EA018466B1 - Криогели из сополимера винилового спирта, сополимеры винилового спирта и способы их получения и продукты из них - Google Patents
Криогели из сополимера винилового спирта, сополимеры винилового спирта и способы их получения и продукты из них Download PDFInfo
- Publication number
- EA018466B1 EA018466B1 EA201100494A EA201100494A EA018466B1 EA 018466 B1 EA018466 B1 EA 018466B1 EA 201100494 A EA201100494 A EA 201100494A EA 201100494 A EA201100494 A EA 201100494A EA 018466 B1 EA018466 B1 EA 018466B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- vinyl alcohol
- cryogel
- copolymer
- vinyl
- vinyl acetate
- Prior art date
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K9/00—Medicinal preparations characterised by special physical form
- A61K9/14—Particulate form, e.g. powders, Processes for size reducing of pure drugs or the resulting products, Pure drug nanoparticles
- A61K9/19—Particulate form, e.g. powders, Processes for size reducing of pure drugs or the resulting products, Pure drug nanoparticles lyophilised, i.e. freeze-dried, solutions or dispersions
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K9/00—Medicinal preparations characterised by special physical form
- A61K9/70—Web, sheet or filament bases ; Films; Fibres of the matrix type containing drug
- A61K9/7007—Drug-containing films, membranes or sheets
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L27/00—Materials for grafts or prostheses or for coating grafts or prostheses
- A61L27/14—Macromolecular materials
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L27/00—Materials for grafts or prostheses or for coating grafts or prostheses
- A61L27/50—Materials characterised by their function or physical properties, e.g. injectable or lubricating compositions, shape-memory materials, surface modified materials
- A61L27/52—Hydrogels or hydrocolloids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- C08F218/08—Vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/12—Hydrolysis
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
- C08J3/075—Macromolecular gels
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/56—Acrylamide; Methacrylamide
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- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Proteomics, Peptides & Aminoacids (AREA)
- Inorganic Chemistry (AREA)
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- Biomedical Technology (AREA)
- Neurosurgery (AREA)
- Medicinal Preparation (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
- Materials For Medical Uses (AREA)
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Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US9697608P | 2008-09-15 | 2008-09-15 | |
| PCT/IB2009/054012 WO2010029517A1 (en) | 2008-09-15 | 2009-09-14 | Vinyl alcohol co-polymer cryogels, vinyl alcohol co-polymers, and methods and products thereof |
Publications (2)
| Publication Number | Publication Date |
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| EA201100494A1 EA201100494A1 (ru) | 2011-10-31 |
| EA018466B1 true EA018466B1 (ru) | 2013-08-30 |
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| EA201100494A EA018466B1 (ru) | 2008-09-15 | 2009-09-14 | Криогели из сополимера винилового спирта, сополимеры винилового спирта и способы их получения и продукты из них |
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| EP (1) | EP2331587A1 (https=) |
| JP (1) | JP5694167B2 (https=) |
| KR (1) | KR20110069093A (https=) |
| CN (1) | CN102149735A (https=) |
| AU (1) | AU2009290442A1 (https=) |
| BR (1) | BRPI0918673A2 (https=) |
| CA (1) | CA2736833A1 (https=) |
| EA (1) | EA018466B1 (https=) |
| IL (1) | IL211383A0 (https=) |
| MX (1) | MX2011002746A (https=) |
| NZ (1) | NZ591708A (https=) |
| WO (1) | WO2010029517A1 (https=) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120160254A1 (en) * | 2009-03-16 | 2012-06-28 | Protista Biotechnology Ab | Cryotropic hydrogels and their use as filters |
| EP2440321B1 (en) | 2009-06-11 | 2017-11-22 | Case Western Reserve University | Low density hydrophobic material and method of making the same |
| US8608991B2 (en) | 2009-06-11 | 2013-12-17 | Case Western Reserve University | Porous material having controlled voids and method of making the same |
| EP2701745B1 (en) * | 2011-04-28 | 2018-07-11 | President and Fellows of Harvard College | Injectable preformed macroscopic 3-dimensional scaffolds for minimally invasive administration |
| JP5705056B2 (ja) * | 2011-07-28 | 2015-04-22 | 日本合成化学工業株式会社 | ポリビニルアルコール系重合体粒子の製造方法 |
| WO2014022749A1 (en) * | 2012-08-02 | 2014-02-06 | President And Fellows Of Harvard College | Porous electrolytic polymer cryogels for enhanced electrical collapsibility |
| RU2543895C2 (ru) * | 2013-05-17 | 2015-03-10 | Общество С Ограниченной Ответственностью "Научно-Производственный Центр "Амфион" | Гидрогелевый материал на основе сшиваемого поливинилового спирта |
| US10939677B2 (en) * | 2013-06-12 | 2021-03-09 | Nanyang Technological University | Antibacterial cryogel and porous hydrogel, their preparation method, and their use for disinfecting water |
| CN105859945B (zh) * | 2016-03-24 | 2018-06-15 | 合众(佛山)化工有限公司 | 一种改性聚乙烯醇共聚物交联型陶瓷坯体增强剂的制备方法 |
| RU2729025C1 (ru) * | 2019-07-19 | 2020-08-03 | Федеральное государственное бюджетное учреждение "Национальный медицинский исследовательский центр травматологии и ортопедии имени Н.Н. Приорова" Министерства здравоохранения Российской Федерации (ФГБУ "НМИЦ ТО им. Н.Н. Приорова" Минздрава России) | Способ хирургического лечения гнойно-воспалительных процессов костных и мягкотканых структур опорно-двигательной системы пациента с использованием мягких спейсеров, импрегнированных антибактериальными средствами |
| CN112825981B (zh) * | 2020-12-31 | 2023-05-09 | 内江师范学院 | 芦荟皮饲料用功能添加剂、制备方法及应用 |
| CN114014969B (zh) * | 2021-11-15 | 2023-08-11 | 上海华峰新材料研发科技有限公司 | 一种水溶性聚合物及其制备方法和应用 |
| CN114426681B (zh) * | 2021-12-24 | 2023-11-10 | 东华大学 | 一种稠杂环类还原物-聚丙烯酰胺粘附水凝胶的制备方法 |
| WO2025154722A1 (en) * | 2024-01-16 | 2025-07-24 | Kuraray Co., Ltd. | Polyvinyl alcohol copolymer and particulate water-soluble diverting agent formed therefrom |
| CN119979127A (zh) * | 2025-02-26 | 2025-05-13 | 上海第二工业大学 | 一种冷链运输用高焓值相变凝胶材料及其制备方法 |
| CN121554813A (zh) * | 2026-01-22 | 2026-02-24 | 浙江省肿瘤医院 | 一种用于术后腹腔组织积液引流的高强可变形多孔水凝胶 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0058497B1 (en) * | 1981-02-05 | 1985-08-28 | Nippon Oil Co. Ltd. | Process for preparing a hydrogel |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB835651A (en) | 1957-03-15 | 1960-05-25 | Shawinigan Chem Ltd | Stable vinyl acetate-acrylamide copolymer emulsions and water-resistant films therefrom |
| JPS5227455A (en) * | 1975-07-24 | 1977-03-01 | Sumitomo Chem Co Ltd | Process for preparing a high polymer material having water absorption properties |
| JPS57130543A (en) * | 1981-02-05 | 1982-08-13 | Nippon Oil Co Ltd | Preparation of gel |
| US4326980A (en) | 1981-02-23 | 1982-04-27 | Betz Laboratories, Inc. | Acrylic copolymer composition inhibits scale formation and disperses oil in aqueous systems |
| US5981826A (en) * | 1997-05-05 | 1999-11-09 | Georgia Tech Research Corporation | Poly(vinyl alcohol) cryogel |
| JP4132467B2 (ja) | 1999-09-14 | 2008-08-13 | 株式会社クラレ | ビニルアルコール系重合体の製法 |
| US20030153708A1 (en) | 2002-01-11 | 2003-08-14 | Caneba Gerald Tablada | Free radical retrograde precipitation copolymers and process for making same |
| CN100415821C (zh) * | 2003-04-15 | 2008-09-03 | 英诺格尔股份公司 | 聚乙烯醇凝胶 |
| RU2252945C1 (ru) | 2003-10-30 | 2005-05-27 | Институт элементоорганических соединений им. А.Н. Несмеянова РАН (ИНЭОС РАН) | Полимерная композиция для получения криогеля поливинилового спирта |
| CN1320931C (zh) * | 2004-05-14 | 2007-06-13 | 中国科学院长春应用化学研究所 | 含药物、壳聚糖的聚乙烯醇水凝胶敷料及其制备方法 |
| KR101429774B1 (ko) * | 2005-05-09 | 2014-10-02 | 바이오스피어 메디칼 에스.에이. | 마이크로스피어 및 비이온성 조영제를 사용하는 조성물 및방법 |
| CA2641582A1 (en) | 2006-02-09 | 2007-08-16 | Gerard T. Caneba | Multifunctional multipolymeric surfactants for oil and bitumen recovery and other applications |
-
2009
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- 2009-09-14 US US12/998,077 patent/US8975309B2/en not_active Expired - Fee Related
- 2009-09-14 EA EA201100494A patent/EA018466B1/ru not_active IP Right Cessation
- 2009-09-14 JP JP2011526620A patent/JP5694167B2/ja not_active Expired - Fee Related
- 2009-09-14 KR KR1020117008637A patent/KR20110069093A/ko not_active Withdrawn
- 2009-09-14 CA CA2736833A patent/CA2736833A1/en not_active Abandoned
- 2009-09-14 MX MX2011002746A patent/MX2011002746A/es unknown
- 2009-09-14 AU AU2009290442A patent/AU2009290442A1/en not_active Abandoned
- 2009-09-14 EP EP09787192A patent/EP2331587A1/en not_active Withdrawn
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- 2009-09-14 NZ NZ591708A patent/NZ591708A/xx not_active IP Right Cessation
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2011
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0058497B1 (en) * | 1981-02-05 | 1985-08-28 | Nippon Oil Co. Ltd. | Process for preparing a hydrogel |
Non-Patent Citations (3)
| Title |
|---|
| BARBANI ET AL.: "Bioartif icial materials based on blends of dextran and polyvinyl alcohol-co-acrylic acid", EUROPEAN POLYMER JOURNAL, PERGAMON PRESS LTD. OXFORD, GB, vol. 41, no. 12, 1 December 2005 (2005-12-01), pages 3004-3010, XP005105737, ISSN: 0014-3057, paragraph [02.2], abstract * |
| BARBANI N., TRICOLI F., CRISTALLINI С., BERTONI F., FERRI F., GIUSTI P.: "Hydrogels based on poly(vinly alcohol-co-acrylic acid) as an innovative system for controlled drug delivery", JOURNAL OF APPLIED BIOMATERIALS & BIOMECHANICS, vol. 2, 2004, page 192, XP002554229, cited in the application, the whole document * |
| MA R.Y. ET AL.: "Synthesis and properties of physically crossl inked poly (vinyl alcohol) hydrogels", JOURNAL OF CHINA UNIVERSITY OF MINING AND TECHNOLOGY, vol. 18, no. 2, 1 June 2008 (2008-06-01), pages 271-274, XP022942449, ISSN: 1006-1266 [retrieved on 2008-06-01], paragraph [02.1], abstract * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102149735A (zh) | 2011-08-10 |
| KR20110069093A (ko) | 2011-06-22 |
| EA201100494A1 (ru) | 2011-10-31 |
| IL211383A0 (en) | 2011-04-28 |
| MX2011002746A (es) | 2011-05-30 |
| NZ591708A (en) | 2013-07-26 |
| WO2010029517A1 (en) | 2010-03-18 |
| US20110230567A1 (en) | 2011-09-22 |
| AU2009290442A1 (en) | 2010-03-18 |
| US8975309B2 (en) | 2015-03-10 |
| CA2736833A1 (en) | 2010-03-18 |
| BRPI0918673A2 (pt) | 2015-12-01 |
| EP2331587A1 (en) | 2011-06-15 |
| JP5694167B2 (ja) | 2015-04-01 |
| JP2012503036A (ja) | 2012-02-02 |
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