et son utilisation dans un procede d’hydrotraitement et/ou d’hydrocraquage |
| US10981151B2 (en) | 2018-06-29 | 2021-04-20 | Uop Llc | Poorly crystalline transition metal molybdotungstate |
| US10737246B2 (en) * | 2018-06-29 | 2020-08-11 | Uop Llc | Poorly crystalline transition metal tungstate |
| US11041128B2 (en) | 2018-08-07 | 2021-06-22 | Chevron U.S.A. Inc. | Catalytic remedy for advanced UCO bleed reduction in recycle hydrocracking operations |
| WO2020033483A1 (en) * | 2018-08-07 | 2020-02-13 | Chevron U.S.A. Inc. | A catalytic remedy for advanced uco bleed reduction in recycle hydrocracking operations |
| CN108993556B (zh) * | 2018-08-09 | 2021-01-19 | 贵州理工学院 | 硅掺杂钨酸锌/氧化锌复合材料、制备方法及其应用 |
| US10933407B2 (en) | 2018-12-13 | 2021-03-02 | Uop Llc | Ammonia-free synthesis for Al or Si based multimetallic materials |
| US11213803B2 (en) | 2018-12-13 | 2022-01-04 | Uop Llc | Ammonia-free synthesis for Al or Si based multimetallic materials |
| US11426711B2 (en) | 2019-05-22 | 2022-08-30 | Uop Llc | Method of making highly active metal oxide and metal sulfide materials |
| KR20220045965A (ko) | 2019-08-12 | 2022-04-13 | 셰브런 유.에스.에이.인크. | 기유 수율 개선을 위한 프로세스 |
| CN112517022B (zh) * | 2019-09-17 | 2023-02-03 | 中国石油化工股份有限公司 | 一种加氢处理催化剂的制备方法 |
| RU2753597C2 (ru) * | 2020-01-24 | 2021-08-18 | Публичное акционерное общество "Нефтяная компания "Роснефть" (ПАО "НК "Роснефть") | Способ гидрооблагораживания вакуумного газойля (варианты) |
| EP3865210A1 (en) * | 2020-02-14 | 2021-08-18 | BASF Corporation | Aluminium-silicon-supported nickel-based catalyst, its precursor with high total intrusion volume, their preparation processes, and process for hydrogenation of petrochemical resins using said catalyst |
| WO2021183155A1 (en) * | 2020-03-13 | 2021-09-16 | Racional Energy And Environment Company | Low-solids flash chemical ionizing pyrolysis |
| CN115605290A (zh) * | 2020-05-04 | 2023-01-13 | 雪佛龙美国公司(Us) | 四金属本体加氢处理催化剂 |
| CN111715295B (zh) * | 2020-07-01 | 2021-02-02 | 北方工业大学 | 一种海绵镍基光催化复合材料的制备方法 |
| US11639475B2 (en) * | 2020-07-29 | 2023-05-02 | Chevron U.S.A. Inc. | Feed flexible hydrocracking operations |
| CN114733577B (zh) * | 2021-01-07 | 2023-10-10 | 中国石油化工股份有限公司 | 一种硫化型加氢催化剂及其制备方法和应用 |
| US11590485B2 (en) * | 2021-01-13 | 2023-02-28 | Saudi Arabian Oil Company | Process for modifying a hydroprocessing catalyst |
| CN116867880A (zh) | 2021-01-26 | 2023-10-10 | 雪佛龙美国公司 | 用于制造光亮油料基础油产品的工艺 |
| JP2024506820A (ja) | 2021-01-26 | 2024-02-15 | シェブロン ユー.エス.エー. インコーポレイテッド | 重質グレード基油製品を製造するプロセス |
| JP7830492B2 (ja) * | 2021-02-16 | 2026-03-16 | シェブロン ユー.エス.エー. インコーポレイテッド | 多金属バルク水素化処理触媒 |
| KR20230148827A (ko) * | 2021-02-22 | 2023-10-25 | 셰브런 유.에스.에이.인크. | 다중-금속성 벌크 수첨가공 촉매 |
| CA3221474C (en) | 2021-06-22 | 2025-06-17 | Chevron U.S.A. Inc. | MULTI-METALLIC BULK HYDROTHERAPY CATALYST |
| US11577235B1 (en) * | 2021-08-13 | 2023-02-14 | Chevron U.S.A. Inc. | Layered catalyst reactor systems and processes for hydrotreatment of hydrocarbon feedstocks |
| KR102673713B1 (ko) * | 2021-12-13 | 2024-06-07 | 재단법인 한국탄소산업진흥원 | 메탄의 직접 분해를 통한 수소 생산용 고효율 촉매 및 그 제조 방법 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007070394A2 (en) * | 2005-12-14 | 2007-06-21 | Advanced Refining Technologies Llc | Method of making hydroprocessing catalyst |
| US7288182B1 (en) * | 1997-07-15 | 2007-10-30 | Exxonmobil Research And Engineering Company | Hydroprocessing using bulk Group VIII/Group VIB catalysts |
Family Cites Families (89)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US288182A (en) * | 1883-11-06 | moeeis | ||
| US1955829A (en) | 1929-08-31 | 1934-04-24 | Standard Ig Co | Conversion of carbonaceous materials into useful hydrocarbon products |
| US3673079A (en) * | 1970-01-21 | 1972-06-27 | Chevron Res | Catalyst manufacture |
| US3709814A (en) * | 1970-03-06 | 1973-01-09 | Chevron Res | Hydrofining-hydrocracking process using palladium-containing catalyst |
| US3795632A (en) | 1971-11-05 | 1974-03-05 | Chevron Res | Hydroconversion catalyst preparation methods |
| US4003851A (en) * | 1973-10-31 | 1977-01-18 | American Cyanamid Company | Stable alumina catalyst support, process therefor, and promoted support |
| US4009096A (en) * | 1976-01-12 | 1977-02-22 | Uop Inc. | Hydroprocessing of hydrocarbons |
| US4226742A (en) | 1978-07-14 | 1980-10-07 | Exxon Research & Engineering Co. | Catalyst for the hydroconversion of heavy hydrocarbons |
| US4430442A (en) | 1982-07-20 | 1984-02-07 | Exxon Research And Engineering Co. | Catalysts from molybdenum polysulfide precursors and their preparation |
| US4542121A (en) * | 1982-07-20 | 1985-09-17 | Exxon Research And Engineering Co. | Catalysts from molybdenum polysulfide precursors, their preparation and use |
| US4540481A (en) * | 1982-07-20 | 1985-09-10 | Exxon Research And Engineering Co. | Catalysts from molybdenum polysulfide precursors, their preparation and use |
| US4826797A (en) | 1982-07-20 | 1989-05-02 | Exxon Research And Engineering Company | Carbon-containing molybdenum and tungsten sulfide catalysts |
| US4508847A (en) | 1982-07-20 | 1985-04-02 | Exxon Research & Engineering Co. | Carbon-containing molybdenum and tungsten sulfide catalysts |
| US4820677A (en) | 1984-04-02 | 1989-04-11 | Jacobson Allan J | Amorphous, iron promoted Mo and W sulfide hydroprocessing catalysts and process for their preparation |
| US4595672A (en) | 1984-04-25 | 1986-06-17 | Exxon Research And Engineering Co. | Method of making self-promoted hydrotreating catalysts |
| US4831002A (en) | 1984-04-25 | 1989-05-16 | Exxon Research And Engineering Company | Cr-promoted hydrotreating catalysts |
| US4721558A (en) * | 1984-09-28 | 1988-01-26 | Exxon Research And Engineering Company | Hydrotreating catalysts comprising a mixture of a sulfide of a promoter metal amorphous sulfide of trivalent chromium and microcrystalline molybdenum or tungsten sulfide |
| US4666878A (en) * | 1984-12-28 | 1987-05-19 | Exxon Research And Engineering Company | Amorphous, iron promoted Mo and W sulfide hydroprocessing catalysts and uses thereof |
| US4579728A (en) * | 1985-04-24 | 1986-04-01 | Shell Oil Company | Wide pore alumina supports |
| US4637870A (en) * | 1985-04-29 | 1987-01-20 | Exxon Research And Engineering Company | Hydrocracking with phosphomolybdic acid and phosphoric acid |
| US4836912A (en) | 1985-09-04 | 1989-06-06 | Exxon Research And Engineering Company | Hydroconversion process using aromatic metal chelate compositions |
| US4719002A (en) * | 1986-04-21 | 1988-01-12 | Exxon Research And Engineering Company | Slurry hydroconversion process |
| US4740295A (en) * | 1986-04-21 | 1988-04-26 | Exxon Research And Engineering Company | Hydroconversion process using a sulfided molybdenum catalyst concentrate |
| US4765882A (en) | 1986-04-30 | 1988-08-23 | Exxon Research And Engineering Company | Hydroconversion process |
| US4976848A (en) * | 1988-10-04 | 1990-12-11 | Chevron Research Company | Hydrodemetalation and hydrodesulfurization using a catalyst of specified macroporosity |
| US4962077A (en) | 1989-07-11 | 1990-10-09 | Exxon Research And Engineering Company | Transition metal tris-dithiolene and related complexes as precursors to active catalysts |
| US5037532A (en) | 1989-09-28 | 1991-08-06 | Exxon Research & Engineering Company | Slurry hydrotreating process |
| US5039392A (en) | 1990-06-04 | 1991-08-13 | Exxon Research And Engineering Company | Hydroconversion process using a sulfided molybdenum catalyst concentrate |
| US5053376A (en) * | 1990-06-04 | 1991-10-01 | Exxon Research & Engineering Company | Method of preparing a sulfided molybdenum catalyst concentrate |
| US5278121A (en) * | 1990-10-01 | 1994-01-11 | Exxon Research & Engineering Company | Multimetallic sulfide catalyst containing noble metals for hydrodenitrogenation |
| US5252199A (en) * | 1990-10-01 | 1993-10-12 | Exxon Research & Engineering Company | Hydrotreating process using novel multimetallic sulfide catalysts |
| JPH04243547A (ja) | 1991-01-22 | 1992-08-31 | Sumitomo Metal Mining Co Ltd | 炭化水素油の水素化処理用触媒を製造する方法 |
| US5122258A (en) | 1991-05-16 | 1992-06-16 | Exxon Research And Engineering Company | Increasing VI of lube oil by hydrotreating using bulk Ni/Mn/Mo or Ni/Cr/Mo sulfide catalysts prepared from ligated metal complexes |
| EP0515084B1 (en) * | 1991-05-24 | 2000-07-05 | Imperial Chemical Industries Plc | Thermal transfer printing ink sheet |
| EP0526988A3 (en) | 1991-07-10 | 1993-03-31 | Texaco Development Corporation | Hydrotreatment process employing a mono-modal catalyst with specified pore size distribution |
| CA2105940C (en) * | 1992-10-05 | 2001-12-25 | Robert M. Koros | Bubble column, tube side slurry process and apparatus |
| US5300212A (en) | 1992-10-22 | 1994-04-05 | Exxon Research & Engineering Co. | Hydroconversion process with slurry hydrotreating |
| US5397456A (en) | 1993-02-19 | 1995-03-14 | Texaco Inc. | Hydroconversion process employing catalyst with specified pore size distribution |
| EP0759809B1 (en) | 1994-05-17 | 1998-07-15 | Exxon Research And Engineering Company | Process and catalyst for aromatics hydrogenation |
| US5648577A (en) * | 1994-07-12 | 1997-07-15 | Exxon Research And Engineering Company | Dispersed metal sulfide catalysts for hydroprocessing (LAW105) |
| US5695632A (en) * | 1995-05-02 | 1997-12-09 | Exxon Research And Engineering Company | Continuous in-situ combination process for upgrading heavy oil |
| US5935421A (en) * | 1995-05-02 | 1999-08-10 | Exxon Research And Engineering Company | Continuous in-situ combination process for upgrading heavy oil |
| DE19533484A1 (de) * | 1995-09-12 | 1997-03-13 | Basf Ag | Monomodale und polymodale Katalysatorträger und Katalysatoren mit engen Porengrößenverteilungen und deren Herstellverfahren |
| US5872073A (en) * | 1995-10-08 | 1999-02-16 | The United States Of America As Represented By The United States Department Of Energy | Reduced ternary molybdenum and tungsten sulfides and hydroprocessing catalysis therewith |
| US6030915A (en) * | 1996-03-11 | 2000-02-29 | Akzo Nobel N.V. | Process for preparing a large pore hydroprocessing catalyst |
| US5900384A (en) | 1996-07-18 | 1999-05-04 | Arco Chemical Technology L.P. | Double metal cyanide catalysts |
| US6620313B1 (en) | 1997-07-15 | 2003-09-16 | Exxonmobil Research And Engineering Company | Hydroconversion process using bulk group VIII/Group VIB catalysts |
| US6156695A (en) * | 1997-07-15 | 2000-12-05 | Exxon Research And Engineering Company | Nickel molybdotungstate hydrotreating catalysts |
| US6712955B1 (en) | 1997-07-15 | 2004-03-30 | Exxonmobil Research And Engineering Company | Slurry hydroprocessing using bulk multimetallic catalysts |
| US6635599B1 (en) | 1997-07-15 | 2003-10-21 | Exxonmobil Research & Engineering Company | Mixed metal catalyst, its preparation by co-precipitation, and its use |
| US6162350A (en) | 1997-07-15 | 2000-12-19 | Exxon Research And Engineering Company | Hydroprocessing using bulk Group VIII/Group VIB catalysts (HEN-9901) |
| US6783663B1 (en) * | 1997-07-15 | 2004-08-31 | Exxonmobil Research And Engineering Company | Hydrotreating using bulk multimetallic catalysts |
| US6758963B1 (en) | 1997-07-15 | 2004-07-06 | Exxonmobil Research And Engineering Company | Hydroprocessing using bulk group VIII/group vib catalysts |
| US7229548B2 (en) * | 1997-07-15 | 2007-06-12 | Exxonmobil Research And Engineering Company | Process for upgrading naphtha |
| US6755963B2 (en) | 1997-07-15 | 2004-06-29 | Exxonmobil Chemical Patents Inc. | Hydrogenation process for hydrocarbon resins |
| US7232515B1 (en) | 1997-07-15 | 2007-06-19 | Exxonmobil Research And Engineering Company | Hydrofining process using bulk group VIII/Group VIB catalysts |
| US5935418A (en) | 1997-08-29 | 1999-08-10 | Exxon Research And Engineering Co. | Slurry hydroprocessing |
| US6562752B2 (en) * | 1998-06-25 | 2003-05-13 | Institut Francais Du Petrole | Metallic sulphide catalysts, processes for synthesising said catalysts and use thereof |
| US5977192A (en) | 1998-11-13 | 1999-11-02 | Exxon Research And Engineering Co. | Small catalyst particle addition to slurry reactor |
| US6534437B2 (en) * | 1999-01-15 | 2003-03-18 | Akzo Nobel N.V. | Process for preparing a mixed metal catalyst composition |
| US6171471B1 (en) | 1999-04-30 | 2001-01-09 | Exxon Research And Engineering Company | Heavy oil upgrading process (LAW813) |
| US6299760B1 (en) | 1999-08-12 | 2001-10-09 | Exxon Research And Engineering Company | Nickel molybodtungstate hydrotreating catalysts (law444) |
| US6461995B1 (en) * | 2000-05-08 | 2002-10-08 | Corning Incorporated | Extruded honeycomb dehydrogenation catalyst and method |
| DE60134140D1 (de) * | 2000-07-12 | 2008-07-03 | Albemarle Netherlands Bv | Verfahren zur herstellung eines ein additiv enthaltenden mischmetallkatalysators |
| WO2002004117A1 (en) | 2000-07-12 | 2002-01-17 | Akzo Nobel N.V. | Process for preparing an additive-based mixed metal catalyst |
| DE10111198A1 (de) * | 2001-03-08 | 2002-09-19 | Basf Ag | Methanolreformierungskatalysator mit verringertem Volumenschwund |
| DE10111197A1 (de) * | 2001-03-08 | 2002-09-19 | Basf Ag | Verfahren zur Herstellung von Katalysatoren mit geringem Volumenschwund |
| US6531516B2 (en) | 2001-03-27 | 2003-03-11 | Exxonmobil Research & Engineering Co. | Integrated bitumen production and gas conversion |
| GB0214383D0 (en) | 2002-06-21 | 2002-07-31 | Isis Innovation | Catalyst |
| FR2850299B1 (fr) * | 2003-01-29 | 2006-12-01 | Inst Francais Du Petrole | Catalyseurs partiellement cokes utilisables dans l'hydrotraitement des coupes contenant des composes soufres et des olefines |
| AR043243A1 (es) * | 2003-02-24 | 2005-07-20 | Shell Int Research | Composicion de catalizador ,su preparacion y uso |
| US20040235657A1 (en) | 2003-05-21 | 2004-11-25 | Fina Technology, Inc. | Freeze dry process for the preparation of a high surface area and high pore volume catalyst |
| US7183005B2 (en) * | 2004-08-20 | 2007-02-27 | Exxonmobil Chemical Patents Inc. | Impact strength improvement of regrind |
| US7591942B2 (en) * | 2004-09-22 | 2009-09-22 | Exxonmobil Research And Engineering Company | Bulk bi-metallic catalysts made from precursors containing an organic agent |
| US7648941B2 (en) | 2004-09-22 | 2010-01-19 | Exxonmobil Research And Engineering Company | Bulk bimetallic catalysts, method of making bulk bimetallic catalysts and hydroprocessing using bulk bimetallic catalysts |
| US7544632B2 (en) | 2004-09-22 | 2009-06-09 | Exxonmobil Research And Engineering Company | Bulk Ni-Mo-W catalysts made from precursors containing an organic agent |
| EP1807198B1 (en) | 2004-11-03 | 2011-02-16 | Shell Internationale Research Maatschappij B.V. | Synthesis of hydrocarbons using titania catalysts |
| EP1827685A1 (en) | 2004-12-23 | 2007-09-05 | Shell Internationale Research Maatschappij B.V. | Method of preparing catalyst support from a waste catalyst |
| BRPI0519581A2 (pt) * | 2004-12-29 | 2009-02-17 | Saudi Arabian Oil Co | catalisadores para hidrocraqueamento de mistura desmetalizada de gasàleo de vÁcuo |
| CA2605505C (en) * | 2005-04-21 | 2015-06-16 | China Petroleum & Chemical Corporation | A hydrogenation catalyst and use thereof |
| US8476184B2 (en) * | 2005-10-26 | 2013-07-02 | Albemarle Corporation | Bulk catalyst composition and a process preparing the bulk catalyst composition |
| WO2007050634A2 (en) * | 2005-10-26 | 2007-05-03 | Exxonmobil Research And Engineering Company | Hydroprocessing using hydrothermally-prepared bulk multimetallic catalysts |
| WO2007050636A2 (en) * | 2005-10-26 | 2007-05-03 | Exxonmobil Research And Engineering Company | Hydroprocessing using bulk bimetallic catalysts |
| JP5060044B2 (ja) * | 2005-12-08 | 2012-10-31 | 日本ケッチェン株式会社 | 炭化水素油の水素化処理触媒およびその製造方法、並びに炭化水素油の水素化処理方法 |
| JP4563954B2 (ja) | 2006-03-27 | 2010-10-20 | 京セラ株式会社 | 携帯電話機、電話番号管理サーバ、電話番号変更システム、電話番号ダウンロード方法、及び電話番号ダウンロードプログラム |
| WO2008016971A2 (en) | 2006-08-03 | 2008-02-07 | Shell Oil Company | A catalyst containing molybdenum and a group viii metal and its use for hydrodesulfrization hydrogen distillate |
| US7951746B2 (en) | 2006-10-11 | 2011-05-31 | Exxonmobil Research And Engineering Company | Bulk group VIII/group VIB metal catalysts and method of preparing same |
| US8206575B2 (en) | 2007-10-31 | 2012-06-26 | Chevron U.S.A. Inc. | Hydroconversion processes employing multi-metallic catalysts and method for making thereof |
| EP2103347A1 (en) | 2008-03-17 | 2009-09-23 | ExxonMobil Research and Engineering Company | Hydrocarbon hydroprocessing using bulk catalyst composition |
-
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- 2008-10-28 US US12/259,435 patent/US8206575B2/en active Active
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7288182B1 (en) * | 1997-07-15 | 2007-10-30 | Exxonmobil Research And Engineering Company | Hydroprocessing using bulk Group VIII/Group VIB catalysts |
| WO2007070394A2 (en) * | 2005-12-14 | 2007-06-21 | Advanced Refining Technologies Llc | Method of making hydroprocessing catalyst |
Non-Patent Citations (1)
| Title |
|---|
| Material Safety Data Sheet - Malic Acid Datasheet [online] Sciencelab com, 2005 [retrieved on 2008 12 23] Retrieved from the internet <URL http://web.archive.org./web/20060723113929/http://www.sciencelab.com/ xMSDS-DL_Malic_acid-9927566 * |
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