EA016209B1 - Способ извлечения диоксида углерода из газового потока - Google Patents
Способ извлечения диоксида углерода из газового потока Download PDFInfo
- Publication number
- EA016209B1 EA016209B1 EA200970638A EA200970638A EA016209B1 EA 016209 B1 EA016209 B1 EA 016209B1 EA 200970638 A EA200970638 A EA 200970638A EA 200970638 A EA200970638 A EA 200970638A EA 016209 B1 EA016209 B1 EA 016209B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- absorbent
- stream
- amine
- gas
- carbon dioxide
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 56
- 230000008569 process Effects 0.000 title claims abstract description 22
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title description 198
- 229910002092 carbon dioxide Inorganic materials 0.000 title description 99
- 239000001569 carbon dioxide Substances 0.000 title description 62
- 238000011084 recovery Methods 0.000 title description 4
- 239000002250 absorbent Substances 0.000 claims abstract description 104
- 230000002745 absorbent Effects 0.000 claims abstract description 104
- 150000001412 amines Chemical class 0.000 claims abstract description 57
- 239000007789 gas Substances 0.000 claims description 110
- 238000011069 regeneration method Methods 0.000 claims description 27
- 230000008929 regeneration Effects 0.000 claims description 26
- 150000003335 secondary amines Chemical class 0.000 claims description 23
- 150000003141 primary amines Chemical group 0.000 claims description 22
- 125000003277 amino group Chemical group 0.000 claims description 19
- 150000003512 tertiary amines Chemical group 0.000 claims description 14
- 229920000768 polyamine Polymers 0.000 claims description 10
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 9
- KJAMZCVTJDTESW-UHFFFAOYSA-N tiracizine Chemical compound C1CC2=CC=CC=C2N(C(=O)CN(C)C)C2=CC(NC(=O)OCC)=CC=C21 KJAMZCVTJDTESW-UHFFFAOYSA-N 0.000 claims description 9
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 8
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- 125000000524 functional group Chemical group 0.000 claims description 7
- 238000011068 loading method Methods 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 125000001302 tertiary amino group Chemical group 0.000 claims description 7
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 claims description 6
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- WFCSWCVEJLETKA-UHFFFAOYSA-N 2-piperazin-1-ylethanol Chemical compound OCCN1CCNCC1 WFCSWCVEJLETKA-UHFFFAOYSA-N 0.000 claims description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 2
- 125000005189 alkyl hydroxy group Chemical group 0.000 claims description 2
- 150000001728 carbonyl compounds Chemical class 0.000 claims description 2
- 238000004821 distillation Methods 0.000 claims description 2
- 238000001179 sorption measurement Methods 0.000 claims description 2
- AIRVQKRIUOSQNR-UHFFFAOYSA-L O=[S+2]=O.[O-]S([O-])=O Chemical class O=[S+2]=O.[O-]S([O-])=O AIRVQKRIUOSQNR-UHFFFAOYSA-L 0.000 claims 1
- 150000003863 ammonium salts Chemical class 0.000 claims 1
- 238000001256 steam distillation Methods 0.000 claims 1
- 239000002253 acid Substances 0.000 abstract description 3
- 238000010521 absorption reaction Methods 0.000 description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 17
- 239000002904 solvent Substances 0.000 description 17
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 13
- 239000000243 solution Substances 0.000 description 12
- 239000007788 liquid Substances 0.000 description 10
- 238000010438 heat treatment Methods 0.000 description 8
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 7
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 5
- 239000006096 absorbing agent Substances 0.000 description 5
- 239000012190 activator Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 4
- -1 amine salt Chemical class 0.000 description 4
- 150000004985 diamines Chemical class 0.000 description 4
- 230000007246 mechanism Effects 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 239000002803 fossil fuel Substances 0.000 description 3
- 238000006703 hydration reaction Methods 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- 229920002873 Polyethylenimine Polymers 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000003546 flue gas Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- AUJLDZJNMXNESO-UHFFFAOYSA-N 3-ethylhex-3-ene Chemical group CCC=C(CC)CC AUJLDZJNMXNESO-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- MMOXZBCLCQITDF-UHFFFAOYSA-N N,N-diethyl-m-toluamide Chemical compound CCN(CC)C(=O)C1=CC=CC(C)=C1 MMOXZBCLCQITDF-UHFFFAOYSA-N 0.000 description 1
- 241000009298 Trigla lyra Species 0.000 description 1
- XZAHJRZBUWYCBM-UHFFFAOYSA-N [1-(aminomethyl)cyclohexyl]methanamine Chemical compound NCC1(CN)CCCCC1 XZAHJRZBUWYCBM-UHFFFAOYSA-N 0.000 description 1
- 238000010669 acid-base reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- BVCZEBOGSOYJJT-UHFFFAOYSA-N ammonium carbamate Chemical group [NH4+].NC([O-])=O BVCZEBOGSOYJJT-UHFFFAOYSA-N 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 229960001673 diethyltoluamide Drugs 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- OHMBHFSEKCCCBW-UHFFFAOYSA-N hexane-2,5-diol Chemical compound CC(O)CCC(C)O OHMBHFSEKCCCBW-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000013020 steam cleaning Methods 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical class S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1475—Removing carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/204—Amines
- B01D2252/2041—Diamines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/204—Amines
- B01D2252/20415—Tri- or polyamines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/204—Amines
- B01D2252/20436—Cyclic amines
- B01D2252/20447—Cyclic amines containing a piperazine-ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/204—Amines
- B01D2252/20478—Alkanolamines
- B01D2252/20484—Alkanolamines with one hydroxyl group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/204—Amines
- B01D2252/20478—Alkanolamines
- B01D2252/20489—Alkanolamines with two or more hydroxyl groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/60—Additives
- B01D2252/604—Stabilisers or agents inhibiting degradation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/302—Sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Gas Separation By Absorption (AREA)
- Treating Waste Gases (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/616,992 US7601315B2 (en) | 2006-12-28 | 2006-12-28 | Process for the recovery of carbon dioxide from a gas stream |
| PCT/CA2007/002341 WO2008080221A1 (en) | 2006-12-28 | 2007-12-14 | Process for the recovery of carbon dioxide from a gas stream |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA200970638A1 EA200970638A1 (ru) | 2009-12-30 |
| EA016209B1 true EA016209B1 (ru) | 2012-03-30 |
Family
ID=39584258
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA200970638A EA016209B1 (ru) | 2006-12-28 | 2007-12-14 | Способ извлечения диоксида углерода из газового потока |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7601315B2 (enExample) |
| EP (1) | EP2097156A4 (enExample) |
| JP (1) | JP5484067B2 (enExample) |
| CN (1) | CN101657247B (enExample) |
| AU (1) | AU2007339756B2 (enExample) |
| CA (1) | CA2673781C (enExample) |
| EA (1) | EA016209B1 (enExample) |
| NO (1) | NO20092701L (enExample) |
| WO (1) | WO2008080221A1 (enExample) |
Families Citing this family (67)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8414853B2 (en) * | 2008-03-21 | 2013-04-09 | Alstom Technology Ltd | System and method for enhanced removal of CO2 from a mixed gas stream via use of a catalyst |
| US8343445B2 (en) * | 2008-03-21 | 2013-01-01 | Alstom Technology Ltd | System and method for enhanced removal of CO2 from a mixed gas stream |
| AU2009230879B2 (en) * | 2008-04-01 | 2013-12-19 | Commonwealth Scientific And Industrial Research Organisation | Improved alkanolamines for CO2 removal from gas streams |
| MX2011005814A (es) * | 2008-12-08 | 2011-07-13 | Huntsman Petrochemical Llc | Presencia disminuida de contaminantes derivados de amina en - y/o degradacion de soluciones de solvente de amina. |
| NO332812B1 (no) | 2009-03-13 | 2013-01-21 | Aker Clean Carbon As | Amin utslippskontroll |
| CA2673711A1 (en) * | 2009-07-23 | 2011-01-23 | Cansolv Technologies Inc. | Carbon dioxide and hydrogen sulfide absorbents and process for their use |
| CA2769772C (en) | 2009-08-04 | 2014-05-06 | Co2 Solution Inc. | Formulation and process for co2 capture using carbonates and biocatalysts |
| US8309047B2 (en) | 2009-09-15 | 2012-11-13 | Alstom Technology Ltd | Method and system for removal of carbon dioxide from a process gas |
| US8784761B2 (en) * | 2009-11-20 | 2014-07-22 | Alstom Technology Ltd | Single absorber vessel to capture CO2 |
| US8647413B2 (en) * | 2009-10-30 | 2014-02-11 | General Electric Company | Spray process for the recovery of CO2 from a gas stream and a related apparatus |
| FR2953735B1 (fr) * | 2009-12-16 | 2013-03-29 | Inst Francais Du Petrole | Procede d'elimination de composes acides d'un effluent gazeux avec une solution absorbante a base de diamines i,ii/iii. |
| CN101766947B (zh) * | 2010-03-11 | 2012-09-26 | 南京信息工程大学 | 一种用于膜接触器捕集co2气体的复合吸收剂 |
| CN101785954A (zh) * | 2010-03-11 | 2010-07-28 | 南京信息工程大学 | 一种膜吸收co2气体的复合溶液 |
| US8795618B2 (en) | 2010-03-26 | 2014-08-05 | Babcock & Wilcox Power Generation Group, Inc. | Chemical compounds for the removal of carbon dioxide from gases |
| CN101804326A (zh) * | 2010-04-01 | 2010-08-18 | 南京信息工程大学 | 用于膜接触器捕集co2气体的高效吸收剂 |
| FR2959675B1 (fr) * | 2010-05-06 | 2015-07-17 | Inst Francais Du Petrole | Solution absorbante a base de n,n,n',n'-tetraethyldiethylenetriamine et procede d'elimination de composes acides d'un effluent gazeux |
| US8702071B2 (en) * | 2010-06-09 | 2014-04-22 | Chevron U.S.A. Inc. | Liquid distributor for a rotating packed bed |
| US8262787B2 (en) * | 2010-06-09 | 2012-09-11 | Uop Llc | Configuration of contacting zones in vapor liquid contacting apparatuses |
| US8197778B2 (en) * | 2010-07-08 | 2012-06-12 | Air Products And Chemicals, Inc. | Handling of acids from compressed oxyfuel-derived CO2 |
| US9919259B2 (en) | 2010-07-09 | 2018-03-20 | Carbon Capture Scientific, Llc | Gas pressurized separation column and process to generate a high pressure product gas |
| US8425655B2 (en) | 2010-07-09 | 2013-04-23 | Carbon Capture Scientific, Llc | Gas pressurized separation column and process to generate a high pressure product gas |
| CN103221114A (zh) | 2010-09-02 | 2013-07-24 | 加州大学评议会 | 从气流中俘获二氧化碳和/或二氧化硫的方法和系统 |
| RS60589B1 (sr) * | 2010-10-29 | 2020-08-31 | Saipem Spa | Procesi desorpcije co2 poboljšani enzimom |
| WO2012062724A2 (de) * | 2010-11-10 | 2012-05-18 | Siemens Aktiengesellschaft | Aufbereitung eines aminbasierten, durch den eintrag von schwefeloxiden verunreinigten lösungsmittels |
| EP2667958B1 (en) * | 2011-01-24 | 2019-09-18 | Electrosep Technologies Inc. | Method for removing heat stable base salts from a contaminated basic solution |
| US20120235087A1 (en) * | 2011-03-18 | 2012-09-20 | Dow Global Technologies Llc | Method for the removal of heat stable amine salts from an amine absorbent |
| EP2691163B1 (de) | 2011-03-31 | 2015-05-13 | Basf Se | Rückhaltung von aminen bei der entfernung saurer gase mittels amin-absorptionsmitteln |
| US8529857B2 (en) | 2011-03-31 | 2013-09-10 | Basf Se | Retention of amines in the removal of acid gases by means of amine absorption media |
| CN102151477B (zh) * | 2011-04-07 | 2013-09-04 | 上海华畅环保设备发展有限公司 | 烟道气二氧化碳捕集系统复合胺溶液旋流净化方法与装置 |
| DE102011050329A1 (de) * | 2011-05-13 | 2012-11-15 | Hitachi Power Europe Gmbh | Verfahren und Vorrichtung zur Abscheidung von CO2 aus einem Rauchgasstrom |
| CA2868895C (en) * | 2012-03-29 | 2018-08-14 | Htc Purenergy Inc. | System and process for reclaiming single and mixed amine solvents |
| JP5868795B2 (ja) * | 2012-06-25 | 2016-02-24 | 株式会社東芝 | 酸性ガス吸収剤、酸性ガス除去方法および酸性ガス除去装置 |
| US9272242B2 (en) * | 2012-07-30 | 2016-03-01 | Exxonmobil Research And Engineering Company | High cyclic capacity amines for high efficiency CO2 scrubbing processes |
| EP2892633B1 (de) | 2012-09-05 | 2016-07-27 | Basf Se | Verfahren zur abtrennung von sauergasen aus einem wasserhaltigen fluidstrom |
| CN102794095B (zh) * | 2012-09-12 | 2014-11-05 | 湖南大学 | 三(2-氨乙基)胺作为二氧化碳吸收剂方面的应用 |
| US8501130B1 (en) * | 2012-09-24 | 2013-08-06 | Mitsubishi Heavy Industries, Ltd. | Carbon dioxide recovery system and method |
| FR2996464B1 (fr) * | 2012-10-05 | 2015-10-16 | IFP Energies Nouvelles | Procede d'absorption selective du sulfure d'hydrogene d'un effluent gazeux comprenant du dioxyde de carbone par une solution absorbante a base d'amines comprenant un agent viscosifiant |
| DE102012111185A1 (de) * | 2012-11-20 | 2014-05-22 | Thyssenkrupp Uhde Gmbh | Apparat zur Gaswäsche |
| US20140178278A1 (en) * | 2012-12-21 | 2014-06-26 | Exxonmobil Research And Engineering Company | Co2 capture via amine-co2 product phase separation |
| WO2014099241A2 (en) * | 2012-12-21 | 2014-06-26 | Exxonmobil Research And Engineering Company | Amine promotion for co2 capture |
| US8660672B1 (en) | 2012-12-28 | 2014-02-25 | The Invention Science Fund I Llc | Systems and methods for managing emissions from an engine of a vehicle |
| US9468883B2 (en) | 2013-03-29 | 2016-10-18 | The University Of Kentucky Research Foundation | Solvent and method for removal of an acid gas from a fluid stream |
| US9409125B2 (en) | 2013-03-29 | 2016-08-09 | The University Of Kentucky Research Foundation | Method of increasing mass transfer rate of acid gas scrubbing solvents |
| US9266102B2 (en) | 2013-03-29 | 2016-02-23 | The University Of Kentucky Research Foundation | Catalysts and methods of increasing mass transfer rate of acid gas scrubbing solvents |
| JP6147339B2 (ja) * | 2013-05-28 | 2017-06-14 | 関西電力株式会社 | Co2回収装置及びco2回収方法 |
| JP6070851B2 (ja) | 2013-09-17 | 2017-02-01 | 株式会社Ihi | 排ガスの処理システム及び処理方法 |
| WO2016068698A1 (en) | 2014-10-27 | 2016-05-06 | Carbonoro B.V. | Process and apparatus for separating entrained amines from a gas stream |
| EP3212309A1 (en) | 2014-10-27 | 2017-09-06 | CarbonOro B.V. | Process and apparatus for separating entrained amines from a gas stream |
| US9764274B2 (en) | 2014-12-11 | 2017-09-19 | General Electric Company | System and method for treatment of a flue gas |
| WO2017003711A1 (en) * | 2015-06-30 | 2017-01-05 | Uop Llc | Heat exchangers for low temperature carbon dioxide separation from natural gas |
| CN116764689A (zh) * | 2015-08-20 | 2023-09-19 | 埃克-泰克股份有限公司 | 一种从离子交换树脂中汽提氨基甲酸酯的方法 |
| AU2016355919B2 (en) * | 2015-11-16 | 2021-09-23 | Kc8 Capture Technologies Ltd | A process and contactor vessel |
| JP6507089B2 (ja) * | 2015-12-14 | 2019-04-24 | 株式会社東芝 | 二酸化炭素回収システム |
| US20170354980A1 (en) | 2016-06-14 | 2017-12-14 | Pacific Air Filtration Holdings, LLC | Collecting electrode |
| US10882053B2 (en) | 2016-06-14 | 2021-01-05 | Agentis Air Llc | Electrostatic air filter |
| US10828646B2 (en) | 2016-07-18 | 2020-11-10 | Agentis Air Llc | Electrostatic air filter |
| CA3041192A1 (en) * | 2016-11-01 | 2018-05-11 | Cansolv Technologies Inc | Process for producing a purified gas stream |
| PL420589A1 (pl) * | 2017-02-21 | 2018-08-27 | Ciech R&D Spółka Z Ograniczoną Odpowiedzialnością | Sposób odzyskiwania ditlenku węgla do wzbogacania strumieni gazowych stosowanych w wytwarzaniu węglanu sodu i wodorowęglanu sodu metodą Solvaya |
| JP6963393B2 (ja) * | 2017-02-23 | 2021-11-10 | 川崎重工業株式会社 | 二酸化炭素分離回収システム |
| CA3056375A1 (en) | 2017-04-12 | 2018-10-18 | Anemos Company Ltd. | Apparatus and method for recovering carbon dioxide in combustion exhaust gas |
| KR102032417B1 (ko) * | 2017-12-20 | 2019-10-16 | 재단법인 포항산업과학연구원 | 다단 분리막을 이용한 제철 부생가스로부터의 고농도 유효가스의 분리 방법 및 장치 |
| US10875034B2 (en) | 2018-12-13 | 2020-12-29 | Agentis Air Llc | Electrostatic precipitator |
| US10792673B2 (en) | 2018-12-13 | 2020-10-06 | Agentis Air Llc | Electrostatic air cleaner |
| CN111603895A (zh) * | 2020-05-29 | 2020-09-01 | 中国华电科工集团有限公司 | 一种添加低共熔溶剂的co2吸收液及其制备方法和应用 |
| JP7388567B2 (ja) * | 2020-08-31 | 2023-11-29 | 株式会社Ihi | 二酸化炭素回収システム |
| US20240307820A1 (en) * | 2023-03-16 | 2024-09-19 | Uop Llc | Solvent-based co2 capture process incorporating overhead vapor compression |
| US12172125B1 (en) | 2023-07-28 | 2024-12-24 | Susteon Inc. | High performance CO2 capture solvent compositions, and CO2 capture systems and processes utilizing same |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002009849A2 (en) * | 2000-07-27 | 2002-02-07 | Continental Engineering B.V. | Method and installation for the recovery of pure co2 from flue gas |
| WO2002013948A2 (en) * | 2000-08-17 | 2002-02-21 | Hamilton Sundstrand Corporation | Sorbent, system and method for absorbing carbon dioxide (co2) |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3851041A (en) * | 1966-02-01 | 1974-11-26 | A Eickmeyer | Method for removing acid gases from gaseous mixtures |
| AU506199B2 (en) | 1975-06-26 | 1979-12-20 | Exxon Research And Engineering Company | Absorbtion of co2 from gaseous feeds |
| US4217237A (en) | 1975-06-26 | 1980-08-12 | Exxon Research & Engineering Co. | Process for removing carbon dioxide containing acidic gases from gaseous mixtures using a basic salt activated with a hindered amine |
| US4096085A (en) * | 1976-10-29 | 1978-06-20 | The Dow Chemical Company | Gas scrubbing system |
| DE2815447B1 (de) * | 1978-04-10 | 1979-08-16 | Linde Ag | Verfahren zum Auswaschen von sauren Gasen aus einem Gasgemisch |
| US4624838A (en) | 1985-04-29 | 1986-11-25 | Exxon Research And Engineering Company | Process for removing acidic gases from gaseous mixtures using aqueous scrubbing solutions containing heterocyclic nitrogen compounds |
| US5277885A (en) | 1988-05-24 | 1994-01-11 | Elf Aquitaine Production | Liquid absorbing acidic gases and use thereof in deacidification of gases |
| KR0123107B1 (ko) | 1992-02-27 | 1997-11-12 | 아끼야마 요시히사 | 연소배기가스중의 2산화탄소의 제거방법 |
| JPH05237341A (ja) * | 1992-02-27 | 1993-09-17 | Kansai Electric Power Co Inc:The | 燃焼排ガス中の二酸化炭素を除去する方法 |
| JPH0731830A (ja) * | 1993-03-30 | 1995-02-03 | Kyowa Hakko Kogyo Co Ltd | トリアミン化合物を有効成分とする二酸化炭素吸収剤 |
| DE69428057T2 (de) | 1993-10-06 | 2002-04-18 | Mitsubishi Jukogyo K.K., Tokio/Tokyo | Verfahren zur Abscheidung von Kohlendioxid aus Verbrennungsabgasen |
| US5618506A (en) | 1994-10-06 | 1997-04-08 | The Kansai Electric Power Co., Inc. | Process for removing carbon dioxide from gases |
| US6337059B1 (en) | 1999-05-03 | 2002-01-08 | Union Carbide Chemicals & Plastics Technology Corporation | Absorbent compositions for the removal of acid gases from gas streams |
| JP4523691B2 (ja) * | 2000-03-10 | 2010-08-11 | 三菱重工業株式会社 | 脱炭酸設備の吸収液の制御方法及び装置 |
| US6755892B2 (en) | 2000-08-17 | 2004-06-29 | Hamilton Sundstrand | Carbon dioxide scrubber for fuel and gas emissions |
| US6582498B1 (en) | 2001-05-04 | 2003-06-24 | Battelle Memorial Institute | Method of separating carbon dioxide from a gas mixture using a fluid dynamic instability |
| DE10135370A1 (de) | 2001-07-20 | 2003-01-30 | Basf Ag | Verfahren zur Entfernung saurer Gase aus einem Gasstrom |
| ATE551112T1 (de) * | 2003-04-04 | 2012-04-15 | Univ Texas | Polyamin-/alkalisalzmischungen zur entfernung von kohlendioxid aus gasströmen |
| US7056482B2 (en) | 2003-06-12 | 2006-06-06 | Cansolv Technologies Inc. | Method for recovery of CO2 from gas streams |
| MX276488B (es) | 2003-07-22 | 2010-06-09 | Dow Global Technologies Inc | Regeneracion de fluidos de tratamiento que contienen gas acido. |
| DE102004011429A1 (de) | 2004-03-09 | 2005-09-29 | Basf Ag | Verfahren zum Entfernen von Kohlendioxid aus Gasströmen mit niedrigen Kohlendioxid-Partialdrücken |
| JP4690659B2 (ja) | 2004-03-15 | 2011-06-01 | 三菱重工業株式会社 | Co2回収装置 |
| FR2877858B1 (fr) * | 2004-11-12 | 2007-01-12 | Inst Francais Du Petrole | Procede de desacidification d'un gaz avec une solution absorbante a regeneration fractionnee |
| JP2006150298A (ja) | 2004-11-30 | 2006-06-15 | Mitsubishi Heavy Ind Ltd | 吸収液、吸収液を用いたco2又はh2s除去装置及び方法 |
| JP5039276B2 (ja) | 2004-12-13 | 2012-10-03 | 三菱重工業株式会社 | 吸収液、吸収液を用いたガス中のco2又はh2s除去装置及び方法 |
| JP4699039B2 (ja) * | 2005-02-10 | 2011-06-08 | 関西電力株式会社 | 排気ガスの処理方法及び処理装置 |
| EP1703491B1 (en) | 2005-03-18 | 2012-02-22 | Sony Deutschland GmbH | Method for classifying audio data |
| EP1872846B1 (en) | 2005-04-04 | 2013-07-24 | Mitsubishi Heavy Industries, Ltd. | Absorbing solution and method for absorbing co2 or h2s or both |
| US7384616B2 (en) * | 2005-06-20 | 2008-06-10 | Cansolv Technologies Inc. | Waste gas treatment process including removal of mercury |
| JP2007245011A (ja) * | 2006-03-16 | 2007-09-27 | Sumika Chemtex Co Ltd | 空気浄化装置 |
-
2006
- 2006-12-28 US US11/616,992 patent/US7601315B2/en active Active
-
2007
- 2007-12-14 EP EP07855621A patent/EP2097156A4/en not_active Withdrawn
- 2007-12-14 CN CN2007800508816A patent/CN101657247B/zh active Active
- 2007-12-14 CA CA2673781A patent/CA2673781C/en active Active
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- 2007-12-14 JP JP2009543312A patent/JP5484067B2/ja active Active
- 2007-12-14 AU AU2007339756A patent/AU2007339756B2/en active Active
-
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- 2009-07-17 NO NO20092701A patent/NO20092701L/no not_active Application Discontinuation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002009849A2 (en) * | 2000-07-27 | 2002-02-07 | Continental Engineering B.V. | Method and installation for the recovery of pure co2 from flue gas |
| WO2002013948A2 (en) * | 2000-08-17 | 2002-02-21 | Hamilton Sundstrand Corporation | Sorbent, system and method for absorbing carbon dioxide (co2) |
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| CN101657247A (zh) | 2010-02-24 |
| CN101657247B (zh) | 2013-06-26 |
| WO2008080221A1 (en) | 2008-07-10 |
| US7601315B2 (en) | 2009-10-13 |
| CA2673781C (en) | 2013-03-19 |
| JP5484067B2 (ja) | 2014-05-07 |
| AU2007339756A1 (en) | 2008-07-10 |
| EA200970638A1 (ru) | 2009-12-30 |
| EP2097156A4 (en) | 2011-11-09 |
| EP2097156A1 (en) | 2009-09-09 |
| CA2673781A1 (en) | 2008-07-10 |
| NO20092701L (no) | 2009-07-17 |
| US20080159937A1 (en) | 2008-07-03 |
| AU2007339756B2 (en) | 2012-01-19 |
| JP2010514549A (ja) | 2010-05-06 |
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